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Geology topics

L. Mandon

Publications and source records attributed to L. Mandon.

8 recordsLinked to original sources

From hydrated silica to quartz: Potential hydrothermal precipitates found in Jezero crater, Mars

On Earth, silica-rich phases from opal to quartz are important indicators and tracers of geological processes. Hydrated silica, such as opal, is a particularly good matrix for the preservation of molecular and macroscopic biosignatures. Cherts, a type of silica-dominated rocks, provide a unique archive of ancient terrestrial life while quartz is the emblematic mineral of the Earth's continental crust. On Mars, hydrated silica has been detected in several locations based on remote sensing and rover-based studies. In the present article we report on the detection of cobbles made of hydrated silica (opal or chalcedony), as well as well-crystallized quartz. These detections were made with the SuperCam instrument onboard Perseverance (Mars 2020 mission), using a combination of LIBS, infrared and Raman spectroscopy. Quartz-dominated stones are detected unambiguously for the first time on the Martian surface, and based on grain size and crystallinity are proposed to be of hydrothermal origin. Although these rocks were all found as float, we propose that these detections are part of a common hydrothermal system, and represent different depths / temperatures of precipitation. This attests that hydrothermal processes were active in and around Jezero crater, possibly triggered by the Jezero crater-forming impact. These silica-rich rocks, in particular opaline silica, are very promising targets for sampling and return to Earth given their high biosignature preservation potential.

Earth and Planetary Science Letters↗

Ultramafic float rocks at Jezero crater (Mars): Excavation of lower crustal rocks or mantle peridotites by impact cratering?

Based on observation and data from meteorites and in situ scientific missions, experiments as well as models, the Martian mantle is assumed to share some compositional and mineralogical affinity with the terrestrial mantle. However, there might be subtle differences like the Martian mantle being more ferroan. Yet, we do not have any direct analysis of a Martian mantle rock to confirm this assumption. NASA’s Perseverance rover found olivine-rich boulder-sized float rocks on the upper Jezero fan (Mars). These boulders have an ultramafic composition and their mineralogy is dominantly composed of Fo 73±3 olivine with high-Mg orthopyroxene, Cr-rich Ti-Fe oxides and minor plagioclase and high-Ca pyroxene. Microtextural and petrological analysis reveals that these minerals crystallized at equilibrium. In addition, these boulders are different from all the bedrocks analyzed by Perseverance along its traverse which are crustal igneous rocks and sediments. Comparing our data to Martian meteorites and available Mars bulk silicate models (BSM), we discuss that these boulders could represent primitive melts and/or lower crustal material, and we specifically hypothesize that they could be mantle peridotites. We propose that these putative mantle rocks could have been excavated by the succession of impacts from the shallow mantle or lower crust in the Isidis region where Jezero crater is located. These olivine-rich boulders could thereby constitute the first direct analysis of a Martian mantle rock.

Earth and Planetary Science Letters↗

Intense alteration on early Mars revealed by high-aluminum rocks at Jezero Crater

The NASA Perseverance rover discovered light-toned float rocks scattered across the surface of Jezero crater that are particularly rich in alumina ( ~ 35 wt% Al 2 O 3 ) and depleted in other major elements (except silica). These unique float rocks have heterogeneous mineralogy ranging from kaolinite/halloysite-bearing in hydrated samples, to spinel-bearing in dehydrated samples also containing a dehydrated Al-rich phase. Here we describe SuperCam and Mastcam-Z observations of the float rocks, including the first in situ identification of kaolinite or halloysite on another planet, and dehydrated phases including spinel and apparent partially dehydroxylated kaolinite. The presence of spinel in these samples is likely detrital in origin, surviving kaolinitization, pointing to an ultramafic origin. However, the association of low hydration with increased Al 2 O 3 abundances suggests heating-induced dehydration which could have occurred during the lithification or impact excavation of these rocks. Given the orbital context of kaolinite-bearing megabreccia in the Jezero crater rim, we propose an origin for these rocks involving intense aqueous alteration of the parent material, followed by dehydration/lithification potentially through impact processes, and dispersion into Jezero crater through flood or impact-related processes.

Communications Earth & Environment↗

Likely ferromagnetic minerals identified by the Perseverance rover and implications for future paleomagnetic analyses of returned Martian samples

Although Mars today does not have a core dynamo, magnetizations in the Martian crust and in meteorites suggest a magnetic field was present prior to 3.7 billion years (Ga) ago. However, the lack of ancient, oriented Martian bedrock samples available on Earth has prevented accurate estimates of the dynamo's intensity, lifetime, and direction. Constraining the nature and lifetime of the dynamo are vital to understanding the evolution of the Martian interior and the potential habitability of the planet. The Perseverance rover, which is exploring Jezero crater, is providing an unprecedented opportunity to address this gap by acquiring absolutely oriented bedrock samples with estimated ages from ∼2.3 to >4.1 Ga. As a first step in establishing whether these samples could contain records of Martian paleomagnetism, it is important to determine their ferromagnetic mineralogy, the grain sizes of the phases, and the forms of any natural remanent magnetization. Here, we synthesize data from various Perseverance instruments to achieve those goals and discuss the implications for future laboratory paleomagnetic analyses. Using the rover's instrument payload, we find that cored samples likely contain iron oxides enriched in Cr and Ti. The relative proportions of Fe, Ti, and Cr indicate that the phases may be titanomagnetite or Fe-Ti-Cr spinels that are ferromagnetic at room temperature, but we cannot rule out the presence of non-ferromagnetic ulvöspinel, ilmenite, and chromite due to signal mixing. Importantly, the inferred abundance of iron oxides in the samples suggests that even <1 mm-sized samples will be easily measurable by present-day magnetometers.

Journal of Geophysical Research: Planets↗

An examination of soil crusts on the floor of Jezero crater, Mars

Martian soils are critically important for understanding the history of Mars, past potentially habitable environments, returned samples, and future human exploration. This paper examines soil crusts on the floor of Jezero crater encountered during initial phases of the Mars 2020 mission. Soil surface crusts have been observed on Mars at other locations, starting with the two Viking Lander missions. Rover observations show that soil crusts are also common across the floor of Jezero crater, revealed in 45 of 101 locations where rover wheels disturbed the soil surface, 2 out of 7 helicopter flights that crossed the wheel tracks, and 4 of 8 abrasion/drilling sites. Most soils measured by the SuperCam laser-induced breakdown spectroscopy (LIBS) instrument show high hydrogen content at the surface, and fine-grained soils also show a visible/near infrared (VISIR) 1.9 µm H 2 O absorption feature. The Planetary Instrument for X-ray Lithochemistry (PIXL) and SuperCam observations suggest the presence of salts at the surface of rocks and soils. The correlation of S and Cl contents with H contents in SuperCam LIBS measurements suggests that the salts present are likely hydrated. On the “Naltsos” target, magnesium and sulfur are correlated in PIXL measurements, and Mg is tightly correlated with H at the SuperCam points, suggesting hydrated Mg-sulfates. Mars Environmental Dynamics Analyzer (MEDA) observations indicate possible frost events and potential changes in the hydration of Mg-sulfate salts. Jezero crater soil crusts may therefore form by salts that are hydrated by changes in relative humidity and frost events, cementing the soil surface together.

Journal of Geophysical Research: Planets↗

In situ recording of Mars soundscape

Prior to the Perseverance rover landing, the acoustic environment of Mars was unknown. Models predicted that: (i) atmospheric turbulence changes at centimeter scales or smaller at the point where molecular viscosity converts kinetic energy into heat 1 , (ii) the speed of sound varies at the surface with frequency 2,3 , and (iii) high frequency waves are strongly attenuated with distance in CO 2 2–4 . However, theoretical models were uncertain because of a lack of experimental data at low pressure, and the difficulty to characterize turbulence or attenuation in a closed environment. Here using Perseverance microphone recordings, we present the first characterization of Mars’ acoustic environment and pressure fluctuations in the audible range and beyond, from 20 Hz to 50 kHz. We find that atmospheric sounds extend measurements of pressure variations down to 1,000 times smaller scales than ever observed before, revealing a dissipative regime extending over 5 orders of magnitude in energy. Using point sources of sound (Ingenuity rotorcraft, laser-induced sparks), we highlight two distinct values for the speed of sound that are ~10 m/s apart below and above 240 Hz, a unique characteristic of low-pressure CO 2 -dominated atmosphere. We also provide the acoustic attenuation with distance above 2 kHz, allowing us to elucidate the large contribution of the CO 2 vibrational relaxation in the audible range. These results establish a ground truth for modelling of acoustic processes, which is critical for studies in atmospheres like Mars and Venus ones.

Nature↗

Aqueously altered igneous rocks sampled on the floor of Jezero crater, Mars

The Perseverance rover landed in Jezero crater, Mars, to investigate ancient lake and river deposits. We report observations of the crater floor, below the crater’s sedimentary delta, finding the floor consists of igneous rocks altered by water. The lowest exposed unit, informally named Séítah, is a coarsely crystalline olivine-rich rock, which accumulated at the base of a magma body. Fe-Mg carbonates along grain boundaries indicate reactions with CO 2 -rich water, under water-poor conditions. Overlying Séítah is a unit informally named Máaz, which we interpret as lava flows or the chemical complement to Séítah in a layered igneous body. Voids in these rocks contain sulfates and perchlorates, likely introduced by later near-surface brine evaporation. Core samples of these rocks were stored aboard Perseverance for potential return to Earth.

Science↗