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L. L. Marking

Publications and source records attributed to L. L. Marking.

At least 55 records · Page 3Linked to original sources
USGS1976

Removal of toxic chemicals from water with activated carbon

Activated carbon was effective in removing fish toxicants and anesthetics from water solutions. Its capacity to adsorb 3‐trifluoromethyl‐4‐nitrophenol (TFM), antimycin, Noxfish (R) (5% rotenone), Dibrom (R) , juglone, MS‐222, and benzocaine ranged from 0.1 to 64 mg per gram of carbon. The adsorptive capacity (end point considered as a significant discharge) of activated carbon for removal of TFM was determined at column depths of 15, 30, and 60 cm; temperatures of 7, 12, 17, and 22 C; pHˈs of 6.5, 7.5, 8.5, and 9.5; and flow rates of 50, 78, 100, 200, and 940 ml/min. Adsorptive capacity increased when the contact time was increased by reducing the flow rate or increasing the column depth. The adsorptive capacity was not significantly influenced by temperature but was substantially higher at pH 6.5 than at the other pHˈs tested. A practical and efficient filter for purifying chemically treated water was developed.

Transactions of the American Fisheries Society↗
USGS1975

Effects of pH on toxicity of antimycin to fish

Detoxification of antimycin at pH 9.5 was caused by two factors. The piscicide was biologically unavailable at the high pH, and this unavailability was reversed by decreasing the pH of water solutions. Simultaneously antimycin detoxified with time, and the resulting loss in toxicity was irreversible. The toxicity of antimycin was related to the amount of un-ionized molecules; however, the dissociation curve resulting from the published pKa of 5.1 does not agree with the implied dissociation when based on toxicity. Toxicity of antimycin decreased gradually from pH 6.5 to 8.5 and abruptly from 8.5 to 9.5 with carp ( Cyprinus carpio ), green sunfish ( Lepomis cyanellus ), and bluegill ( Lepomis macrochirus ). As previously suggested, water hardness had little or no effect on toxicity.

Journal of the Fisheries Research Board of Canada↗
USGS1975

Long-term effects of 4-aminopyridine exposure to birds and fish

The avian frightening agent, 4-aminopyridine (4AP), was tested on five avian and two fish species to assess the effects of long-term 4AP exposure to nontarget vertebrates. Adult bobwhites ( Colinus virginianus ), mourning doves ( Zenaida macroura ), and ring-necked pheasants ( Phasianus colchicus ) were fed diets containing 3 percent 4AP-treated cracked corn diluted with various ratios of untreated corn for 7 to 35 days. Minimum dilution ratios that produced more than 50 percent mortality were 1:29 for bobwhites and 1:99 for doves. Mortality caused by 4AP could not be determined for pheasants because of their inability to subsist only on corn during the test periods. LCso's were determined for doves (316 ppm) and coturnix quail ( Coturnix coturnix ) (479 ppm) fed exclusively on uniformly treated laboratory rations for 28 to 40 days. Starlings ( Sturnus vulgaris ) treated by gavage daily for 25 days with 1.78 mg/kg 4AP showed no intoxication symptoms. Mortality in all avian species appeared to be the result of acute poisoning, and no evidence of cumulative toxicity was noted in species fed uniformly-treated rations. In 96-hour static tests, channel catfish ( Ictalurus punctatus ) and bluegill (Lepomis macrochirus) showed increasing sensitivity to 4AP with time in test waters ranging from very soft to very hard and from 12 to 22 C. The 96-hour LC 50 's for both species ranged from 2.43 to 7.56 mg/liter (ppm). Toxicity appeared to decrease with increasing water temperatures but was generally unaffected by water hardness. On the basis of the data presented, and the currently registered application rate for 4AP in agricultural crops (0.34 g/ha), long-term hazards to nontarget wildlife were judged to be minimal.

Colorado↗
USGS1973

Toxicity of TFM (lampricide) to six early stages of rainbow trout (Salmo gairdneri)

The lampricide TFM (3-trifluoromethyl-4-nitrophenol) was tested against the following life stages of rainbow trout ( Salmo gairdneri ): green eggs, eyed eggs, sac fry, swim-up fry, fry, and fingerlings in four water hardnesses (12, 44, 170, and 320 mg/liter as CaCO 3 ). The eyed-egg stage was one of the most resistant stages tested, and the sac-fry stage was one of the least resistant. Increased water hardness decreases toxicity to all stages. The LC50’s range from 0.532 mg/liter to 40.0 mg/liter depending upon life stage, water hardness, and duration of exposure. The margin of safety for coexisting species exposed to TFM ranges from 3.2 to 4.1 in natural waters. The margin of safety for early life stages of rainbow trout and larval lamprey under controlled laboratory conditions ranges from 4.2 to 12.2. Therefore, all six early life stages of rainbow trout are safe in minimum lampricidal concentrations of TFM.

Journal of the Fisheries Research Board of Canada↗