Geology topics

Kevin B. Jones

Publications and source records attributed to Kevin B. Jones.

11 recordsLinked to original sources

USGS2019

Preliminary GIS representation of deep coal areas for carbon dioxide storage in the contiguous United States and Alaska

This report and its accompanying geospatial data outline many areas of coal in the United States beneath more than 3,000 ft of overburden. Based on depth, these areas may be targets for injection and storage of supercritical carbon dioxide. Additional areas where coal exists beneath more than 1,000 ft of overburden are also outlined; these may be targets for geologic storage of carbon dioxide in conjunction with enhanced coalbed methane production. These areas of deep coal were compiled as polygons into a shapefile for use in a geographic information system (GIS). The coal-bearing formation names, coal basin or field names, geographic provinces, coal ranks, coal geologic ages, and estimated individual coalbed thicknesses (if known) of the coal-bearing formations were included. An additional point shapefile, coal_co2_projects.shp, contains the locations of pilot projects for carbon dioxide injection into coalbeds. This report is not a comprehensive study of deep coal in the United States. Some areas of deep coal were excluded based on geologic or data-quality criteria, while others may be absent from the literature and still others may have been overlooked by the authors.

Open-File Report↗

USGS2018

Subseasonal variations in marine reservoir age from pre-bomb Donax obesulus and Protothaca asperrima shell carbonate

Two Donax obesulus and two Protothaca asperrima shells collected prior to the nuclear testing of the 1950's were micromilled at sub-seasonal resolution to yield new reservoir effect (ΔR) estimates for the coast of Peru. Shells from northern (4°40′S to 8°14′S) and central (13°52′S) Peru produced ΔR values of 123 ± 50 and 110 ± 49 years respectively. We found such values statistically indistinguishable from each other while reporting intra-annual ΔR variability along shells ontogeny in agreement with previously published regional ΔR values. This similarity suggests radiocarbon dating of short-lived (<1.5 years) mollusks shells is a useful tool for comparing marine radiocarbon signals. Additionally, our analysis of ΔR and δ 18 O changes along shells' ontogeny found a tenuous relationship between them. We are not the first one to report these phenomena in Peruvian upwelling , but we are the first to suggest that fast Lagrangian water mixing as a mechanism behind it.

Chemical Geology↗

USGS2017

Radiocarbon chronometry of Site QJ-280, Quebrada Jaguay, a terminal Pleistocene to early Holocene fishing site in southern Peru

Excavations in 1970, 1996, and 1999 at Site QJ-280, Quebrada Jaguay, in southern Peru, yielded enough dateable terrestrial plant material to establish an extensive radiocarbon chronology for the site. QJ-280 is one of oldest well-dated fishing sites in the Americas: it was occupied from the terminal Pleistocene to the mid-Holocene (about 13,000–8,300 calibrated years BP) based on 42 terrestrial radiocarbon dates, encompassing the Jaguay and Machas Phases of the local archaeological sequence. In addition to the terrestrial dates, radiocarbon measurements on valves of two marine surf clam ( Mesodesma donacium ) individuals from a single, well-dated mid-Holocene Manos Phase archaeological context have provided insight into marine upwelling conditions during the occupation of Quebrada Jaguay. The marine reservoir age varied between 130 and 730 14 C years during the brief lives of the two clams (up to 5 years each), and varied by up to 530 14 C years within an individual valve, suggesting strong and variable deep marine upwelling; conditions broadly similar to those that exist in coastal Peru today. These rapid variations in marine radiocarbon age suggest that marine radiocarbon dates from environments with variable upwelling could be skewed by up to hundreds of years.

Journal of Island and Coastal Archaeology↗

USGS2017

Leaching of trace elements from Pittsburgh coal mill rejects compared with coal combustion products from a coal-fired power plant in Ohio, USA

We investigated the leachability of elements from mill rejects from the high-sulfur, bituminous Upper Pennsylvanian Pittsburgh coal, using the synthetic groundwater leaching procedure (SGLP), long-term leaching (LTL), and the U.S. Environmental Protection Agency's (EPA's) toxicity characteristic leaching procedure (TCLP), and compared their leaching behavior with that of three coal combustion products (CCPs)—bottom ash, economizer fly ash , and fly ash—from the same coal. None of the environmentally hazardous Resource Conservation and Recovery Act of 1976 (RCRA) metals analyzed in the leachates from the mill rejects or the CCPs exceeded U.S. EPA toxicity characteristics (As, Ba, Cd, Cr, Hg, Pb, and Se). Most trace elements leached the least from mill rejects and bottom ash and leached the most from fly ash. The elements Ca, Co, Mg, Mn, and Sr, however, were more concentrated in mill reject leachates than CCP leachates. Most trace elements increased in concentration with increasing SGLP and LTL leaching duration, but As and V decreased in concentration with time in mill reject leachates, suggesting sorption or precipitation of these elements was occurring.

Ohio↗

USGS2016

Centuries of marine radiocarbon reservoir age variation within archaeological Mesodesma Donacium shells from Southern Peru

Mollusk shells provide brief (<5 yr per shell) records of past marine conditions, including marine radiocarbon reservoir age ( R ) and upwelling. We report 21 14 C ages and R calculations on small (∼2 mg) samples from 2 Mesodesma donacium (surf clam) shells. These shells were excavated from a semi-subterranean house floor stratum 14 C dated to 7625±35 BP at site QJ-280, Quebrada Jaguay, southern Peru. The ranges in marine 14 C ages (and thus R ) from the 2 shells are 530 and 170 14 C yr; R from individual aragonite samples spans 130±60 to 730±170 1 4 C yr. This intrashell 14 C variability suggests that 14 C dating of small (time-slice much less than 1 yr) marine samples from a variable- R (i.e. variable-upwelling) environment may introduce centuries of chronometric uncertainty.

Radiocarbon↗

USGS2015

Carbon dioxide storage in unconventional reservoirs workshop: summary of recommendations

“Unconventional reservoirs” for carbon dioxide (CO 2 ) storage—that is, geologic reservoirs in which changes to the rock trap CO 2 and therefore contribute to CO 2 storage—including coal, shale, basalt, and ultramafic rocks, were the focus of a U.S. Geological Survey (USGS) workshop held March 28 and 29, 2012, at the National Conservation Training Center in Shepherdstown, West Virginia. The goals of the workshop were to determine whether a detailed assessment of CO 2 storage capacity in unconventional reservoirs is warranted, and if so, to build a set of recommendations that could be used to develop a methodology to assess this storage capacity. Such an assessment would address only the technically available resource, independent of economic or policy factors. At the end of the workshop, participants agreed that sufficient knowledge exists to allow an assessment of the potential CO 2 storage resource in coals, organic-rich shales, and basalts. More work remains to be done before the storage resource in ultramafic rocks can be meaningfully assessed. In order to assess the CO 2 storage capacity of coals and organic-rich shales, the workshop participants agreed that the following several factors are key: sorption mechanisms and capacity, pore fluid composition and saturation, thermal maturity, formation thickness, and whether hydrocarbons have been extracted from the formation previously (for example, by enhanced gas or oil recovery). In order to assess the CO 2 storage capacity of basalts, the workshop participants agreed that key factors include temperature, pressure, pH, water chemistry, mineral chemistry, organic content, mineralogy, porosity, permeability, relative permeabilities, and CO 2 phase. The storage capacity for all unconventional reservoirs may be modeled using a volumetric equation starting with the extent of the rock unit and adjusted using these key factors and reaction terms. The ideas that were developed during this workshop can be used by USGS scientists to develop a methodology to assess the CO 2 storage resource in unconventional reservoirs. This methodology could then be released for public comment and peer review. After completing this development process, the USGS could then use the methodology to assess the CO 2 storage resource in unconventional reservoirs.

Open-File Report↗

USGS2013

Marine radiocarbon reservoir age variation in Donax obesulus shells from northern Peru: Late Holocene evidence for extended El Niño

For at least 6 m.y., El Niño events have posed the greatest environmental risk on the Peruvian coast. A better understanding of El Niño is essential for predicting future risk and growth in this tropical desert. To achieve this we analyzed archaeological and modern pre-bomb shells from the surf clam Donax for the radiocarbon reservoir effect (ΔR) to characterize late Holocene coastal upwelling conditions in northern Peru (8°14′S). Mean ΔR values from these shells suggest that modern upwelling conditions in this region were likely established between A.D. 539 and A.D. 1578. Our radiocarbon data suggest that upwelling conditions ca. A.D. 539 were less intense than those in modern times. The observed coastal water enrichment in 14 C may be consequence of frequent strong El Niño events or extended El Niño–like conditions. These ΔR-inferred marine conditions are in agreement with proposed extended El Niño activity in proxy and archaeological records of ca. A.D. 475–530. Extended El Niño conditions have been linked to political destabilization, societal transformation, and collapse of the Moche civilization in northern Peru. A return to such conditions would have significant impacts on the dense population of this region today and in the near future.

Geology↗

USGS2013

Partitioning of selected trace elements in coal combustion products from two coal-burning power plants in the United States

Samples of feed coal (FC), bottom ash (BA), economizer fly ash (EFA), and fly ash (FA) were collected from power plants in the Central Appalachian basin and Colorado Plateau to determine the partitioning of As, Cr, Hg, Pb, and Se in coal combustion products (CCPs). The Appalachian plant burns a high-sulfur (about 3.9 wt.%) bituminous coal from the Upper Pennsylvanian Pittsburgh coal bed and operates with electrostatic precipitators (ESPs), with flue gas temperatures of about 163 °C in the ESPs. At this plant, As, Pb, Hg, and Se have the greatest median concentrations in FA samples, compared to BA and EFA. A mass balance (not including the FGD process) suggests that the following percentages of trace elements are captured in FA: As (48%), Cr (58%), Pb (54%), Se (20%), and Hg (2%). The relatively high temperatures of the flue gas in the ESPs and low amounts of unburned C in FA (0.5% loss-on-ignition for FA) may have led to the low amount of Hg captured in FA. The Colorado Plateau plant burns a blend of three low-S (about 0.74 wt.%) bituminous coals from the Upper Cretaceous Fruitland Formation and operates with fabric filters (FFs). Flue gas temperatures in the baghouses are about 104 °C. The elements As, Cr, Pb, Hg, and Se have the greatest median concentrations in the fine-grained fly ash product (FAP) produced by cyclone separators, compared to the other CCPs at this plant. The median concentration of Hg in FA (0.0983 ppm) at the Colorado Plateau plant is significantly higher than that for the Appalachian plant (0.0315 ppm); this higher concentration is related to the efficiency of FFs in Hg capture, the relatively low temperatures of flue gas in the baghouses (particularly in downstream compartments), and the amount of unburned C in FA (0.29% loss-on-ignition for FA).

International Journal of Coal Geology↗

USGS2012

Leaching of elements from bottom ash, economizer fly ash, and fly ash from two coal-fired power plants

To assess how elements leach from several types of coal combustion products (CCPs) and to better understand possible risks from CCP use or disposal, coal ashes were sampled from two bituminous-coal-fired power plants. One plant located in Ohio burns high-sulfur (about 3.9%) Upper Pennsylvanian Pittsburgh coal from the Monongahela Group of the Central Appalachian Basin; the other in New Mexico burns low-sulfur (about 0.76%) Upper Cretaceous Fruitland Formation coal from the San Juan Basin, Colorado Plateau. The sampled CCPs from the Ohio plant were bottom ash (BA), economizer fly ash (EFA), and fly ash (FA); the sampled CCPs from the New Mexico plant were BA, mixed FA/EFA, FA, and cyclone-separated coarse and fine fractions of a FA/EFA and FA blend. Subsamples of each ash were leached using the long-term leaching (60-day duration) component of the synthetic groundwater leaching procedure (SGLP) or the toxicity characteristic leaching procedure (TCLP, 18-hour duration). These ashes were all alkaline. Leachate concentrations and leachabilities of the elements from the CCPs were similar between corresponding CCP types (BA, EFA, and FA) from each plant. The leachabilities of most elements were lowest in BA (least leachable) and increased from EFA to FA (most leachable). Ca and Sr were leached more from EFA than from either BA or FA. Leachability of most elements also increased as FA particle size decreased, possibly due in part to increasing specific surface areas. Several oxyanion-forming elements (As, Mo, Se, U, and V) leached more under SGLP than under TCLP; the opposite was true for most other elements analyzed.

International Journal of Coal Geology↗

USGS2012

USGS workshop on CO2 sequestration in unconventional reservoirs

The U.S. Geological Survey (USGS) held a workshop titled “CO2 Sequestration in Unconventional Reservoirs” at the National Conservation Training Center, Shepherdstown, West Virginia, USA, on March 28th – 29th, 2012. Currently the USGS National Geologic Carbon Sequestration Assessment estimates potential subsurface storage volumes only in the existing pore spaces of sandstones, limestones, and dolostones (Brennan and others, 2010). Other lithologies prevalent in geologic strata, such as coal, organicrich shale, basalt, and ultramafic rocks, are not included in the current assessment. These lithologies can store CO 2 by trapping mechanisms (sorption or mineralogic reaction) other than the buoyant and residual trapping mechanisms currently being assessed (Brennan and others, 2010). Thirty-six participants representing academia, industry, and Federal and State government agencies took part in this workshop to discuss CO 2 storage in unconventional reservoirs.

Greenhouse News↗

USGS1998

Large impact features on Europa: Results of the Galileo Nominal Mission

The Galileo Orbiter examined several impact features on Europa at considerably better resolution than was possible from Voyager. The new data allow us to describe the morphology and infer the geology of the largest impact features on Europa, which are probes into the crust. We observe two basic types of large impact features: (1) “classic” impact craters that grossly resemble well-preserved lunar craters of similar size but are more topographically subdued (e.g., Pwyll) and (2) very flat circular features that lack the basic topographic structures of impact craters such as raised rims, a central depression, or central peaks, and which largely owe their identification as impact features to the field of secondary craters radially sprayed about them (e.g., Callanish). Our interpretation is that the classic craters (all <30 km diameter) formed entirely within a solid target at least 5 to 10 km thick that exhibited brittle behavior on time scales of the impact events. Some of the classic craters have a more subdued topography than fresh craters of similar size on other icy bodies such as Ganymede and Callisto, probably due to the enhanced viscous relaxation produced by a steeper thermal gradient on Europa. Pedestal ejecta facies on Europa (and Ganymede) may be produced by the relief-flattening movement of plastically deforming but otherwise solid ice that was warm at the time of emplacement. Callanish and Tyre do not appear to be larger and even more viscously relaxed versions of the classic craters; rather they display totally different morphologies such as distinctive textures and a series of large concentric structural rings cutting impact-feature-related materials. Impact simulations suggest that the distinctive morphologies would not be produced by impact into a solid ice target, but may be explained by impact into an ice layer ∼10 to 15 km thick overlying a low-viscosity material such as water. The very wide (near antipodal) separation of Callanish and Tyre imply that ∼10–15 km may have been the global average thickness of the rigid crust of Europa when these impacts occurred. The absence of detectable craters superposed on the interior deposits of Callanish suggests that it is geologically young (<10 8 years). Hence, it seems likely that our preliminary conclusions about the subsurface structure of Europa apply to the current day.

Icarus↗