Geology topics

Kevin Alexander Ryan

Publications and source records attributed to Kevin Alexander Ryan.

6 recordsLinked to original sources

USGS2026

Water table rise sustains carbon release from soils in wetland-dominated landscapes: An intact soil core study

Wetland-dominated landscapes influence carbon cycling through their potential to act as both carbon sinks and sources. Wetlands in low-relief landscapes have dynamic terrestrial-aquatic interfaces that change seasonally with variable surface water and groundwater levels. However, few studies have directly quantified dissolved organic matter (DOM) release and greenhouse gas (CO 2 , CH 4 ) fluxes from wetland soils along terrestrial-aquatic interfaces as they are seasonally re-saturated by groundwater. To estimate groundwater-mediated soil DOM and gas fluxes, we performed laboratory simulations of vertical groundwater rise on intact soil cores collected from four Delmarva bay wetlands located in the Mid-Atlantic United States. At each wetland, one core was collected from within the wetland basin and the other from the transitional zone at the basin edge. Cores were re-saturated with groundwater over 15 days and then kept fully saturated for an additional 25 days. Source groundwater, soil porewater, and exfiltrated surface water samples were collected and analyzed for pH, ORP, DOM concentration, and DOM optical indices. In both the wetland and transition zone cores, porewater DOM concentrations increased over the wet up and were sustained during prolonged saturation. Optical indices shifted from recently produced, microbial-like signatures towards aromatic, terrestrial-like signatures. Fluxes of CO 2 decreased as the duration of soil saturation increased and soil cores switched from CH 4 sinks to sources upon full soil core saturation. Results indicate that groundwater rise sustains carbon mobilization from soils in wetland-dominated landscapes, emphasizing the need to understand how climate-driven changes to groundwater dynamics may affect carbon fluxes along terrestrial-aquatic interfaces.

Delaware, Maryland↗

USGS2026

Evaluating drivers of environmental change in a lake sediment core: Insights from spectroscopic metrics of water-extractable organic matter and stable carbon isotopes

Freshwater lakes play a critical role in the global carbon cycle by storing and transforming organic matter (OM) from both terrestrial and aquatic sources. Small lakes in northern temperate regions, despite their limited surface area, disproportionately influence regional carbon budgets. Buried sediments integrate OM inputs over time and archive ecosystem responses to natural and anthropogenic disturbances. However, the direction and magnitude of recent environmental changes on sediment carbon (C) dynamics remain poorly understood. A 23-cm core was collected from a small temperate lake in northeastern USA to evaluate sediment OM content and composition over timescales relevant to historical land-use change, damming, and recovery from acid deposition. Patterns in OM burial and source contributions were revealed via elemental and isotopic analyses of bulk OM and ultraviolet-visible spectrophotometry of water-extractable organic matter (WEOM). The optical metrics expanded observations of likely OM sources beyond the information gained from bulk carbon metrics (total carbon, δ 13 C). The aromaticity of WEOM increased downcore, which is consistent with a shift from increased terrestrial inputs during early logging and damming activity (pre ∼1920) to more microbial-derived OM in recent surficial sediments. Future applications of WEOM optical properties as complements to traditional geochemical metrics can enhance interpretations of lake ecosystem responses recorded in lake sediments to environmental perturbations in temperate lakes.

New York↗

USGS2024

Riverine dissolved organic matter transformations increase with watershed area, water residence time, and Damköhler numbers in nested watersheds

Quantifying the relative influence of factors and processes controlling riverine ecosystem function is essential to predicting future conditions under global change. Dissolved organic matter (DOM) is a fundamental component of riverine ecosystems that fuels microbial food webs, influences nutrient and light availability, and represents a significant carbon flux globally. The heterogeneous nature of DOM molecular composition and its propensity for interaction (i.e., functional diversity) can characterize riverine ecosystem function across spatiotemporal scales. To investigate fundamental drivers of DOM diversity, we collected seasonal water samples from 42 nested locations within five watersheds spanning multiple watershed sizes (~5 to 30,000 km2) across the United States. Patterns in DOM molecular richness, aromaticity, relative abundance of N-containing formulas, and putative biochemical transformations derived from high-resolution mass spectrometry were assessed across gradients of explanatory variables associated with watershed characteristics (e.g., watershed area, water residence time, land cover). We found that putative biochemical transformations were more strongly related to explanatory variables across watersheds than common bulk DOM parameters and that watershed area, surface water residence time and derived Damköhler numbers representing DOM reactivity timescales were strong predictors of DOM diversity. The data also indicate that catchment-specific land cover factors can significantly influence DOM diversity in diverging directions. Overall, the results highlight the importance of considering water residence time and land cover when interpreting longitudinal patterns in DOM chemistry and the continued challenge of identifying generalizable drivers that are transferable across watershed and regional scales for application in Earth system models. This work also introduces a Findable Accessible Interoperable Reusable (FAIR) dataset (>300 samples) to the community for future syntheses.

Biogeochemistry↗

USGS2024

Underwater flashlights: What light can tell us about water quality

Water is essential for life. The particles and dissolved chemicals found in rivers, lakes, and oceans are constantly changing with weather, seasons, and human activities. The substances found in water can be helpful or harmful to humans and other organisms. New technologies allow scientists to use waterproof computers (called sensors) to record the quality of water as it changes throughout the day or night. Many sensors use the interaction of water with light, or other energy forms, to learn about what is in it. Through observing what happens to light energy in water, scientists can reveal the sources and movements of harmful pollutants or essential nutrients for plants, animals, and bacteria. Networks containing many sensors work together to provide continuous information about the ever-changing conditions that affect all living organisms that depend on water.

Frontiers for Young Minds↗

USGS2024

Widespread chemical dilution of streams continues as long-term effects of acidic deposition slowly reverse

Studies of recovery from acidic deposition have focused on reversal of acidification and its associated effects, but as recovery proceeds slowly, chemical dilution of surface waters is emerging as a key factor in the recovery process that has significant chemical and biological implications. This investigation uses long-term chemical records from 130 streams in the Adirondack region of New York, USA, to evaluate the role of ongoing decreases in conductance, an index of dilution, in the recovery of these streams. Stream chemistry data spanning up to 40 years (1980s–2022) showed that acid-neutralizing capacity has increased in 92% of randomly selected streams, but that harmful levels of acidification still occur in 37% of these streams. Conductance and Ca 2+ concentrations decreased in 79% of streams, and SO 4 2− concentrations in streams continued to show strong decreases but remained several times higher than concentrations in precipitation. These changes were ongoing through 2022 even though acidic deposition levels were approaching those estimated for pre-industrialization. Further dilution is continuing through ongoing decreases in stream SO 4 2− . Nevertheless, Ca 2+ continued to be leached from soils by SO 4 2− , organic acids and NO 3 − , limiting the replenishment of available soil Ca 2+ , a prerequisite to stem further dilution of stream water.

Environmental Pollution↗

USGS2024

Recent, widespread nitrate decreases may be linked to persistent dissolved organic carbon increases in headwater streams recovering from past acidic deposition

Long-term monitoring of water quality responses to natural and anthropogenic perturbation of watersheds informs policies for managing natural resources. Dissolved organic carbon (DOC) and nitrate (NO 3 − ) in streams draining forested landscapes provide valuable information on ecosystem function due to their biogeochemical reactivity and solubility in water. Here we evaluate a 20-year record (2001−2021) of biweekly stream-water samples ( n > 3000) and continuous discharge in three forested catchments in the Adirondack region of New York to investigate and interpret long-term trends in DOC and NO 3 − concentrations. Results from the intensively monitored catchments were compared with data from synoptic surveys of streams throughout the Adirondack region. A weighted regressions on time, discharge, and season (WRTDS) model, used to estimate daily flow-normalized concentrations, determined that DOC increased by ~30 to 50 % while NO 3 − decreased by ~50 to 70 % over the study period. The large amount of data from catchments with different soil properties permitted us to assess the relative effects of hydrology, season, and land cover factors on temporal trends in DOC and NO 3 − concentrations. We found weak evidence of climatic forcing of long-term increases in DOC, and instead contend that declining ionic strength in precipitation linked to declining anthropogenic acid deposition is driving DOC trends in stream waters. Nitrate concentrations were more variable but clearly decreased in recent years possibly related to declining N deposition. The recent increase in DOC:NO 3 − in all catchments indicates a major shift in stream stoichiometry that reflects changes in ecosystem functioning that may have important biogeochemical implications for terrestrial as well as aquatic ecosystems.

Science of the Total Environment↗