Geology topics

Kathleen A. Patnode

Publications and source records attributed to Kathleen A. Patnode.

3 recordsLinked to original sources

USGS2020

Insights into mercury source identification and bioaccumulation using stable isotope approaches in the Hannibal Pool of the Ohio River

Mercury contamination in river systems due to historic and current Hg releases is a persistent concern for both wildlife and human health. In larger rivers, like the Ohio River, USA, it is difficult to directly link Hg discharges to bioaccumulation due to the existence of multiple industrial Hg sources as well as the varied dietary and migratory habits of biota. To better understand how industrial effluent influences the cycling and bioaccumulation of Hg within the Ohio River, Hg stable isotope analysis was applied to various nonbiological and biological media. High Hg concentrations in suspended particulate matter suggest this vector was the largest contributor of Hg to the water column, and distinct Hg source signatures were observed in effluent particulates from different industrial processes, such as chlor‐alkali activity (δ 202 Hg = −0.52‰) and coal power plant discharge (δ 202 Hg = −1.39‰). Despite this distinction, average sediments (δ 202 Hg = −1.00 ± 0.23‰) showed intermediate isotopic signatures that suggest the accumulation of a mixed Hg source driven by multiple industrial discharges. Biota in the system were shown to have a conserved range of δ 202 Hg and estimation approaches related these signatures back to particulate matter within Hannibal Pool. Mussels were found to conserve Hg isotopes signatures independently of food web drivers and served as ideal water column indicators of bioaccumulated Hg sources. This study highlights the complexity of Hg cycling within an industrialized river and shows that an isotope tracer approach can provide insight to water column sources of Hg. Integr Environ Assess Manag 2021;17:233−242. Published 2020. This article is a US Government work and is in the public domain in the USA.

Ohio↗

USGS2015

Effects of high salinity wastewater discharges on unionid mussels in the Allegheny River, Pennsylvania

We examined the effect of high salinity wastewater (brine) from oil and natural gas drilling on freshwater mussels in the Allegheny River, Pennsylvania, during 2012. Mussel cages (N = 5 per site) were deployed at two sites upstream and four sites downstream of a brine treatment facility on the Allegheny River. Each cage contained 20 juvenile northern riffleshell mussels Epioblasma torulosa rangiana). Continuous specific conductance and temperature data were recorded by water quality probes deployed at each site. To measure the amount of mixing throughout the entire study area, specific conductance surveys were completed two times during low-flow conditions along transects from bank to bank that targeted upstream (reference) reaches, a municipal wastewater treatment plant discharge upstream of the brine-facility discharge, the brine facility, and downstream reaches. Specific conductance data indicated that high specific conductance water from the brine facility (4,000–12,000 µS/cm; mean 7,846) compared to the reference reach (103–188 µS/cm; mean 151) is carried along the left descending bank of the river and that dilution of the discharge via mixing does not occur until 0.5 mi (805 m) downstream. Juvenile northern riffleshell mussel survival was severely impaired within the high specific conductance zone (2 and 34% at and downstream of the brine facility, respectively) and at the municipal wastewater treatment plant (21%) compared to background (84%). We surveyed native mussels (family Unionidae) at 10 transects: 3 upstream, 3 within, and 4 downstream of the high specific conductance zone. Unionid mussel abundance and diversity were lower for all transects within and downstream of the high conductivity zone compared to upstream. The results of this study clearly demonstrate in situ toxicity to juvenile northern riffleshell mussels, a federally endangered species, and to the native unionid mussel assemblage located downstream of a brine discharge to the Allegheny River.

Pennsylvania↗

USGS2014

Changes in polychlorinated biphenyl (PCB) exposure in tree swallows ( Tachycineta bicolor ) nesting along the Sheboygan River, WI, USA

Exposure to polychlorinated biphenyls (PCBs) in tree swallow ( Tachycineta bicolor ) eggs on the Sheboygan River, Wisconsin in the 1990s was higher at sites downstream (geometric means = 3.33–8.69 μg/g wet wt.) of the putative PCB source in Sheboygan Falls, Wisconsin than it was above the source (1.24 μg/g) with the exposure declining as the distance downstream of the source increased. A similar pattern of declining exposure was present in the 2010s as well. Although exposure to PCBs in eggs along the Sheboygan River at sites downstream of Sheboygan Falls has declined by ~60 % since the mid-1990s (8.69 down to 3.27 μg/g) there still seems to be residual pockets of contamination that are exposing some individuals (~25 %) to PCB contamination, similar to exposure found in the 1990s. The exposure patterns in eggs and nestlings among sites, and the changes between the two decades, are further validated by accumulation rate information.

Wisconsin↗