Geology topics

Katharine Maher

Publications and source records attributed to Katharine Maher.

4 recordsLinked to original sources

USGS2021

Concentration-discharge relationships of dissolved rhenium in Alpine catchments reveal its use as a tracer of oxidative weathering

Oxidative weathering of sedimentary rocks plays an important role in the global carbon cycle. Rhenium (Re) has been proposed as a tracer of rock organic carbon (OC petro ) oxidation. However, the sources of Re and its mobilization by hydrological processes remain poorly constrained. Here we examine dissolved Re as a function of water discharge, using samples collected from three alpine catchments that drain sedimentary rocks in Switzerland (Erlenbach, Vogelbach) and Colorado, USA (East River). The Swiss catchments reveal a higher Re flux in the catchment with higher erosion rates, but have similar [Re]/[Na + ] and [Re]/[SO 4 2- ] ratios, which indicate a dominance of Re from OC petro . Despite differences in rock type and hydro-climatic setting, the three catchments have a positive correlation between river water [Re]/[Na + ] and [Re]/[SO 4 2- ] and water discharge. We propose that this reflects preferential routing of Re from a near-surface, oxidative weathering zone. The observations support the use of Re as a proxy to trace rock-organic carbon oxidation, and suggest it may be a hydrological tracer of vadose zone processes. We apply the Re proxy, and estimate CO 2 release by OC petro oxidation of 5.7 +6.6 / -2.0 tC km -2 yr -1 for the Erlenbach. The overall weathering intensity was ∼40%, meaning that the corresponding export of un-weathered OC petro in river sediments is large, and the findings call for more measurements of OC petro oxidation in mountains and rivers as thet cross floodplains.

Water Resources Research↗

USGS2020

Integrating airborne remote sensing and field campaigns for ecology and Earth system science

In recent years, the availability of airborne imaging spectroscopy (hyperspectral) data has expanded dramatically. The high spatial and spectral resolution of these data uniquely enable spatially explicit ecological studies including species mapping, assessment of drought mortality and foliar trait distributions. However, we have barely begun to unlock the potential of these data to use direct mapping of vegetation characteristics to infer subsurface properties of the critical zone. To assess their utility for Earth systems research, imaging spectroscopy data acquisitions require integration with large, coincident ground‐based datasets collected by experts in ecology and environmental and Earth science. Without coordinated, well‐planned field campaigns, potential knowledge leveraged from advanced airborne data collections could be lost. Despite the growing importance of this field, documented methods to couple such a wide variety of disciplines remain sparse. We coordinated the first National Ecological Observatory Network Airborne Observation Platform (AOP) survey performed outside of their core sites, which took place in the Upper East River watershed, Colorado. Extensive planning for sample tracking and organization allowed field and flight teams to update the ground‐based sampling strategy daily. This enabled collection of an extensive set of physical samples to support a wide range of ecological, microbiological, biogeochemical and hydrological studies. We present a framework for integrating airborne and field campaigns to obtain high‐quality data for foliar trait prediction and document an archive of coincident physical samples collected to support a systems approach to ecological research in the critical zone. This detailed methodological account provides an example of how a multi‐disciplinary and multi‐institutional team can coordinate to maximize knowledge gained from an airborne survey, an approach that could be extended to other studies. The coordination of imaging spectroscopy surveys with appropriately timed and extensive field surveys, along with high‐quality processing of these data, presents a unique opportunity to reveal new insights into the structure and dynamics of the critical zone. To our knowledge, this level of co‐aligned sampling has never been undertaken in tandem with AOP surveys and subsequent studies utilizing this archive will shed considerable light on the breadth of applications for which imaging spectroscopy data can be leveraged.

Colorado↗

USGS2018

A molecular investigation of soil organic carbon composition across a subalpine catchment

The dynamics of soil organic carbon (SOC) storage and turnover are a critical component of the global carbon cycle. Mechanistic models seeking to represent these complex dynamics require detailed SOC compositions, which are currently difficult to characterize quantitatively. Here, we address this challenge by using a novel approach that combines Fourier transform infrared spectroscopy (FT-IR) and bulk carbon X-ray absorption spectroscopy (XAS) to determine the abundance of SOC functional groups, using elemental analysis (EA) to constrain the total amount of SOC. We used this SOC functional group abundance (SOC-fga) method to compare variability in SOC compositions as a function of depth across a subalpine watershed (East River, Colorado, USA) and found a large degree of variability in SOC functional group abundances between sites at different elevations. Soils at a lower elevation are predominantly composed of polysaccharides, while soils at a higher elevation have more substantial portions of carbonyl, phenolic, or aromatic carbon. We discuss the potential drivers of differences in SOC composition between these sites, including vegetation inputs, internal processing and losses, and elevation-driven environmental factors. Although numerical models would facilitate the understanding and evaluation of the observed SOC distributions, quantitative and meaningful measurements of SOC molecular compositions are required to guide such models. Comparison among commonly used characterization techniques on shared reference materials is a critical next step for advancing our understanding of the complex processes controlling SOC compositions.

Soil Systems↗

USGS2014

Improving paleoecology studies for future predictions: Role of spatial and temporal scales for understanding ecology of the arid and semiarid landscape of the Southwest

Paleoecology (or ecological biogeography) describes the past distribution of species or communities and is an informative path used to understand the future in the face of climate change. Paleoecological changes in the Southwest over the past several thousand years happened in the presence of landscape manipulations by humans, a factor that adds relevance but increases difficulty of interpretation. What paleo-records are needed for (1) understanding past climate-driven changes (climate proxies), (2) resolving species sensitivity to and resilience against change (biogeographical data), and (3) understanding past ecosystem function and changes (environmental data)? What information is most urgently needed for ecosystem forecasts, and are there kinds of monitoring we need to start now so that we will have ground truth in the near future? These are major questions. Answering them for the arid and semiarid landscape of the Southwest in part relies on careful thought about the spatial and temporal scales of data needed.

Southwest United States↗