Search USGSSearch

Geology topics

K.L. Crepeau

Publications and source records attributed to K.L. Crepeau.

2 recordsLinked to original sources

Rice pesticide concentrations in the Colusa Basin Drain and the Sacramento River, California, 1990-1993

The pesticides molinate, thiobencarb, and carbofuran are applied to rice (Oryza sativa L.) fields in the Sacramento Valley, California, each year during April through June. These pesticides are of concern because of their adverse effects on water quality and their potential adverse effects on aquatic life. Therefore, the California Regional Water Quality Control Board (CRWQCB) mandated the holding of irrigation-return water in rice fields to increase pesticide degradation and dissipation before the water is released to the Sacramento River. The CRWQCB also established performance goals to maintain drinking Water quality for the city of Sacramento and to protect the habitat for aquatic life. The objectives of this study were to determine the effects of increased irrigation-return water holding times on rice pesticide concentrations and loads in the Colusa Basin Drain and the Sacramento River. Dissolved pesticide concentrations were measured in water samples collected in May through July during 1990-1993 at the Colusa Basin Drain at Road 99E near Knights Landing (Colusa Basin Drain) and at the Sacramento River at Sacramento. Pesticide concentrations and loads at both sites showed a decrease from 1990-1992 and an increase in 1993. This trend cannot be explained by the yearly holding time regulations but can be explained by the amount of yearly emergency releases. The yearly changes in pesticide concentration detected demonstrate that continued monitoring and management of pesticides is necessary to maintain water quality.

Conference Paper

Determination of pesticides associated with suspended sediments in the San Joaquin River, California, USA, using gas chromatography-ion trap mass spectrometry

An analytical method useful for the quantification of a range of pesticides and pesticide degradation products associated with suspended sediments was developed by testing a variety of extraction and cleanup schemes. The final extraction and cleanup methods chosen for use are suitable for the quantification of the listed pesticides using gas chromatography-ion trap mass spectrometry and the removal of interfering coextractable organic material found in suspended sediments. Methylene chloride extraction followed by Florisil cleanup proved most effective for separation of coextractives from the pesticide analytes. Removal of elemental sulfur was accomplished with tetrabutylammonium hydrogen sulfite. The suitability of the method for the analysis of a variety of pesticides was evaluated, and the method detection limits (MDLs) were determined (0.1-6.0 ng/g dry weight of sediment) for 21 compounds. Recovery of pesticides dried onto natural sediments averaged 63%. Analysis of duplicate San Joaquin River suspended-sediment samples demonstrated the utility of the method for environmental samples with variability between replicate analyses lower than between environmental samples. Eight of 21 pesticides measured were observed at concentrations ranging from the MDL to more than 80 ng/g dry weight of sediment and exhibited significant temporal variability. Sediment-associated pesticides, therefore, may contribute to the transport of pesticides through aquatic systems and should be studied separately from dissolved pesticides.

Toxicological and Environmental Chemistry