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K. R. Simmons

Publications and source records attributed to K. R. Simmons.

At least 19 recordsLinked to original sources

Sr-Isotope record of Quaternary marine terraces on the California coast and off Hawaii

Strontium-isotopic ratios of dated corals have been obtained from submerged reefs formed during Quaternary glacial periods off the Hawaiian islands. These data, combined with data from deep-sea sediments, tightly constrain the secular variation of marine 87Sr 86Sr for the past 800,000 yr. Although long-term trends are apparent, no significant (>0.02???), rapid (<100,000 yr) excursions in 87Sr 86Sr were resolved nor did we observe any samples with 87Sr 86Sr greater than that of modern seawater. Strontium in mollusks from elevated marine terraces formed during interglacial periods on the southern California coast show resolvable and consistent variations in 87Sr 86Sr which, when compared to the trend of Quaternary marine 87Sr 86Sr, can be used to infer uplift rates and define approximate ages for the higher terraces. The Sr-isotope age estimates indicate that uplift rates vary among crustal blocks and were not necessarily constant with time. No contrast in Sr-isotopic ratios between similar-age Hawaiian and California fossils was observed, confirming that any change in marine 87Sr 86Sr from glacial to interglacial periods must be small. A realistic appraisal of the potential of Sr-isotope stratigraphy for chronometric applications in the Quaternary suggests that the technique will be limited to relatively coarse distinctions in age. ?? 1992.

Quaternary Research

Fertilizer-derived uranium and sulfur in rangeland soil and runoff: A case study in central Florida

Fertilizer applications to rangeland and pastures in central Florida have potential impact on the nutrient-sensitive ecosystems of Lake Okeechobee and the Northern Everglades. To investigate the effects of fertilizer applications, three soil profiles from variably managed and improved rangeland, and four samples of surface runoff from both fertilized and unfertilized pasture were collected. In addition to determining nutrient concentrations, isotopic analyses of uranium (U) and sulfur (S) were performed to provide isotopic evidence for U derived from historically applied phosphate (P)-bearing fertilizer ( 234 U 238U activity ratio =1.0 ?? 0.05), and Sderived from recently applied ammonium sulfate fertilizer(??34 S=3.5permil).The distribution and mobility of fertilizer-derived U in these samples is considered to be analogous to that of fertilizer-derived phosphate.Variations of U concentrations and 234 U/238 U activity ratios in soils indicate contribution of fertilizer-derived U in the upper portions of the fertilized soil (15-}34 percent of total U). The U isotope data for runoff from the fertilized field also are consistent with some contribution from fertilizer-derived U. Parallel investigations of S showed no consistent chemical or isotopic evidence for significant fertilizer-derived sulfate in rangeland soil or runoff. Relatively abundant and isotopically variable S present in the local environment hinders detection of fertilizer-derived sulfate. The results indicate a continuing slow-release of fertilizer-derived U and, by inference, P, to the P-sensitive ecosystem, and a relatively rapid release of sulfate of possible natural origin. ?? Springer 2006.

Water, Air, & Soil Pollution

Weathering of the meade peak phosphatic shale member, phosphoria formation: Observations based on uranium and its decay products

Variably weathered outcrop samples of the Meade Peak Phosphatic Shale Member of the Phosphoria Formation have 5-10% of the contained uranium (U) in a form readily extractable by 0.1 M sodium bicarbonate. Fission track radiography of outcrop samples and other less-weathered channel and core samples indicate that this mobile fraction of U is likely hosted by organic matter, secondary iron oxides and clay minerals, trace uraninite, and very fine-grained apatite cement. During weathering, this extractable U fraction is especially susceptible to redistribution, which produces small but measurable departures (1-15%) from radioactive (secular) equilibrium in the 238 U decay-series. The most weath- ered samples show the strongest isotopic evidence for redistribution of U during the last 350 ka, but sequestration of U by alteration products limits open-system losses of U at the whole-rock scale. In less-weathered samples, isotopic evidence for minor U loss (or gain) over longer time periods (1 Ma) is consistent with relatively non-aggressive attack of phosphatic rock during weathering. Comparative extractability of selenium (Se) suggests that a larger fraction of Se (19%) is readily available for mobilization during the earliest stages of weathering.

Book chapter

Key Largo Limestone revisited: Pleistocene shelf-edge facies, Florida Keys, USA

New dates and analysis of 12 deep and 57 shallow cores allow a more detailed interpretation of the Pleistocene shelf edge of the Florida Platform as found in various facies of the Key Largo Limestone beneath the Florida Keys. In this study a three-phase evolution of the Quaternary units (Q1-Q5) of the Key Largo is presented with new subdivision of the Q5. (1) In the first phase, the Q1 and Q2 (perhaps deposited during oxygen-isotope stage 11) deep-water quartz-rich environment evolved into a shallow carbonate phase. (2) Subsequently, a Q3 (presumably corresponding to oxygen-isotope stage 9) flourishing reef and productive high-platform sediment phase developed. (3) Finally, a Q4 and Q5 (corresponding to oxygen-isotope stages 7 and 5) stabilization phase occurred with reefs and leeward productive lagoons, followed by lower sea levels presenting a sequence of younger (isotope substages 5c, 5a) shelf-margin wedges, sediment veneers and outlier reefs. The Key Largo Limestone provides an accessible model of a carbonate shelf edge with fluctuating water depth, bordering a deep seaward basin for a period of at least 300 ka. During this time, at least four onlaps/offlaps, often separated by periods of karst development with associated diagenetic alterations, took place. The story presented by this limestone not only allows a better understanding of the history of south Florida but also aids in the interpretation of similar persistent shelf-edge sites bordering deep basins in other areas.

Florida

Timing and warmth of the Last Interglacial period: New U-series evidence from Hawaii and Bermuda and a new fossil compilation for North America

The timing and duration of the Last Interglacial period have been controversial, with some studies suggesting a relatively short duration that is orbitally forced and others suggesting a long duration that is at most only partly related to orbital forcing. New, high-precison thermal ionization mass spectrometric (TIMS) U-series ages of Last Interglacial corals from Hawaii and Bermuda test these competing hypotheses. Waimanalo Formation corals from slowly uplifting Oahu, Hawaii range in age from ???134 to ???113 ka, with most ages between ???125 and ???115 ka. Combined with published U-series ages from nearby Lanai, the data suggest a long Last Interglacial period that may have occurred from ???136 to at least 115 ka. The results indicate that orbital forcing may not have been the only control on ice sheet growth and decay, because sea level would have been high at times of relatively low Northern Hemisphere summer insolation. On tectonically stable Bermuda, deposits from the ???200 ka (penultimate interglacial period), ???120 ka (peak Last Interglacial period) and ???80 ka (late Last Interglacial period) high sea stands have been newly dated. Fossil corals on Bermuda are derived from patch reefs that likely were "catch-up" responses to sea level rise. It is expected that U-series ages of Last-Interglacial corals on Bermuda should overlap with, but not be as old as the range of corals on Oahu. Last-Interglacial corals on Bermuda give a range of ???125-113 ka, which supports this hypothesis. A large number of emergent marine deposits on Hawaii, Bermuda and along coastal North America have now been dated to the Last Interglacial period. Both Oahu and Bermuda have marine invertebrate faunas with a number of extralimital southern species of mollusks, suggesting warmer-than-present waters during the Last Interglacial period. Warmer waters are also suggested for Last-Interglacial localities around most of North America, from Florida to Canada and Greenland and Baja California to Alaska. These observations are consistent with similar warm-water faunas of Last-Interglacial age reported from Japan, the Mediterranean basin and Western Australia. It is likely that significant changes in ocean currents took place during the Last Interglacial period, with a movement of relatively warm waters to higher latitudes than is the case today. ?? 2002 Elsevier Science Ltd. All rights reserved.

Quaternary Science Reviews

The last interglacial period on the Pacific Coast of North America: Timing and paleoclimate

New, high-precision U-series ages of solitary corals ( Balanophyllia elegans ) coupled with molluscan faunal data from marine terraces on the Pacific Coast of North America yield information about the timing and warmth of the last interglacial sea-level highstand. Balanophyllia elegans takes up U in isotopic equilibrium with seawater during growth and shortly after death. Corals from the second terrace on San Clemente Island (offshore southern California), the third terrace on Punta Banda (on the Pacific Coast of northern Baja California), and the Discovery Point Formation on Isla de Guadalupe (in the Pacific Ocean offshore Baja California) date to the peak of the last interglacial period and have U-series ages ranging from ca. 123 to 114 ka. The first terrace on Punta Banda has corals with ages ranging from ca. 83 to 80 ka, which corresponds to a sea-level highstand formed in the late last interglacial period. U-series analyses of corals from the Cayucos terrace (central California) and the Nestor terrace at Point Loma (southern California) show that these fossils have evidence of open-system history, similar to what has been reported by other workers for the same localities. Nevertheless, a model of continuous, secondary U and Th uptake shows that two ages of corals are likely present at these localities, representing the ca. 105 and ca. 120 ka sea-level highstands reported elsewhere. U-series ages of last interglacial corals from the Pacific Coast overlap with, but are on average younger than the ages of corals from Barbados, the Bahamas, and Hawaii. This age difference is explained by the nature of the geomorphic response to sea-level change: fringing or barrier reefs on low-latitude coastlines have an accretionary growth style that keeps pace with rising sea level, whether on a tectonically rising or stable coastline. In contrast, midlatitude, high-energy coastlines are sites of platform cutting during the early part of a sea-level high stand and terrace scouring and concomitant sediment and fossil deposition as sea level starts to recede. The youngest ages of corals from the Pacific Coast suggest that sea level was still relatively high at ca. 116 ka, which is not in agreement with other estimates of relatively large global ice volume at that time. Reliably dated, ca. 120 ka marine-terrace deposits on the Pacific Coast have fossil mollusks that indicate water temperatures as warm or warmer than at present. In contrast, ca. 80 ka marine deposits reported here and elsewhere have fossil mollusks indicating cooler-than-modern water temperatures. The presence of both ca. 105 ka and ca. 120 ka corals on the Nestor and Cayucos terraces explains a previously enigmatic mixture of warm-water and cool-water mollusks. At ca. 105 ka, a relatively high sea level with cool waters may have "captured" the terrace formed during the 120 ka sea-level highstand, in areas of low uplift rate. The inference of cooler-than-modern waters off the Pacific Coast of North America at ca. 80 ka and ca. 105 ka, based on marine-terrace faunas, does not agree with estimates of sea-surface temperatures derived from alkenone studies in the Santa Barbara Basin. However, cooler water temperatures at these times are in agreement with paleo-temperature estimates from planktonic foraminiferal data for the Santa Barbara Basin. All records, from central California to Baja California, whether from marine terraces or offshore cores, indicate at least seasonably warmer-than-modern waters during the peak of the last interglacial period at ca. 120 ka.

Pacific Coast

Use of 234U and 238U isotopes to identify fertilizer-derived uranium in the Florida Everglades

Surface water and peat in the northern Everglades have very low natural concentrations of U and are therefore sensitive to the addition of small amounts of U from anthropogenic sources such as fertilizer. Peat samples collected along a nutrient gradient in the northern Everglades have unusually high concentrations of U (> 1 ??g/g, dry basis) and also have a distinctive 234U/238U activity ratio (AR). AR values for U-enriched peat fall in the narrow range of AR values for commercial phosphate fertilizer (1.00 ??0.05) In contrast, AR values for low-U peat from background sites exceed 1.05. The spatial distribution of anomalous U concentration, and of fertilizer-like AR values in peat, parallel a previously documented pattern of P enrichment These results strongly suggest that some of the U in nutrient-impacted peatlands is fertilizer-derived. Agricultural drainage water sampled in the northern Everglades has high concentrations of dissolved U (0.3-2.4 ??g/1) compared to surface water from background sites (<0 1 ??g/1) Measured AR values in drainage water (0.949-0.990) are also permissive of a fertilizer origin for the U and are different from AR values in surface water or peat at background sites (AR > 1.05). Synoptic sampling of surface water along drainage canals indicate that Lake Okeechobee, and some drainage from agricultural fields, are sources of dissolved U, whereas wetlands farther downstream act as sinks for U. Historically cultivated agricultural soft has only a marginally elevated (+0.2 ??g/g) average concentration of U compared to nearby uncultivated soil and incorporates only 20% of the U from an aqueous solution that was slurried with the soil. In contrast, a similar experiment with fresh Everglades peat indicated uptake of 90% of the added U. These experiments support the proposed removal of U from agricultural fields and concentration of U in downstream peatlands. The methodology of this study can be used to describe the behavior of fertilizer-derived U in other low-U environments.

Applied Geochemistry

Lithostratigraphy, geophysics, biostratigraphy, and strontium-isotope stratigraphy of the surficial aquifer system of eastern Collier County and northern Monroe County, Florida

In 1997, ten cores were drilled in eastern Collier County and northern Monroe County, within the limits of the Big Cypress National Preserve. These cores represent a continuation of the study of seven cores in western Collier County begun in 1996 and reported in Weedman and others (1997) and Edwards and others (1998). This joint U.S. Geological Survey and Florida Geological Survey project is designed to acquire subsurface geologic and hydrologic data in southwest Florida to extend current ground-water models, thereby expanding the utility of these models for land and water management. In this report we describe the lithostratigraphy, geophysical logging, sedimentological analysis, dinocyst biostratigraphy, and strontium-isotope stratigraphy of these ten cores. The three geophysical logs (natural gamma-ray, induction conductivity, and neutron porosity) assumed to be related to formation lithology and water quality show that a number of clay-rich zones are present in all of the boreholes, and that pore-water conductivity increases with depth. The clay-rich zones are confirmed by visual examination of core material and sedimentological analysis. The relative transmissivity calculated at 10-foot-thick intervals shows that in six of the boreholes, high values are associated with the shallow aquifer in the 0-40 ft interval. Two of the boreholes (the most northerly and the most easterly) showed relatively higher values of transmissivity in permeable zones at or somewhat below 100 ft in depth. Core geology and logs indicate that the deeper aquifers are not more permeable than similar deeper zones in the other boreholes, but rather that the shallow aquifer appears to be less permeable in these two coreholes. The Arcadia (?) Formation was only penetrated in the deepest core where it is late Miocene in age. The Peace River Formation was penetrated in all but the two westernmost cores. It yields a late Miocene age, based on both dinocysts and strontium-isotope stratigraphy. The top is an irregular surface. Age and stratigraphic relations suggest that the upper part of the Peace River and lower part of the unnamed formation are at least partially equivalent laterally. The unnamed formation was recovered in every core. It is thinnest in the northernmost core and thickest to the west. Ages calculated from strontium isotopes range from 6.9 to 4.6 million years ago (late Miocene to early Pliocene). The top of the unnamed formation is deepest to the north and it becomes shallower to the southwest. The Tamiami Formation also was recovered in every core and consistently yields early Pliocene ages; it yields late Pliocene ages near the top in two cores. The age and lateral relations strongly suggest that the lower part of the Tamiami Formation and the upper part of the unnamed formation are lateral facies of each other. The Fort Thompson (?) Formation, Miami Limestone, and undifferentiated siliciclastic sediments and limestone at the very top of the cores were not dated.

Florida

Late Quaternary slip on the Santa Cruz Island fault, California

The style, timing, and pattern of slip on the Santa Cruz Island fault were investigated by trenching the fault and by analysis of offset late Quaternary landforms. A trench excavated across the fault at Christi Beach, on the western coast of the island, exposed deformation of latest Pleistocene to Holocene sediments and pre-Quaternary rocks, recording repeated large-magnitude rupture events. The most recent earthquake at this site occurred ca. 5 ka. Coastal terraces preserved on western Santa Cruz Island have been dated using the uranium-series technique and by extrapolation using terrace elevations and the eustatic record. Offset of terraces and other landforms indicates that the Santa Cruz Island fault is predominantly left lateral, having a horizontal slip rate of not more than 1.1 mm/yr and probably about 0.8 mm/yr. The fault also has a smaller reverse component, slipping at a rate of between 0.1 and 0.2 mm/yr. Combined with measurements of slip per event, this information suggests a long-term average recurrence interval of at least 2.7 k.y. and probably 4–5 k.y., and average earthquake magnitudes of Mw 7.2–7.5. Sense of slip, recurrence interval, and earthquake magnitudes calculated here for the Santa Cruz Island fault are very similar to recent results for other faults along the southern margin of the western Transverse Range, including the Malibu Coast fault, the Santa Monica fault, the Hollywood fault, and the Raymond fault, supporting the contention that these faults constitute a continuous and linked fault system, which is characterized by large but relatively infrequent earthquakes.

California

Reinterpretation of the peninsular Florida Oligocene: An integrated stratigraphic approach

A very thick (> 300 m) nearly continuous Oligocene section exists in southern peninsular Florida, as revealed by lithostratigraphic, biostratigraphic (mollusks and dinocysts), chronostratigraphic (Sr isotopes) and petrographic analyses of twelve cores and two quarries. The Oligocene deposits in the subsurface of southern Florida are the thickest documented in the southeastern U.S., and they also may represent the most complete record of Oligocene deposition in this region. No major unconformities within the Oligocene section are detected in the southern portion of the peninsula; hiatuses at the Eocene-Oligocene boundary, the early Oligocene-late Oligocene boundary, and the late Oligocene-Miocene boundary, are of limited duration if they exist at all. No significant disconformity is recognized between the Suwannee Limestone and the Arcadia Formation in southern Florida. However, on the east coast of Florida a hiatus of more than 12 m.y., spanning from at least the middle of the early Oligocene to early Miocene is present. The Suwannee Limestone was deposited during the early Oligocene. The top of the Suwannee Limestone appears to be diachronous across the platform. The 'Suwannee' Limestone, previously identified incorrectly as a late Oligocene unit, is herein documented to be early Oligocene and is encompassed in the lower Oligocene Suwannee Limestone. An unnamed limestone, found on the east coast of the peninsula is, at least in part, correlative with the Suwannee Limestone. The Arcadia Formation, basal Hawthorn Group, accounts for a large portion of the Oligocene deposition in southern Florida, spanning the interval from the middle of the early Oligocene to at least the early Miocene. Comparisons of the depositional patterns, and the distribution of dolomite and phosphate within the Suwannee Limestone and the Arcadia Formation, suggest fluctuating sea levels and that the paleo-Gulf Stream played a role in determining the nature and extent of Oligocene deposition in peninsular Florida.

Florida

Thorium-230 ages of corals and duration of the last interglacial sea-level high stand on Oahu, Hawaii

Thorium-230 ages of emergent marine deposits on Oahu, Hawaii, have a uniform distribution of ages from ∼114,000 to ∼131,000 years, indicating a duration for the last interglacial sea-level high stand of ∼17,000 years, in contrast to a duration of ∼8000 years inferred from the orbitally tuned marine oxygen isotope record. Sea level on Oahu rose to ≥1 to 2 meters higher than present by 131,000 years ago or ∼6000 years earlier than inferred from the marine record. Although the latter record suggests a shift back to glacial conditions beginning at ∼119,000 years ago, the Oahu coral ages indicate a near present sea level until ∼114,000 years ago.

Hawaii

234U/238U as a ground-water tracer, SW Nevada-SE California

The 234U/238U ratio of uranium in oxidizing ground waters is potentially an excellent ground-water tracer because of its high solubility and insensitivity to chemical reactions. Moreover, recent advances in analytical capability have made possible very precise uranium-isotopic analyses on modest (approx.100 ml) amounts of normal ground water. Preliminary results on waters from SW Nevada/Se California indicate two main mixing trends, but in detail indicate significant complexity requiring three or more main components.

California, Nevada

U-Pb dating of uranium deposits in collapse breccia pipes of the Grand Canyon region

Two major periods of uranium mineralization are indicated by U-Pb isotope dating of uranium ores from collapse breeeia pipes in the Grand Canyon region, northern Arizona. The Hack 2 and 3, Kanab North, and EZ 1 and 2 orebodies apparently formed in the interval of 200 + or - 20 Ma, similar to ages inferred for strata-bound, Late Triassic-hosted uranium deposits in southern Utah and northern Arizona. Samples from the Grand Canyon and Pine Nut pipes, however, indicate a distinctly older age of about 260 Ma. The Pigeon, Orphan, and Arizona-1 deposits were apparently mineralized before 220, 186, and 169 Ma, respectively, but no useful upper age limits can be inferred. There is no evidence in the U-Pb isotope data for uranium mineralization related to Laramide tectonism, mid-Tertiary volcanism, or late Tertiary uplift. The clustering in ages for a variety of uranium deposits at about (or slightly younger than) the age of the lower part of the Chinle Formation (Late Triassic) suggests that uranium in these deposits may have been derived by leaching from volcanic ash in the Chinle and mobilized by ground-water movement resulting from changing hydrologic gradients caused by regional uplift to the southwest. Pb isotope ratios of galenas in mineralized pipes are more radiogenic than those of sulfides from either uranium-poor pipes or occurrences away from pipes. This isotopic contrast suggests that fluids which passed through the pipes had interacted with the Proterozoic basement, possibly through the vertical fractures which influenced the location and evolution of the pipes themselves. Regardless of the source of the common Pb in the uranium-bearing pipes, the generally distinct Pb isotope composition of their galenas (compared to those of barren pipes and nonpipe sulfides in the region) may provide a useful exploration guide.

Economic Geology

Mass-spectrometric 230Th-234U-238U dating of the Devils Hole calcite vein

The Devils Hole calcite vein contains a long-term climatic record, but requires accurate chronologic control for its interpretation. Mass-spectrometric U-series ages for samples from core DH-11 yielded 230 Th ages with precisions ranging from less than 1,000 years (2σ) for samples younger than ∼140 ka (thousands of years ago) to less than 50,000 years for the oldest samples (∼566 ka). The 234 U/ 238 U ages could be determined to a precision of ∼20,000 years for all ages. Calcite accumulated continuously from 566 ka until ∼60 ka at an average rate of 0.7 millimeter per 10 3 years. The precise agreement between replicate analyses and the concordance of the 230 Th/ 238 U and 234 U/ 238 U ages for the oldest samples indicate that the DH-11 samples were closed systems and validate the dating technique in general.

Nevada

Crustal subsidence rate off Hawaii determined from 234U/238U ages of drowned coral reefs

A series of submerged coral reefs off northwestern Hawaii was formed during (largely glacial) intervals when the rate of local sea-level rise was less than the maximum upward growth rate of the reefs. Mass-spectrometric 234 U/ 238 U ages for samples from six such reefs range from 17 to 475 ka and indicate that this part of the Hawaiian Ridge has been subsiding at a roughly uniform rate of 2.6 mm/yr for the past 475 ka. The 234 U/ 238 U ages are in general agreement with model ages of reef drowning (based on estimates of paleo-sea-level stands derived from oxygen-isotope ratios of deep-sea sediments), but there are disagreements in detail. The high attainable precision (±10 ka or better on samples younger than ∼800 ka), large applicable age range, relative robustness against open-system behavior, and ease of analysis for this technique hold great promise for future applications of dating of 50-1000 ka coral.

Hawaii

Age of uranium mineralization at the Jabiluka and Ranger deposits, Northern Territory, Australia: New U-Pb isotope evidence

The Ranger and Jabiluka uranium deposits are the largest in the Alligator Rivers uranium field, which contains at least 20 percent of the world's low-cost uranium reserves. Ore occurs in early Proterozoic metasediments, below an unconformity with sandstones of the 1.65-b.y.-old Kombolgie Formation. This study has used U-Pb isotope data from a large number of whole-rock drill core samples with a variety of mineral assemblages and textures. Ranger samples indicate a well-defined age of 1,737 + or - 20 m.y., consistent with earlier suggestions of the antiquity of this deposit. This age is distinctly pre-Kombolgie, so the Ranger deposit cannot have been formed by processes requiring its presence. The age is consistent, however, with mineralization related to heating associated with either the emplacement of early postmetamorphic granites, or possibly, with intrusion of the nearby Oenpelli Dolerite. In contrast, data for the least-altered Jabiluka ores yield a concordia intercept age of 1,437 + or - 40 m.y.--significantly younger than the Ranger age and also younger than the Kombolgie Formation. This age may correspond to a regional thermal event, as indicated both by mafic dikes of roughly this age and a zircon lower intercept age from a nearby granite-gneiss. Thus our data indicate that there must be at least three distinct periods of major U mineralization in the Alligator Rivers uranium field (including the previously determined approximately 900-m.y. age of the Nabarlek deposit), despite the fact that all of the deposits share strong similarities in their host rock, mineralogy, alteration, and geologic setting.Both Ranger and Jabiluka reflect a common, profound isotopic disturbance at about 400 to 600 m.y. This disturbance, which was especially pronounced at Jabiluka, may correspond to the development of basins and associated basalt flows to the west and southwest, as suggested by Crick et al. (1980).

Economic Geology