Geology topics

K. J. Breen

Publications and source records attributed to K. J. Breen.

6 recordsLinked to original sources

USGS2010

Carbon and hydrogen isotopic evidence for the origin of combustible gases in water-supply wells in north-central Pennsylvania

The origin of the combustible gases in groundwater from glacial-outwash and fractured-bedrock aquifers was investigated in northern Tioga County, Pennsylvania. Thermogenic methane (CH 4 ) and ethane (C 2 H 6 ) and microbial CH 4 were found. Microbial CH 4 is from natural in situ processes in the shale bedrock and occurs chiefly in the bedrock aquifer. The δ 13 C values of CH 4 and C 2 H 6 for the majority of thermogenic gases from water wells either matched or were between values for the samples of non-native storage-field gas from injection wells and the samples of gas from storage-field observation wells. Traces of C 2 H 6 with microbial CH 4 and a range of C and H isotopic compositions of CH 4 indicate gases of different origins are mixing in sub-surface pathways; gas mixtures are present in groundwater. Pathways for gas migration and a specific source of the gases were not identified. Processes responsible for the presence of microbial gases in groundwater could be elucidated with further geochemical study.

Pennsylvania↗

USGS1995

Simulated ground-water flow and sources of water in the Killbuck Creek Valley near Wooster, Wayne County, Ohio

The stratified-drift aquifer in the 3,000-ft (feet)-wide and 100-ft-deep buried valley of Killbuck Creek near Wooster in northeastern Ohio was studied. The stratified drift with adjacent sandstone and shale bedrock produce a system of ground-water flow representative of the western part of the glaciated north-eastern United States. The stratified-drift aquifer is an excellent source of water for municipal and industrial wells. The aquifer is recharged locally by water from precipitation on the valley floor and uplands, by infiltration from streams, and by lateral flow to the valley from the uplands. As a result, the aquifer is vulnerable to surface or subsurface spills of contaminants in the valley or the adjacent uplands. Quality of water in the stratified drift is affected by influx of water from bedrock lateral to or beneath the valley. This influx is controlled, in part, by the pumping stress placed on the stratified-drift aquifer. Hydrogeologic and aqueous-geochemical data were analyzed to establish the framework necessary for stead-state and transient simulations of ground-water flow in stratified drift and bedrock with a three-layer ground-water-flow model. A new model routine, the Variable-Recharge procedure, was developed to simulate areal recharge and the contribution of the uplands to the drift system. This procedure allows for water applied to land surface to infiltrate or to be rejected. Rejected recharge and ground water discharged when the water table is at land surface form surface runoff-this excess upland water can be redirected as runoff to other parts of the model. Infiltration of streamwater, areal recharge to uplands and valley, and lateral subsurface flow from the uplands to the valley are sources of water to the stratufued0druft aquifer. Water is removed from the stratified-drift aquifer at Wooster primarily by production wells pumping at a rate of approximately 8.5 ft3/s (cubic feet per second). The ground-water budget resulting from two types of simulations of ground-water flow in this study indicates the primary sources of water to the wells are recharge at or near land surface and lateral subsurface flow from the shale and sandstone bedrock. Components of recharge at land surface include induced infiltration from streams, precipitation on the valley floor, and infiltration of unchanneled upland runoff that reaches the valley floor. The steady-state simulation was designed to represent conditions during the fall of 1984. The transient simulation was designed to represent an 11-day snowmelt event, 23 February to 5 March 1985, that caused water levels to rise significantly throughout the valley. Areal recharge to the valley and flow from the uplands to the valley were determined through the Variable-Recharge procedure. The total steady-state recharge to the valley was 12.5 ft3/s. Upland sources, areal valley recharge, and induced infiltration from Killnuck Creek accounted for 63, 23, and 8 percent, respectively, of the valley recharge. An analysis of the simulated vertical flow to the buried stratified drift through surficial slit, clay, and fine sand indicates that about 75 percent of the total recharge to the buried deposits is the sum of areally extensive, relatively small flows less than about 0.01 ft? /s per model node), whereas about 25 percent of the recharge results from a really restricted, relatively large flows (greater than about 0.01 ft? /s per model node). The large-magnitude flows are located primarily beneath Clear and Little Killbuck Creeks where seepage provides abundant recharge and the surficial sediments grade into coarser alluvial-fan deposits. Chemical and isotopic studies of ground water and streamwater combined with measurements of stream infiltration provide independent support for the conclusions derived from computer simulation of ground-water flow. In addition, the chemical and isotopic studies helped quantity the rate and pathways of infiltrating water from

Water-Resources Investigations Report↗

USGS1991

National Water-Quality Assessment Program; The Lower Susquehanna River basin

In 1991, the U.S. Geological Survey (USGS) began to implement a full-scale National Water-Quality Assessment (NAWQA) program. The three major objectives of the NAWQA program are to provide a consistent description of current waterquality conditions for a large part of the Nation's water resources, define long-term trends in water quality, and identify, describe, and explain the major factors that affect water-quality conditions and trends. The program will produce water-quality information that will be useful to policy makers and managers at the national, State, and local levels. The program will be implemented through 60 separate investigations of river basins and aquifer systems, called study units. These study-unit investigations will be conducted at the State and local level, and will form the foundation on which national- and regional-level assessments are based. The 60 study units are hydrologic systems that include parts of most major river basins and aquifer systems. The study-unit areas range from 1,200 to more than 65,000 square miles and include about 60 to 70 percent of the Nation's water use and population served by public water supply. In 1991, the Lower Susquehanna River basin was among the first 20 NAWQA study units selected for study under the full-scale implementation plan.

Open-File Report↗

USGS1991

Geohydrology and quality of water in aquifers in Lucas, Sandusky, and Wood counties, northwestern Ohio

The hydrology and quality of ground water were evaluated for the surficial sand and carbonate aquifers in northwestern Ohio. A locally important surficial sand aquifer in western Lucas County was evaluated on the basis of data from 10 wells completed in undeveloped and developed areas. The carbonate aquifer in Silurian and Devonian bedrock at its northernmost extent on the Ohio mainland was evaluated on the basis of data from previous studies and data from 466 wells and 11 springs. Most data are for the period 1985-88. The unconfined surficial sand aquifer is less than 50 ft. (feet) thick. Clay-rich drift, which restricts vertical movement of water, underlines the aquifer. Recharge is from precipitation, and discharge is by evapotranspiration and by flow to local streams and drainage ditches. Water levels are generally 2 to 8 ft. below land surface and fluctuate a total of about 3.5 ft. seasonally in a forested area. Concentrations of iron and manganese in ground water are excessive in some areas. Waters from shallow drive-point wells in residential areas contained larger concentrations of dissolved solids, hardness, sodium, and chloride than did waters from identical wells in undeveloped areas. The presence of nitrate nitrogen an other selected constituents in ground water in residential areas, and the absence of these constituents in ground water in undeveloped areas, indicate that the surficial sand aquifer has been affected by development. In carbonate aquifer, fractures, bedding-plane joints, and other secondary openings are the principal water-bearing zones. These zones can be areally and stratigraphically separated by low-permeability rock. Leaky artesian or semiconfined conditions predominate beneath most of the 1,400-mi? study area. The aquifer is confined by relatively impermeable underlying shale of Silurian age and overlying clay-rich drift of Quaternary age. Unproductive strata, including evaporites, within the sequence of carbonate rocks also confine some water-bearing zones. The carbonate aquifer is part of a regional ground-water-flow system; however, subsystems such as the eastern karst and central outcrops are locally important. The potentiometric surface indicates that recharge from areas south and west of the study area flows toward discharge areas along major rivers (Maumee, Portage, and Sandusky) , to a buried bedrock valley in central Sandusky County, and to springs and flowing wells. The potentiometric surface flattens markedly near the southern shore of Lake Erie, where ground-water levels approximate those of the lake, indicating a hydraulic connection between the lake and the aquifer. Hydrogeologic characteristics and water-quality data indicate that Lake Erie is not a major source of recharge to the aquifer. Ground-water ages inferred from tritium concentrations and potentiometric-surface maps indicate that recharge from precipitation enters the aquifer by subsurface drainage in karstified strata in eastern Sandusky County and by infiltration in shallow bedrock areas where drift is less than 20 ft. thick. The quality of water in the carbonate aquifer is described with reference to 52 properties and constituents that characterize chemical, radiochemical, bacteriologic, and physical conditions. Ground-water samples from 135 wells and 11 springs are used in the characterization. On the basis of these data, water from the aquifer is generally suitable for drinking and for most domestic purposes. The most areally widespread aesthtic factors limiting the use of ground water are hardness, concentrations of dissolved solids, sulfate and iron, and the presence of hydrogen sulfide. Selected bacteria are commonly present and may compromise the potability of water from the aquifer. Coliform bacteria from surface sources were found in 47 of 143 water samples. Analyses for total coliform bacteria indicate that 36 of the 125 samples from wells maintained for potable supply have bacteria counts of 4

Water-Resources Investigations Report↗

USGS1989

Hydrogeology and water quality near a solid- and hazardous-waste landfill, Northwood, Ohio

Hydrogeology and water quality of ground water and selected streams were evaluated near a landfill in northwestern Ohio. The landfill is used for codisposal of solid and hazardous waste. Water-level and geologic data were collected from 36 wells and 3 surface-water sites during the period November 1983 to November 1985. Water-quality samples were collected from 18 wells and 3 surface-water sites this during this same period. The primary aquifers in the area are the Greenfield Dolomite and underlying Lockport Dolomite of Silurian age. These bedrock carbonates are overlain by two clay tills of Wisconsin age. The tills are capped by a glacial lake clay. The tills generally are saturated, but do not yield sufficient water to be considered an aquifer. Two wells in the study area yield water, in part, from discontinuous deposits of outwash sand and gravel at the lower till-bedrock interface. Regional ground-water flow is from southwest to northeast; local flow is influenced by a ground-water mound centered under the northernmost cells of the landfill. Water levels in wells penetrating refuse within the landfill and the presence of leachate seeps indicate that the refuse is saturated. Head relations among the landfill, till, and dolomite aquifer indicate a vertical component of flow downward from the landfill to the dolomite aquifer. Water levels near the landfill fluctuate as much as 14 feet per year, in contrast to fluctuations of less than 3 feet per year in wells upgradient landfill. Ground waters from wells completed in the dolomite aquifer and glacial till were found to have major-iron concentrations controlled, in large part, by reaction with calcite, dolomite, and other minerals in the aquifer. Only minor departures from equilibrium mineral saturation were noted for ground water, except in wells affected by cement/grout contamination. Molal ratios of calcuim:magnesium in ground water suggest a similar chemical evolution of waters throughout the dolomite aquifer in the study area. Stable-isotope ratios of oxygen and hydrogen indicate the source of water in the till unit and dolomite aquifer is atmospheric precipitation. Elevated levels of total dissolved solids, boron, ammonia, and iron in the leachate and in wells downgradient of the landfill may indicate mixing of ground water with leachate. Oxygen and hydrogen stable-isotope ratios were used to differentiate waters from the glacial till and dolomite aquifer. Isotope ratios also show a shift off the local mixing line for leachate and for a well just downgradient from the landfill. The shift to heavier values of o D in the well water may be indicative of leachate mixing with ground water. The effect of this mixing denoted by hydrologic, isotopic, and chemical-quality data is limited mostly to elevated levels of the common ions. Analysis did not indicate significant levels of toxic metals or organic contaminants except phenol, which was present at concentrations of from 1 to 5 micrograms per liter in six wells. Analysis of water-quality data from nearby streams suggest that surface leaching from the landfill does not significantly affect stream-water quality, but may contribute to higher level of trace metals in the streambed sediments.

Water-Resources Investigations Report↗

USGS1985

Chemical and isotopic characteristics of brines from three oil- and gas-producing sandstones in eastern Ohio, with applications to the geochemical tracing of brine sources

Chemical and isotopic characteristics of selected inorganic constituents are reported for brines from the Berea Sandstone of Mississippian age, the Clinton sandstone, Albion Sandstone of Silurian age, and the Rose Run formation of Cambrian and Ordovician age in 24 counties in eastern Ohio. Ionic concentrations of dissolved constituents in brines from these formations generally fall in the following ranges (in millimoles per kilogram of brine): Na, Cl > 1,000; 100 < Ca, Mg < 1,000; 1 < K, Br, Sr, Li, Fe, SO4 < 100; Mn, Zn, Al, I, HCO3, SiO2 < 1. Mean ionic concentrations of Ca, Mg, Na, Cl, K, SO4 and Br, and mean values of density and dissolved solids are significantly different at the 95-percent confidence level in each formation. Only potassium has a unique concentration range in each formation. Selected concentration ratios are identified as potential indicators for geochemical tracing of brines having some history of dilution. The k:Na ratios work best for identifying the source formation of an unidentified brine. Isotopic characteristics of hydrogen and oxygen indicate a meteoric origin for the water matrix of the brines. Sulfur isotopes may have utility for differentiating brines from oxidizing ground water.

Ohio↗