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K. Cartwright

Publications and source records attributed to K. Cartwright.

7 recordsLinked to original sources

Hydrochemistry of the Mahomet Bedrock Valley Aquifer, East-Central Illinois: Indicators of recharge and ground-water flow

A conceptual model of the ground-water flow and recharge to the Mahomet Bedrock Valley Aquifer (MVA), east-central Illinois, was developed using major ion chemistry and isotope geochemistry. The MVA is a “basal” fill in the east-west trending buried bedrock valley composed of clean, permeable sand and gravel to thicknesses of up to 61 m. It is covered by a thick sequence of glacial till containing thinner bodies of interbedded sand and gravel. Ground water from the MVA was found to be characterized by clearly defined geochemical regions with three distinct ground-water types. A fourth ground-water type was found at the confluence of the MVA and the Mackinaw Bedrock Valley Aquifer (MAK) to the west. Ground water in the Onarga Valley, a northeastern tributary of the MVA, is of two types, a mixed cation-SO 4 2- type and a mixed cation-HCO 3 type. The ground water is enriched in Na + Ca 2+ , Mg 2+ , and SO 4 2- which appears to be the result of an upward hydraulic gradient and interaction of deeper ground water with oxidized pyritic coals and shale. We suggest that recharge to the Onarga Valley and overlying aquifers is 100% from bedrock (leakage) and lateral flow from the MVA to the south. The central MVA (south of the Onarga Valley) is composed of relatively dilute ground water of a mixed cation-HC0 3 type, with low total dissolved solids, and very low concentrations of Cl - and SO 4 2- . Stratigraphie relationships of overlying aquifers and ground-water chemistry of these and the MVA suggest recharge to this region of the MVA (predominantly in Champaign County) is relatively rapid and primarily from the surface. Midway along the westerly flow path of the MVA (western MVA), ground water is a mixed cation-HCO 3 - type with relatively high Cl - , where Cl - increases abruptly by one to two orders of magnitude. Data suggest that the increase in Cl - is the result of leakage of saline ground water from bedrock into the MVA. Mass-balance calculations indicate that approximately 9.5% of recharge in this area is from bedrock. Concentrations of Na + , HCO 3 - , As, and TDS also increase in the western MVA. Ground water in the MAK is of a Ca 2+ -HCO 3 2- type. Mass-balance calculations, using Cl - as a natural, conservative tracer, indicate that approximately 17% of the ground water flowing from the confluence area is derived from the MVA.

Groundwater

Impact of urban development on the chemical composition of ground water in a fen-wetland complex

A 15-month-long hydrogeologic investigation of a fen-wetland complex in northeastern Illinois, USA indicated the encroachment of ground-water-borne anthropogenic contaminants into two of three high quality fens. Ground-water flow directions and chemical evidence indicated that plumes of ground water with anomalously large concentrations of Na − and Cl − originated from a private septic system and from rock salt spread on an adjacent road. The contamination, in turn, had an adverse effect on fen vegetation; within the plumes, diverse vegetation was replaced by the more salt-tolerant narrow-leaf cattail ( Typha angustifolia ). Ground water of the third fen contained large concentrations of SO 4 2− as high as 516 mg/L. The SO 4 2− anomaly was observed on a transient and/or seasonal basis in the fen ground water and in an adjacent marsh and pond. Isotopically light δ 34 S values in these waters indicated that the addition of SO 4 2− resulted from the oxidation of pyrite within underlying peat and/or pyritic gravel. However, the large SO 4 2− concentrations had no discernible effect on fen vegetation. The results of this investigation indicate how easily construction of houses with private septic systems and deicing agents from roadway maintenance can contaminate fen ground water with relatively large concentrations of Na + and Cl − , resulting in a significant loss of biodiversity in fens.

Illinois

Water movement through an experimental soil liner

A field-scale soil liner was constructed to test whether compacted soil barriers in cover and liner systems could be built to meet the U.S. EPA saturated hydraulic conductivity requirement (⩽ 1 × 10 −7 cm s −1 ). The 8 × 15 × 0.9 m liner was constructed in 15 cm compacted lifts using a 20,037 kg pad-foot compactor and standard engineering practices. Water infiltration into the liner has been monitored for one year. Monitoring will continue until water break through at the base of the liner occurs. Estimated saturated hydraulic conductivities were 2.5 × 10 −9 , 4.0 × 10 −8 , and 5.0 × 10 −8 cm s −1 based on measurements of water infiltration into the liner by large- and small-ring infiltrometers and a water balance analysis, respectively. Also investigated in this research was the variability of the liner's hydraulic properties and estimates of the transit times for water and tracers. Small variances exhibited by small-ring flux data suggested that the liner was homogeneous with respect to infiltration fluxes. The predictions of water and tracer breakthrough at the base of the liner ranged from 2.4–12.6 y, depending on the method of calculation and assumptions made. The liner appeared to be saturated to a depth between 18 and 33 cm at the end of the first year of monitoring. Transit time calculations cannot be verified yet, since breakthrough has not occurred. The work conducted so far indicates that compacted soil barriers can be constructed to meet the saturated hydraulic conductivity requirement established by the U.S. EPA.

Waste Management and Research

Infiltration through layered-soil trench covers: Response to an extended period of rainfall

Four experimental waste disposal trench covers were constructed to test the effectiveness of layered-soil cover designs in reducing infiltration. Three covers each consisted of a layer of gravel between an overlying wick layer of compacted fine-grained material (either silt or loam) and a compacted loam base; the fourth consisted of compactd silt over a loam base. Capillary pressures were monitored at various depths within each cover during October through December, 1985, a period of high rainfall following a dry summer. Moisture movement in response to the rainfall was rapid within the upper layers of all four test covers, but was retained within the upper layers of the three wick-system trenches, despite variations in the design thickness and composition of the wick layers. In the wick systems, moisture did not enter the gravel until a threshold level of pressure approaching saturation was established in the wick layer. Once this level was reached, moisture moved into and through the gravel. This experiment demonstrates the functionality of field-scale wick systems.

Journal of Contaminant Hydrology

Geological considerations in hazardous waste disposal

Present regulations assume that long-term isolation of hazardous wastes - including toxic chemical, biological, radioactive, flammable and explosive wastes - may be effected by disposal in landfills that have liners of very low hydraulic conductivity. In reality, total isolation of wastes in humid areas is not possible; some migration of leachate from wastes buried in the gound will always occur. Regulations should provide performance standards applicable on a site-by-site basis rather than rigid criteria for site selection and design. The performance standards should take into account several factors: (1) the categories, segregation, degradation and toxicity of the wastes; (2) the site hydrogeology, which governs the direction and rate of contaminant transport; (3) the attenuation of contaminants by geochemical interactions with geologic materials; and (4) the release rate of unattenuated pollutants to surface or groundwater. An adequate monitoring system is essential. The system should both test the extent to which the operation of the site meets performance standards and provide sufficient warning of pollution problems to allow implementation of remedial measures. In recent years there has been a trend away from numerous, small disposal sites toward fewer and larger sites. The size of a disposal site should be based on the attenuation capacity of the geologic material, which has a finite, though generally not well-defined, limit. For slowly degradable wastes, engineered sites with leachate-collection systems appear to be only a temporary solution since the leachate collected will also require final disposal.

Journal of Hydrology

Hydraulic potential in Lake Michigan bottom sediments

The magnitude and direction of groundwater flux in the bottom sediments of Lake Michigan were deduced from measurements made during three shipboard cruises between 1973 and 1975. These factors affect the geochemical environment of the sediments and therefore the distribution of trace elements reported to be present. The near-shore, sandy-bottom and fine-grained, soft, deep-lake sediments were investigated; areas of hard till or bedrock were not included in the study. Thirty-three piezometers were placed in near-shore sands in waters 5-15 m deep. The piezometers were placed an average of 3 m into the bottom sediment. Water levels from the piezometers averaged 0.6 cm above the lake level, equivalent to an upward hydraulic gradient of about 0.002 cm/cm. Water samples taken from the piezometers have a distinctly different chemical composition from that of the lake water. The total dissolved mineral content and hardness of the groundwater are about twice those of the lake water. Twenty-two hydraulic gradient measurements were made in the fine-grained soft deep-lake sediments in waters 48-140 m deep by using a differential-pressure transducer dropped into the sediments. These measurements show an upward gradient averaging 0.2 cm/cm. No chemical data were obtained for the groundwater in the deep-lake sediments. The results of this study indicate that the groundwater flux is upward through the bottom sediments into Lake Michigan and that there is a chemical change in the water near the water-sediment contact.

Lake Michigan

Measurement of fluid velocity using temperature profiles: Experimental verification

Temperature profiling has been used to predict the rate and direction of groundwater movement. A controlled field experiment was conducted to ascertain the validity of the rate calculations made using this method. The vertical velocity, or leakage, of groundwater between two aquifers was calculated utilizing both hydrologic and temperature measurements in a well drilled into the Paw Paw buried bedrock valley in northern Illinois. The experiment showed that accurate estimates of leakage can be made in stable boreholes where there are no geologic complications. Estimates utilizing temperature and hydrologic methods produced similar results for one of two aquicludes. However, the methods produced dissimilar results for the second aquiclude. It is speculated that the presence of a thin organic silt caused most of the problem; other complicating factors were lithologic variation and a very low hydraulic gradient. Nevertheless, the method appears to have great promise in many geologic environments.

Illinois