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Julie Roberge

Publications and source records attributed to Julie Roberge.

3 recordsLinked to original sources

Pre-eruptive characteristics of “suspect” silicic magmas in Carlin-type Au-forming systems

World-class Carlin-type Au deposits hosted in sedimentary rock were formed when profuse Eocene silicic magmatism swept across northern Nevada in response to arc migration. Carlin-type Au deposits formed along with porphyry/skarn Cu-Mo-W-Au deposits, epithermal Ag-Au deposits, and distal disseminated Ag-Au deposits. But unlike these other Au-bearing deposits that have clear associations with igneous intrusions, Carlin-type ore deposits appear to have formed distant from concealed plutons, and their origin remains controversial. Despite decades of abundant geophysical, geochronological, and geochemical studies suggesting the involvement of magmas, concrete evidence for magmatic involvement is still lacking. Consequently, the involvement of contemporaneous igneous systems remains inferred based on age, proximity, and variable isotopic, geochemical, and geophysical clues. A recent synthesis of deposit models postulates that Carlin-type Au deposits are intrusion-related, but that the causative magmas reside deeper (∼6–12 km) than in typical porphyry and peripheral systems (∼3–5 km), meaning that Carlin-type deposits are perhaps more distal expressions of igneous intrusions. We investigate a collection of “suspect” magmatic systems over a ∼7 m.y. timespan (∼41–34 Ma) that are contemporaneous with and near known Carlin-type ore deposits. We report results of a multifaceted array of in situ geochemical analyses (FTIR, EMP, SHRIMP-RG, LA-ICP-MS) of quartz-hosted melt inclusions, biotite, and quartz to better characterize the pre-eruptive characteristics of these magmas. We also report results of thermobarometry and thermodynamic phase equilibria modeling to help place constraints on magmatic reservoir depths and processes. Rather than a single “flavor” of silicic magma, we observe a surprisingly broad compositional spectrum of rhyolites, with one end of the spectrum exhibiting more arc-like (I-type) characteristics and the other end displaying more post-subduction, thick-crust extensional (A-type) characteristics. This broad compositional spectrum suggests a more complex picture of silicic crustal magmatism operating over a narrow span of time during slab rollback. Despite this spectrum, magmatic systems in this study are consistently ferroan and generally peraluminous, which we interpret as an expression of the relatively elevated geotherm at the time and incorporation of variable amounts of highly peraluminous metasedimentary crustal components. The silicic magma spectrum encompasses a range of mineralization associations, including subduction-related Cu-Mo-W-Au-Ag and post-subduction, thick-crust extensional rare-metal Mo-Sn-W-F-Be-Ag-Au, consistent with the prolific and diverse array of ore deposits that formed during this time. Carlin-type Au deposition appears to be associated with nearly the entire magmatic spectrum. This apparent indifference to silicic magma “flavor” would seem to imply that if magmas are involved in Carlin-type Au deposit genesis, they perhaps do not need to be compositionally specialized and/or possibly are only relevant as heat sources driving circulation to remobilize and redistribute metals.

Nevada↗

Pre- and post-eruptive geochemical and isotopic fingerprints of rhyolites parental to volcano-sedimentary lithium brine and clay resources in the western USA & central Andes

Lithium is a high-demand, critical element used not only in lightweight rechargeable lithium-ion batteries, but also in nuclear applications and industries producing ceramics, aluminum, and medical products. It is extracted primarily from pegmatites and volcano-sedimentary brines and clays in arid, closed lacustrine or caldera basins. Lithium brines of the central Andean salars in the AltiplanoPuna Plateau contain around ~70% of the world’s lithium resources. In contrast, Clayton Valley, Nevada is the only current producer of lithium brines in the United States and accounts for ~6% of current global lithium production. Clayton Valley hosts a newly defined Li-clay resource where locally exposed rhyolite tuffs have been proposed as a lithium source. Identifying magma evolution processes and determining the importance of syn- and post-eruptive processes on the source, mobility, and distribution of lithium is an ongoing area of research. These two regions illustrate distinctive magmatic-tectonic regimes for volcano-sedimentary lithium enrichment and therefore represent ideal regions to explore the key geological processes critical to the enrichment of lithium resources.

Clayton Valley, Puna Plateau↗

Pre-eruptive conditions of the Hideaway Park topaz rhyolite: Insights into metal source and evolution of magma parental to the Henderson porphyry molybdenum deposit, Colorado

The Hideaway Park tuff is the only preserved extrusive volcanic unit related to the Red Mountain intrusive complex, which produced the world-class Henderson porphyry Mo deposit. Located within the Colorado Mineral Belt, USA, Henderson is the second largest Climax-type Mo deposit in the world, and is therefore an excellent location to investigate magmatic processes leading to Climax-type Mo mineralization. We combine an extensive dataset of major element, volatile, and trace element abundances in quartz-hosted melt inclusions and pumice matrix glass with major element geochemistry from phenocrysts to reconstruct the pre-eruptive conditions and the source and evolution of metals within the magma. Melt inclusions are slightly peraluminous topaz rhyolitic in composition and are volatile-charged (&le;6&thinsp;wt % H 2 O, &le;600&thinsp;ppm CO 2 , &sim;0&middot;3&ndash;1&middot;0&thinsp;wt % F, &sim;2300&ndash;3500&thinsp;ppm Cl) and metal-rich (&sim;7&ndash;24&thinsp;ppm Mo, &sim;4&ndash;14&thinsp;ppm W, &sim;21&ndash;52&thinsp;ppm Pb, &sim;28&ndash;2700&thinsp;ppm Zn, <0&middot;1&ndash;29&thinsp;ppm Cu, &sim;0&middot;3&ndash;1&middot;8&thinsp;ppm Bi, &sim;40&ndash;760&thinsp;ppb Ag, &sim;690&ndash;1400&thinsp;ppm Mn). Melt inclusion and pumice matrix glass chemistry reveal that the Hideaway Park magma evolved by large degrees of fractional crystallization (&le;60&ndash;70%) during quartz crystallization and melt inclusion entrapment at pressures of &le;300&thinsp;MPa (&le;8&thinsp;km depth), with little to no crystallization upon shallow ascent and eruption. Filter pressing, crystal settling, magma recharge and mixing of less evolved rhyolite melt, and volatile exsolution were important processes during magma evolution; the low estimated viscosities (&sim;10 5 &ndash;10 10&thinsp; Pa s) of these H 2 O- and F-rich melts probably enhanced these processes. A noteworthy discrepancy between the metal contents in the pumice matrix glass and in the melt inclusions suggests that after quartz crystallization ceased upon shallow magma ascent and eruption, the Hideaway Park magma exsolved an aqueous fluid into which Mo, Bi, Ag, Zn, Mn, Cs, and Y strongly partitioned. Given that the Henderson deposit contains anomalous abundances of not only Mo, but also W, Pb, Zn, Cu, Bi, Ag, and Mn, we suggest that these metals were sourced from similar fluids exsolved from unerupted portions of the same magmatic system. Trace element ratios imply that Mo was sourced deep, from either the lower crust or metasomatized mantle. The origin of sulfur remains unresolved; however, given the extremely low S solubility of rhyolite melts in the shallow crust we favor the possibility that another source of S might supplement or account for that present in the ore deposit, probably the comagmatic, mantle-derived lamprophyres that occur in minor quantities with the voluminous topaz rhyolites in the area. To account for the 437&thinsp;Mt of MoS 2 (&sim;1&middot;0&thinsp;&times;&thinsp;10 6&thinsp; t Mo) present in the Henderson ore deposit, a volume of &sim;45&thinsp;km 3 of Hideaway Park rhyolite magma would have been necessary to supply the Mo (a cylindrical pluton measuring 3&middot;1&thinsp;km&thinsp;&times;&thinsp;6&middot;0&thinsp;km) along with sparging of &sim;6&middot;8&thinsp;&times;&thinsp;10 5&thinsp; t of S from &sim;0&middot;05&thinsp;km 3 of lamprophyre magma. Based on a weighted mean 40 Ar/ 39 Ar age of 27&middot;58&thinsp;&plusmn;&thinsp;0&middot;24&thinsp;Ma, similar melt geochemistry, and characteristically F-rich biotite phenocrysts, we conclude that the Hideaway Park tuff was cogenetic with the intrusions at Red Mountain that formed the Henderson deposit.

Colorado↗