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Julie A. Dumoulin

Publications and source records attributed to Julie A. Dumoulin.

At least 19 recordsLinked to original sources
USGS2026

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology↗
USGS2025

Chemostratigraphy of the Cretaceous Hue Shale in Arctic Alaska: Exploring paleoceanographic controls on trace element enrichment, organic matter accumulation, and source-rock evolution

We document chemostratigraphy in an outcrop of late Albian to early Campanian (∼103–82 Ma) marine source rocks to better understand paleoenvironmental controls on trace element (TE) enrichment and organic matter accumulation in the distal Colville foreland basin of Arctic Alaska and how those drivers are linked to arc volcanism and successions of Cretaceous oceanographic and climatic biogeochemical events. This unique, 113-m-thick section of Cretaceous Hue Shale deposited during a series of previously undocumented Arctic Cretaceous oceanic anoxic events (Lease et al., 2024) is the only known exposure of thermally immature (0.48–0.52% R o , random vitrinite reflectance) Hue Shale in Arctic Alaska. Strata comprise mainly clay-rich mudstone with elevated total organic carbon (TOC) and hydrogen index values reaching 26.3 wt% (mean = 7.5 wt%) and 689 mg hydrocarbon (HC)/g TOC (mean = 385 mg HC/g TOC), respectively. Maceral composition consists predominantly of fluorescent amorphous organic matter, with abundant brightly fluorescent alginite, including Tasmanites , acritarchs, and Leiosphaeridia . Discrete layers of volcanic ash (preserved as bentonite) are present throughout the section and provide quantitative age control based on U–Pb dates. Chemostratigraphic trends are investigated to advance our understanding of local oceanographic conditions and controls on stratigraphic and temporal heterogeneity of Brookian source rocks. Concurrent sedimentary enrichment in Mo, U, V, Pb, and Cu across the Albian–Cenomanian boundary of the exposed basal gamma-ray zone, may reflect anoxic to euxinic benthic redox conditions favoring organic matter accumulation and preservation. Fluctuating degrees of anoxia-euxinia are inferred throughout the overlying Hue Shale succession, reflected by varying patterns of TE enrichment and TE–TOC covariation. Elevated C org /P molar ratios (>250) across most of the section, with several values exceeding 690, signify that enhanced biological productivity is sustained throughout deposition. Enhanced productivity, recorded by both C org /P and excess Ba, also parallels increases in source rock richness (elevated TOC and S 2 values) during the late Albian–early Cenomanian and late Cenomanian – Turonian. Enhanced productivity and variations in oceanic circulation/stratification likely both drove changes in benthic redox conditions that favored organic carbon accumulation and preservation. Increased continental arc volcanism (e.g., Okhotsk–Chukotka volcanic belt) and High Arctic Large Igneous Province magmatic eruptions throughout the Cretaceous, inferred to have influenced nutrient cycling and local aqueous nutrient availability, also have been invoked as potential drivers of organic carbon burial and source-rock development across the sedimentary sequence. Results presented here document the organic-rich and oil-prone source-rock quality of the Hue Shale in the distal part of the Colville foreland basin and bolster the potential for a Cretaceous petroleum system beneath the eastern North Slope.

Alaska↗
USGS2024

Facies variation within outcrops of the Triassic Shublik Formation, northeastern Alaska

The Shublik Formation (Middle to Upper Triassic) is a heterogeneous unit that is a major hydrocarbon source rock in northern Alaska and the largest known Triassic phosphate accumulation in the world. This formation, which occurs in the subsurface and crops out within the Arctic Alaska basin, was deposited on a gently sloping ramp along the northwestern Laurentian margin. In this study, we document spatial and temporal facies variations within the Shublik and the overlying Karen Creek Sandstone (Upper Triassic) through 19 outcrop localities in the northeastern Brooks Range. New organic and inorganic geochemical data from these localities support and extend our sedimentologic and petrographic findings. The petrographic data come from an analysis of more than 900 thin sections, whereas age constraints come mainly from species of the pelecypod genera Daonella , Halobia , Eomonotis , and Monotis . Thirteen sites make up a main outcrop belt within which facies of the Shublik are spatially consistent but show marked vertical changes. Six additional outcrops located south of the main belt contain more distal facies of the Shublik that accumulated farther from land. Exposures of the Shublik Formation in its main outcrop belt are divisible into five informal lithologic units, each of which formed during a distinct transgressive to regressive sequence. The basal unit of the Shublik (Anisian? to Ladinian; Middle Triassic) is quartz siltstone to very fine grained sandstone that is locally phosphatic. The three middle units (Ladinian to middle Norian; Middle to Upper Triassic) contain various proportions of siliciclastic, carbonate, phosphatic, and organic material. The uppermost unit (middle to upper Norian; Upper Triassic) is mainly shale and mudstone. Highly phosphatic strata (10–34 percent phosphorus pentoxide) are chiefly Ladinian and lower to middle Norian. Highly phosphatic Ladinian strata have been transported, are granular, and formed during transgression and early regression. In contrast, highly phosphatic Norian strata include event beds and hardgrounds, contain displaced and in situ phosphate peloids and nodules, and cap regressive parasequences. The total organic content reaches 4.97 weight percent in the main belt and is highest in muddy beds, which are found mainly in the lower parts of the three middle units. Distal sections of the Shublik are typically finer grained, more organic-rich (total organic content as high as 6.33 weight percent), and less fossiliferous than those in the main belt. Both temporal and spatial factors shaped facies in the Shublik Formation. Shublik strata accumulated at a time of reduced tectonic activity in Arctic Alaska, resulting in diminished siliciclastic input. Marine upwelling along the northwestern Laurentian margin facilitated the development of heterozoan carbonates, as well as local concentrations of phosphatic and organic matter. Large- and small-scale eustatic cycles also affected this margin and provided further controls on Shublik facies distribution.

Alaska↗
USGS2024

Arctic Alaska deepwater organic carbon burial and environmental changes during the late Albian–early Campanian (103–82 Ma)

The middle Cretaceous greenhouse period experienced profound environmental change including episodes of enhanced global burial of organic carbon marked by carbon isotopic excursions (CIEs). However, the role and response of polar regions like the newly formed, partially enclosed Arctic Ocean Basin during middle Cretaceous carbon burial remains enigmatic. We present the first Arctic deepwater CIE record that characterizes conditions offshore of the Alaska margin north of 75°N paleolatitude. Organic carbon isotopes (δ 13 C org ) and 103–82 Ma ash zircon U-Pb dates from the distal Hue Shale record multiple Albian–Campanian CIEs during slow ∼3–15 m/Myr sediment accumulation rates. Average total organic carbon (TOC) increased substantially during large 2–3 ‰ CIEs of the ∼101 Ma Albian-Cenomanian boundary event (from 7 to 18 % TOC) and ∼94 Ma Cenomanian-Turonian boundary event (5 to 10 % TOC). Turonian TOC remained elevated (8–13 %) during high global sea levels and temperatures of the Cretaceous Thermal Maximum, followed by an increase from 7 to 11 % TOC during the ∼90 Ma late Turonian event 1.5 ‰ CIE. Average TOC subsequently decreased in the Coniacian–Campanian, but relative maxima occurred during subtle 0.5–1 ‰ CIEs interpreted as the ∼87 Ma late Coniacian event (increase from 4 to 7 % TOC), ∼85 Ma Horseshoe Bay event (3.5 to 4.5 % TOC), and ∼84 Ma Santonian-Campanian boundary event (3.5 to 5 % TOC). Increases in hydrogen index and productivity proxies (P, Ba, Nd) that accompanied each CIE episode with enhanced TOC suggest a strong link between marine productivity and organic carbon burial at short-term CIE timescales. However, long-term (>5–8 Myr) changes in trace metal redox (Mo, Fe, V) and salinity (B/Ga) proxies suggest shifts in prevailing environmental conditions at timescales longer than the CIEs. Late Albian–middle Turonian marine salinity occurred during euxinic (103–98 Ma) and suboxic (98–90 Ma) conditions with deposition interpreted to have occurred within and beneath an oxygen minimum zone, respectively. In contrast, late Turonian–early Campanian (90–82 Ma) freshening and restricted euxinic basin conditions may signal the start of widespread restriction known to characterize the Paleogene Arctic. Overall, these results highlight that middle Cretaceous Arctic deepwater remained a productive marine carbon sink coupled to the global carbon cycle despite evolving Arctic greenhouse conditions.

Alaska↗
USGS2022

Ordovician geology of Alaska

Ordovician rocks, found in northern, east-central, interior and southern Alaska, formed in a variety of depositional and palaeogeographic settings. Shallow- and deep-water strata deposited along the northwestern Laurentian margin occur in east-central Alaska (Yukon River area) and probably correlative rocks crop out to the north in the Porcupine River area. Ordovician strata elsewhere in Alaska are parts of continental or island arc fragments that, as indicated by faunal and detrital zircon data, have been variously displaced. In northern Alaska, Ordovician rocks are included in the Arctic Alaska–Chukotka Microplate (AACM), a composite tectonic entity with a complex history. Some Ordovician strata in the AACM (parts of the North Slope subterrane) represent displaced fragments of the northern Laurentian margin. Coeval strata in southwestern parts of the AACM (York and Seward terranes, Hammond subterrane) share distinctive lithologic and biotic features with Ordovician rocks in interior Alaska (Farewell and related terranes). Ordovician strata in southeastern Alaska (Alexander terrane) also likely compose a composite crustal fragment that accumulated in a complex arc system. Shared features between many of these units suggest similar origins as part of one or more crustal fragments situated in the palaeo-Arctic between Laurentia, Baltica and Siberia during early Paleozoic time.

Alaska↗
USGS2022

Detrital zircon ages from upper Paleozoic–Triassic clastic strata on St. Lawrence Island, Alaska: An enigmatic component of the Arctic Alaska–Chukotka microplate

New lithologic and detrital zircon (DZ) U-Pb data from Devonian–Triassic strata on St. Lawrence Island in the Bering Sea and from the western Brooks Range of Alaska suggest affinities between these two areas. The Brooks Range constitutes part of the Arctic Alaska–Chukotka microplate, but the tectonic and paleogeographic affinities of St. Lawrence Island are unknown or at best speculative. Strata on St. Lawrence Island form a Devonian–Triassic carbonate succession and a Mississippian(?)–Triassic clastic succession that are subdivided according to three distinctive DZ age distributions. The Devonian–Triassic carbonate succession has Mississippian-age quartz arenite beds with Silurian, Cambrian, Neoproterozoic, and Mesoproterozoic DZ age modes, and it exhibits similar age distributions and lithologic and biostratigraphic characteristics as Mississippian-age Utukok Formation strata in the Kelly River allochthon of the western Brooks Range. Consistent late Neoproterozoic, Cambrian, and Silurian ages in each of the Mississippian-age units suggest efficient mixing of the DZ prior to deposition, and derivation from strata exposed by the pre-Mississippian unconformity and/or Endicott Group strata that postdate the unconformity. The Mississippian(?)–Triassic clastic succession is subdivided into feldspathic and graywacke subunits. The feldspathic subunit has a unimodal DZ age mode at 2.06 Ga, identical to Nuka Formation strata in the Nuka Ridge allochthon of the western Brooks Range, and it records a distinctive depositional episode related to late Paleozoic juxtaposition of a Paleoproterozoic terrane along the most distal parts of the Arctic Alaska–Chukotka microplate. The graywacke subunit has Triassic maximum depositional ages and abundant late Paleozoic grains, likely sourced from fringing arcs and/or continent-scale paleorivers draining Eurasia, and it has similar age distributions to Triassic strata from the Lisburne Peninsula (northwestern Alaska), Chukotka and Wrangel Island (eastern Russia), and the northern Sverdrup Basin (Canadian Arctic), but, unlike the Devonian–Triassic carbonate succession and feldspathic subunit of the Mississippian(?)–Triassic clastic succession, it has no obvious analogue in the western Brooks Range allochthon stack. These correlations establish St. Lawrence Island as conclusively belonging to the Arctic Alaska–Chukotka microplate, thus enhancing our understanding of the circum-Arctic region in late Paleozoic–Triassic time.

Alaska↗
USGS2022

Biosiliceous, organic-rich, and phosphatic facies of Triassic strata of northwest Alaska: Transect across a high-latitude, low-angle continental margin

The Shublik Formation (Middle and Upper Triassic) is a mixed siliciclastic-carbonate-phosphatic unit in northern Alaska. It generated oil found in Prudhoe Bay and other accumulations and is a prospective self-sourced resource play on Alaska’s North Slope. Its distal, deeper-water equivalent—the Otuk Formation—consists largely of radiolarian chert, mudstone, and limestone and contains potential gas accumulations in the Brooks Range foothills to the south. New petrographic, fossil, geochemical, spectral gamma-ray, and zircon U-Pb data yield insights into facies changes in these units, which were deposited across a shallowly dipping shelf margin in a high-latitude setting. Samples come from four localities along a transect that extends ~410 km from present-day northeast (proximal) to southwest (distal) in northwest Alaska. Proximal Shublik facies (Brontosaurus 1 well) contain abundant siliciclastic detritus and local phosphate. Shublik-Otuk transitional facies occur in the probable onshore extension of the Hanna Trough (Surprise Creek); new zircon U-Pb data indicate an early Norian age for a bentonite bed in this section. Distal Otuk facies (Red Dog district, Cape Lisburne) are fine grained, biosiliceous, and organic rich. New detrital zircon U-Pb data from a distinctive sandstone member in the Otuk Formation at Cape Lisburne reinforce previous interpretations of a provenance to the present-day northwest and indicate a protracted history of Triassic magmatism for this source area. Triassic facies patterns in northwestern Alaska were shaped by sea-level change, climate, and regional tectonism. Organic-rich facies developed best at times (Ladinian–middle Norian) and/or in settings (distal shelf, Hanna Trough) with minimal dilution of organic matter by other detritus.

Alaska↗
USGS2021

The Sedimentary Geochemistry and Paleoenvironments Project

Geobiology explores how Earth's system has changed over the course of geologic history and how living organisms on this planet are impacted by or are indeed causing these changes. For decades, geologists, paleontologists, and geochemists have generated data to investigate these topics. Foundational efforts in sedimentary geochemistry utilized spreadsheets for data storage and analysis, suitable for several thousand samples, but not practical or scalable for larger, more complex datasets. As results have accumulated, researchers have increasingly gravitated toward larger compilations and statistical tools. New data frameworks have become necessary to handle larger sample sets and encourage more sophisticated or even standardized statistical analyses.

Geobiology↗
USGS2021

Diagenetic barite-pyrite-wurtzite formation and redox signatures in Triassic mudstone, Brooks Range, northern Alaska

Mineralogical and geochemical studies of interbedded black and gray mudstones in the Triassic part of the Triassic-Jurassic Otuk Formation (northern Alaska) document locally abundant barite and pyrite plus diverse redox signatures. These strata, deposited in an outer shelf setting at paleolatitudes of ~45 to 60°N, show widespread sedimentological evidence for bioturbation. Barite occurs preferentially in black mudstones (TOC = 0.93–6.46 wt%), forming displacive euhedral crystals with pyrite inclusions and rims, and late albite inclusions or intergrowths. Pyrite also occurs as small (3–20 μm) framboids, discontinuous laminae, euhedral and anhedral crystals, and replacements of barite and fossils (mainly radiolarians). Paragenetically early wurtzite is present as clusters of very small (1–3 μm) aggregates of radiating crystals 0.5 to 1.0 μm long with cores of organic matter that overgrow framboidal pyrite; later wurtzite forms 10- to 30-μm bladed crystals. Equant grains (3–30 μm) and small (20 μm) angular clusters of zinc sulfide that include <1-μm-long, comb-like structures are sphalerite or wurtzite, or both. Minor siderite forms euhedral crystals intergrown with albite that enclose wurtzite and barite. Illite shows intergrowths with sphalerite; rare K-feldspar is intergrown with barite. Formation of these minerals and assemblages is attributed to early diagenetic processes. Whole-rock geochemical data for 15 samples show large ranges in redox proxies including Post Archean Average Shale (PAAS)-normalized enrichment factors (EFs) for V, U, Mo, and Re, and Al-normalized ratios for V, U, and Mo. Results for most black mudstones, with or without abundant barite and/or pyrite, suggest deposition within an oxygen minimum zone. Cerium anomalies, PAAS-normalized and calculated on a detrital-free basis, range widely from 0.49 to 0.96 and may reflect diagenetic overprinting by Ce-depleted fluids. Considering data for both black and gray mudstones, the overall geochemical pattern together with evidence from pyrite framboid sizes suggest that redox conditions fluctuated greatly from euxinic to oxic, like the redox profiles reported for modern shelf sediments offshore Peru and Namibia. The euxinic redox signatures in some Otuk black mudstones may correlate with widespread Early to Middle Triassic ocean anoxic events proposed for other regions. Calculations of median EFs for trace elements in Otuk black mudstones reveal both enrichments and depletions. Normalizations to the median composition of the three least-mineralized black mudstones show that barite- and/or pyrite-rich samples display large (>50%) positive changes for Li (+80.4%), V (+75.6%), Sr (+75.9%), Ba (+790%), Cu (+92.1%), Ni (+169%), Ag (+156%), Au (+3091%), As (+109%), Sb (+476%), and Se (+205%); Zn shows a moderate positive change of +42.1%. Moderate negative changes are evident only for Ge (−47.2%) and W (−30.6%). The local enrichments may reflect one or more factors including redox variations in bottom waters and pore fluids, element mobility during diagenesis, and selective fractionation into minerals such as barite, pyrite, and wurtzite. Anomalously low U/Al and UEF values, compared to those for other modern and ancient organic-rich sediments and sedimentary rocks, are attributed to increased solubility and loss of U during bioturbation-related oxygenation in the subsurface. Physicochemical constraints on barite, pyrite, and wurtzite formation are informed by use of a pH-fO2 plot constructed at 10 °C. Based on paragenetic evidence for multistage deposition of these three minerals, together with the presence of illite intergrown with ZnS and K-feldspar with barite, proposed diagenetic trends involve an increase in pH and fO2 related to the ingress of sulfate-rich pore fluids during bioturbation, followed by a return to lower then higher pH and fO2 conditions linked to carbon, sulfur, barium, and iron cycling during diagenesis. Labile Ba of marine pelagic origin was mobilized from organic-rich sediment upward to the sulfate-methane transition zone where barite precipitated during the interaction of reduced Ba- and CH4-rich fluids with sulfate-bearing pore fluids. The formation of paragenetically early wurtzite (ZnS) crystals, as well as locally high EF values for Cu, Ni, Ag, and Au, is attributed to metal enrichment of pore fluids, with sources being derived in part from water-column deposition from hydrothermal plumes related to coeval Triassic seafloor vent systems including a volcanogenic massive sulfide deposit in British Columbia and the Wrangellia Large Igneous Province in Alaska.

Alaska↗
USGS2020

Surface to subsurface correlation of the Middle-Upper Triassic Shublik Formation within a revised sequence stratigraphic framework

Recent work on cores and outcrops of the Middle-Upper Triassic Shublik Formation has facilitated surface to subsurface correlation of depositional sequences across the Alaska North Slope. Five transgressive-regressive depositional sequences have been defined within three large-scale stratigraphic units. Outcrop spectral gamma-ray (GR) profiles were used to correlate observed stacking patterns with nearby exploration wells, and GR logs from 161 exploration wells were used to correlate the three large-scale stratigraphic units across the North Slope and nearby offshore. Interpretations of depositional facies and sequence stratigraphy in cores from 26 wells were used to corroborate regional correlations. Isochore maps constructed for each of the three stratigraphic units illustrate the influence of accommodation on depositional patterns and suggest reactivation of several older tectonic elements during Shublik deposition. An isochore map of the richest, oil-prone interval of the Shublik Formation reveals a thick pod south of Harrison Bay, the eastern part of which lies beneath a recent giant Shublik-sourced oil discovery in the Cretaceous Nanushuk Formation. In addition, when integrated with thermal maturity, this isochore map may provide leads for areas that are optimal for unconventional resource exploration.

Alaska↗
USGS2019

Integration of microfacies analysis, inorganic geochemical data, and hyperspectral imaging to unravel mudstone depositional and diagenetic processes in two cores from the Triassic Shublik Formation, Northern Alaska

The Middle – Upper Triassic Shublik Formation is an organic-rich heterogeneous carbonate-siliciclastic-phosphatic unit that generated much of the oil in the Prudhoe Bay field and other hydrocarbon accumulations in northern Alaska. A large dataset, including total organic carbon (TOC), X-ray diffraction (XRD), X-ray fluorescence (XRF) and inductively coupled plasma – mass spectrometry (ICP-MS) measurements, has been built from core and outcrop samples of the Shublik, with a focus on the organic-rich intervals. In addition, two core intervals from the Shublik were analyzed using a hyperspectral imaging system in the visible, near-infrared and shortwave-infrared range. Integration of the hyperspectral results with core descriptions, microfacies interpretations, and analytical data is being used to decipher mudstone depositional and diagenetic processes. Petrographic analysis of Upper Triassic organic-rich intervals within the Shublik suggests that the main microfacies is a laminated bioclastic wackestone/packstone that was episodically disrupted by energetic events of variable intensity. These energetic events produced transitional and sparry calcite bioclastic packstone to grainstone intervals, depending on the depth of sediment column disturbance. By using hyperspectral imaging data from the Ikpikpuk core, individual distribution maps for minerals of interest have been generated and corroborate the microfacies interpretations. These maps also illustrate small-scale vertical changes in mineralogy. The laminated bioclastic wackestone/packstone intervals contain less calcite than the adjacent sparry bioclastic packstone to grainstone intervals. The calcite in these laminated intervals is more iron rich. This interpretation suggests that lower iron concentrations should be expected in the disrupted intervals than in nearby laminated intervals. Textural features are also enhanced in the hyperspectral images relative to visual description of the cores by combining the extraction of the average reflectance in the visible part of the electromagnetic spectrum and the depth of the main carbonate-related feature belonging to calcite. Examples noted in the enhanced imagery include low-angle features, calcite grain-size, and the size, shape and orientation of phosphatic nodules. This enhancement is being used to differentiate laminated from sparry bioclastic packstone to grainstone-rich intervals and provides a more comprehensive assessment of the microfacies than is practical by thin-section analysis.

Alaska↗
USGS2019

Element cycling in the Middle-Late Triassic Shublik Formation: Mineralization vs. recycling of biolimiting nutrients in an unconventional resource play

The Triassic Shublik Formation in northern Alaska is one of the major source rocks in North America, having generated much of the petroleum in Prudhoe Bay and associated fields. The middle Shublik Formation, the focus of this study, is a highly phosphatic, organic-rich carbonate mudstone interval. Apatite cements can occur as phosphatic peloids, steinkerns, elongate or angular nodules, and shells or shell fragments. We propose a model whereby phosphatization is favored in early diagenetic environments that have low concentrations of dissolved iron relative to reactive organic matter in the pore water sulfate reduction zone.

Alaska↗
USGS2018

U-Pb geochronology and tectonic implications of a Silurian ash in the Farewell Terrane, Alaska

The Farewell terrane is an exotic continental fragment in interior Alaska that during the early Paleozoic was the site of a passive margin. We report a 238 U/ 206 Pb zircon age of 432.9±3.0 Ma from a Farewell terrane ash in Mt. McKinley quadrangle, Alaska. This age overlaps with prominent detrital zircon age maxima reported from Silurian and Devonian strata from the Farewell, Arctic Alaska-Chukotka, White Mountains, Alexander, and Yreka terranes, and from parautochtonous Silurian and Devonian foreland-basin strata along the Laurentian margin in the Canadian Arctic and Alaska. These findings can be explained in terms of refinements to the extrusion model of Colpron and Nelson (2011). In the original model, the Farewell terrane was interpreted as having been extruded westward into the paleo-Pacific realm from an initial position along the Siberian margin of the Uralian seaway, that is, the early Paleozoic ocean between Siberia and Baltica. We suggest (1) that the Farewell terrane was deposited along a passive margin that faced into the Uralian seaway; (2) that the terrane more likely originated along the northern or eastern margin of Baltica (present directions), rather than Siberia; and (3) that the Silurian ash and Silurian detrital zircons were derived from a magmatic source along a convergent margin that overrode distal parts of the Farewell passive margin during the Late Ordovician and Silurian. The Farewell terrane was eventually dislodged from Baltica, began to travel with the extruding plate, and was conveyed toward the Pacific to its eventual resting place in Alaska.

Alaska↗
USGS2018

Sulfur isotopes of host strata for Howards Pass (Yukon–Northwest Territories) Zn-Pb deposits implicate anaerobic oxidation of methane, not basin stagnation

A new sulfur isotope stratigraphic profile has been developed for Ordovician-Silurian mudstones that host the Howards Pass Zn-Pb deposits (Canada) in an attempt to reconcile the traditional model of a stagnant euxinic basin setting with new contradictory findings. Our analyses of pyrite confirm the up-section 34 S enrichment reported previously, but additional observations show parallel depletion of carbonate 13 C, an increase in organic carbon weight percent, and a change in pyrite morphology. Taken together, the data suggest that the 34 S enrichment reflects a transition in the mechanism of pyrite formation during diagenesis, not isotopic evolution of a stagnant water mass. Low in the stratigraphic section, pyrite formed mainly in the sulfate reduction zone in association with organic matter–driven bacterial sulfate reduction. In contrast, starting just below the Zn-Pb mineralized horizon, pyrite formed increasingly within the sulfate-methane transition zone in association with anaerobic oxidation of methane. Our new insights on diagenesis have implications for (1) the setting of Zn-Pb ore formation, (2) the reliability of redox proxies involving metals, and (3) the source of ore sulfur for Howards Pass, and potentially for other stratiform Zn-Pb deposits contained in carbonaceous strata.

Northwest Territories, Yukon↗
USGS2018

The Mystic subterrane (partly) demystified: New data from the Farewell terrane and adjacent rocks, interior Alaska

The youngest part of the Farewell terrane in interior Alaska (USA) is the enigmatic Devonian–Cretaceous Mystic subterrane. New U-Pb detrital zircon, fossil, geochemical, neodymium isotopic, and petrographic data illuminate the origin of the rocks of this subterrane. The Devonian–Permian Sheep Creek Formation yielded youngest detrital zircons of Devonian age, major detrital zircon age probability peaks between ca. 460 and 405 Ma, and overall age spectra like those from the underlying Dillinger subterrane. Samples are sandstones rich in sedimentary lithic clasts, and differ from approximately coeval strata to the east that have abundant volcanic lithic clasts and late Paleozoic detrital zircons. The Permian Mount Dall conglomerate has mainly carbonate and chert clasts and yielded youngest detrital zircons of latest Pennsylvanian age. Permian quartz-carbonate sandstone in the northern Farewell terrane yielded abundant middle to late Permian detrital zircons. Late Triassic–Early Jurassic mafic igneous rocks occur in the central and eastern Mystic subterrane. New whole-rock geochemical and isotopic data indicate that magmas were rift related and derived from subcontinental mantle. Triassic and Jurassic strata have detrital zircon age spectra much like those of the Sheep Creek Formation, with major age populations between ca. 430 and 410 Ma. These rocks include conglomerate with clasts of carbonate ± chert and youngest detrital zircons of Late Triassic age and quartz-carbonate sandstone with youngest detrital zircons of Early Jurassic age. Lithofacies indicating highly productive oceanographic conditions (upwelling?) bracket the main part of the Mystic succession: Upper Devonian bedded barite and phosphatic Upper Devonian and Lower Jurassic rocks. The youngest part of the Mystic subterrane consists of Lower Cretaceous (Valanginian–Aptian) limestone, calcareous sandstone, and related strata. These rocks are partly coeval with the oldest parts of the Kahiltna assemblage, an overlap succession exposed along the southern margin of the Farewell terrane. Our findings support previous models suggesting that the Farewell terrane was proximal to the Alexander-Wrangellia-Peninsular composite terrane during the late Paleozoic, and further suggest that such proximity continued into (or recurred during) the Late Triassic–Early Jurassic. But middle to late Permian detrital zircons in northern Farewell require another source; the Yukon-Tanana terrane is one possibility.

Alaska↗
USGS2018

Neoproterozoic–early Paleozoic provenance evolution of sedimentary rocks in and adjacent to the Farewell terrane (interior Alaska)

New detrital zircon U-Pb data from the Farewell terrane of interior Alaska illuminate its early provenance evolution and connections with other Alaskan terranes. Five samples come from Neoproterozoic units in the central Farewell terrane. Basal “ferruginous beds” and the overlying Windy Fork Formation have prominent detrital zircon age populations between 2000 and 1800 Ma, with the Windy Fork Formation also having major age peaks between 700 and 600 Ma. Younger (Lone Formation) samples yield grains mainly between 750 and 550 Ma, with fewer older Proterozoic grains. Eleven samples come from deep-water early Paleozoic rocks (southeastern Farewell terrane). Ordovician sandstone (Post River Formation) has a major age population at ca. 490 Ma and subordinate 785–550 Ma populations that overlap age peaks in the Lone Formation. Turbidites in the overlying Terra Cotta Mountains Sandstone (Silurian) yield distinctly different spectra, with major ca. 450–420 Ma age populations and numerous grains between 2000 and 900 Ma. Devonian Barren Ridge Limestone samples have spectra like those of the Terra Cotta Mountains Sandstone, plus some Early Devonian grains. The Silurian shift in detrital zircon age spectra coincides with a major influx of siliciclastic sediment suggestive of a tectonic (collisional?) event involving the Farewell terrane. Neoproterozoic through Devonian successions in the Arctic Alaska–Chukotka and Alexander terranes show a similar up-section shift in detrital zircon spectra, supporting links between these terranes and the Farewell terrane during the early Paleozoic. Detrital zircon ages from the White Mountains and Livengood terranes, adjacent to the northern Farewell terrane, include major early Paleozoic populations that overlap those seen in partly coeval Farewell strata.

Alaska↗