Selection procedure and salient information for volatile organic compounds emphasized in the National Water-Quality Assessment Program
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Open-File Report↗
Geology topics
John S. Zogorski
Publications and source records attributed to John S. Zogorski.
Pesticides and volatile organic compounds in shallow urban groundwater of the United States
The widespread use of pesticides and volatile organic compounds (VOCs) over the past half century has led to their detection in many hydrologic systems in the United States. However, few systematic investigations of occurrences have been carried out over multistate regions using a consistent study design. Nine urban studies of shallow groundwater have been conducted to date as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Pesticide compounds were detected in 48.6% of the 208 urban wells sampled. Sixteen different pesticide compounds were detected in samples from these wells. Prometon was by far the most frequently detected pesticide compound, being found in 8 of the 9 urban studies. VOCs were detected in 53.4% of the 208 urban wells sampled, with 36 different VOC compounds being found. Measured VOC concentrations exceeded current U.S. Environmental Protection Agency drinking water regulations in 19 wells. Methyl tert -butyl ether (MTBE), a common fuel oxygenate, was the most frequently detected VOC for this study.
Book chapter↗
Environmental behavior and fate of methyl tert-butyl ether (MTBE)
When gasoline that has been oxygenated with methyl tert-butyl ether (MTBE) comes in contact with water, large amounts of MTBE can dissolve; at 25 degrees Celsius the water solubility of MTBE is about 5,000 milligrams per liter for a gasoline that is 10 percent MTBE by weight. In contrast, for a nonoxygenated gasoline, the total hydrocarbon solubility in water is typically about 120 milligrams per liter. MTBE sorbs only weakly to soil and aquifer materials; therefore, sorption will not significantly retard MTBE's transport by ground water. In addition, MTBE generally resists degradation in ground water. The half-life of MTBE in the atmosphere can be as short as 3 days in a regional airshed. MTBE in the air tends to partition into atmospheric water, including precipitation. However, washout of gas-phase MTBE by precipitation would not, by itself, greatly alter the gas-phase concentration of the compound in the air. The partitioning of MTBE to precipitation is nevertheless strong enough to allow for up to 3 micrograms per liter or more inputs of MTBE to surface and ground water.
Fact Sheet↗
Occurrence of the gasoline oxygenate MTBE and BTEX compounds in urban stormwater in the United States, 1991-95
Methyl tert -butyl ether (MTBE) is a gasoline oxygenate. Oxygenates such as MTBE, when added to gasoline, increase the gasoline's oxygen level and decrease vehicular carbon monoxide emissions and ozone levels in the atmosphere. MTBE disperses rapidly in water, was the second most frequently detected volatile organic compound (VOC) in a study of shallow urban ground water, and is less biodegradable than common gasoline compounds, such as benzene, toluene, ethylbenzene, and total xylene (BTEX). Urban Stormwater is a possible source of MTBE found in shallow ground water. The U.S. Geological Survey (USGS) sampled stormwater in 16 cities and metropolitan areas that are required to obtain permits to discharge Stormwater from their municipal storm-sewer system into surface water. Concentrations of 62 VOCs, including MTBE and BTEX compounds, were measured in 592 Stormwater samples collected in these cities and metropolitan areas from 1991 through 1995. Concentration data for MTBE and BTEX compounds in stormwater were compiled and analyzed, and the findings are summarized in this report. This effort was part of an interagency assessment of the scientific basis and effectiveness of the Nation's oxygenated fuel program and was coordinated by the Office of Science and Technology Policy, Executive Office of the President. MTBE was the seventh most frequently detected VOC in urban Stormwater, following toluene, total xylene, chloroform, total trimethylbenzene, tetrachloroethene, and naphthalene. MTBE was detected in 6.9 percent (41 of 592) of Stormwater samples collected. When detected, concentrations of MTBE ranged from 0.2 to 8.7 micrograms per liter (µg/L), with a median of 1.5 µg/L. All detections of MTBE were less than the lower limit of the U.S. Environmental Protection Agency (EPA) draft lifetime health advisory (20 µg/L) for drinking water. Eighty-three percent of all detections of MTBE in Stormwater were in samples collected during the October through March season of each year (1991-95), which corresponds with the expected seasonal use of oxygenated gasoline in areas where carbon monoxide exceeds established air-quality standards. The median concentration of MTBE and benzene for all samples was statistically different and higher in samples collected during the October through March season than samples collected during the April through September season. Sixty-six percent of all MTBE detections occurred with BTEX compounds, and a proportionate increase in concentrations was found when these compounds occurred together. The proportionate increase could indicate a common source of MTBE and BTEX for those samples. Toluene and total xylene were the most frequently detected BTEX compounds and the most frequently detected VOCs in these investigations. Detected concentrations of toluene and total xylene ranged from 0.2 to 6.6 µg/L and 0.2 to 15 µg/L with median concentrations of 0.3 and 0.4 iig/L, respectively
Water-Resources Investigations Report↗
Sources and summaries of water-quality information for the Rapid Creek basin, western South Dakota
This report provides a compilation of water quality information for the Rapid Creek basin in western South Dakota. Two types of information are included: First, past and current water quality monitoring data collected by the South Dakota Department of Water and Natural Resources, U.S. Forest Service, U.S. Geological Survey, and others are described. Second, a summary is included for all past water quality reports, publications, and theses that could be located during this study. A total of 62 documents were abstracted and included journal articles, abstracts, Federal agency reports and publications, university and State agency reports, local agency reports, and graduate theses. The report should be valuable to water resources managers, regulators, and others contemplating water quality research, monitoring, and regulatory programs in the Rapid Creek basin. (USGS)
Open-File Report↗
Basin characteristics, history of stream gaging, and statistical summary of selected streamflow records for the Rapid Creek basin, western South Dakota
The report presents a summary of basin characteristics affecting streamflow, a history of the U.S. Geological Survey 's stream-gaging program, and a compilation of discharge records and statistical summaries for selected sites within the Rapid Creek basin. It is the first in a series which will investigate surface-water/groundwater relations along Rapid Creek. The summary of basin characteristics includes descriptions of the geology and hydrogeology, physiography and climate, land use and vegetation, reservoirs, and water use within the basin. A recounting of the U.S. Geological Survey 's stream-gaging program and a tabulation of historic stream-gaging stations within the basin are furnished. A compilation of monthly and annual mean discharge values for nine currently operated, long-term, continuous-record, streamflow-gaging stations on Rapid Creek is presented. The statistical summary for each site includes summary statistics on monthly and annual mean values, correlation matrix for monthly values, serial correlation for 1 year lag for monthly values, percentile rankings for monthly and annual mean values, low and high value tables, duration curves, and peak-discharge tables. Records of monthend contents for two reservoirs within the basin also are presented. (USGS)
Open-File Report↗
Availability and suitability of municipal wastewater information for use in a National Water-Quality Assessment; a case study of the upper Illinois River basin in Illinois, Indiana, and Wisconsin
The availability and suitability of existing information on municipal wastewater-treatment practices and effluent characteristics for use in a national water-quality assessment were evaluated. The information will be used to determine the effects of changes in wastewater-treatment practices on stream quality and ecosystem health. A large amount of information on treatment practices and effluent characteristics exists, and some of this information is available from Federal and State computer data bases. However, the suitability of existing information to accomplish the objectives of a national water-quality assessment is limited. The suitability of this information would be improved by (1) increasing the number of water-quality constituents routinely analyzed for in samples of municipal effluent, (2) increasing the frequency of effluent sampling at some facilities, (3) developing a quality-assurance plan for wastewater flow-rate determinates, and (4) increasing the amount of effluent water-quality data entered into Federal and State computer data bases.
Open-File Report↗
Hydrologic evaluation of a hypothetical coal-mining site near Chrisney, Spencer County, Indiana
Protecting the water resources of the Nation is a major emphasis of the Surface Mining Control and Reclamation Act, PL 95-87. Permanent regulations established for this Act by the Office of Surface Mining (OSM) require the issuance of a permit before mining begins. An application for a mining permit must include an assessment of the hydrologic characteristics of the mining site and adjacent area, and a projection of the potential impacts of mining activities on surface water and ground water. OSM's permanent regulations and guidelines provide little insight on the "how to" aspect of making the required hydrologic assessment. This investigation was completed to improve the understanding of the kinds of information needed to make such assessments by: (a) reviewing the regulations to determine what hydrologic information is required; (b) preparing an example hydrologic assessment based on the regulations; and (c) using the experience gained in (a) and (b) to identify areas lacking or needing additional data to make the required assessment. Hydrologic data for the study area were obtained from published and unpublished reports, maps, aerial photographs, personal interviews with residents in the area of the hypothetical mine site, and discussions with experts in the field. Where data were unavailable, "synthetic" data were generated by extrapolation from proximate or similar watersheds and (or) by assumptions based on experience or theory. Some field data were collected to corroborate and augment information originating from all these sources.
Indiana↗
Water temperatures of Kentucky
The U.S. Geological Survey in cooperation with the Kentucky Geological Survey has been gathering temperature data on streams throughout Kentucky under a number of different programs for several decades. Periodic water temperature observations, which were made at a frequency of approximately once per month during the past 15 years, were analyzed with the aid of a computer program to describe the annual water temperature cycle at sites in the Commonwealth. Shown on a map of Kentucky, at each site of water-temperature collections, are maximum median monthly temperature, minimum median monthly temperature, and annual average temperature. Stream temperatures in Kentucky vary between 0 and 30 degrees Celsius (deg C) during the year. Maximum median monthly water temperatures occur in July and are typically between 23 and 27 deg C, whereas minimum median monthly water temperatures are recorded in January and are useually within the 2 to 6 deg C range. Annual average water temperatures are between 10 and 18 deg C. (Woodard-USGS)
Kentucky↗
Velocity and depth measurements for use in computation of reaeration coefficients
Empirical computation of reaeration coefficients generally requires knowledge of mean velocity and mean depth of a stream. A practical method for obtaining this knowledge is described herein. The method involves time-of-travel, streamflow, and cross-sectional measurements, the development of discharge-velocity curves, streamflow profiles, and the computation of cross-sectional areas. Values for mean velocity and mean depth are determined and related to mean discharge.
Open-File Report↗