Geology topics

John Crusius

Publications and source records attributed to John Crusius.

41 records · Page 3Linked to original sources

USGS2004

Influence of northwest Pacific productivity on North Pacific Intermediate Water oxygen concentrations during the Bølling-Ållerød interval (14.7-12.9 ka)

Elevated productivity in the northwest Pacific is suggested as a new possible control driving past intervals of low-O 2 intermediate water along the western continental margin of North America. According to this mechanism, O 2 consumption would occur near the site of formation of North Pacific Intermediate Water (NPIW), due to increased respiration of organic carbon in response to a high-productivity event. Evidence is provided for such a productivity increase during the Bølling-Ållerød interval (14.7–12.9 ka), a time when laminated sediments were deposited along the northern California margin. By this mechanism, low-O 2 events in intermediate waters off the western North American margin could occur without significant changes in the rate of NPIW ventilation.

Geology↗

USGS2003

Post-Depositional Behavior of Cu in a Metal-Mining Polishing Pond (East Lake, Canada)

The post-depositional behavior of Cu in a gold-mining polishing pond (East Lake, Canada) was assessed after mine closure by examination of porewater chemistry and mineralogy. The near-surface (upper 1.5 cm) sediments are enriched in Cu, with values ranging from 0.4 to 2 wt %. Mineralogical examination revealed that the bulk of the Cu inventory is present as authigenic copper sulfides. Optical microscopy, energy-dispersion spectra, and X-ray data indicate that the main Cu sulfide is covellite (CuS). The formation of authigenic Cu-S phases is supported by the porewater data, which demonstrate that the sediments are serving as a sink for dissolved Cu below sub-bottom depths of 1-2 cm. The zone of Cu removal is consistent with the occurrence of detectable sulfide and the consumption of sulfate. The sediments can be viewed as a passive bioreactor that permanently removes Cu as insoluble copper sulfides. This process is not unlike that which occurs in other forms of bioremediation, such as wetlands and permeable reactive barriers. Above the zone of Cu removal, dissolved Cu maxima in the interfacial porewaters range from 150 to 450 ??g L-1 and reflect the dissolution of a Cu-bearing phase in the surface sediments. The reactive phase is thought to be a component of treatment sludges delivered to the lake as part of cyanide treatment. Flux calculations indicate that the efflux of dissolved Cu from the sediments to the water column (14-51 ??g cm-2 yr-1) can account for the elevated levels of dissolved Cu in lake waters (???50 ??g L-1). Implications for lake recovery are discussed.

Environmental Science & Technology↗

USGS2003

Gas transfer velocities measured at low wind speed over a lake

The relationship between gas transfer velocity and wind speed was evaluated at low wind speeds by quantifying the rate of evasion of the deliberate tracer, SF 6 , from a small oligotrophic lake . Several possible relationships between gas transfer velocity and low wind speed were evaluated by using 1-min-averaged wind speeds as a measure of the instantaneous wind speed values. Gas transfer velocities in this data set can be estimated virtually equally well by assuming any of three widely used relationships between k 600 and winds referenced to 10-m height, U 10 : (1) a bilinear dependence with a break in the slope at ∼3.7 m s -1 , which resulted in the best fit; (2) a power dependence; and (3) a constant transfer velocity for U 10 < ∼3.7 m s -1 , with a linear dependence on wind speed at higher wind speeds. The lack of a unique relationship between transfer velocity and wind speed at low wind speeds suggests that other processes, such as convective cooling, contribute significantly to gas exchange when the wind speeds are low . All three proposed relationships clearly show a strong dependence on wind for winds >3.7 m s -1 which, coupled with the typical variability in instantaneous wind speeds observed in the field, leads to average transfer velocity estimates that are higher than those predicted for steady wind trends. The transfer velocities predicted by the bilinear steady wind relationship for U 10 < ∼3.7 m s -1 are virtually identical to the theoretical predictions for transfer across a smooth surface.

Limnology and Oceanography↗

USGS2003

Mobility of authigenic rhenium, silver, and selenium during postdepositional oxidation in marine sediments

Sedimentary records of redox-sensitive trace elements hold significant potential as indicators of paleoceanographic environmental conditions. Records of Re can reveal the intensity of past reducing conditions in sediments at the time of deposition, whereas records of Ag may record the magnitude of past diatom fluxes to the seafloor. Confidence in paleoenvironmental reconstruction from records of either metal, however, requires it to have experienced negligible redistribution since deposition. This study examines diagenetic rearrangements of Re and Ag that occur in response to exposure to bottom-water O 2 in environments of low sedimentation rate, including Madeira Abyssal Plain turbidites and eastern Mediterranean basin sapropels. Authigenic Re was remobilized quantitatively by oxidation but poorly retained by the underlying sediments. All records are consistent with previous work demonstrating that only a limited reimmobilization of Re occurs preferentially in C org -rich, reducing sediments. Silver was also mobilized quantitatively by oxidation, but it was subsequently immobilized more efficiently in all cases as sharp peaks immediately into anoxic conditions below active oxidation fronts, and these peaks remain immobile in anoxic conditions during long-term burial. Comparison of Ag, S, and Se records from various cores suggests that Ag is likely to have been immobilized as a selenide, a mechanism previously proposed for Hg in similar situations (Mercone et al., 1999) . Coexisting narrow peaks of Ag and Hg with Se offer a means of assessing whether oxidative burndown has ever occurred at the top of C org - and sulfide-rich sedimentary units. Although these results suggest that caution must be used when inferring paleoenvironmental information from records of Ag and Re in cores with low sediment accumulation rates (<5 cm ka −1 ), they should not affect the promise that authigenic Ag and Re records hold for paleoenvironmental reconstruction in sediments with higher accumulation rates and where anoxic conditions have been maintained continuously.

Geochimica et Cosmochimica Acta↗

USGS2003

Tale of two pit lakes: initial results of a three-year study of the Main Zone and Waterline pit lakes near Houston, British Columbia, Canada

Pit lakes are becoming increasingly common in North America as well as in the rest of the world. They are created as openpit mines fill passively with ground water and surface inflows on cessation of mining activity. In many instances, the water quality in these pit lakes does not meet regulatory requirements due to a number of influences. The most important are the oxidation of sulfide minerals and the associated release of acid and metals and the flushing of soluble metals during pit filling. Examples of pit lakes with severe water-quality problems include the Berkeley Pit lake (Butte, MT) and the Liberty Pit lake (Nevada), whose waters are characterized by a pH near 3 and Cu concentrations as high as ~150 mg/L (Miller et al., 1996; Davis and Eary, 1997). The importance of the problem can be seen in the fact that some of these sites in the United States are Superfund sites.

British Columbia;Texas↗