Search USGS⌕ Search

Geology topics

John A. Izbicki

Publications and source records attributed to John A. Izbicki.

At least 73 records · Page 4Linked to original sources

Inorganic, isotopic, and organic composition of high-chloride water from wells in a coastal southern California aquifer

Chloride concentrations were as high as 230 mg/L in water from the surface discharge of long-screened production wells in Pleasant Valley, Calif., about 100 km NW of Los Angeles. Wells with the higher Cl − concentrations were near faults that bound the valley. Depending on well construction, high-Cl − water from different sources may enter a well at different depths. For example, Cl − concentration in the upper part of some wells completed in overlying aquifers influenced by irrigation return were as high as 220 mg/L, and Cl − concentrations in water sampled within wells at depths greater than 450 m were as high as 500 mg/L. These high-Cl − waters mix within the well during pumping and produce the water sampled at the surface discharge. Changes in the major ion, minor ion, trace element, and δ 34 S and δ 13 C isotopic composition of water in wells with depth were consistent with changes resulting from SO 4 reduction, precipitation of calcite, and cation exchange. The chemical and isotopic composition of high-Cl − water from deep wells trends towards the composition of oil-field production water from the study area. Chloride concentrations in oil-field production water present at depths 150 m beneath freshwater aquifers were 2200 mg/L, and Cl − concentrations in underlying marine rock were as high as 4400 mg/L. High-Cl − concentrations in water from deeper parts of wells were associated with dissolved organic C composed primarily of hydrophobic neutral compounds believed to be similar to those associated with petroleum in underlying deposits. These compounds would not be apparent using traditional sampling techniques and would not be detected using analytical methods intended to measure contamination.

Applied Geochemistry↗

Evaluation of geohydrologic framework, recharge estimates and ground-water flow of the Joshua Tree area, San Bernardino County, California

Ground water historically has been the sole source of water supply for the community of Joshua Tree in the Joshua Tree ground-water subbasin of the Morongo ground-water basin in the southern Mojave Desert. The Joshua Basin Water District (JBWD) supplies water to the community from the underlying Joshua Tree ground-water subbasin. The JBWD is concerned with the long-term sustainability of the underlying aquifer. To help meet future demands, the JBWD plans to construct production wells in the adjacent Copper Mountain ground-water subbasin. As growth continues in the desert, there may be a need to import water to supplement the available ground-water resources. In order to manage the ground-water resources and to identify future mitigating measures, a thorough understanding of the ground-water system is needed. The purpose of this study was threefold: (1) improve the understanding of the geohydrologic framework of the Joshua Tree and Copper Mountain ground-water subbasins, (2) determine the distribution and quantity of recharge using field and numerical techniques, and (3) develop a ground-water flow model that can be used to help manage the water resources of the region. The geohydrologic framework was refined by collecting and interpreting water-level and water-quality data, geologic and electric logs, and gravity data. The water-bearing deposits in the Joshua Tree and Copper Mountain ground-water subbasins are Quarternary alluvial deposits and Tertiary sedimentary and volcanic deposits. The Quarternary alluvial deposits were divided into two aquifers (referred to as the 'upper' and the 'middle' alluvial aquifers), which are about 600 feet (ft) thick, and the Tertiary sedimentary and volcanic deposits were assigned to a single aquifer (referred to as the 'lower' aquifer), which is as thick as 1,500 ft. The ground-water quality of the Joshua Tree and Copper Mountain ground-water subbasins was defined by collecting 53 ground-water samples from 15 wells (10 in the Joshua Tree ground-water subbasin and 5 in the Copper Mountain ground-water subbasin) between 1980 and 2002 and analyzing the samples for major ions, nutrients, and selected trace elements. Selected samples also were analyzed for oxygen-18, deuterium, tritium, and carbon-14. The water-quality data indicated that dissolved solids and nitrate concentrations were below regulatory limits for potable water; however, fluoride concentrations in the lower aquifer exceeded regulatory limits. Arsenic concentrations and chromium concentrations were generally below regulatory limits; however, arsenic concentrations measured in water from wells perforated in the lower aquifer exceeded regulatory limits. The carbon-14 activities ranged from 2 to 72 percent modern carbon and are consistent with uncorrected ground-water ages (time since recharge) of about 32,300 to 2,700 years before present. The oxygen-18 and deuterium composition of water sampled from the upper aquifer is similar to the volume-weighted composition of present-day winter precipitation indicating that winter precipitation was the predominant source of ground-water recharge. Field studies, conducted during water years 2001 through 2003 to determine the distribution and quantity of recharge, included installation of instrumented boreholes in selected washes and at a nearby control site. Core material and cuttings from the boreholes were analyzed for physical, chemical, and hydraulic properties. Instruments installed in the boreholes were monitored to measure changes in matric potential and temperature. Borehole data were supplemented with temperature data collected from access tubes installed at additional sites along study washes. Streambed hydraulic properties and the response of instruments to infiltration were measured using infiltrometers. Physical and geochemical data collected away from the stream channels show that direct infiltration of precipitation to depths below the root zone and subsequent gro

Scientific Investigations Report↗

Comparison of ground-water flow model particle-tracking results and isotopic data in the Mojave River ground-water basin, southern California, USA

Flow-path and time-of-travel results for the Mojave River ground-water basin, southern California, calculated using the ground-water flow model MODFLOW and particle-tracking model MODPATH were similar to flow path and time-of-travel interpretations derived from delta-deuterium and carbon-14 data. Model and isotopic data both show short flow paths and young ground-water ages throughout the floodplain aquifer along most the Mojave River. Longer flow paths and older ground-water ages as great as 10,000 years before present were measured and simulated in the floodplain aquifer near the Mojave Valley. Model and isotopic data also show movement of water between the floodplain and regional aquifer and subsequent discharge of water from the river to dry lakes in some areas. It was not possible to simulate the isotopic composition of ground-water in the regional aquifer away from the front of the San Gabriel and San Bernardino Mountains - because recharge in these areas does not occur under the present-day climatic conditions used for calibration of the model.

Journal of Hydrology↗

Microbial and dissolved organic carbon characterization of stormflow in the Santa Ana River at Imperial Highway, Southern California, 1999-2002

The Santa Ana River drains about 2,670 square miles of densely populated coastal southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted to ponds where it infiltrates and recharges underlying aquifers pumped to supply water for more than 2 million people. Base flow in the river is almost entirely treated municipal wastewater discharged from upstream treatment plants and, in the past, stormflow was considered a source of high-quality water suitable for use as a source of ground-water recharge that would dilute poorer quality water recharged during base flow. Stormflow in the Santa Ana River at the Imperial Highway diversion contains total coliform bacteria concentrations as high as 3,400,000 colonies per 100 mL (milliliters). Fecal indicator bacteria concentrations, including fecal coliforms, Escherichia coli, and enterococci, were as high as 310,000, 84,000, and 102,000 colonies per 100 mL, respectively. Although concentrations were high owing to urban runoff during the first stormflow of the rainy season, the highest concentrations occurred during the recessional flows of the first stormflow of the rainy season after streamflow returned to pre-storm conditions. Molecular indicators of microbiological organisms in stormflow, including phospholipid fatty acid (PLFA) and genetic data, show that the diversity of the total microbial population decreases during stormflow while fecal indicator bacteria concentrations increase. This suggests that the source of the bacteria must be poorly diverse and dominated by only a few types of bacteria. Although direct runoff of fecal indicator bacteria from urban areas occurs, this process cannot explain the very high concentrations of fecal indicator bacteria in runoff from upstream parts of the basin characterized by urban, agricultural (including more than 300,000 head of dairy cattle), and other land uses. Although other explanations are possible, fecal indicator bacteria concentrations and molecular microbiological data indicate accumulation and extended survival of bacteria in streambed sediments, and subsequent mobilization of those sediments and associated bacteria during stormflow. Both PLFA and genetic data indicate that water from dairy-waste storage ponds was not present during sampled stormflows. This is consistent with the relatively dry conditions and the absence of large stormflows during the study. Dissolved organic carbon (DOC) concentrations in stormflow ranged from 3 to 15.3 mg/L. In general, concentrations increased during stormflow and were distributed across the stormflow hydrograph in a manner similar to that of fecal indicator bacteria. DOC concentrations typically remained high for several days after flow returned to pre-storm conditions. Ultraviolet absorbance, excitation emission spectroscopy, and sequential fractionation of DOC using XAD-8 and XAD-4 resins showed that the composition of DOC changed rapidly during stormflow. Hydrophobic and hydrophilic acids were the largest fraction of DOC composing between 27 and 45 percent and between 24 and 37 percent of the DOC, respectively. The fraction of DOC composed of hydrophobic acids decreased due to urban runoff and increased during the recession of the first stormflow of the rainy season; the hydrophilic-acid fraction generally decreased throughout the stormflow hydrograph; the transhydrophilic-acid fraction did not vary greatly during stormflow; and the hydrophobic-neutral fraction increased from low values in base flow to almost 30 percent of the DOC after more soluble and more mobile hydrophobic and hydrophilic acids were washed from urban areas. Comparison of ultraviolet absorbance data with data collected during previous studies shows that the optical properties and, presumably, the composition of the DOC were different in this study than DOC collected during wetter periods. Samples of shallow ground water collec

California↗

Source and Movement of Ground Water in the Western Part of the Mojave Desert, Southern California, USA

Delta oxygen-18 and delta deuterium composition of precipitation and water from wells in the Mojave River and the Morongo ground-water basins in the western part of the Mojave Desert show that ground-water recharge occurs primarily from winter precipitation near low-altitude passes in the San Bernardino and the San Gabriel Mountains?as opposed to runoff from higher altitudes in the mountains. The resulting deuterium composition of the ground water, about -64 per mil, contrasts sharply with the isotopic composition of water from wells recharged by runoff from higher altitudes of the San Gabriel and the San Bernardino Mountains, about -84 per mil. These differences define the 3-dimensional movement of ground water between aquifers especially downgradient from faults that act as barriers to ground-water flow. Water recharged from runoff in the mountains farther to the east in the Mojave Desert plots to the right of the meteoric water line and after accounting for evaporative effects had an isotopic composition lighter than present-day precipitation.

Water-Resources Investigations Report↗

Movement and Age of Ground Water in the Western Part of the Mojave Desert, Southern California, USA

Tritium and carbon-14 data in water from wells in the Mojave River and the Morongo ground-water basins in the western part of the Mojave Desert show recent recharge focused in the floodplain aquifer along the Mojave River. Older ground water was present in parts of the regional aquifer that surround and underlie the floodplain aquifer. Movement of water between the floodplain and the regional aquifers occurs near on the upgradient side of faults as water from the regional aquifer discharges to the floodplain aquifer and on the downgradient side of the faults where water from the floodplain aquifer recharges the regional aquifer. On the basis of carbon-14 ages, corrected for mineralogic reactions with aquifer materials, water from some wells was recharged more than 20,000 years ago. Geochemical data show ground-water recharge has gradually decreased as the climate changed since that time.

Water-Resources Investigations Report↗

Hydrogeology and geochemistry of aquifers underlying the San Lorenzo and San Leandro areas of the East Bay Plain, Alameda County, California

The East Bay Plain, on the densely populated eastern shore of San Francisco Bay, contains an upper aquifer system to depths of 250 feet below land surface and an underlying lower aquifer system to depths of more than 650 feet. Injection and recovery of imported water has been proposed for deep aquifers at two sites within the lower aquifer system. Successful operation requires that the injected water be isolated from surface sources of poor-quality water during storage and recovery. Hydraulic, geochemical, and isotopic data were used to evaluate the isolation of deeper aquifers. Ground-water responses to tidal changes in the Bay suggest that thick clay layers present within these deposits effectively isolate the deeper aquifers in the northern part of the study area from overlying surficial deposits. These data also suggest that the areal extent of the shallow and deep aquifers beneath the Bay may be limited in the northern part of the study area. Despite its apparent hydraulic isolation, the lower aquifer system may be connected to the overlying upper aquifer system through the corroded and failed casings of abandoned wells. Water-level measurements in observation wells and downward flow measured in selected wells during nonpumped conditions suggest that water may flow through wells from the upper aquifer system into the lower aquifer system during nonpumped conditions. The chemistry of water from wells in the East Bay Plain ranges from fresh to saline; salinity is greater than seawater in shallow estuarine deposits near the Bay. Water from wells completed in the lower aquifer system has higher pH, higher sodium, chloride, and manganese concentrations, and lower calcium concentrations and alkalinity than does water from wells completed in the overlying upper aquifer system. Ground-water recharge temperatures derived from noble-gas data indicate that highly focused recharge processes from infiltration of winter streamflow and more diffuse recharge processes from infiltration of precipitation occur within the study area. However, recharge of imported water from leaking water-supply pipes, believed by previous investigators to be a large source of ground-water recharge, was not supported on the basis of oxygen-18 and deuterium data collected as part of this study. Based on tritium/helium-3 ages, most water in the upper aquifer system is relatively young and was recharged after 1952; however, water in the lower aquifer system is older and does not contain detectable tritium. Carbon-14 ages interpreted for water from wells in the lower aquifer system and underlying partly consolidated rocks range from 500 to more than 20,000 years before present. The greatest ages were in water from wells completed in the partly consolidated deposits that underlie the northern part of the study area. Ground water from wells in the lower aquifer system near the proposed Bayside injection/recovery site was recharged about 9,400 years before present and appears to be isolated from surface sources of recharge and ground-water contamination.

California↗

Geologic Setting, Geohydrology, and Ground-Water Quality near the Helendale Fault in the Mojave River Basin, San Bernardino County, California

The proximity of the Mojave River ground-water basin to the highly urbanized Los Angeles region has resulted in rapid population growth and, consequently, an increase in the demand for water. The Mojave River, the primary source of surface water for the region, normally is dry--except for periods of flow after intense storms; therefore, the region relies almost entirely on ground water to meet its agricultural and municipal needs. The area where the Helendale Fault intersects the Mojave River is of particular hydrogeologic interest because of its importance as a boundary between two water-management subareas of the Mojave Water Agency. The fault is the boundary between the upper Mojave River Basin (Oeste, Alto, and Este subareas) and the lower Mojave River Basin (Centro and Baja subareas); specifically, the fault is the boundary between the Alto and the Centro subareas. To obtain the information necessary to help better understand the hydrogeology of the area near the fault, multiple-well monitoring sites were installed, the surface geology was mapped in detail, and water-level and water-quality data were collected from wells in the study area. Detailed surficial geologic maps and water-level measurements indicate that the Helendale Fault impedes the flow of ground water in the deeper regional aquifer, but not in the overlying floodplain aquifer. Other faults mapped in the area impede the flow of ground water in both aquifers. Evidence of flowing water in the Mojave River upgradient of the Helendale Fault exists in the historical record, suggesting an upward gradient of ground-water flow. However, water-level data from this study indicate that pumping upstream of the Helendale Fault has reversed the vertical gradient of ground-water flow since predevelopment conditions, and the potential now exists for water to flow downward from the floodplain aquifer to the regional aquifer. Sixty-seven ground-water samples were analyzed for major ions, nutrients, and stable isotopes of oxygen and hydrogen from 34 wells within the study area between May 1990 and November 1999. Dissolved-solids concentrations in water samples from 14 wells in the floodplain aquifer ranged from 339 to 2,330 milligrams per liter (mg/L) with a median concentration of 825 mg/L. Concentrations in water from 11 of these wells exceeded the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL) of 500 mg/L. Dissolved-solids concentrations of water from nine wells sampled in the regional aquifer ranged from 479 to 946 mg/L with a median concentration of 666 mg/L. Concentrations in at least one sample of water from each of the wells in the regional aquifer exceeded the USEPA SMCL for dissolved solids. Arsenic concentrations in water from 14 wells in the floodplain aquifer ranged from less than the detection limit of 2 micrograms per liter (?g/L) to a maximum of 34 ?g/L with a median concentration of 6 ?g/L. Concentrations in water from six of the 14 wells exceeded the USEPA Maximum Contaminant Level (MCL) for arsenic of 10 ?g/L. Arsenic concentrations in water from nine wells in the regional aquifer ranged from less than the detection limit of 2 to 130 ?g/L with a median concentration of 11 ?g/L. Concentrations in water from five of these nine wells exceeded the USEPA MCL for arsenic. Dissolved-solids concentrations in water from seven wells completed in the igneous and metamorphic basement rocks that underlie the floodplain and regional aquifers ranged from 400 to 3,190 mg/L with a median concentration of 1,410 mg/L. Concentrations in water from all but one of the seven wells sampled exceeded the USEPA SMCL for dissolved solids. Concentrations in water from the basement rocks exceeded the USEPA SMCL for arsenic of 10 ?g/L in five of the seven wells. The high concentrations of arsenic, dissolved solids, and other constituents probably occur naturally. Stable isotopes of oxygen and hydrogen indicate that before pumping began in

Water-Resources Investigations Report↗

Evaluation of unsaturated zone water fluxes in heterogeneous alluvium at a Mojave Basin Site

Vertical and horizontal water fluxes in the unsaturated zone near intermittent streams critically affect ecosystems, water supply, and contaminant transport in arid and semiarid regions. The subsurface near the Oro Grande Wash is typical in having great textural diversity, pronounced layer contrasts, and extremely low hydraulic conductivities associated with nearly dry media. These features prevent a straightforward application of the Darcian method for recharge estimation, which has provided high‐quality flux estimates at simpler, wetter sites. We have augmented the basic Darcian method with theoretical developments such that a small number of core sample unsaturated hydraulic property measurements, combined with additional, easily obtained data (e.g., drillers' logs) can provide useful flux estimates and knowledge of two‐dimensional water behavior beneath the wash.

Water Resources Research↗

Data from a thick unsaturated zone underlying Oro Grande and Sheep Creek washes in the western part of the Mojave Desert, near Victorville, San Bernardino County, California

This report presents data on the physical properties of unsaturated alluvial deposits and on the chemical and isotopic composition of soil water and soil gas collected at 12 monitoring sites in the western part of the Mojave Desert, near Victorville, California. Sites were installed using the ODEX air-hammer method. Seven sites were located in the active channels of Oro Grande and Sheep Creek Washes. The remaining five sites were located away from the active washes. Most sites were drilled to a depth of about 100 feet below land surface; two sites were drilled to the water table almost 650 feet below land surface. Drilling procedures, lithologic and geophysical data, and site construction and instrumentation are described. Core material was analyzed for water content, bulk density, water potential, particle size, and water retention. The chemical composition of leachate from almost 1,000 subsamples of cores and cuttings was determined. Water extracted from selected subsamples of cores was analyzed for tritium and the stable isotopes of oxygen and hydrogen. Water from suction-cup lysimeters and soil-gas samples also were analyzed for chemical and isotopic composition. In addition, data on the chemical and isotopic composition of bulk precipitation from five sites and on ground water from two water-table wells are reported.

California↗

Stormflow chemistry in the Santa Ana River below Prado Dam and at the diversion downstream from Imperial Highway, southern California, 1995-98

The Santa Ana River drains about 2,670 square miles of the densely populated coastal area of southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted into ponds where it infiltrates and recharges underlying aquifers. About 2 million people are dependent on these aquifers for water supply. Stormflow in the Santa Ana River is considered a source of "high-quality" water suitable for use as a source of ground-water recharge. To test this assumption, stormflow samples were collected at two locations--below Prado Dam and at the diversion point downstream from Imperial Highway--for 12 winter storms between 1995 and 1998. Nitrate concentrations decreased during stormflow from a median concentration of 7.8 milligrams per liter in base flow to concentrations less than 1 milligram per liter in some large storms. Concentrations of chemically reduced forms of nitrogen (nitrite, ammonia, and organic nitrogen) increased during stormflow and are the predominant forms of nitrogen in large stormflows. Dissolved organic carbon (DOC) concentrations increased from a median concentration of 4.6 milligrams per liter in base flow to more than 20 milligrams per liter in some stormflows. Concentrations of DOC were especially high during the first storm of the rainy season, and large increases in DOC concentrations were measured even as a result of small early season storms that did not cause large increases in streamflow. DOC present during early season stormflow had less ultraviolet absorbance at 254 nanometers (UV 254 ) per unit of carbon than did DOC from late season stormflows. DOC in water held in storage behind Prado Dam had the highest UV 254 absorbance per unit of carbon. Maximum pesticide concentrations in stormflow did not exceed U.S. Environmental Protection Agency Maximum Contaminant Levels. Most pesticide concentrations were less than 1 microgram per liter and less than the detection limits obtained using standard drinking water analyses. Increases in concentrations of pesticides such as diazinon, malathion, and chlorpyrifos in stormflow result from runoff from urban areas downstream from Prado Dam. In general, large late season stormflows have the most pesticide detections of all stormflows sampled. Concentrations of methyl tert-butyl ether (MTBE), a gasoline additive, during base flow were as high as 0.9 microgram per liter and concentrations decreased during stormflow. Like pesticides, the concentrations did not exceed the U.S. Environmental Protection Agency Maximum Contaminant Levels for MTBE.

California↗

Water resources of the Blackstone River basin, Massachusetts

By 2020, demand for water in the Blackstone River Basin is expected to be 52 million gallons per day, one-third greater than the demand of 39 million gallons per day in 1980. Most of this increase is expected to be supplied by increased withdrawals of ground water from stratified-drift aquifers in the eastern and northern parts of the basin. Increased withdrawals from stratified-drift aquifers along the Blackstone River and in the western part of the basin also are expected. The eastern and northern parts of the Blackstone River Basin contain numerous small, discontinuous aquifers which, as a group, comprise the largest ground-water resource of the study area. Fifteen aquifers, ranging in areal extent from 0.57 to 4.3 square miles, were identified. These aquifers have maximum saturated thicknesses ranging from less than 10 feet to 105 feet and maximum transmissivities ranging from less than 1,000 to more than 20,000 feet squared per day. Yields of nine study aquifers were estimated by use of digital ground-water-flow models. Yields depend on the hydraulic properties of the aquifer and the amount of streamflow available for depletion by wells. If streamflow is maintained at 98-percent duration, long-term yields from the aquifers that would be expected to be equaled or exceeded 50 percent of the time range from 0.22 to 11 million gallons per day, and long-term yields equaled or exceeded 95 percent of the time range from 0.06 to 1.0 million gallons per day. If streamflow is maintained at 99.5-percent duration, long-term yields equaled or exceeded 50 percent of the time range from 0.22 to 11 million gallons per day, long-term yields equaled or exceeded 95 percent of the time range from 0.04 to 1.4 million gallons per day, and longterm yields equaled or exceeded 98 percent of the time range from 0.02 to 0.39 million gallons per day. Maintaining streamflow at 98-percent duration is a more restrictive criterion than maintaining streamflow at 99.5-percent duration. The upper Lake Quinsigamond, upper West River, and Stone Brook aquifers are capable of sustaining withdrawals of at least 1 million gallons per day more than their rates in the mid-1980s. The upper Mill River and Auburn aquifers are not capable of sustaining additional withdrawals of 0.25 million gallons per day. Ground-water quality in the Auburn aquifer has been degraded by activities and contaminants associated with urbanization. A nearly continuous deposit of stratified drift almost 30 miles long and from 400 feet to more than 1 mile wide occupies lowland areas along the southeastern part of the Blackstone River. These deposits were divided into four aquifers ranging in areal extent from 1.8 to 3.5 square miles. These aquifers have maximum saturated thicknesses ranging from 54 to 170 feet and maximum transmissivities ranging from less than 1,500 to more than 20,000 feet squared per day. The Blackstone River receives substantial amounts of treated municipal wastewater. Infiltration of poor-quality surface water has significantly increased the specific conductance and the concentrations of all major ions, ammonia, iron, and manganese in the water pumped from at least two wells near the river. These wells derive about 41 and 48 percent of their yield from infiltrated surface water. At both sites, aquifer heterogeneity controlled the movement of infiltrated water to the wells. At one of these sites, where the flow of infiltrated water was tracked (by use of a digital model) in three dimensions, infiltrated water moved to the well through gravel layers that did not constitute the entire thickness of the aquifer. Changes in stream discharge that resulted in changes in surface-water quality also affected the quality of ground water at that site. The western part of the Blackstone River Basin contains the smallest aquifers evaluated in the study area. Six aquifers, ranging in areal extent from 0.05 to 1.3 square miles, were identified. The hydraulic properties of most of these aquifers have not been determined, but available data indicate that maximum saturated thicknesses range from 28 to 71 feet and maximum transmissivities range from 2,300 to 15,000 feet squared per day.

Massachusetts↗

U.S. Geological Survey combined well-bore flow and depth-dependent water sampler

The U.S. Geological Survey has developed a combined well-bore flow and depth-dependent sample collection tool. It is suitable for use in existing production wells having limited access and clearances as small as 1 inch. The combination of well-bore flow and depth-dependent water-quality data is especially effective in assessing changes in aquifer properties and water quality with depth. These are direct measures of changes in well yield and ground-water quality with depth under actual operating conditions. Combinations of other geophysical tools capable of making these measurements, such as vertical-axis current meters used with wire-line samplers, are commercially available but these tools are large and can not easily enter existing production wells.

Fact Sheet↗

Water-quality trends in the Santa Ana River at MWD Crossing and below Prado Dam, Riverside County, California

The Santa Ana River, located in an extensively urbanized basin, drains about 2,670 square miles near Los Angeles, California. Almost all flow in the river, about 200,000 acre-feet annually, is diverted to ponds where it infiltrates and recharges underlying aquifers. About 2 million people are dependent on these aquifers for water supply. In recent years, base flow in the river has increased as a result of increased discharge of treated municipal wastewater, and high flows have increased as a result of increase precipitation and urbanization. Trends in water quality were calculated for two sites?at the Metropolitan Water District (MWD) Crossing (an upstream site) and below Prado Dam (a downstream site)?using the computer program ESTREND. Water-quality data for these sites were collected by the U.S. Geological Survey from 1969 to 1995. At MWD Crossing, flow-adjusted downward trends of -1.1 microsiemens per centimeter (iS/cm) per year and -1.6 milligrams per liter (mg/L) per year were calculated for specific conductance and dissolved solids, respectively. In contrast, a flow-adjusted upward trends of 2.2 iS/cm per year for dissolved solids was calculated for the Santa Ana River below Prado Dam. Specific conductance and dissolved solids in the Santa Ana River below Prado Dam had downward unadjusted trends (not adjusted for streamflow) of -8.3 iS/cm per year and -6.0 mg/L per year, respectively. For the Santa Ana River below Prado Dam, downward unadjusted trends were calculated for ammonia (-0.04 mg/L per year) and total organic carbon (0.19 mg/L per year); flow-adjusted upward trends were calculated for nitrite plus nitrate (0.15 mg/L per year), total dissolved nitrogen (0.39 mg/L per year), and orthophosphate (0.03 mg/L per year). Statistically significant unadjusted and flow-adjusted trends were not obtained for organic nitrogen, phosphorus, and dissolved organic carbon. Data for selected trace elements and organic compounds collected between 1970-94 also are summarized in this report.

Water-Resources Investigations Report↗

Chemistry and isotopic composition of ground water along a section near the Newmark area, San Bernardino County, California

Chemical and isotopic analyses and flow-meter measurements in pumped wells were used to determine the source, movement, and age of ground water along a section of the valley-fill aquifer from the San Jacinto Fault to the base of the San Bernardino Mountains near the Newmark area in the Bunker Hill Basin of southern California. Water samples were collected from four multiple-depth well sites, from different depths within three production wells, and from two nearby streams; these samples were analyzed for major ions, selected trace elements, stable isotopes of oxygen and hydrogen (delta oxygen-18 and delta deuterium), tritium, and carbon-14. Within the production wells, variations in vertical flowrate with depth were recorded during pumped conditions using a standard spinner tool. Where saturated, the upper 200 feet of unconsolidated deposits contributed as much as 60 percent of the well discharge; deposits at depths greater than 700 feet contributed less than 10 percent. Chemical analyses indicate that three general zones of ground-water quality are present along a north-south section--an oxygenated zone near the base of the San Bernardino Mountains, an oxygen-depleted zone near the San Jacinto Fault, and a deeper zone characterized by concentrations of fluoride greater than 1 mg/L and by a general water-quality composition similar to that of base flow in East Twin Creek. The presence of tritium in water from wells along the section indicates that post-1952 recharge has moved rapidly through the valley-fill aquifer to depths as great as 800 feet. Carbon-14 data indicate that the maximum age of ground water, sampled at depths ranging from 600 to 1,000 feet, is less than 5,000 years before present. Ground water along the study section is much younger than ground water from similar depths in other nearby basins. Delta oxygen-18 and delta deuterium data indicate that as much as 25 percent of the discharge from some wells near the base of the San Bernardino Mountains is water that was imported from northern California. Improved knowledge of depth-dependent ground-water flow along this section can aid in the design of an effective strategy for basin management, including remediation of the Newmark area, which is designated by the U.S. Environmental Protection Agency as a Superfund cleanup site.

Water-Resources Investigations Report↗

Statistical analysis and mathematical modeling of a tracer test on the Santa Clara River, Ventura County, California

To better understand flow processes, solute-transport processes, and ground-water/surface-water interactions on the Santa Clara River in Ventura County, California, a 24-hour fluorescent-dye tracer study was performed under steady-state flow conditions on a 28-mile reach of the river. The study reach includes perennial (uppermost and lowermost) subreaches and ephemeral subreaches of the lower Piru Creek and the middle Santa Clara River. Dye was injected at a site on Piru Creek, and fluorescence of river water was measured continuously at four sites and intermittently at two sites. Discharge measurements were also made at the six sites. The time of travel of the dye, peak dye concentration, and time-variance of time-concentration curves were obtained at each site. The long tails of the time-concentration curves are indicative of sources/sinks within the river, such as riffles and pools, or transient bank storage. A statistical analysis of the data indicates that, in general, the transport characteristics follow Fickian theory. These data and previously collected discharge data were used to calibrate a one-dimensional flow model (DAFLOW) and a solute-transport model (BLTM). DAFLOW solves a simplified form of the diffusion-wave equation and uses empirical relations between flow rate and cross-sectional area, and flow rate and channel width. BLTM uses the velocity data from DAFLOW and solves the advection-dispersion transport equation, including first-order decay. The simulations of dye transport indicated that (1) ground-water recharge explains the loss of dye mass in the middle, ephemeral, subreaches, and (2) ground-water recharge does not explain the loss of dye mass in the uppermost and lowermost, perennial, subreaches. This loss of mass was simulated using a linear decay term. The loss of mass in the perennial subreaches may be caused by a combination of photodecay or adsorption/desorption.

Water-Resources Investigations Report↗