Crystal structure of fabianite, CaB3O5(OH), and comparison with the structure of its synthetic dimorph
No abstract available.
Geology topics
Publications and source records attributed to Joan R. Clark.
No abstract available.
Triclinic ulexite crystals contain isolated borate polyanions [B 5 O 6 (OH) 6 ] 3- related to the well known pentaborate polyanion [B 5 O 6 (OH) 4 ] - by addition of two hydroxyl groups to two opposite B-O triangles. The isolated ulexite polyanions form the [B 5 O 7 (OH) 4 ] n 3n- chains previously found in crystals of the related mineral probertite, NaCaB 5 O 7 (OH) 4 ·3H 2 O.
The optical properties of rutherfordine, UO 2 CO 3 , previously determined on microscopic crystals, have been redetermined on considerably larger crystals; and the relations among the indices of refraction, the morphology, and the crystal structure have been examined. Rutherfordine is orthorhombic, biaxial positive, with α = 1.715, β = 1.730, γ = 1.795, 2V = 53° (calc.); X = b, Y = c (elongation, Z = a. The crystal structure of UO 2 CO 3 consists of layers of carbonate groups parallel to (010) with linear (O-U-O) ions normal to the layers. The indices β and γ correspond to vibration directions parallel to layers; the unexpectedly large difference in value between β and γ is ascribed to the optical anisotropy of the uranium-oxygen bonding in the layer. Indexed X-ray powder data are given.
No abstract available.