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Jill N. Densmore

Publications and source records attributed to Jill N. Densmore.

At least 19 recordsLinked to original sources
USGS2026

Evaluation of water quality in the Langford Valley–Irwin Groundwater Subbasin, Fort Irwin National Training Center, California, 1993–2019

The U.S. Army Fort Irwin National Training Center (NTC), 120 miles northeast of Los Angeles in the Mojave Desert of California, obtains its potable water supply from the Bicycle Valley and Langford Valley groundwater basins; Langford Valley groundwater basin is further subdivided into the Langford Well Lake and Irwin groundwater subbasins. The Irwin groundwater subbasin contains younger, unconsolidated deposits that have a saturated thickness of as much as 200 feet (ft) and a lower aquifer within older unconsolidated deposits as thick as 650 ft. Groundwater recharge under predevelopment conditions (before 1941) occurred primarily from infiltration of intermittent streamflow in small washes that cross the Irwin groundwater subbasin. Since that time, groundwater recharge has increased because of growth of the NTC in recent years and as a result of other processes, including (1) infiltration of treated wastewater into the aquifer through ponds near the NTC wastewater treatment facility (WWTF) and (2) infiltration of imported water and treated wastewater used for landscape irrigation at base housing and athletic fields. Water samples were collected from 17 wells and analyzed for field parameters, chemical constituents, and isotope composition in the Irwin groundwater subbasin between 2014 and 2019. These data were supplemented with water-chemistry data collected during 1993–95 and at other times if available. Between 1993–95 and 2015–19, median dissolved solids and nitrate concentrations in water from wells in the Irwin groundwater subbasin increased from 620 to 1,030 milligrams per liter (mg/L) and from 2.8 to 4.5 mg/L as nitrogen, respectively. After 2014, dissolved solids and nitrate concentrations in water from wells near the NTC WWTF decreased as a result of changes in source water quality attributable to reverse osmosis of treated drinking water delivered within the Irwin groundwater subbasin and to increased levels of treatment at the NTC WWTF. Based on delta oxygen-18 and delta deuterium isotope data, increases in dissolved solids concentrations in water from most wells were consistent with evaporation prior to recharge and mobilization of soluble salts from the unsaturated zone. Arsenic and fluoride concentrations in water from wells decreased between 1993–95 and 2015–19 as the basin filled with treated wastewater, but 2015–19 concentrations generally exceeded the California State Water Resources Control Board maximum contaminant levels of 10 micrograms per liter for arsenic and 2 mg/L for fluoride. Most groundwater in the Irwin groundwater subbasin has unadjusted carbon-14 ages ranging from 18,400 to 12,350 years before present. However, water from well 10E3, located along the wash near the subbasin outflow in the southeastern part of the Irwin groundwater subbasin, contained measurable tritium, which is consistent with infiltration of intermittent streamflow and groundwater recharge from the wash after 1952. Chemical and isotopic data indicate that treated wastewater is present in water from most wells in the upper aquifer that underlies the Irwin groundwater subbasin. Wells were not sampled to adequately determine the extent of treated wastewater and changes in water quality within the lower aquifer that underlies the Irwin groundwater subbasin.

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USGS2024

Evaluation of the characteristics, discharge, and water quality of selected springs at Fort Irwin National Training Center, San Bernardino County, California

Eight springs and seeps at Fort Irwin National Training Center were described and categorized by their general characteristics, discharge, geophysical properties, and water quality between 2015 and 2017. The data collected establish a modern (2017) baseline of hydrologic conditions at the springs. Two types of springs were identified: (1) precipitation-fed upland springs (Cave, Desert King, Devouge, No Name, and Panther Springs) and (2) groundwater discharge-fed basin springs (Garlic, Bitter, and Jack Springs). Comparison of electrical resistivity tomography data collected at groundwater basin springs from 2015 to 2017 indicated that spring discharge and connection to the underlying groundwater system is highly focused, although the springs themselves appear diffuse and are spread out over a large area. Spring discharge was consistently less than reported by Thompson (1929), except at Garlic Spring where discharges and vegetation have increased in recent years. Multiple discrete flume and seepage meter measurements taken between October 2015 and April 2016 indicated that discharge changed predictably on diurnal and seasonal timescales in response to evapotranspiration. These preliminary results and the lush vegetation noted at some of the springs, particularly at Bitter, Garlic, and Jack Springs, indicated plant evapotranspiration accounts for a substantial part of the discharge from these springs. The quality of water ranges from fresh in precipitation-fed upland springs (Cave, Desert King, Devouge, and Panther Springs) to slightly saline (Garlic and Jack Springs) and moderately saline (Bitter Spring) in groundwater-fed discharge springs. Nitrate concentrations from water at most of the springs were less than 3 milligrams per liter, except for samples from Devouge and Desert King Springs and one sample from Jack Spring. An analysis of delta nitrogen-15 in nitrate (δ 15 N-NO 3 ) and delta oxygen-18 in nitrate (δ 18 O-NO 3 ) indicates high nitrate concentrations in excess of the U.S. Environmental Protection Agency maximum contaminant level at Jack Spring and Desert King Spring resulting from the dissolution of nitrate-bearing caliche deposits; nitrate concentrations at Devouge Spring are a result of algal growth within the spring, and the source of nitrate concentrations in Garlic Spring are consistent with a treated wastewater origin from Langford Valley-Irwin subbasin upgradient. The source of water in upland springs, indicated by values of delta oxygen-18 (δ 18 O) and delta deuterium (δD) are consistent with recharge from winter precipitation. In groundwater basin springs, values of δ 18 O and δD are consistent with groundwater sampled from nearby wells. Summer monsoonal precipitation appears to contribute little water to spring flow. Most springs contain low levels of tritium and appear to be primarily older (pre-1950s) groundwater. Groundwater basin springs with detectable tritium may result from occasional streamflow in nearby washes. These springs could be susceptible to decreases in flow during extended dry periods when the localized recharge may be reduced due to the loss of focused recharge through nearby washes. Groundwater samples from Garlic and Bitter Springs contained arsenic concentrations above the U.S. Environmental Protection Agency maximum contaminant level. Groundwater samples from all springs, except Cave, Desert King, and Devouge Springs, exceeded the State of California maximum contaminant level for fluoride. Garlic Spring was the only sampled spring that contained vanadium concentrations that exceeded the State of California notification level. Only a single water sample from Jack Spring contained uranium at a concentration that exceeded the U.S. Environmental Protection Agency maximum contaminant level. Many other constituents of concern were analyzed, including those from anthropogenic sources that may be a result of military activities. Most of these constituents were not detected above their respective reporting levels in spring water; only 15 were detected in spring waters. Diesel and gasoline degradants, many of which also occur naturally, were the most commonly detected compounds. Several other organic compounds, primarily solvents or their degradants, were detected in groundwater basin springs. These constituents, in order of decreasing detection frequency, were carbon disulfide; perchlorate; mercury; acetone; methylnaphthalene; toluene; methyl ethyl ketone; cyanide; and styrene; 4-iso-propyl-toluene; isopropylbenzene; methyl salicylate; and phenol. Except for Garlic Spring, which is affected by discharges of treated wastewater, the quality of water from most springs appears to be relatively unaffected by activities at the Fort Irwin National Training Center.

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USGS2022

Characterization of subsurface conditions and recharge at the irrigated four-plex baseball field, Fort Irwin National Training Center, California, 2018–20

The U.S. Geological Survey performed subsurface and geophysical site characterization of the irrigated four-plex baseball field in the Langford Valley–Irwin Groundwater Subbasin, as part of a research study in cooperation with the U.S. Environmental Protection Agency, the Agricultural Research Service, and the Fort Irwin National Training Center, California. To help meet future demands, the Fort Irwin National Training Center is evaluating the efficacy of gravity-fed drywells to enhance storm-water recharge into the Langford Valley–Irwin Groundwater Subbasin by bypassing fine-grained, less permeable deposits between land surface and the water table. The amount, rate, and location of recharge beneath an irrigated baseball field in the groundwater basin at the Fort Irwin National Training Center is not well understood, so data were collected using physical and geophysical techniques to characterize subsurface materials, geologic controls, and the vertical movement of water through the unsaturated zone to the water table near the drywell at the Fort Irwin National Training Center. Based on the data collected and interpreted from these techniques, several fine-grained deposits were identified. Although these deposits appear to impede the downward movement of water through the unsaturated zone locally, they are not laterally continuous, and water appears to continue to move downward when it reaches the edges of the deposits. These data will help managers evaluate recharge at the site and determine if the use of gravity-fed drywells enhances recharge from surface runoff.

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USGS2022

Hydrogeologic characterization of the San Antonio Creek Valley watershed, Santa Barbara County, California

The San Antonio Creek Valley watershed (SACVW) is located in western Santa Barbara County, about 15 miles south of Santa Maria and 55 miles north of Santa Barbara, California. The SACVW is about 135 square miles and encompasses the San Antonio Creek Valley groundwater basin; the SACVW is separated from adjacent groundwater basins by the Casmalia and Solomon Hills to the north, and the Purisima Hills to the south. At the western, downstream part of the valley, uplifted, consolidated rocks cause groundwater to discharge at land surface at Barka Slough. Since the late 1800s, groundwater has been the primary source of water for agricultural, military, municipal, and domestic uses. Groundwater withdrawal by pumping exceeded the amount of water replenishing the aquifer system during water years 1948–2018, causing groundwater-level declines of more than 150 feet in parts of the valley and reducing base flow at Barka Slough. Reliance on groundwater for agricultural water use (primarily for the irrigation and frost protection of vineyards, and fruit and berry crops) continues to strain the sustainability of the groundwater system. Through a cooperative agreement, the Santa Barbara County Water Agency and Vandenberg Space Force Base invited the U.S. Geological Survey to address declines in groundwater levels, develop a better understanding of the hydrogeologic system, and provide tools to help evaluate and manage the effects of future development of the San Antonio Creek Valley groundwater basin within the encompassing San Antonio Creek Valley watershed (SACVW). The objectives of this study were to (1) refine the hydrogeologic framework of the San Antonio Creek Valley watershed, (2) quantify the hydrologic budget of the valley, and (3) develop hydrologic modeling tools to evaluate and aid in managing the groundwater resource. This report focuses on the first and second objectives to construct a hydrogeologic framework and characterize the historical and present-day hydrologic conditions of the SACVW during water years 1948–2018. As part of the second objective, work included quantifying the hydrologic budget and evaluating the hydrogeologic system using a combination of existing data and geologic and hydrologic data collected for this study. The groundwater-flow system in the SACVW consists of five hydrogeologic units. These separate water-bearing units were identified based on hydrogeologic properties, such as sediment grain size, vertical-head differences in multiple-depth, monitoring-well sites, long-term groundwater level responses to pumping and climate, and the chemical character of groundwater and groundwater age in the mostly semi-consolidated to unconsolidated basin-fill sediments. The hydrogeologic units that comprise the different aquifers vary in their lithologic composition. The upper and lower aquifers (upper Paso Robles Formation, and lower Paso Robles Formation and Careaga Sandstone, respectively) are relatively coarse grained and are comprised of sand, gravel, and clay; the middle confining unit (the middle Paso Robles Formation) is relatively fine grained and is comprised of primarily clay, silt, and sand. The Pezzoni-Casmalia and Los Alamos faults, which are inferred to transect the SACVW between the western and eastern areas of the valley floor, do not appear to substantially affect the groundwater system. Present-day recharge to the study area occurs primarily as infiltration from precipitation and streams in the upland areas of the Casmalia Hills and Solomon Hills, and along the main channel of San Antonio Creek. Reported estimates of annual natural recharge during water years 1948–2018 generally ranged from about 5,000 acre-feet to more than about 30,000 acre-feet. Stable and radioactive isotopes show that groundwater from the lower aquifer is old and probably was recharged as infiltration from precipitation and streams in the eastern upland areas of the Solomon Hills; however, the infiltration and recharge from these sources probably does not occur under present-day climatic conditions. Anthropogenic recharge, from sources such as return flow from agricultural irrigation, municipal water systems, and wastewater effluent, was estimated to range from about 600 acre-feet in 1948 to about 6,600 acre-feet in 2018. The average annual amount of groundwater removed from the SACVW by pumping during 1948–2018 was estimated to be about 17,200 acre-feet per year, increasing from about 3,000 acre-feet in 1948 to about 32,600 acre-feet in 2018. Estimates of annual pumpage generally exceeded estimates of annual recharge beginning in the mid-1970s and continuing through 2018. The predominant direction of groundwater flow under historical and present-day conditions was from the eastern uplands in the Solomon Hills to the west along San Antonio Creek to the discharge area in Barka Slough, and from the northern uplands in the Casmalia Hills south to San Antonio Creek. Pumpage since the early 1900s and the subsequent groundwater-level declines have substantially reduced the amount of natural groundwater discharge at Barka Slough. Estimates of base flow to San Antonio Creek at the western, downstream extent of the SACVW have varied over time in response to changes in groundwater pumpage and climate; however, there was an overall decline in base flow during water years 1956–2018, decreasing from an average of about 1,700 acre-feet per year during 1956–69, to about 300 acre-feet per year during 2016–18. The long-term extraction of groundwater correlates with a decrease in groundwater levels by more than about 150 feet since the early 1940s in the eastern part of the basin near Los Alamos, and as much as about 50 feet in the upland areas and in the western part of the basin. At Barka Slough, groundwater levels have declined below land surface in some places, altering native riparian vegetation in and around the slough. Surface-water quality in the SACVW varied depending on location and the time of year the samples were collected and on the amount of annual precipitation Most groundwater in the SACVW was calcium-bicarbonate-type water with total dissolved-solids concentrations of about 500–800 milligrams per liter generally representing water naturally recharged as infiltration from precipitation and streams. Total dissolved-solids concentrations in some wells ranged from 800 to 8,000 milligrams per liter, suggesting mixing of naturally recharged infiltrated water with water associated with oil-bearing geologic formations, agricultural products, or the evaporation of shallow groundwater. Concentrations of total dissolved solids and the chemical constituents chloride, nitrate plus nitrite (as nitrogen), calcium, and magnesium at selected wells generally increased during water years 1980–2018; increasing concentrations of these constituents may be associated with the expansion of agriculture in the watershed over time and the corresponding increase in the use of nitrates and calcium- and magnesium-based fertilizers and soil additives in modern agricultural practices. The predominant direction of groundwater flow during historical and present-day conditions was from the eastern uplands in the Solomon Hills to the west along San Antonio Creek toward Barka Slough, and from the western uplands in the Casmalia Hills south to San Antonio Creek. The age of groundwater in the SACVW was evaluated using radioactive isotopes, and the flow of groundwater within the SACVW was evaluated using radioactive and stable isotopes. Modern groundwater (recharged after 1952) was generally found adjacent to San Antonio Creek and its tributaries in wells with perforated depths that averaged about 270 feet below land surface. Pre-modern groundwater (recharged before 1952) was found in wells that had average perforation depths of about 540 ft below land surface. Pre-modern groundwater identified in wells in the eastern upland area is interpreted to have had long, slow travel times to the western part of the SACVW where it was eventually discharged as base flow at Barka Slough or extracted as groundwater pumpage.

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USGS2019

Summary of hydrologic testing, wellbore-flow data, and expanded water-level and water-quality data, 2011–15, Fort Irwin National Training Center, San Bernardino County, California

In view of the U.S. Army’s historical reliance and plans to increase demands on groundwater to supply its operations at Fort Irwin National Training Center (NTC), California, coupled with the continuing water-level declines in some developed groundwater basins as a result of pumping, the U.S. Geological Survey (USGS), in cooperation with the U.S. Army, evaluated the water resources, including water quality and potential groundwater supply, of undeveloped basins in the NTC. Previous work in the three developed groundwater basins—Langford, Bicycle, and Irwin—provided information to support water-resources management of those basins. During 2009–12, the USGS installed 41 wells at the NTC; 34 wells were at 14 single- or multiple-well monitoring sites, and 7 wells were long-screen test wells. The majority of the wells were installed in previously undeveloped or minimally developed groundwater basins (Cronise, Red Pass, the Central Corridor area, Superior, Goldstone, and Nelson Basins). During 2012–15, the USGS tested hydrologic properties at 32 wells in 8 basins to help characterize the aquifer system. This report presents data and analyses from core samples; slug tests and single-well aquifer tests; coupled measurements of wellbore flow, water levels, and water-quality constituents; and results from two-dimensional numerical modeling. This information provides a basis for developing and constraining basin-scale hydrogeologic framework and groundwater-flow models to further evaluate water resources in each groundwater basin. Core samples were tested for vertical saturated hydraulic conductivity, physical properties, and particle-size distribution. Vertical saturated hydraulic conductivities of the cores ranged from less than 0.00001 to 18.13 feet per day, and porosities ranged from 0.15 to 0.56. These physical properties and particle-size analyses indicate the high degree of heterogeneity of the hydrogeologic deposits penetrated by the boreholes. Horizontal hydraulic conductivities estimated from slug tests in 22 monitoring wells in 6 basins (Cronise, Central Corridor area, Goldstone, Langford, Bicycle, and Nelson Basins) ranged from less than 0.1 to 40 feet per day. Results of the aquifer tests at six test wells in the Goldstone, Nelson, and Superior Basins indicate hydraulic conductivities ranged from 0.37 to 66 feet per day; associated transmissivity values ranged from 130 to 28,000 feet squared per day. Wellbore-flow data, collected from the six test wells under unpumped and pumped conditions, generally showed downward movement of water. Flow data collected under unpumped conditions indicate groundwater entered the well through the upper part of the screened interval and exited to aquifer zones in the lower part of the screened interval at rates ranging from 1 to 3 gallons per minute. Flow data collected under pumping conditions show increased flow downward in the test wells, indicating higher yields from deeper aquifers. Water levels, measured periodically between 2011 and 2015, remained stable during this period in the majority of the wells measured since 2011, except at two monitoring sites in developed basins (Bicycle and Langford). Vertical hydraulic gradients were generally low throughout the NTC, but ranged from –0.0003 to 0.27 during the summer of 2015. Multiple-well monitoring sites in Bicycle, Central Corridor area, Cronise, Goldstone, Nelson, and Superior Basins, had downward vertical gradients. Groundwater in wells in Nelson and Superior Basins, and wells BLA5, CCT1, and GOLD2 #2, was characterized as sodium-bicarbonate water, whereas groundwater from the remaining wells in Goldstone Basin was characterized as sodium-chloride water and Cronise Basin, and well LL04 was characterized by sodium-sulfate water. Total dissolved solids (TDS) ranged from 285 to 13,400 milligrams per liter (mg/L) TDS and chloride concentrations ranged from 19 to 1,030 mg/L chloride, with lowest concentrations of each in groundwater from Superior and Nelson Basins and highest concentrations in Cronise Basin. Nitrate plus nitrite as nitrogen ranged from less than 0.040 mg/L in groundwater from Cronise and Goldstone Basins to about 20 mg/L in Nelson Basin. Groundwater from wells in Nelson Basin was isotopically light, whereas groundwater samples from wells CRTH1, CRTH2, and LL04 were isotopically heavier and plotted along an evaporative trend line. No measurable tritium was detected in groundwater from 13 wells sampled in 2015, indicating that groundwater was recharged prior to 1952. Measured carbon-14 ( 14 C) activities in groundwater from four wells sampled in 2015 ranged from about 7.9 to 23.5 percent modern carbon and had apparent (uncorrected) ages of 11,970–20,980 years. Arsenic concentrations were above the maximum contaminant level of 10 micrograms per liter in groundwater from all wells, except those in Goldstone Basin and the two deepest wells in Langford Basin (LL04); likewise, fluoride concentrations were above the California maximum contaminant level of 2 mg/L in groundwater from most wells, except those in Goldstone and Superior Basins, the middle well in Langford Basin, middle and deep wells in two locations in Cronise Basin, and two wells in Nelson Basin. Wellbore flow was simulated for each well by using an integrated-flow analysis tool, AnalyzeHOLE, to evaluate aquifer properties and heterogeneity. Horizontal layers in the model (hydrogeologic units) were defined by lithostratigraphic‐geophysical units, interpreted from lithologic and geophysical logs for each well, and were adjusted during calibration. The saturated hydraulic conductivities derived from the calibrated simulations ranged from less than 0.01 to 60 feet per day in Nelson, Goldstone, and Superior Basins.

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USGS2019

Evaluation of land subsidence and ground failures at Bicycle Basin, Fort Irwin National Training Center, California, 1992–2017

Groundwater has been pumped in the Bicycle Basin at Fort Irwin National Training Center since the 1960s, and the amount pumped has generally increased since the 1990s. After a large crack (approximately 0.5-kilometer long) formed at the surface of Bicycle Lake playa during 2005–06 in the area used as an aircraft runway, a monitoring study was initiated by the U.S. Geological Survey, in cooperation with the U.S. Army Fort Irwin National Training Center, to help determine the cause. The extent and effect of groundwaterlevel declines and land-surface deformation in Bicycle Basin were evaluated using a number of approaches, including water-level measurements from December 2007 to June 2017, land surveys across the playa area, interferometric synthetic aperture radar (InSAR) analyses, geophysical surveys of the playa area, and numerical experiments to test hypotheses about soil mechanical processes. A specific objective of this study was to evaluate the recent development of ground failures in the form of large, surface cracks that pose a hazard to aircraft operations on the Bicycle Lake playa airstrip. Another large crack and set of interconnected cracks formed at the surface of Bicycle Lake playa in 2013 following a period of inundation similar to that of 2005–06; however, the 2013 cracks formed a network rather than a single feature. Groundwater pumping resulted in more than 27 meters (90 feet) of water-level declines in wells north of the Bicycle Lake playa from 1990 to 2017, and InSAR interferograms indicated more than 400 millimeters (16 inches) of subsidence during 1993–2015. Subsidence rates calculated from InSAR interferograms were variable, temporally and spatially. Results of leveling surveys indicated differential subsidence between 2009 and 2016 along a transect across the playa to the area of maximum subsidence; there was less subsidence south of the 2005–06 crack than north of it. The steepest subsidence gradient for this time was in the area of maximum subsidence. Repeat tape-extensometer measurements from April 2009 to November 2017 across the main-runway crack indicated slight opening along part of the crack. A baseline lidar (light detection and ranging) survey of the main-runway crack was done in January 2009 to track the development of this feature. During the 95-months from January 2009 to December 2016, 0.5 meters (19.7 inches) of subsidence was observed next to the subsidence pit in the crack along the western end of the scanned area, presumably due to erosion and backfilling when the lake was inundated. Standing water in the crack along the eastern end of the scanned area prevented determining change for that part of the crack. Time-series, shaded-relief images show the progression of change in the crack from January 2009 through December 2016, with the crack closing and opening, depending on the time of most recent inundation relative to when the scans were taken. Volumetric changes in the size of the crack, calculated between the sequential lidar surveys, show that from 2009 to 2016, the cumulative volumetric change was 1.5 cubic meters (54 cubic feet). This volume is a minimum estimate because the crack volume below the water surface in the pits was not included in the calculations. Subsurface imaging of the 2005–06 main-runway crack by a series of electrical resistivity tomography surveys in 2008 and 2017 indicated that the crack could extend 5 meters (16 feet) in the subsurface. Electromagnetic induction surveys in 2008, 2014, and 2015 evaluated the technique for ground-failure monitoring and showed that the technique was effective at revealing anomalies correlated with the features of concern in the playa area, such as the 2005–06 crack, numerous ”healed” macropolygon features, and scattered sink-like depressions. Results from numerical experiments simulating watertable decline at depth indicated that the material deposits in the desaturating capillary fringe zone might not be able to transmit large enough stresses up through the overlying soil to cause cracks at the land surface. Results from simulations of desiccation in the presence of a regional tectonically induced stress field, however, tended to support the hypothesis that the combined processes could control the formation of giant desiccation macropolygons in certain areas, such as Bicycle Lake playa.

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USGS2018

Geohydrology, geochemistry, and numerical simulation of groundwater flow and land subsidence in the Bicycle Basin, Fort Irwin National Training Center, California

Groundwater pumping from Bicycle Groundwater Basin (referred to as Bicycle Basin) in the Fort Irwin National Training Center, California, began in 1967. From 1967 to December 2010, about 46,000 acre-feet of water had been pumped from the basin and transported to the Irwin Basin. During this time, not only did water levels in the basin decline by as much as 100 feet, the quality of the groundwater pumped from the basin also deteriorated in some wells. The U.S. Geological Survey collected geohydrologic data from existing wells, test holes, and 16 additional monitoring wells installed at 6 sites in Bicycle Basin during 1992–2011 to determine the quantity and quality of groundwater available in the basin. Geophysical surveys, including electrical, gravity, and seismic refraction surveys, were completed to help determine the geometry of the structural basin, delineate depths to the interface between Quaternary and Tertiary rocks, map the depth to the water table, and used to develop a geohydrologic framework and groundwater-flow model for Bicycle Basin. Water samples were used to determine the groundwater quality in the basin and to delineate potential sources of poor-quality groundwater. Analysis of stable isotopes of oxygen and hydrogen in groundwater indicated that presentday precipitation is not a major source of recharge to the basin. Tritium and carbon-14 data indicated that most of the groundwater in the basin was recharged prior to 1952 and had an apparent age of 15,625–39,350 years. Natural recharge to the basin was not sufficient to replenish the groundwater pumped from the basin. Interferograms from synthetic aperture radar data (InSAR), analyzed to evaluate land-surface subsidence between 1993 and 2010, showed 0.23 to 1.1 feet of subsidence during this period near one production well north of Bicycle Lake (dry) playa. A groundwater-flow model of Bicycle Basin was developed and calibrated using groundwater levels for 1964– 2010, and a subsidence model using land-surface deformation data for 1993–2010. Between January 1967 and December 2010, the simulated total recharge from precipitation runoff and underflow from adjacent basins was about 5,100 acre-feet and pumpage from the Bicycle Basin was about 47,000 acrefeet of water. Total outflows exceeded natural recharge during this period, resulting in a net loss of about 42,100 acre-feet of groundwater storage in the basin. The Fort Irwin National Training Center is considering various groundwater-management options in the Bicycle Basin. The groundwater-flow model was used to (1) evaluate changes in groundwater levels and subsidence with the addition of capture and recharge of simulated runoff in retention basins (scenario 1) for predevelopment through 2010; (2) simulate a base case (scenario 2) for reference; and (3) compare projections of alternative future pumping strategies for 2011–60 (scenarios 3–5). Model results from the runoff-capture simulation (scenario 1) indicated that total recharge, including runoff captured using retention basins, locally increased water levels, which partially offset, but did not mitigate, groundwater depletion associated with pumping. Groundwater-storage depletion in scenario 1 was about 14 percent less than without runoff capture. Simulated-drawdown results in model layer 1 in the eastern part of the basin indicated that, because of the captured runoff, simulated heads were as much as 100 feet higher in December 2010 than prior to the onset of development in 1967. In contrast, simulated drawdown for model without runoff capture indicated that, without captured runoff, simulated heads for December 2010 in this area were 80–90 feet lower than during the predevelopment period. Subsidence was mitigated slightly in scenario 1 compared to without runoff capture; the largest decrease in subsidence at observation sites was about 0.07 feet.

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USGS2018

Evaluation of the Source and Transport of High Nitrate Concentrations in Ground Water, Warren Subbasin, California

Ground water historically has been the sole source of water supply for the Town of Yucca Valley in the Warren subbasin of the Morongo ground-water basin, California. An imbalance between ground-water recharge and pumpage caused ground-water levels in the subbasin to decline by as much as 300 feet from the late 1940s through 1994. In response, the local water district, Hi-Desert Water District, instituted an artificial recharge program in February 1995 using imported surface water to replenish the ground water. The artificial recharge program resulted in water-level recoveries of as much as 250 feet in the vicinity of the recharge ponds between February 1995 and December 2001; however, nitrate concentrations in some wells also increased from a background concentration of 10 milligrams per liter to more than the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 44 milligrams per liter (10 milligrams per liter as nitrogen). The objectives of this study were to: (1) evaluate the sources of the high-nitrate concentrations that occurred after the start of the artificial-recharge program, (2) develop a ground-water flow and solute-transport model to better understand the source and transport of nitrates in the aquifer system, and (3) utilize the calibrated models to evaluate the possible effect of a proposed conjunctive-use project. These objectives were accomplished by collecting water-level and water-quality data for the subbasin and assessing changes that have occurred since artificial recharge began. Collected data were used to calibrate the ground-water flow and solute-transport models. Data collected for this study indicate that the areal extent of the water-bearing deposits is much smaller (about 5.5 square miles versus 19 square miles) than that of the subbasin. These water-bearing deposits are referred to in this report as the Warren ground-water basin. Faults separate the ground-water basin into five hydrogeologic units: the west, the midwest, the mideast, the east and the northeast hydrogeologic units. Water-quality analyses indicate that septage from septic tanks is the primary source of the high-nitrate concentrations measured in the Warren ground-water basin. Water-quality and stable-isotope data, collected after the start of the artificial recharge program, indicate that mixing occurs between imported water and native ground water, with the highest recorded nitrate concentrations in the midwest and the mideast hydrogeologic units. In general, the timing of the increase in measured nitrate concentrations in the midwest hydrogeologic unit is directly related to the distance of the monitoring well from a recharge site, indicating that the increase in nitrate concentrations is related to the artificial recharge program. Nitrate-to-chloride and nitrogen-isotope data indicate that septage is the source of the measured increase in nitrate concentrations in the midwest and the mideast hydrogeologic units. Samples from four wells in the Warren ground-water basin were analyzed for caffeine and selected human pharmaceutical products; these analyses suggest that septage is reaching the water table. There are two possible conceptual models that explain how high-nitrate septage reaches the water table: (1) the continued downward migration of septage through the unsaturated zone to the water table and (2) rising water levels, a result of the artificial recharge program, entraining septage in the unsaturated zone. The observations that nitrate concentrations increase in ground-water samples from wells soon after the start of the artificial recharge program in 1995 and that the largest increase in nitrate concentrations occur in the midwest and mideast hydrogeologic units where the largest increase in water levels occur indicate the validity of the second conceptual model (rising water levels). The potential nitrate concentration resulting from a water-level rise in the midwest and mideast hydrogeologic units was estimated using a simple mixing-cell model. The estimated value is within the range of concentrations measured in samples from wells, further indicating the validity of the second conceptual model. A ground-water flow model and a solute-transport model were developed for the Warren ground-water basin for the period 1956-2001. MODFLOW-96 was used for the ground-water flow model and MOC3D was used for the solute-transport model. The model cell size is about 500 feet by 500 feet and the models were discretized vertically into three layers. The models were calibrated using a trial-and-error approach using water-level and nitrate-concentration data collected between 1956-2001. In order to better match the measured data, low fault hydraulic characteristic values were required, thereby compartmentalizing the ground-water basin. In addition, it was necessary to parameterize the specific yield distribution for the top model layer where unconfined ground-water conditions occur into three homogeneous zones. Separate sets of specific- yield values were needed to simulate the drawdown and subsequent water-level recovery. In addition, the calibrated natural recharge was about 83 acre-feet per year. The entrainment of unsaturated-zone septage was simulated as recharge having an associated nitrate concentration. The volume of recharge was a function of the measured water-level rise between 1994-98 and the moisture content of the unsaturated zone. The nitrate concentration of the recharge water was a weighted function of the assumed nitrate concentration in the infiltrating water associated with the overlying land use. The simulated hydraulic head and nitrate concentration results were in good agreement with the measured data indicating that the mechanism for the increase in nitrate concentrations was rising water levels entraining high-nitrate septage in the unsaturated-zone. The calibrated models were used to simulate the possible effects of a planned conjunctive-use project in the western part of the ground-water basin. The simulated project included the addition of a new recharge pond and a new extraction well. In addition, recharge at two existing recharge ponds was increased and three existing production wells were pumped, treated in a nitrate-removal facility, and used for water supply. The simulated hydraulic heads increased in the west, the mideast, and parts of the east hydrogeologic units; however, the simulated hydraulic heads decreased in the midwest and northeast hydrogeologic units. The simulated nitrate concentrations increased to above the MCL of 44 milligrams per liter (10 milligrams per liter as nitrogen) in parts of the west as a result of the increase in simulated hydraulic head. The simulated nitrate concentrations decreased in part of the midwest hydrogeologic unit as a result of the artificial recharge and pumping from the nitrate-removal wells. The simulated nitrate concentrations increased to above the MCL of 44 milligrams per liter in part of the mideast and parts of the east hydrogeologic units beneath commercial land-use areas.

California↗
USGS2018

Against the current— The Mojave River from sink to source: The 2018 Desert Symposium field trip road log

The Mojave River evolved over the past few million years by “fill and spill” from upper basins near its source in the Transverse Ranges to lower basins. Each newly “spilled into” basin in the series? sustained a long-lived lake but gradually filled with Mojave River sediment, leading to spill to a yet lower elevation? basin. The Mojave River currently terminates at Silver Lake, near Baker, CA, but previously overflowed this terminus onward to Lake Manly in Death Valley during the last glacial cycle. The river’s origin and evolution are intricately interwoven with tectonic, climatic, and geomorphic processes through time, beginning with San Andreas fault interactions that created a mountain range across a former externally draining river. We will see and discuss the Mojave River’s predecessor streams and basins, its evolution as it lengthened to reach the central Mojave Desert, local and regional tectonic controls, groundwater flow, flood history, and support of isolated perennial stream reaches that host endemic species. In association with these subjects are supporting studies such as paleoclimate records, location and timing for groundwater and wetlands in the central Mojave Desert, and effects of modern water usage. The trip introduces new findings for the groundwater basin of Hinkley Valley, including an ongoing remediation project that provides a wealth of information on past and present river flow and associated development of the groundwater system.

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USGS2017

Water-resources and land-surface deformation evaluation studies at Fort Irwin National Training Center, Mojave Desert, California

The U.S. Army Fort Irwin National Training Center (NTC), in the Mojave Desert, obtains all of its potable water supply from three groundwater basins (Irwin, Langford, and Bicycle) within the NTC boundaries (fig. 1; California Department of Water Resources, 2003). Because of increasing water demands at the NTC, the U.S. Geological Survey (USGS), in cooperation with the U.S. Army, completed several studies to evaluate water resources in the developed and undeveloped groundwater basins underlying the NTC. In all of the developed basins, groundwater withdrawals exceed natural recharge, resulting in water-level declines. However, artificial recharge of treated wastewater has had some success in offsetting water-level declines in Irwin Basin. Additionally, localized water-quality changes have occurred in some parts of Irwin Basin as a result of human activities (i.e., wastewater disposal practices, landscape irrigation, and/or leaking pipes). As part of the multi-faceted NTC-wide studies, traditional datacollection methods were used and include lithological and geophysical logging at newly drilled boreholes, hydrologic data collection (i.e. water-level, water-quality, aquifer tests, wellbore flow). Because these data cover a small portion of the 1,177 square-mile (mi2 ) NTC, regional mapping, including geologic, gravity, aeromagnetic, and InSAR, also were done. In addition, ground and airborne electromagnetic surveys were completed and analyzed to provide more detailed subsurface information on a regional, base-wide scale. The traditional and regional ground and airborne data are being analyzed and will be used to help develop preliminary hydrogeologic framework and groundwater-flow models in all basins. This report is intended to provide an overview of recent water-resources and land-surface deformation studies at the NTC.

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USGS2015

Initial characterization of the groundwater system near the Lower Colorado Water Supply Project, Imperial Valley, California

In 2009, the U.S. Geological Survey, in cooperation with the city of Needles, began a study of the hydrogeology along the All-American Canal, which conveys water from the Colorado River to the Imperial Valley. The focus of this study was to gain a better understanding of the effect of lining the All-American Canal, and other management actions, on future total dissolved solids concentrations in groundwater pumped by Lower Colorado Water Supply Project wells that is delivered to the All-American Canal. The study included the compilation and evaluation of previously published hydrogeologic and geochemical information, establishment of a groundwater-elevation and groundwater-quality monitoring network, results of monitoring groundwater elevations and groundwater quality from 2009 to 2011, site-specific hydrologic investigations of the Lower Colorado Water Supply Project area, examination of groundwater salinity by depth by using time-domain electromagnetic surveys, and monitoring of groundwater-storage change by using microgravity methods. Prior to the completion of the All-American Canal in 1940, groundwater in the study area flowed from east to west, and groundwater was recharged primarily by underflow from the Colorado River Valley. After construction of the All-American Canal, groundwater elevations were altered in the study area as seepage of Colorado River water from the All-American Canal and other canals became the dominant recharge source. By 2005, groundwater elevations had increased by as much as 50–70 feet along the All-American Canal. Superimposed on the east-to-west groundwater gradient was groundwater movement away from the All-American Canal to the north and, most likely, to the south into Mexico. After lining the All-American Canal, from 2007 to 2010, groundwater elevations declined as seepage from the All-American Canal decreased. Between 2005 (the last complete groundwater-elevation survey prior to lining the All-American Canal) and 2011, groundwater elevations declined 20–40 feet along the All-American Canal and as much as 40–45 feet in the vicinity of Lower Colorado Water Supply Project pumping wells. Water-quality and isotope data were used to differentiate historically recharged groundwater from groundwater more recently recharged by seepage of Colorado River surface water from the All-American Canal. Prior to the completion of the All-American Canal in 1940, groundwater in the southern part of the study area was primarily sodium-chloride/sulfate type water that had relatively low total dissolved solids concentrations (500–820 milligrams per liter). During 2007–11, groundwater in the southern part of the study area, near the All-American Canal, ranged from sodium-chloride type water to mixed-cation-sulfate type water that had total dissolved solids concentrations generally less than 879 milligrams per liter. The stable-isotopic signature of groundwater near the All-American Canal sampled in 2009–11 indicated inputs of Colorado River water that had been affected by evaporation, and radioactive isotopes indicated that a substantial fraction of water had been recharged recently, within the past 60 years. This contrasted with historically recharged groundwater near the All-American Canal, which had higher sodium and chloride concentrations, and lower calcium and sulfate concentrations, than recent recharge from the All-American Canal. Groundwater at a distance from the All-American Canal, in the East Mesa, Algodones Dunes, Pilot Knob Mesa, and Cargo Muchacho Mountains piedmont, was found to have higher total dissolved solids concentrations (generally greater than 1,000 milligrams per liter) than recently recharged groundwater near the All-American Canal. Time-domain electromagnetic data indicated that low-salinity groundwater was present down to about 377 feet below land surface near the All-American Canal; groundwater salinity at depth increased with distance north from the All-American Canal. Groundwater several miles or more from the canal also did not contain tritium and had a residence time on the order of thousands to tens of thousands of years. The groundwater in the piedmont of the Cargo Muchacho Mountains had a distinctly light stable-isotopic signature indicative of recharge by runoff from local precipitation, whereas the stable isotopic signature of groundwater in the East Mesa and the Algodones Dunes indicated a mixture of local precipitation and historic Colorado River recharge sources. During and after lining the All-American Canal (2007–11), groundwater elevations in the Lower Colorado Water Supply Project area declined, while total dissolved solids concentrations remained relatively constant. The total dissolved solids concentrations in well LCWSP-2 ranged from 650 to 800 milligrams per liter during this study. Depth-specific water-quality and isotope sampling at well LCWSP-2 indicated the groundwater pumped from the deeper part of the screened interval (240–280 feet below land surface) contained a greater proportion of historical groundwater than the groundwater pumped from the shallower part of the screened interval (350–385 feet below land surface). Age-tracer data at well LCWSP-2 indicated that all depths of the screened interval had received recent recharge from seepage of Colorado River water from the All-American Canal.

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USGS2014

Alpha-emitting isotopes and chromium in a coastal California aquifer

The unadjusted 72-h gross alpha activities in water from two wells completed in marine and alluvial deposits in a coastal southern California aquifer 40 km north of San Diego were 15 and 25 picoCuries per liter (pCi/L). Although activities were below the Maximum Contaminant Level (MCL) of 15 pCi/L, when adjusted for uranium activity; there is concern that new wells in the area may exceed MCLs, or that future regulations may limit water use from the wells. Coupled well-bore flow and depth-dependent water-quality data collected from the wells in 2011 (with analyses for isotopes within the uranium, actinium, and thorium decay-chains) show gross alpha activity in marine deposits is associated with decay of naturally-occurring 238 U and its daughter 234 U. Radon activities in marine deposits were as high as 2230 pCi/L. In contrast, gross alpha activities in overlying alluvium within the Piedra de Lumbre watershed, eroded from the nearby San Onofre Hills, were associated with decay of 232 Th, including its daughter 224 Ra. Radon activities in alluvium from Piedra de Lumbre of 450 pCi/L were lower than in marine deposits. Chromium VI concentrations in marine deposits were less than the California MCL of 10 μg/L (effective July 1, 2014) but δ 53 Cr compositions were near zero and within reported ranges for anthropogenic chromium. Alluvial deposits from the nearby Las Flores watershed, which drains a larger area having diverse geology, has low alpha activities and chromium as a result of geologic and geochemical conditions and may be more promising for future water-supply development.

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USGS2014

Construction, water-level, and water-quality data for multiple-well monitoring sites and test wells, Fort Irwin National Training Center, San Bernardino County, California, 2009-12

Because of increasing water demands at the U.S. Army Fort Irwin National Training Center, the U.S. Geological Survey in cooperation with the U.S. Army carried out a study to evaluate the water quality and potential groundwater supply of undeveloped basins within the U.S. Army Fort Irwin National Training Center. In addition, work was performed in the three developed basins—Langford, Bicycle, and Irwin—proximal to or underlying cantonment to provide information in support of water-resources management and to supplement monitoring in these basins. Between 2009 and 2012, the U.S. Geological Survey installed 41 wells to expand collection of water-resource data within the U.S. Army Fort Irwin National Training Center. Thirty-four monitoring wells (2-inch diameter) were constructed at 14 single- or multiple-well monitoring sites and 7 test wells (8-inch diameter) were installed. The majority of the wells were installed in previously undeveloped or minimally developed basins (Cronise, Red Pass, the Central Corridor area, Superior, Goldstone, and Nelson Basins) proximal to cantonment (primary base housing and infrastructure). Data associated with well construction, water-level monitoring, and water-quality sampling are presented in this report.

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USGS2014

Analysis of potential water-supply management options, 2010-60, and documentation of revisions to the model of the Irwin Basin Aquifer System, Fort Irwin National Training Center, California

The Fort Irwin National Training Center is considering several alternatives to manage their limited water-supply sources in the Irwin Basin. An existing three-dimensional, finite-difference groundwater-flow model—the U.S. Geological Survey’s MODFLOW—of the aquifer system in the basin was updated and the initial input dataset was supplemented with groundwater withdrawal data for the period 2000–10. The updated model was then used to simulate four combinations, or scenarios, of groundwater withdrawal and recharge over the next 50 years (January 2011 through December 2060). The scenarios included combinations of continuing withdrawals from currently active production wells, supplementing any increases in demand with withdrawals from an inactive production well, reducing withdrawal amounts and rates, and reducing the discharge of treated wastewater to infiltration ponds that provide a recharge source to the underlying aquifer. Results of the simulations indicated that, depending on the scenario implemented, groundwater levels would rise (over the next 50 years) from 40 feet to as much as 65 feet in the northwestern part of the Irwin Basin, and from 5 feet to 10 feet in the southeastern part.

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USGS2013

Geohydrology, geochemistry, and groundwater simulation (1992-2011) and analysis of potential water-supply management options, 2010-60, of the Langford Basin, California

Groundwater withdrawals began in 1992 from the Langford Basin within the Fort Irwin National Training Center (NTC), California. From April 1992 to December 2010, approximately 12,300 acre-feet of water (averaging about 650 acre-feet per year) has been withdrawn from the basin and transported to the adjacent Irwin Basin. Since withdrawals began, water levels in the basin have declined by as much as 40 feet, and the quality of the groundwater withdrawn from the basin has deteriorated. The U.S. Geological Survey collected geohydrologic data from Langford Basin during 1992–2011 to determine the quantity and quality of groundwater available in the basin. Geophysical surveys, including gravity, seismic refraction, and time-domain electromagnetic induction surveys, were conducted to determine the depth and shape of the basin, to delineate depths to the Quaternary-Tertiary interface, and to map the depth to the water table and changes in water quality. Data were collected from existing wells and test holes, as well as 11 monitor wells that were installed at 5 sites as part of this study. Water-quality samples collected from wells in the basin were used to determine the groundwater chemistry within the basin and to delineate potential sources of poor-quality groundwater. Analysis of stable isotopes of oxygen and hydrogen in groundwater indicates that present-day precipitation is not a major source of recharge to the basin. Tritium and carbon-14 data indicate that most of the basin was recharged prior to 1952, and the groundwater in the basin has an apparent age of 12,500 to 30,000 years. Recharge to the basin, estimated to be less than 50 acre-feet per year, has not been sufficient to replenish the water that is being withdrawn from the basin. A numerical groundwater-flow model was developed for the Langford Basin to better understand the aquifer system used by the Fort Irwin NTC as part of its water supply, and to provide a tool to help manage groundwater resources at the NTC. Measured groundwater-level declines since the initiation of withdrawals (1992–2011) were used to calibrate the groundwater-flow model. The simulated recharge was about 46 acre-feet per year, including approximately 6 acre-feet per year of natural recharge derived from precipitation runoff and as much as 40 acre-feet per year of underflow from the Irwin Basin. Between April 1992 and December 2010, an average of about 650 acre-feet per year of water was withdrawn from the Langford Basin. Groundwater withdrawals in excess of natural recharge resulted in a net loss of 11,670 acre-feet of groundwater storage within the basin for the simulation period. The Fort Irwin NTC is considering various groundwater-management options to address the limited water resources in the Langford Basin. The calibrated Langford Basin groundwater-flow model was used to evaluate the hydrologic effects of four groundwater-withdrawal scenarios being considered by the Fort Irwin NTC over the next 50 years (January 2011 through December 2060). Continuation of the 2010 withdrawal rate in the three existing production wells will result in 70 feet of additional drawdown in the central part of the basin. Redistributing the 2010 withdrawal rate equally to the three existing wells and two proposed new wells in the northern and southern parts of the basin would result in about 10 feet less drawdown in the central part of the basin but about 100 feet of additional drawdown in the new well in the northern part of the basin and about 50 feet of additional drawdown in the new well in the southern part of the basin. Reducing the withdrawals from the three existing production wells in the central part of the basin from about 45,000 acre-feet to about 32,720 acre-feet would result in about 40 feet of additional drawdown in the central basin near the pumping wells, about 25 feet less than if withdrawals were not reduced. The combination of reducing and redistributing the cumulative withdrawals to the three existing and two proposed new wells results in about 40 feet of additional drawdown in the central and southern parts of the basin and about 70 feet in the northern part of the basin. These results show that reducing and redistributing the groundwater withdrawals would maintain the upper aquifer at greater than 50 percent of its predevelopment saturated thickness throughout the groundwater basin. The scenarios simulated for this study demonstrate how the calibrated model can be utilized to evaluate the hydrologic effects of different water-management strategies.

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USGS2009

Ground-water quality data in the Owens and Indian Wells Valleys study unit, 2006: Results from the California GAMA Program

Ground-water quality in the approximately 1,630 square-mile Owens and Indian Wells Valleys study unit (OWENS) was investigated in September-December 2006 as part of the Priority Basin Project of Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board (SWRCB). The Owens and Indian Wells Valleys study was designed to provide a spatially unbiased assessment of raw ground-water quality within OWENS study unit, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 74 wells in Inyo, Kern, Mono, and San Bernardino Counties. Fifty-three of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 21 wells were selected to evaluate changes in water chemistry in areas of interest (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater- indicator compounds], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), and 1,2,3- trichloropropane (1,2,3-TCP)], naturally occurring inorganic constituents [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, and carbon-14, and stable isotopes of hydrogen and oxygen in water], and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. This study evaluated the quality of raw ground water in the aquifer in the OWENS study unit and did not attempt to evaluate the quality of treated water delivered to consumers. Water supplied to consumers typically is treated after withdrawal from the ground, disinfected, and blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and non-regulatory thresholds established for aesthetic concerns (secondary maximum contamination levels, SMCL-CA) by CDPH. VOCs and pesticides were detected in samples from less than one-third of the grid wells; all detections were below health-based thresholds, and most were less than one-one hundredth of threshold values. All detections of perchlorate and nutrients in samples from OWENS were below health-based thresholds. Most detections of trace elements in ground-water samples from OWENS wells were below health-based thresholds. In samples from the 53 grid wells, three constituents were detected at concentrations above USEPA maximum contaminant levels: arsenic in 5 samples, uranium in 4 samples, and fluoride in 1 sample. Two constituents were detected at concentrations above CDPH notification levels (boron in 9 samples and vanadium in 1 sample), and two were above USEPA lifetime health advisory levels (molybdenum in 3 samples and strontium in 1 sample). Most of the samples from OWENS wells had concentrations of major elements, TDS, and trace elements below the non-enforceable standards set for aesthetic concerns. Samples from nine grid wells had concentrations of manganese, iron, or TDS above the SMCL-CAs.

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USGS2005

Evaluation of volatile organic compounds in two Mojave Desert basins-Mojave River and Antelope Valley-in San Bernardino, Los Angeles, and Kern Counties, California, June-October 2002

The California Aquifer Susceptibility Assessment of the Ground-Water Ambient Monitoring and Assessment Program was developed to assess water quality and susceptibility of ground-water resources to contamination from surficial sources. This study focuses on the Mojave River and the Antelope Valley ground-water basins in southern California. Volatile organic compound (VOC) data were evaluated in conjunction with tritium data to determine a potential correlation with aquifer type, depth to top of perforations, and land use to VOC distribution and occurrence in the Mojave River and the Antelope Valley Basins. Detection frequencies for VOCs were compiled and compared to assess the distribution in each area. Explanatory variables were evaluated by comparing detection frequencies for VOCs and tritium and the number of compounds detected. Thirty-three wells were sampled in the Mojave River Basin (9 in the floodplain aquifer, 15 in the regional aquifer, and 9 in the sewered subset of the regional aquifer). Thirty-two wells were sampled in the Antelope Valley Basin. Quality-control samples also were collected to identify, quantify, and document bias and variability in the data. Results show that VOCs generally were detected slightly more often in the Antelope Valley Basin samples than in the Mojave River Basin samples. VOCs were detected more frequently in the floodplain aquifer than in the regional aquifer and the sewered subset. Tritium was detected more frequently in the Mojave River Basin samples than in the Antelope Valley Basin samples, and it was detected more frequently in the floodplain aquifer than in the regional aquifer and the sewered subset. Most of the samples collected in both basins for this study contained old water (water recharged prior to 1952). In general, in these desert basins, tritium need not be present for VOCs to be present. When VOCs were detected, young water (water recharge after 1952) was slightly more likely to be contaminated than old water. Trihalomethanes (THMs) were detected less frequently in the Mojave River Basin samples than in the Antelope Valley Basin samples. The THMs that were detected in the Mojave River Basin were detected more frequently in the floodplain aquifer than in the regional aquifer and sewered subset. Solvents were detected more frequently in the Mojave River samples than in the Antelope Valley samples. In the Mojave River Basin samples, solvents were detected less frequently in the floodplain aquifer than in the regional aquifer and the sewered subset. Benzene, toluene, ethylbenzene and xylene (BTEX) were not detected in either study area. Methyl tert-butyl ether (MTBE) was detected in one sample from both the Mojave River and Antelope Valley Basins. The most frequently detected compound (detected in more than 10 percent of the wells) in the Mojave River Basin was chloroform. The two most frequently detected compounds in the Antelope Valley Basin were chloroform and tetrachloroethylene (PCE). In the Mojave River Basin, aquifer type and land use within 1,640 ft (500 m) of the well head were not statistically correlated with the number of VOCs detected, although VOCs were detected more frequently in the floodplain aquifer than in the regional aquifer and the sewered subset. Depth to the top of the perforations was an explanatory factor for the number of VOCs detected in the Mojave River Basin; the detection frequency was greater for shallow wells than for deep wells. In the Antelope Valley Basin, neither aquifer type, depth to the top of the perforations, nor land use within 1,640 ft of the well head were explanatory factors for the number of VOCs detected. Although aquifer type and depth to top of the perforations did explain the presence of tritium in the Mojave River Basin, land use within 1,640 ft of the well head was not a statistically significant explanatory factor for the presence of tritium in this basin. Aquifer type, depth to the top of the perfora

Scientific Investigations Report↗