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Jessica D. Garrett

Publications and source records attributed to Jessica D. Garrett.

15 recordsLinked to original sources

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri↗

Sediment and nutrient retention on a reconnected floodplain of an Upper Mississippi River tributary, 2013–2018

The connection of rivers with their floodplains has been greatly reduced in agricultural drainage basins, especially in the Upper Mississippi River Basin. The restriction of the Mississippi River from its floodplain has reduced the sediment trapping and nutrient deposition capabilities of the floodplain, exacerbating water quality problems in the river and in downstream waterbodies. A small part of the Maquoketa River, a tributary to the Upper Mississippi River, was permanently reconnected to its floodplain in 2010 when a levee failure resulted in breaches in two locations. This study quantified the water quality benefits of that reconnection from October 2013 through September 2018. As part of the study, data from groundwater monitoring wells were used to determined hydraulic connectivity and surface-water/groundwater mixing; soil samples were collected in the floodplain to quantify floodplain sediment and nutrient retention potential during postflood and dry, interflood periods; and sensors were placed in the Maquoketa River to quantify total suspended solids, nitrogen, and phosphorus concentrations and loads. The floodplain aquifer in the study area had low hydraulic gradients toward the Maquoketa (mean of 0.017) and Mississippi Rivers (mean of 0.0029) and reducing water-quality conditions (dissolved oxygen less than 1.0 milligram per liter [mg/L] and nitrate less than 0.04 mg/L as nitrogen) capable of denitrification. A specific conductance-based mixing indicated precipitation was the predominate source of groundwater; however, specific conductance-based mixing analysis was unable to distinguish between the river or direct precipitation as the source. The floodplain was fully inundated five times during the study: in June–July 2014, March 2015, January 2017, February 2018, and September 2018. During the March 2015 flood (the only inundation event with sufficient duration to leave quantifiable sediment deposition in the study area), the equivalent of 0.91 percent of the nitrate load and 3.8 percent of the phosphorus load was deposited as sediment on the floodplain. Potential nitrogen losses on the floodplain because of denitrification ranged from 250 kilograms per day (kg/d) as nitrogen in March 2015 to 668 kg/d as nitrogen in October 2014. Potential denitrification rates indicate that when the soil is inundated, inorganic nitrogen present in the soil and in the water column is rapidly denitrified. Soil phosphorus measurements indicated that floodplain soils contain a mean of 365 milligrams per kilogram as phosphorus but still have the capacity to remove phosphorus from flood waters of the Maquoketa River depending on the surface water phosphorus concentration. Results from this study indicate that restoration of even small river-floodplain connections can improve water quality in the Upper Mississippi River.

Iowa↗

Central Midwest Water Science Center— Harmful Algal Blooms team

The U.S. Geological Survey (USGS) Central Midwest Water Science Center (CMWSC) includes three States—Illinois, Iowa, and Missouri. USGS water science centers across the Nation provide information on water resources including streamflow, water use, water availability, and the quality of surface water and groundwater ( https://www.usgs.gov/mission-areas/water-resources ). The USGS CMWSC Harmful Algal Blooms (HABs) team is dedicated to studying the complexity of HABs and is currently (2021) researching ways to better predict the timing, magnitude, and toxicity of HABs. Updated information about the HABs team including current projects, data releases, and publications are available on the CMWSC website ( https://www.usgs.gov/centers/cm-water/science-topics/harmful-algal-blooms ).

Fact Sheet↗

Total phosphorus loadings for the Cedar River at Palo, Iowa, 2009–20

In support of nutrient reduction efforts, total phosphorus loads and yields were computed using turbidity-surrogate and LOAD ESTimator (LOADEST) models for the Cedar River at Palo, Iowa, for January 1, 2009, to December 15, 2020. Sample data were used to create a total phosphorus concentration turbidity-surrogate model. Total phosphorus loads also were computed from two streamflow-based LOADEST load models for the periods 2009–20 and 2016–20. The 2009–20 model was used for comparison with previously published loads at this site. The 2016–20 LOADEST model was used with the turbidity-surrogate model before sensor deployment and during periods of missing sensor data to obtain a more complete annual total phosphorus load. This report presents computed loads and methods needed to compute site-specific loads accurately and track annual progress toward nutrient reduction goals within the State. A comparison of loads from Weighted Regressions on Time, Discharge, and Season; LOADEST; and surrogate models indicated substantial differences at this site among these methods. Changes in both monitoring approaches (high-frequency sensor and surrogate data) and changes in load-calculation methods present potential challenges in assessing trends, such as assessment of load reduction. Annual total phosphorus loads for the Cedar River at Palo, Iowa, ranged from 1,370 to 2,360 U.S. short tons per year for 2018–20, based on the turbidity-surrogate model with gaps in sensor data filled with the 2016–20 LOADEST model. Annual total phosphorus yields for the Cedar River ranged from 0.67 to 1.16 pounds per acre per year for 2018–20. Although this load estimate is lower than previous estimates for the benchmark period of 2006–10, when normalized by streamflow, nearly all the apparent reduction can be attributed to differences in the load-calculation methods.

Palo↗

Nutrient concentrations, loads, and yields in the Middle Iowa River Basin, Iowa

Concentrations, loads, and yields of nitrate plus nitrite, total nitrogen, and total phosphorus were assessed in the Iowa River upstream from the Coralville Reservoir in east-central Iowa. The results of this study describe baseline nutrient transport during two historical reference periods, 1980–96 and 2006–10, that can be used to evaluate the progress of the implementation of reduction strategies in the Middle Iowa River Basin. Where available, nutrient data during the more recent period 2011–18 are also described. Data included nutrient concentrations and streamflow from multiple Federal, State, and Tribal agencies, and loads were computed using multiple techniques to provide valuable insights, which would otherwise not be possible. Despite an upward trend for mean annual and base streamflow (the trend in high streamflow was not significant), average nutrient loads and yields in the Iowa River were smaller in the recent period (2011–18) than in either historical reference period. Notably smaller loads during the 2012 drought, however, caused pronounced skewed average loads for 2011–18. Comparisons among periods were difficult to make because of a short period of data upstream from Marshalltown, Iowa, at the upstream boundary of the study area and a lack of recent data near Marengo, Iowa, at the downstream boundary of the study area. Though spring and summer loads were a disproportionate part of annual loads, up to 90 percent, seasonal load comparisons to determine load reduction were more sensitive to one or the other historical period than was assessment of annual loads. Runoff-transport relations may provide an additional tool to assess load reduction.

Iowa↗

The use of continuous water-quality time-series data to compute total phosphorus loadings for the Turkey River at Garber, Iowa, 2018–20

In support of nutrient reduction efforts, total phosphorus loads and yields were computed for the Turkey River at Garber, Iowa (U.S. Geological Survey station 05412500), for January 1, 2018, to April 30, 2020, based on continuously monitored turbidity sensor data. Sample data were used to create a total phosphorus turbidity-surrogate model. Streamflow-based total phosphorus models were used during periods of missing sensor data to obtain a more complete annual total phosphorus load. This report presents methods needed to accurately compute site-specific loads and track annual progress toward nutrient reduction goals within the State. Annual total phosphorus loads for the Turkey River at Garber, Iowa, were 1,740 and 1,490 U.S. short tons for 2018 and 2019, respectively, with annual yields ranging from 3.01 to 3.53 pounds per acre per year, compared to a mean statewide yield of 0.73 pound per acre per year needed to achieve the total phosphorus-reduction goal.

Iowa↗

The use of continuous water-quality time-series data to compute nutrient loadings for selected Iowa streams, 2008–17

In support of nutrient reduction efforts, nitrate (as nitrate plus nitrite) and phosphorus loads and yields were computed for selected streams in Iowa based on continuously monitored sensor data for 2008–17 and 2014–17, respectively. Sample data were used to assess nitrate sensor bias and to create phosphorus-turbidity surrogate models. Where needed, nitrate loads were corrected for site-specific sensor bias, which was determined to be as high as 9.25 percent. Nitrate loads presented in this report using continuous (generally 15-minute interval) data were on average 4 percent less, but as much as 38 percent less, than annual loads computed from daily mean nitrate concentrations not corrected for sensor bias. Streamflow-based phosphorus models had poorer fit (adjusted coefficient of determination values less than 0.75) than turbidity-based models (adjusted coefficient of determination approximately 0.9). However, alternate models based on streamflow were used to obtain a more complete annual phosphorus load despite seasonal and fragmentary sensor data. Mean annual nitrate yields for 18 selected sites (96 site-years) ranged from 1.68 to 164 pounds per square mile per day (lb/mi 2 /d), compared to 19.4 lb/mi 2 /d average statewide yield needed to achieve the nitrate-reduction goal. Mean annual phosphorus yields for selected sites on the Maquoketa River, South Raccoon River, and West Nishnabotna River range from 1.57 to 7.19 lb/mi 2 /d, compared to 1.06 lb/mi 2 /d average statewide yield needed to achieve the phosphorus-reduction goal.

Iowa↗

Design and methods of the Midwest Stream Quality Assessment (MSQA), 2013

During 2013, the U.S. Geological Survey (USGS) National Water-Quality Assessment Project (NAWQA), in collaboration with the USGS Columbia Environmental Research Center, the U.S. Environmental Protection Agency (EPA) National Rivers and Streams Assessment (NRSA), and the EPA Office of Pesticide Programs assessed stream quality across the Midwestern United States. This Midwest Stream Quality Assessment (MSQA) simultaneously characterized watershed and stream-reach water-quality stressors along with instream biological conditions, to better understand regional stressor-effects relations. The MSQA design focused on effects from the widespread agriculture in the region and urban development because of their importance as ecological stressors of particular concern to Midwest region resource managers. A combined random stratified selection and a targeted selection based on land-use data were used to identify and select sites representing gradients in agricultural intensity across the region. During a 14-week period from May through August 2013, 100 sites were selected and sampled 12 times for contaminants, nutrients, and sediment. This 14-week water-quality “index” period culminated with an ecological survey of habitat, periphyton, benthic macroinvertebrates, and fish at all sites. Sediment was collected during the ecological survey for analysis of sediment chemistry and toxicity testing. Of the 100 sites, 50 were selected for the MSQA random stratified group from 154 NRSA sites planned for the region, and the other 50 MSQA sites were selected as targeted sites to more evenly cover agricultural and urban stressor gradients in the study area. Of the 50 targeted sites, 12 were in urbanized watersheds and 21 represented “good” biological conditions or “least disturbed” conditions. The remaining 17 targeted sites were selected to improve coverage of the agricultural intensity gradient or because of historical data collection to provide temporal context for the study. This report provides a detailed description of the MSQA study components, including surveys of ecological conditions, routine water sampling, deployment of passive polar organic compound integrative samplers, and stream sediment sampling at all sites. Component studies that were completed to provide finer scale temporal data or more extensive analysis at selected sites, included continuous water-quality monitoring, daily pesticide sampling, laboratory and in-stream water toxicity testing efforts, and deployment of passive suspended-sediment samplers.

Illinois, Indiana, Iowa, Kansas, Kentucky, Michiga↗

Neonicotinoid insecticide removal by prairie strips in row-cropped watersheds with historical seed coating use

Neonicotinoids are a widely used class of insecticides that are commonly applied as seed coatings for agricultural crops. Such neonicotinoid use may pose a risk to non-target insects, including pollinators and natural enemies of crop pests, and ecosystems. This study assessed neonicotinoid residues in groundwater, surface runoff water, soil, and native plants adjacent to corn and soybean crop fields with a history of being planted with neonicotinoid-treated seeds from 2008-2013. Data from six sites with the same crop management history, three with and three without in-field prairie strips, were collected in 2015-2016, 2-3 years after neonicotinoid (clothianidin and imidacloprid) seed treatments were last used. Three of the six neonicotinoids analyzed were detected in at least one environmental matrix: the two applied as seed coatings on the fields (clothianidin and imidacloprid) and another widely used neonicotinoid (thiamethoxam). Sites with prairie strips generally had lower concentrations of neonicotinoids: groundwater and footslope soil neonicotinoid concentrations were significantly lower in the sites with prairie strips than those without; mean concentrations for groundwater were 11 and 20 ng/L (p = 0.048) and <1 and 6 ng/g (p = 0.0004) for soil, respectively. Surface runoff water concentrations were not significantly (p = 0.38) different for control sites (44 ng/L) or sites with prairie strips (140 ng/L). Consistent with the decreased inputs of neonicotinoids, concentrations tended to decrease over the sampling timeframe. Two sites recorded concentration increases, however, potentially due to disturbance of previous applications or influence from nearby fields where use of seed treatments continued. There were no detections (limit of detection: 1 ng/g) of neonicotinoids in the foliage or roots of plants comprising prairie strips, indicating a low likelihood of exposure to pollinators and other insects visiting these plants following the cessation of seed coating use. Offsite transport of neonicotinoids to aquatic systems through the groundwater and surface water were furthermore reduced with prairie strips. This study demonstrates the potential for prairie strips comprising 10% of an agricultural catchment to mitigate the non-target impacts of neonicotinoids.

Agriculture, Ecosystems and Environment↗

Using large databases of groundwater chemistry in the northern Midwest USA: The effects of geologic and anthropogenic factors

Regional geochemical databases for the northern Midwest USA are being compiled to examine the various geogenic and anthropogenic factors that control the chemistry of groundwater. At the regional scale, variations are seen that are attributable to agricultural and urban effects, or to geologic factors. Examples of the former include enrichments of nitrate in groundwater, while examples of the latter mainly highlight geochemical differences between carbonate rocks and all other rock types in the region. This paper examines a few of these regional effects and the spatial scales at which they can be observed.

Article↗

Effects of land use and sample location on nitrate-stream flow hysteresis descriptors during storm events

The U.S. Geological Survey's New Jersey and Iowa Water Science Centers deployed ultraviolet-visible spectrophotometric sensors at water-quality monitoring sites on the Passaic and Pompton Rivers at Two Bridges, New Jersey, on Toms River at Toms River, New Jersey, and on the North Raccoon River near Jefferson, Iowa to continuously measure in-stream nitrate plus nitrite as nitrogen (NO 3 + NO 2 ) concentrations in conjunction with continuous stream flow measurements. Statistical analysis of NO 3 + NO 2 vs . stream discharge during storm events found statistically significant links between land use types and sampling site with the normalized area and rotational direction of NO 3 + NO 2 -stream discharge (N-Q) hysteresis patterns. Statistically significant relations were also found between the normalized area of a hysteresis pattern and several flow parameters as well as the normalized area adjusted for rotational direction and minimum NO 3 + NO 2 concentrations. The mean normalized hysteresis area for forested land use was smaller than that of urban and agricultural land uses. The hysteresis rotational direction of the agricultural land use was opposite of that of the urban and undeveloped land uses. An r 2 of 0.81 for the relation between the minimum normalized NO 3 + NO 2 concentration during a storm vs . the normalized NO 3 + NO 2 concentration at peak flow suggested that dilution was the dominant process controlling NO 3 + NO 2 concentrations over the course of most storm events.

Iowa, New Jersey↗

Effects of aquifer storage and recovery activities on water quality in the Little Arkansas River and Equus Beds Aquifer, south-central Kansas, 2011–14

The Equus Beds aquifer in south-central Kansas is aprimary water source for the city of Wichita. The Equus Beds aquifer storage and recovery (ASR) project was developed to help the city of Wichita meet increasing current (2016) and future water demands. The Equus Beds ASR project pumps water out of the Little Arkansas River during above-base flow conditions, treats it using drinking-water quality standards as a guideline, and recharges it into the Equus Beds aquifer for later use. Phase II of the Equus Beds ASR project currently (2016) includes a river intake facility and a surface-water treatment facility with a 30 million gallon per day capacity. Water diverted from the Little Arkansas River is delivered to an adjacent presedimentation basin for solids removal. Subsequently, waste from the surface-water treatment facility and the presedimentation basin is returned to the Little Arkansas River through a residuals return line. The U.S. Geological Survey, in cooperation with the city of Wichita, developed and implemented a hydrobiological monitoring program as part of the ASR project to characterize and quantify the effects of aquifer storage and recovery activities on the Little Arkansas River and Equus Beds aquifer water quality. Data were collected from 2 surface-water sites (one upstream and one downstream from the residuals return line), 1 residuals return line site, and 2 groundwater well sites (each having a shallow and deep part): the Little Arkansas River upstream from the ASR facility near Sedgwick, Kansas (upstream surface-water site 375350097262800), about 0.03 mile (mi) upstream from the residuals return line site; the Little Arkansas River near Sedgwick, Kans. (downstream surface-water site 07144100), about 1.68 mi downstream from the residuals return line site; discharge from the Little Arkansas River ASR facility near Sedgwick, Kansas (residuals return line site 375348097262800); 25S 01 W 07BCCC01 SMW–S11 near CW36 (MW–7 shallow groundwater well site 375327097285401); 25S01 W 07BCCC02 DMW–S10 near CW36 (MW–7 deep groundwater well site 375327097285402); 25S 01W 07BCCA01 SMW–S13 near CW36 (MW–8 shallow groundwater well site 375332097284801); and 25S 01W 07BCCA02 DMW–S14 near CW36 (MW–8 deep groundwater well site 375332097284802). The U.S. Geological Survey, in cooperation with the city of Wichita, assessed the effects of the ASR Phase II facility residuals return line discharges on stream quality of the Little Arkansas River by measuring continuous physicochemical properties and collecting discrete water-quality and sediment samples for about 2 years pre- (January 2011 through April 2013) and post-ASR (May 2013 through December 2014) Phase II facility operation upstream and downstream from the ASR Phase II facility. Additionally, habitat variables were quantified and macroinvertebrate and fish communities were sampled upstream and downstream from the ASR Phase II facility during the study period. To assess the effects of aquifer recharge on Equus Beds groundwater quality, continuous physicochemical properties were measured and discrete water-quality samples were collected before and during the onset of Phase II aquifer recharge in two (shallow and deep) groundwater wells. Little Arkansas River streamflow was about 10 times larger after the facility began operating because of greater rainfall. Residuals return line release volumes were a very minimal proportion (0.06 percent) of downstream streamflow volume during the months the ASR facility was operating. Upstream and downstream continuously measured water temperature and dissolved oxygen median differences were smaller post-ASR than pre-ASR. Turbidity generally was smaller at the downstream site throughout the study period and decreased at both sites after the ASR Phase II facility began discharging despite a median residuals return line turbidity that was about an order of magnitude larger than the median turbidity at the downstream site. Upstream and downstream continuously measured turbidity median differences were larger post-ASR than pre-ASR. Median post-ASR continuously measured nitrite plus nitrate and continuously computed total suspended solids and suspended-sediment concentrations were smaller than pre-ASR likely because of higher streamflows and dilution; whereas, median continuously computed dissolved and total organic carbon concentrations were larger likely because of higher streamflows and runoff conditions. None of the discretely measured water-quality constituents (dissolved and suspended solids, primary ions, suspended sediment, nutrients, carbon, trace elements, viral and bacterial indicators, and pesticides) in surface water were significantly different between the upstream and downstream sites after the ASR Phase II facility began discharging; however, pre-ASR calcium, sodium, hardness, manganese, and arsenate concentrations were significantly larger at the upstream site, which indicates that some water-quality conditions at the upstream and downstream sites were more similar post-ASR. Most of the primary constituents that make up dissolved solids decreased at both sites after the ASR Phase II facility began operation. Discretely collected total suspended solids concentrations were similar between the upstream and downstream sites before the facility began operating but were about 27 percent smaller at the downstream site after the facility began operating, despite the total suspended solids concentrations in the residuals return line being 15 times larger than the downstream site. Overall habitat scores were indicative of suboptimal conditions upstream and downstream from the ASR Phase II facility throughout the study period. Substrate fouling and sediment deposition mean scores indicated marginal conditions at the upstream and downstream sites during the study period, demonstrating that sediment deposition was evident pre- and post-ASR and no substantial changes in these habitat characteristics were noted after the ASR Phase II facility began discharging. Macroinvertebrate community composition (evaluated using functional feeding, behavioral, and tolerance metrics) generally was similar between sites during the study period. Fewer macroinvertebrate metrics were significant between the upstream and downstream sites post-ASR (6) than pre-ASR (14), which suggests that macroinvertebate communities were more similar after the ASR facility began discharging. Upstream-downstream comparisons in macroinvertebrate aquatic-life-support metrics had no significant differences for the post-ASR time period and neither site was fully supporting for any of the Kansas Department of Health and Environment aquatic-life-support metrics (Macroinvertebrate Biotic Index; Kansas Biotic Index with tolerances for nutrients and oxygen-demanding substances; Ephemeroptera, Plecoptera, and Trichoptera [EPT] richness; and percentage of EPT species). Overall, using macroinvertebrate aquatic life-support criteria from the Kansas Department of Health and Environment, upstream and downstream sites were classified as partially supporting before and after the onset of ASR facility operations. Fish community trophic status and tolerance groups generally were similar among sites during the study period. Fish community Little Arkansas River Basin Index of Biotic Integrity scores at the upstream and downstream sites were indicative of fair-to-good conditions before the facility began operating and decreased to fair conditions after the facility began operating. Groundwater physicochemical changes concurrent with the beginning of recharge operations at the Sedgwick basin were more pronounced in shallow groundwater. No constituent concentrations in the pre-recharge period in comparison to the post-recharge period increased to concentrations exceeding drinking water regulations; however, nitrate decreased significantly from a pre-recharge exceedance of the U.S. Environmental Protection Agency maximum contaminant level to a post recharge nonexceedance. Shallow groundwater chemical concentrations or rates of detection increased after artificial recharge began for the ions potassium, chloride, and fluoride; phosphorus and organic carbon species; trace elements barium, manganese, nickel, arsenate, arsenic, and boron; agricultural pesticides atrazine, metolachlor, metribuzin, and simazine; organic disinfection byproducts bromodichloromethane and trichloromethane; and gross beta levels. Additionally, water temperature, and pH were larger after recharge began; and total solids and slime-forming bacteria concentrations and densities were smaller. Total solids, nitrate, and selenium significantly decreased; and potassium, chloride, nickel, arsenic, fluoride, phosphorus and carbon species, and gross beta levels significantly increased in shallow groundwater after artificial recharge. Results of biological activity reaction tests indicated that water quality microbiology was different before and after artificial recharge began; at times, these differences may lead to changes in dominant bacterial populations that, in turn, may lead to formation and expansion in populations that may cause bioplugging and other unwanted effects. Calcite, iron (II) hydroxide, hydroxyapatite, and similar minerals, had shifts in saturation indices that generally were from undersaturation toward equilibrium and, in some cases, toward oversaturation. These shifts toward neutral saturation indices might suggest reduced weathering of the minerals present in the Equus Beds aquifer. Chemical weathering in the shallow parts of the aquifer may be accelerated because of the increased water temperatures and the system is more vulnerable to clogged pores and mineral dissolution as the equilibrium state is affected by recharge and withdrawal. When oversaturation is indicated for iron minerals, plugging of aquifer materials may happen.

Kansas↗

Design and methods of the Southeast Stream Quality Assessment (SESQA), 2014

During 2014, the U.S. Geological Survey (USGS) National Water-Quality Assessment Program (NAWQA) assessed stream quality across the Piedmont and southern Appalachian Mountain regions of the southeastern United States. This Southeast Stream Quality Assessment (SESQA) simultaneously characterized watershed and stream-reach water-quality stressors along with instream biological conditions, in order to better understand regional stressor-effects relations. The goal of SESQA is to provide communities and policymakers with information about those human and environmental factors that have the greatest impact on stream quality across the region. The SESQA design focused on hydrologic alteration and urbanization because of their importance as ecological stressors of particular concern to Southeast region resource managers. Streamflow and land-use data were used to identify and select sites representing gradients in urbanization and streamflow alteration across the region. One hundred fifteen sites were selected and sampled for as many as 10 weeks during April, May, and June 2014 for contaminants, nutrients, and sediment. This water-quality &ldquo;index&rdquo; period culminated with an ecological survey of habitat, periphyton, benthic macroinvertebrates, and fish at all sites. Sediment was collected during the ecological survey for analysis of sediment chemistry and toxicity testing. Of the 115 sites, 59 were on streams in watersheds with varying degrees of urban land use, 5 were on streams with multiple confined animal feeding operations, and 13 were reference sites with little or no development in their watersheds. The remaining 38 &ldquo;hydro&rdquo; sites were on streams in watersheds with relatively little agricultural or urban development but with hydrologic alteration, such as a dam or reservoir. This report provides a detailed description of the SESQA study components, including surveys of ecological conditions, routine water sampling, deployment of passive polar organic compound integrative samplers for pesticides and contaminants of emerging concern, and synoptic sediment sampling and toxicity testing at all urban, confined animal feeding operation, and reference sites. Continuous water-quality monitoring and daily pesticide sampling efforts conducted at a subset of urban sites are also described.

Alabama, Georgia, North Carolina, South Carolina, ↗

Optical techniques for the determination of nitrate in environmental waters: Guidelines for instrument selection, operation, deployment, maintenance, quality assurance, and data reporting

The recent commercial availability of in situ optical sensors, together with new techniques for data collection and analysis, provides the opportunity to monitor a wide range of water-quality constituents on time scales in which environmental conditions actually change. Of particular interest is the application of ultraviolet (UV) photometers for in situ determination of nitrate concentrations in rivers and streams. The variety of UV nitrate sensors currently available differ in several important ways related to instrument design that affect the accuracy of their nitrate concentration measurements in different types of natural waters. This report provides information about selection and use of UV nitrate sensors by the U.S. Geological Survey to facilitate the collection of high-quality data across studies, sites, and instrument types. For those in need of technical background and information about sensor selection, this report addresses the operating principles, key features and sensor design, sensor characterization techniques and typical interferences, and approaches for sensor deployment. For those needing information about maintaining sensor performance in the field, key sections in this report address maintenance and calibration protocols, quality-assurance techniques, and data formats and reporting. Although the focus of this report is UV nitrate sensors, many of the principles can be applied to other in situ optical sensors for water-quality studies.

Techniques and Methods↗

Concentrations, loads, and yields of select constituents from major tributaries of the Mississippi and Missouri Rivers in Iowa, water years 2004-2008

Excess nutrients, suspended-sediment loads, and the presence of pesticides in Iowa rivers can have deleterious effects on water quality in State streams, downstream major rivers, and the Gulf of Mexico. Fertilizer and pesticides are used to support crop growth on Iowa's highly productive agricultural landscape and for household and commercial lawns and gardens. Water quality was characterized near the mouths of 10 major Iowa tributaries to the Mississippi and Missouri Rivers from March 2004 through September 2008. Stream loads were calculated for select ions, nutrients, and sediment using approximately monthly samples, and samples from storm and snowmelt events. Water-quality samples collected using standard streamflow-integrated protocols were analyzed for major ions, nutrients, carbon, pesticides, and suspended sediment. Statistical data summaries of sample data used parametric and nonparametric techniques to address potential bias related to censored data and multiple levels of censoring of data below analytical detection limits. Constituent stream loads were computed using standard pre-defined models in S-LOADEST that include streamflow and time terms plus additional terms for streamflow variability and streamflow anomalies. Streamflow variability terms describe the difference in streamflow from recent average conditions, whereas streamflow anomaly terms account for deviations from average conditions from long- to short-term sequentially. Streamflow variability or anomaly terms were included in 44 of 80 site/constituent individual models, demonstrating the usefulness of these terms in increasing accuracy of the load estimates. Constituent concentrations in Iowa streams exhibit streamflow, seasonal, and spatial patterns related to the landform and climate gradients across the studied basins. The streamflow-concentration relation indicated dilution for ions such as chloride and sulfate. Other constituent concentrations, such as dissolved organic carbon and suspended sediment, increased with streamflow. Nitrogen concentrations (total nitrogen and nitrate plus nitrite) increased with low and moderate streamflows, but decreased with high streamflows. Seasonal patterns observed in constituent concentrations were affected by streamflow, algae blooms, and pesticide application. The various landform regions produced different water-quality responses across the study basins; for example, total phosphorus, suspended sediment, and turbidity were greatest from the steep, loess-dominated southwestern Iowa basins. Nutrient concentrations, though not regulated for drinking water at the study sites, were high compared to drinking-water limits and criteria for protection of aquatic life proposed for other Midwestern states (Iowa criteria for aquatic life have not been proposed). Nitrate plus nitrite concentrations exceeded the drinking-water limit [10 milligrams per liter (mg/L)] in 11 percent of all samples at the 10 sites, and exceeded Minnesota's proposed aquatic life criteria (4.9 mg/L) in 68 percent of samples. The Wisconsin standard for total phosphorus (0.1 mg/L) was exceeded in 92 percent of samples. Ammonia standards, current during sample collection and at publication of this report, for protection of aquatic life were met for all samples, but draft criteria proposed in 2009 to protect more sensitive species like mussels, were exceeded at three sites. Loads and yields also differed among sites and years. The Big Sioux, Little Sioux, and Des Moines Rivers produced the greatest sulfate yields. Mississippi River tributaries had greater chloride yields than Missouri River tributaries. The Big Sioux River also had the lowest silica yields and total nitrogen and nitrate yields, whereas nitrogen yields were greater in the northeastern rivers. The Boyer and Nishnabotna River total phosphorus yields were the greatest in the study. The Boyer River orthophosphate yields were greatest except in 2008, when the Maquoketa River produced the greatest yield. Rivers in southwestern Iowa's Western Loess Hills and Steeply Rolling Loess Prairie ecoregions had the greatest suspended-sediment yields, whereas the smallest yields were in the Big Sioux and Wapsipinicon Rivers. In the 10 Iowa rivers studied, combined annual total nitrogen stream transport ranged from 3.68 to 9.95 tons per square mile per year, and total phosphorus transport ranged from 0.138 to 0.570 tons per square mile per year. Six-month loads relative to fertilizer use ranged from 8 to 56 percent for nitrogen, and 1.0 to 11.1 percent for phosphorus. The smallest loads relative to fertilizer use for both nitrogen and phosphorus occurred in July-December of dry years, and the largest nitrogen and phosphorus loads relative to use were in wet years from January-June.

Iowa;Minnesota;South Dakota↗