Search USGS⌕ Search

Geology topics

Jerri V. Davis

Publications and source records attributed to Jerri V. Davis.

At least 19 recordsLinked to original sources

A comparison of algal, macroinvertebrate, and fish assemblage indices for assessing low-level nutrient enrichment in wadeable Ozark streams

Biotic indices for algae, macroinvertebrates, and fish assemblages can be effective for monitoring stream enrichment, but little is known regarding the value of the three assemblages for detecting perturbance as a consequence of low-level nutrient enrichment. In the summer of 2006, we collected nutrient and biotic samples from 30 wadeable Ozark streams that spanned a nutrient-concentration gradient from reference to moderately enriched conditions. Seventy-three algal metrics, 62 macroinvertebrate metrics, and 60 fish metrics were evaluated for each of the three biotic indices. After a group of candidate metrics had been identified with multivariate analysis, correlation procedures and scatter plots were used to identify the four metrics having strongest relations to a nutrient index calculated from log transformed and normalized total nitrogen and total phosphorus concentrations. The four metrics selected for each of the three biotic indices were: algae—the relative abundance of most tolerant diatoms, the combined relative abundance of three species of Cymbella , mesosaprobic algae percent taxa richness, and the relative abundance of diatoms that are obligate nitrogen heterotrophs; macroinvertebrate—the relative abundance of intolerant organisms, Baetidae relative abundance, moderately tolerant taxa richness, and insect biomass; fish—herbivore and detritivore taxa richness, pool species relative abundance, fish catch per unit effort, and black bass ( Micropterus spp.) relative abundance. All three biotic indices were negatively correlated to nutrient concentrations but the algal index had a higher correlation (rho = −0.89) than did the macroinvertebrate and fish indices (rho = −0.63 and −0.58, respectively). Biotic index scores were lowest and nutrient concentrations were highest for streams with basins having the highest poultry and cattle production. Because of the availability of litter for fertilizer and associated increases in grass and hay production, cattle feeding capacity increases with poultry production. Studies are needed that address the synergistic effect of poultry and cattle production on Ozark streams in high production areas before ecological risks can be adequately addressed.

Arkansas, Oklahoma↗

Surface-Water Quality Conditions and Long-Term Trends at Selected Sites within the Ambient Water-Quality Monitoring Network in Missouri, Water Years 1993-2008

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, collects data pertaining to the surface-water resources of Missouri. These data are collected as part of the Missouri Ambient Water-Quality Monitoring Network and constitute a valuable source of reliable, impartial, and timely information for developing an improved understanding of water resources in the State. Six sites from the Ambient Water-Quality Monitoring Network, with data available from the 1993 through 2008 water years, were chosen to compare water-quality conditions and long-term trends of dissolved oxygen, selected physical properties, total suspended solids, dissolved nitrate plus nitrite as nitrogen, total phosphorous, fecal indicator bacteria, and selected trace elements. The six sites used in the study were classified in groups corresponding to the physiography, main land use, and drainage basin size, and represent most stream types in Missouri. Long-term trends in this study were analyzed using flow-adjusted and non-flow adjusted models. Highly censored datasets (greater than 5 percent but less than 50 percent censored values) were not flow-adjusted. Trends that were detected can possibly be related to changes in agriculture or urban development within the drainage basins. Trends in nutrients were the most prevalent. Upward flow-adjusted trends in dissolved nitrate plus nitrite (as nitrogen) concentrations were identified at the Elk River site, and in total phosphorus concentrations at the South Fabius and Grand River sites. A downward flow-adjusted trend was identified in total phosphorus concentrations from Wilson Creek, the only urban site in the study. The downward trend in phosphorus possibly was related to a phosphorus reduction system that began operation in 2001 at a wastewater treatment plant upstream from the sampling site. Total suspended solids concentrations indicated an upward non-flow adjusted trend at the two northern sites (South Fabius and Grand Rivers). The increase in total suspended solids concentrations could be because of soil erosion from land cultivated for row crops. Most trace element data examined in the study were highly censored and could not be used for flow-adjusted trend analyses. Water-quality conditions were assessed to explore relations between data from sites and to the State water-quality standards where applicable for selected constituents. Streamflow varied at each site because of drainage area, land use, and groundwater inputs. Dissolved oxygen and water temperature were similar at all sites except the urban site located on Wilson Creek. Specific conductance was similar between the most northern (South Fabius and Grand River sites) and the most southern sites (Current and Elk River sites). Total suspended solids concentrations were near the method reporting level at all sites, except the northern sites. Streams in northern Missouri are more turbid than streams in southern Missouri and are affected by large volumes of sediment deposition because of soil erosion from land cultivated for row crops. Geometric means of Escherichia coli were calculated from the recreational seasons within the study period. Only the Grand River site exceeded the whole-body-contact standard for frequently used waters. The South Fabius and Grand River sites and the Wilson Creek site had statistically larger densities of both fecal indicator bacteria types than the remaining sites.

Scientific Investigations Report↗

Occurrence and sources of Escherichia coli in metropolitan St. Louis streams, October 2004 through September 2007

The occurrence and sources of Escherichia coli (E. coli) , one of several fecal indicator bacteria, in metropolitan St. Louis streams known to receive nonpoint source runoff, occasional discharges from combined and sanitary sewers, and treated wastewater effluent were investigated from October 2004 through September 2007. Three Missouri River sites, five Mississippi River sites, and six small basin tributary stream sites were sampled during base flow and storm events for the presence of E. coli and their sources. E. coli host-source determinations were conducted using local library based genotypic methods. Human fecal contamination in stream samples was additionally confirmed by the presence of Bacteroides thetaiotaomicron , an anaerobic, enteric bacterium with a high occurrence in, and specificity to, humans. Missouri River E. coli densities and loads during base flow were approximately 10 times greater than those in the Mississippi River above its confluence with the Missouri River. Although substantial amounts of E. coli originated from within the study area during base flow and storm events, considerable amounts of E. coli in the Missouri River, as well as in the middle Mississippi River sections downstream from its confluence with the Missouri River, originated in Missouri River reaches upstream from the study area. In lower Mississippi River reaches, bacteria contributions from the numerous combined and sanitary sewer overflows within the study area, as well as contributions from nonpoint source runoff, greatly increased instream E. coli densities. Although other urban factors cannot be discounted, average E. coli densities in streams were strongly correlated with the number of upstream combined and sanitary sewer overflow points, and the percentage of upstream impervious cover. Small basin sites with the greatest number of combined and sanitary sewer overflows (Maline Creek and the River des Peres) had larger E. coli densities, larger loads, and a greater percentage of E. coli attributable to humans than other small basin sites; however, even though small basin E. coli densities typically were much larger than in large river receiving streams, small basins contributed, on average, only a small part (a maximum of 16 percent) of the total E. coli load to larger rivers. On average, approximately one-third of E. coli in metropolitan St. Louis streams was identified as originating from humans. Another one-third of the E. coli was determined to have originated from unidentified sources; dogs and geese contributed lesser amounts, 10 and 20 percent, of the total instream bacteria. Sources of E. coli were largely independent of hydrologic conditions—an indication that sources remained relatively consistent with time.

Missouri↗

Quality of Surface Water in Missouri, Water Year 2007

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a series of monitoring stations on streams throughout Missouri known as the Ambient Water-Quality Monitoring Network. During the 2007 water year (October 1, 2006 through September 30, 2007), data were collected at 67 stations including two U.S. Geological Survey National Stream Quality Accounting Network stations and one spring sampled in cooperation with the U.S. Forest Service. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, fecal coliform bacteria, dissolved nitrite plus nitrte, total phosphorus, dissolved and total recoverable lead and zinc, and selected pesticide data summaries are presented for 64 of these stations, which primarily have been classified in groups corresponding to the physiography of the State, main land use, or unique station types. In addition, a summary of hydrologic conditions in the State during water year 2007 is presented.

Open-File Report↗

Quality of Surface Water in Missouri, Water Year 2008

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, designed and operates a series of monitoring stations on streams throughout Missouri known as the Ambient Water-Quality Monitoring Network. During the 2008 water year (October 1, 2007, through September 30, 2008), data were collected at 67 stations, including two U.S. Geological Survey National Stream Quality Accounting Network stations and one spring sampled in cooperation with the U.S. Forest Service. Dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, fecal coliform bacteria, Escherichia coli bacteria, dissolved nitrate plus nitrite, total phosphorus, dissolved and total recoverable lead and zinc, and selected pesticide data summaries are presented for 64 of these stations. The stations primarily have been classified into groups corresponding to the physiography of the State, primary land use, or unique station types. In addition, a summary of hydrologic conditions in the State including peak discharges, monthly mean discharges, and seven-day low flow is presented.

Open-File Report↗

Nutrient and Suspended-Sediment Trends in the Missouri River Basin, 1993-2003

Trends in streamflow and concentration of total nitrogen, nitrite plus nitrate, ammonia, total phosphorus, orthophosphorus, and suspended sediment were determined for the period from 1993 to 2003 at selected stream sites in the Missouri River Basin. Flow-adjusted trends in concentration (the trends that would have occurred in the absence of natural changes in streamflow) and non-flow-adjusted trends in concentration (the overall trends resulting from natural and human factors) were determined. In the analysis of flow-adjusted trends, the removal of streamflow as a variable affecting concentration allowed trends caused by other factors such as implementation of best management practices to be identified. In the analysis of non-flow-adjusted trends, the inclusion of any and all factors affecting concentration allowed trends affecting aquatic ecosystems and the status of streams relative to water-quality standards to be identified. Relations between the flow-adjusted and non-flow-adjusted trends and changes in streamflow, nutrient sources, ground-water inputs, and implementation of management practices also were examined to determine the major factors affecting the trends. From 1993 to 2003, widespread downward trends in streamflow indicated that drought conditions from about 2000 to 2003 led to decreasing streamflow throughout much of the Missouri River Basin. Flow-adjusted trends in nitrite plus nitrate and ammonia concentrations were split nearly equally between nonsignificant and downward; at about one-half of the sites, management practices likely were contributing to measurable decreases in concentrations of nitrite plus nitrate and ammonia. Management practices had less of an effect on concentrations of total nitrogen; downward flow-adjusted trends in total nitrogen concentrations occurred at only 2 of 19 sites. The pattern of non-flow-adjusted trends in nitrite plus nitrate concentrations was similar to the pattern of flow-adjusted trends; non-flow-adjusted trends were split nearly equally between nonsignificant and downward. A substantial source of nitrite plus nitrate to these streams likely was ground water; because of the time required for ground water to travel to streams, there may have been a lag time between the implementation of some pollution-control strategies and improvement in stream quality, contributing to the nonsignificant trends in nitrite plus nitrate. There were more sites with downward non-flow-adjusted trends than flow-adjusted trends in both ammonia and total nitrogen concentrations, possibly a result of decreased surface runoff from nonpoint sources associated with the downward trends in streamflow. No strong relations between any of the nitrogen trends and changes in nutrient sources or landscape characteristics were identified. Although there were very few upward trends in nitrogen from 1993 to 2003, there were upward flow-adjusted trends in total phosphorus concentrations at nearly one-half of the sites. At these sites, not only were pollution-control strategies not contributing to measurable decreases in total phosphorus concentrations, there was likely an increase in phosphorus loading on the land surface. There were fewer upward non-flow-adjusted than flow-adjusted trends in total phosphorus concentrations; at the majority of sites, overall total phosphorus concentrations did not change significantly during this period. The preponderance of upward flow-adjusted trends and nonsignificant non-flow-adjusted trends indicates that in some areas of the Missouri River Basin, overall concentrations of total phosphorus would have been higher without the decrease in streamflow and the associated decrease in surface runoff during the study period. During the study period, phosphorus loads from fertilizer generally increased at over one-half of the sites in the basin. Upward flow-adjusted trends were related to increasing fertilizer use in the upstream drainage area, particularly in the 10 percent

Scientific Investigations Report↗

Assessment of possible sources of microbiological contamination in the water column and streambed sediment of the Jacks Fork, Ozark National Scenic Riverways, Missouri — Phase III

In 1998, a 5 river-mile reach of the Jacks Fork was included on Missouri's list of impaired waters as required by Section 303(d) of the Federal Clean Water Act. The identified pollutant on the Jacks Fork was fecal coliform bacteria. The length of the impaired reach was changed to 7 miles on the Missouri 2002 303(d) list because of data indicating the fecal coliform bacteria problem existed over a broader area. The U.S. Geological Survey, in cooperation with the National Park Service, conducted a study to better understand the extent and sources of microbiological contamination within the Jacks Fork from Alley Spring to the mouth, which includes the 7-mile 303(d) reach. Ten sites were sampled from June 2003 through October 2003 and from June 2004 through October 2004. Water-column and streambed sediment samples were collected from main-stem and tributary sites mostly during base-flow conditions during a variety of recreational season river uses and analyzed for fecal coliform and Escherichia coli bacteria. Isolates of Escherichia coli obtained from water samples collected at five sites were submitted for rep-PCR analysis to identify presumptive sources of fecal indicator bacteria in the Jacks Fork. Results indicate that recreational users (including boaters and swimmers) are not the primary source of fecal coliform bacteria in the Jacks Fork; rather, the presence of fecal coliform bacteria is associated with other animals, of which horses are the primary source. Increases in fecal coliform bacteria densities in the Jacks Fork are associated with cross-country horseback trail-riding events.

Missouri↗

Specificity of a Bacteroides thetaiotaomicron marker for human feces

A bacterial primer set, known to produce a 542-bp amplicon specific for Bacteroides thetaiotaomicron, generated this product in PCR with 1 ng of extracted DNA from 92% of 25 human fecal samples, 100% of 20 sewage samples, and 16% of 31 dog fecal samples. The marker was not detected in 1 ng of fecal DNA from 61 cows, 35 horses, 44 pigs, 24 chickens, 29 turkeys, and 17 geese. Copyright ?? 2005, American Society for Microbiology. All Rights Reserved.

Applied and Environmental Microbiology↗

Specific electrical conductance

Electrical conductance is a measure of the capacity of a substance to conduct an electrical current. The specific electrical conductance (conductivity) of water is a function of the types and quantities of dissolved substances it contains, normalized to a unit length and unit cross section at a specified temperature. This section of the National Field Manual (NFM) describes U.S. Geological Survey (USGS) guidance and protocols for measurement of conductivity in ground and surface waters.

Techniques of Water-Resources Investigations↗

Assessment of possible sources of microbiological contamination and water-quality characteristics of the Jacks Fork, Ozark National Scenic Riverways, Missouri — Phase II

In 1998, an 8-mile reach of the Jacks Fork was included on Missouri's list of impaired waters as required by Section 303(d) of the Federal Clean Water Act. The identified pollutant on the Jacks Fork was fecal coliform bacteria. Potential sources of fecal contamination to the Jacks Fork include a wastewater treatment plant; campground pit-toilet or septic-system effluent; a large commercial, cross-country horseback trail riding facility; canoeists, boaters, and tubers; and cows. The U.S. Geological Survey, in cooperation with the National Park Service, conducted a study to better understand the extent and sources of microbiological contamination within the Jacks Fork from Alley Spring to the mouth, which includes the 8-mile 303(d) reach. Identification of the sources would provide the National Park Service and the State of Missouri with the information needed to craft a solution of abatement, regulation, prevention, and mitigation with the end result being the removal of the Jacks Fork from the 303(d) list. Fifteen sites were sampled from November 1999 through December 2000. An additional site was sampled one time. Samples were collected mostly during base-flow conditions during a variety of nonrecreational and recreational season river uses. Samples were analyzed for selected fecal indicator bacteria, physical properties, nutrients, and wastewater organic compounds. During the sampling period, the whole-body-contact recreation standard for fecal coliform (200 colonies per 100 milliliters of sample) was exceeded at three sites on August 10, 2000, and also at one site on May 11, June 7, and October 3, 2000. Fecal coliform densities and instantaneous loads generally increased from background concentrations at the Eminence site, peaked about 2 river miles downstream, and then decreased until the most downstream site sampled. Generally, the largest densities and loads at sites downstream from Eminence not related to wet-weather flow were observed during a trail ride held August 6 to 12, 2000. A 24-hour sample collection effort was conducted the weekend of July 15 and 16, 2000, to investigate the effect that large numbers of swimmers, canoeists, and tubers had on fecal coliform densities in the Jacks Fork. Five or six samples were collected at six sites between Saturday morning and the following Sunday afternoon. No fecal coliform density at any of the sites sampled exceeded the whole-body-contact recreation standard. Because bacteria survive longer in stream-bed sediments than in water, a source of bacteria in the water column could be from resuspension of accumulated bacteria from streambed sediments. Water and streambed-sediment samples were collected at three sites on August 3, 2000, 1 week before a trail ride and again at three sites on August 8, 2000, during a trail ride. Sixty-five Escherichia coli isolates obtained from water samples collected at 9 sites and 23 Escherichia coli isolates obtained from stream-bed-sediment samples collected at 5 sites were submitted for ribotyping analysis. Samples were collected in 2000 during a variety of nonrecreational and recreational season river uses, including trail rides, canoeing, tubing, and swimming. Of the 65 isolates from water samples, 40 percent were identified as originating from sewage, 29 percent from horse, 11 percent from cow, and 20 percent from an unknown source. Of the 23 isolates from streambed-sediment samples, 39 percent were identified as originating from sewage, 35 percent from horse, 13 percent from cow, and 13 percent from unknown sources. Analysis of physical property (dissolved oxygen, pH, specific conductance, and temperature) and nutrient (dissolved nitrite plus nitrate and total phosphorus) data indicated that overall few statistically significant differences occurred among the main stem sites of the Jacks Fork. A significant increase in total phosphorus concentrations did occur at site 75 immediately downstream from the Eminence Wastewater Treatment Plant, but the effect diminished quickly downstream. Unlike fecal coliform bacteria, most variations in physical property values or nutrient concentrations were related to seasonal changes, time of day the sample was collected, or hydrologic conditions and not to certain recreational activities. Trace quantities of wastewater organic compounds were detected in all waters sampled for these constituents. Two of the compounds were detected in associated laboratory blanks, and other detected compounds have sources other than sewage effluent. The best indicators of municipal or domestic sewage effluent were the non-ionic detergent metabolites (nonylphenol monoethoxylate, octylphenol monoethoxylate, and para-nonylphenol), phenol, and caffeine; but possible sources of these compounds, which were detected in one or more of the samples, could be the numerous campers, swimmers, and canoeists that were present when the samples were collected.

Missouri↗

Assessment of microbiological contamination of the Jacks Fork within the Ozark National Scenic Riverways, Missouri—phase I

The Ozark National Scenic Riverways (ONSR), the Nation's first scenic riverway, was created by an Act of Congress (Public Law 88-492) on August 24, 1964, for "the purpose of conserving and interpreting unique scenic and other natural values and objects of historic interest, including preservation of parts of the Current River and the Jacks Fork River in Missouri as free-flowing streams, preservation of springs and caves, management of wildlife, and provisions for use and enjoyment of the outdoor recreation resources thereof by the people of the United States" (National Park Service, 1981). The primary natural resources protected by the park are 134 miles of the Current and Jacks Fork Rivers. About 1.5 million people visit the ONSR annually to take advantage of excellent recreational opportunities, including canoeing, johnboating, swimming, fishing, tubing, camping, hiking, caving, horseback riding, and hunting.

Fact Sheet↗

Quality of Ozark streams and ground water, 1992-95

This fact sheet summarizes a previous USGS publication, 'Water Quality in the Ozark Plateaus, Arkansas, Kansas, Missouri, and Oklahoma, 1992' (Circular 1158). The fact sheet describes the effects of some of the major land uses and human activities upon water quality in the Ozarks. Nutrients, bacteria, pesticides, and other organic compounds generally are found in high concentrations or more frequently in agricultural or urban areas than in forested areas. Several metals are found in higher concentrations in water, bed sediment, or biological tissue downstream from mining areas. Nutrient concentrations generally do not make water unsafe for drinking. Bacteria concentrations may be high enough to cause concern in some areas at some times. Pesticides and other organic compounds generally are not of concern. Metal concentrations in some mining areas are of concern to humans and wildlife. Biological communities are being altered by habitat and water-quality changes.

Fact Sheet↗

Water quality in the Ozark Plateaus, Arkansas, Kansas, Missouri, and Oklahoma, 1992-95

This report is intended to summarize major findings that emerged between 1992 and 1995 from the water-quality assessment of the Ozark Plateaus Study Unit and to relate these findings to water-quality issues of regional and national concern. The information is primarily intended for those who are involved in water-resource management. Yet, the information contained here may also interest those who simply wish to know more about the quality of water in the rivers and aquifers in the area where they live.

Arkansas, Kansas, Missouri, Oklahoma↗

Microbiological quality of public-water supplies in the Ozark Plateaus aquifer system, Missouri

In 1986, Congress amended the Safe Drinking Water Act (SDWA) requiring the U.S. Environmental Protection Agency (USEPA) to promulgate disinfection requirements for all public-water supplies. The USEPA promulgated the Surface Water Treatment Rule (SWTR) in June 1989 to establish disinfection requirements for surface-water supplies and for ground water under the direct influence of surface water. To complete the requirements of the SDWA, the USEPA plans to propose and promulgate disinfection requirements for ground water not under the direct influence of surface water to protect the public health of persons served by those systems.

Fact Sheet↗

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma — Nutrients, bacteria, organic carbon, and suspended sediment in surface water, 1993-95

Nutrient, bacteria, organic carbon, and suspended- sediment samples were collected from 1993-95 at 43 surface-water-quality sampling sites within the Ozark Plateaus National Water- Quality Assessment Program study unit. Most surface-water-quality sites have small or medium drainage basins, near-homogenous land uses (primarily agricultural or forest), and are located predominantly in the Springfield and Salem Plateaus. The water-quality data were analyzed using selected descriptive and statistical methods to determine factors affecting occurrence in streams in the study unit. Nitrogen and phosphorus fertilizer use increased in the Ozark Plateaus study unit for the period 1965-85, but the application rates are well below the national median. Fertilizer use differed substantially among the major river basins and physiographic areas in the study unit. Livestock and poultry waste is a major source of nutrient loading in parts of the study unit. The quantity of nitrogen and phosphorus from livestock and poultry wastes differed substantially among the river basins of the study unit's sampling network. Eighty six municipal sewage-treatment plants in the study unit have effluents of 0.5 million gallons per day or more (for the years 1985-91). Statistically significant differences existed in surface-water quality that can be attributed to land use, physiography, and drainage basin size. Dissolved nitrite plus nitrate, total phosphorus, fecal coliform bacteria, and dissolved organic carbon concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. A large difference in dissolved nitrite plus nitrate concentrations occurred between streams draining basins with agricultural land use in the Springfield and Salem Plateaus. Streams draining both small and medium agricultural basins in the Springfield Plateau had much larger concentrations than their counterparts in the Salem Plateau. Drainage basin size was not a significant factor in affecting total phosphorus, fecal coliform bacteria, or dissolved organic carbon concentrations. Suspended-sediment concentrations generally were small and indicative of the clear water in streams in the Ozark Plateaus. A comparison of the dissolved nitrite plus nitrate, total phosphorus, and fecal coliform data collected at the fixed and synoptic sites indicates that generally the data for streams draining basins of similar physiography, land-use setting, and drainage basin size group together. Many of the variations are most likely the result of differences in percent agricultural land use between the sites being compared or are discharge related. The relation of dissolved nitrite plus nitrate, total phosphorus, and fecal coliform concentration to percent agricultural land use has a strong positive 2 Water-Quality Assessment-Nutrients, Bacteria, Organic Carbon, and Suspended Sediment in Surface Water, 1993-95 correlation, with percent agricultural land use accounting for between 42 and 60 percent of the variation in the observed concentrations.

Arkansas, Kansas, Missouri, Oklahoma↗

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma: Organic compounds in surface water, bed sediment, and biological tissue, 1992-95

Organic-compound samples, including pesticides and semi-volatiles, were collected from 1992-95 at 43 surface-water and 27 bed-sediment and biological-tissue sampling sites within the Ozark Plateaus National Water-Quality Assessment Program study unit. Most surface-water, bed-sediment, and biological-tissue sites have drainage basins predominantly in the Springfield and Salem Plateaus. At most surface-water sampling sites, one to three pesticide samples were collected in the spring and early summer of 1994 and 1995; two sites had additional samples collected either weekly, biweekly, or monthly from February 1994 through December 1994. At most bed-sediment and biological-tissue sampling sites, a single organic-compounds sample was collected. Agricultural pesticide use was approximately 4.9 million pounds of active ingredients per year from 1987-91 in the study unit and was generally greatest in the Springfield and Salem Plateaus pasturelands and in the Osage Plains and Mississippi Alluvial Plain cropland areas. The most frequently applied pesticide in the study unit was 2,4-D. Atrazine was the second most frequently applied pesticide. Corn, pasture, rice, sorghum, and soybeans received approximately 85 percent of the pesticides applied within the study unit. The highest pesticide application rate occurred on these crops in the Mississippi Alluvial and Osage Plains. Pastureland was the crop type that received the greatest amount of pesticides in 53 of the 96 counties in the study unit. The most commonly detected herbicide (63 samples) in surface water was atrazine. Five other pesticides--desethylatrazine, tebuthiuron, prometon, metolachlor, and simazine--were detected in 15 or more samples. The most commonly detected insecticide (13 samples) was p,p'-DDE. Two other insecticides, diazinon and cis-permethrin, were detected in seven or more samples. Pesticides were detected at 39 surface-water sites; samples collected at Yocum Creek near Oak Grove, Ark. had the most pesticide detections (13). Seventeen other sites had samples with six or more pesticide detections. Analysis of pesticide data collected at surface-water sites indicates that the largest variety of different pesticides detected (18) was in small, agricultural drainage basins; the largest percentage of detections of a single pesticide (about 80) was in medium, agricultural basins. Pesticide concentrations were small, and in most cases, at or near the detection limit. Maximum concentrations ranged from 0.001 to 0.007 micrograms per liter (mg/L) at small, forest sites; 0.001 to 0.029 mg/L at medium, forest sites; 0.001 to 0.079 mg/L at small, agricultural sites; and 0.003 to 0.29 mg/L at medium, agricultural sites. Pesticides were detected significantly more often in medium, agricultural basins in the Springfield Plateau. The most commonly detected (13 samples) organic compound in bed sediment, in concentrations noticeably above background levels, was 2,6-dimethylnaphthalene; the maximum concentration of 2,6-dimethylnaphthalene was 130 micrograms per kilogram. Seventeen or more compounds were detected in bed-sediment samples collected at three sites. Four compounds were detected in biological-tissue samples: p,p'-DDT in Corbicula fluminea (Asiatic clam) tissue collected at the Osage River near St. Thomas, Mo. and cis-chlordane, trans-chlordane, and trans-nonachlor in C. fluminea tissue collected at the James River near Boaz, Mo. Organic compounds collected at surface-water, bed-sediment, or biological-tissue sampling sites were not detected in concentrations that exceeded any health criteria or standards. Based on this information, organic compounds do not pose any widespread or persistent problems in the study unit.

Arkansas, Kansas, Missouri, Oklahoma↗

Environmental and hydrologic setting of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma

The environmental and hydrologic setting of the Ozark Plateaus National Water-Quality Assessment (NAWQA) study unit and the factors that affect water quality are described in this report. The primary natural and cultural features that affect water- quality characteristics and the potential for future water-quality problems are described. These environmental features include climate, physio- graphy, geology, soils, population, land use, water use, and surface- and ground-water flow systems. The study-unit area is approximately 47,600 square miles and includes most of the Ozark Plateaus Province and parts of the adjacent Osage Plains and Mississippi Alluvial Plain in parts of Arkansas, Kansas, Missouri, and Oklahoma. The geology is characterized by basement igneous rocks overlain by a thick sequence of dolomites, limestones, sandstones, and shales of Paleozoic age. Land use in the study unit is predominantly pasture and forest in the southeastern part, and pasture and cropland in the northwestern part. All or part of the White, Neosho-lllinois, Osage, Gasconade, Meramec, St. Francis, and Black River Basins are within the study unit. Streams in the Boston Mountains contain the least mineralized water, and those in the Osage Plains contain the most mineralized water. The study unit contains eight hydrogeologic units including three major aquifers--the Springfield Plateau, Ozark, and St. Francois aquifers. Streams and aquifers in the study unit generally contain calcium or calcium-magnesium bicarbonate waters. Ground- and surface-water interactions are greatest in the Salem and Springfield Plateaus and least in the Boston Mountains and Osage Plains. Geology, land use, and population probably are the most important environmental factors that affect water quality.

Water-Resources Investigations Report↗