Search USGS⌕ Search

Geology topics

Jason R. Masoner

Publications and source records attributed to Jason R. Masoner.

31 records · Page 2Linked to original sources
USGS2012

GeoChip-based analysis of microbial functional gene diversity in a landfill leachate-contaminated aquifer

The functional gene diversity and structure of microbial communities in a shallow landfill leachate-contaminated aquifer were assessed using a comprehensive functional gene array (GeoChip 3.0). Water samples were obtained from eight wells at the same aquifer depth immediately below a municipal landfill or along the predominant downgradient groundwater flowpath. Functional gene richness and diversity immediately below the landfill and the closest well were considerably lower than those in downgradient wells. Mantel tests and canonical correspondence analysis (CCA) suggested that various geochemical parameters had a significant impact on the subsurface microbial community structure. That is, leachate from the unlined landfill impacted the diversity, composition, structure, and functional potential of groundwater microbial communities as a function of groundwater pH, and concentrations of sulfate, ammonia, and dissolved organic carbon (DOC). Historical geochemical records indicate that all sampled wells chronically received leachate, and the increase in microbial diversity as a function of distance from the landfill is consistent with mitigation of the impact of leachate on the groundwater system by natural attenuation mechanisms.

Oklahoma↗
USGS2011

Emerging contaminants at a closed and an operating landfill in Oklahoma

Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leachate was sampled from landfill cells of three different age ranges from two landfills in Central Oklahoma. Samples were collected from an old cell containing solid waste greater than 25 years old, an intermediate age cell with solid waste between 16 and 3 years old, and operating cell with solid waste less than 5 years old to investigate the chemical variability and persistence of selected ECs in landfill leachate of differing age sources. Twenty-eight of 69 analyzed ECs were detected in one or more samples from the three leachate sources. Detected ECs ranged in concentration from 0.11 to 114 μg/L and included 4 fecal and plant sterols, 13 household\industrial, 7 hydrocarbon, and 4 pesticide compounds. Four ECs were solely detected in the oldest leachate sample, two ECs were solely detected in the intermediate leachate sample, and no ECs were solely detected in the youngest leachate sample. Eleven ECs were commonly detected in all three leachate samples and are an indication of the contents of solid waste deposited over several decades and the relative resistance of some ECs to natural attenuation processes in and near landfills.

Oklahoma↗
USGS2011

Biogeochemical evolution of a landfill leachate plume, Norman, Oklahoma

Leachate from municipal landfills can create groundwater contaminant plumes that may last for decades to centuries. The fate of reactive contaminants in leachate-affected aquifers depends on the sustainability of biogeochemical processes affecting contaminant transport. Temporal variations in the configuration of redox zones downgradient from the Norman Landfill were studied for more than a decade. The leachate plume contained elevated concentrations of nonvolatile dissolved organic carbon (NVDOC) (up to 300 mg/L), methane (16 mg/L), ammonium (650 mg/L as N), iron (23 mg/L), chloride (1030 mg/L), and bicarbonate (4270 mg/L). Chemical and isotopic investigations along a 2D plume transect revealed consumption of solid and aqueous electron acceptors in the aquifer, depleting the natural attenuation capacity. Despite the relative recalcitrance of NVDOC to biodegradation, the center of the plume was depleted in sulfate, which reduces the long-term oxidation capacity of the leachate-affected aquifer. Ammonium and methane were attenuated in the aquifer relative to chloride by different processes: ammonium transport was retarded mainly by physical interaction with aquifer solids, whereas the methane plume was truncated largely by oxidation. Studies near plume boundaries revealed temporal variability in constituent concentrations related in part to hydrologic changes at various time scales. The upper boundary of the plume was a particularly active location where redox reactions responded to recharge events and seasonal water-table fluctuations. Accurately describing the biogeochemical processes that affect the transport of contaminants in this landfill-leachate-affected aquifer required understanding the aquifer's geologic and hydrodynamic framework.

Oklahoma↗
USGS2011

Changes in Selected Metals Concentrations from the Mid-1980s to the Mid-2000s in a Stream Draining the Picher Mining District of Oklahoma

After abandonment in the late 1960s, the Picher mining district of Oklahoma, once the largest source of lead and zinc in the world, continued to be affected by severe environmental degradation, with scattered subsidence and abundant toxic metals such as cadmium and lead seeping from flooded underground mine workings and seeping and running off from as much as 60 million tons of mine tailings remaining at the land surface. Water-quality data collected during the mid-1980s and the mid-2000s at the Tar Creek at 22nd Street Bridge in Miami, Oklahoma streamflow-gaging station (USGS number 07185095), located downstream from much of the district, indicate that total concentrations of iron, manganese, and zinc significantly decreased between the two sampling periods. Those water-quality improvements probably are due to a combination of reclamation activities and natural attenuation processes such as stabilization of exposed minerals in flooded underground mine workings, progressive wind and water erosion of the most readily erodible metalliferous particles from tailings, and colonization of volunteer plants that reduce physical erosion of soils and tailings.

Kansas, Missouri, Oklahoma↗
USGS2011

Stable-isotope ratios of hydrogen and oxygen in precipitation at Norman, Oklahoma, 1996–2008

Precipitation samples for measurement of stable-isotope ratios of hydrogen (delta 2 H) and oxygen (delta 18 O) were collected at the Norman Landfill Research Site in Norman, Oklahoma, from May 1996 to October 2008. Rainfall amounts also were measured at the site (U.S. Geological Survey gaging station 07229053) during the collection period. The delta 2 H of precipitation samples ranged from -121.9 to +8.3 per mil, and the delta 18 O of precipitation ranged from -16.96 to +0.50 per mil. The volume-weighted average values for delta 2 H and delta 18 O of precipitation over the 12-year measurement period were -31.13 per mil for delta 2 H and -5.57 per mil for delta 18 O. Average summer-season delta 2 H and delta 18 O values of precipitation usually were more positive (enriched in the heavier isotopes) than winter values.

Oklahoma↗
USGS2010

A comparison of methods for estimating open-water evaporation in small wetlands

We compared evaporation measurements from a floating pan, land pan, chamber, and the Priestley-Taylor (PT) equation. Floating pan, land pan, and meteorological data were collected from June 6 to July 21, 2005, at a small wetland in the Canadian River alluvium in central Oklahoma, USA. Evaporation measured with the floating pan compared favorably to 12 h chamber measurements. Differences between chamber and floating pan rates ranged from −0.2 to 0.3 mm, mean of 0.1 mm. The difference between chamber and land pan rates ranged from 0.8 to 2.0 mm, mean of 1.5 mm. The mean chamber-to-floating pan ratio was 0.97 and the mean chamber-to-land pan ratio was 0.73. The chamber-to-floating pan ratio of 0.97 indicates the use of a floating pan to measure evaporation in small limited-fetch water bodies is an appropriate and accurate method for the site investigated. One-sided Paired t-Tests indicate daily floating pan rates were significantly less than land pan and PT rates. A two-sided Paired t-Test indicated there was no significant difference between land pan and PT values. The PT equation tends to overestimate evaporation during times when the air is of low drying power and tends to underestimate as drying power increases.

Oklahoma↗
USGS2008

Digital atlas of the upper Washita River basin, southwestern Oklahoma

Numerous types of environmental data have been collected in the upper Washita River basin in southwestern Oklahoma. However, to date these data have not been compiled into a format that can be comprehensively queried for the purpose of evaluating the effects of various conservation practices implemented to reduce agricultural runoff and erosion in parts of the upper Washita River basin. This U.S. Geological Survey publication, 'Digital atlas of the upper Washita River basin, southwestern Oklahoma' was created to assist with environmental analysis. This atlas contains 30 spatial data sets that can be used in environmental assessment and decision making for the upper Washita River basin. This digital atlas includes U.S. Geological Survey sampling sites and associated water-quality, biological, water-level, and streamflow data collected from 1903 to 2005. The data were retrieved from the U.S. Geological Survey National Water Information System database on September 29, 2005. Data sets are from the Geology, Geography, and Water disciplines of the U.S. Geological Survey and cover parts of Beckham, Caddo, Canadian, Comanche, Custer, Dewey, Grady, Kiowa, and Washita Counties in southwestern Oklahoma. A bibliography of past reports from the U.S. Geological Survey and other State and Federal agencies from 1949 to 2004 is included in the atlas. Additionally, reports by Becker (2001), Martin (2002), Fairchild and others (2004), and Miller and Stanley (2005) are provided in electronic format.

Data Series↗
USGS2006

Geographic Information Systems Methods for Determining Drainage-Basin Areas, Stream-Buffered Areas, Stream Length, and Land Uses for the Neosho and Spring Rivers in Northeastern Oklahoma

Geographic Information Systems have many uses, one of which includes the reproducible computation of environmental characteristics that can be used to categorize hydrologic features. The Oklahoma Department of Wildlife Conservation and the Oklahoma Department of Environmental Quality are investigating Geographic Information Systems techniques to determine partial drainage-basin areas, stream-buffer areas, stream length, and land uses (drainage basin and stream characteristics) in northeastern Oklahoma. The U.S Geological Survey, in cooperation with Oklahoma Department of Wildlife Conservation and the Oklahoma Department of Environmental Quality, documented the methods used to determine drainage-basin and stream characteristics for the Neosho and Spring Rivers above Grand Lake Of the Cherokees in northeastern Oklahoma and calculated the characteristics. The drainage basin and stream characteristics can be used by the Oklahoma Department of Wildlife Conservation and the Oklahoma Department of Environmental Quality to aid in natural-resource assessments.

Scientific Investigations Report↗
USGS2004

Water quality and possible sources of nitrate in the Cimarron Terrace Aquifer, Oklahoma, 2003

Water from the Cimarron terrace aquifer in northwest Oklahoma commonly has nitrate concentrations that exceed the maximum contaminant level of 10 milligrams per liter of nitrite plus nitrate as nitrogen (referred to as nitrate) set by the U.S. Environmental Protection Agency for public drinking water supplies. Starting in July 2003, the U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, conducted a study in the Cimarron terrace aquifer to assess the water quality and possible sources of nitrate. A qualitative and quantitative approach based on multiple lines of evidence from chemical analysis of nitrate, nitrogen isotopes in nitrate, pesticides (indicative of cropland fertilizer application), and wastewater compounds (indicative of animal or human wastewater) were used to indicate possible sources of nitrate in the Cimarron terrace aquifer. Nitrate was detected in 44 of 45 ground-water samples and had the greatest median concentration (8.03 milligrams per liter) of any nutrient analyzed. Nitrate concentrations ranged from <0.06 to 31.8 milligrams per liter. Seventeen samples had nitrate concentrations exceeding the maximum contaminant level of 10 milligrams per liter. Nitrate concentrations in agricultural areas were significantly greater than nitrate concentrations in grassland areas. Pesticides were detected in 15 of 45 ground-water samples. Atrazine and deethylatrazine, a metabolite of atrazine, were detected most frequently. Deethylatrazine was detected in water samples from 9 wells and atrazine was detected in samples from 8 wells. Tebuthiuron was detected in water samples from 5 wells; metolachlor was detected in samples from 4 wells; prometon was detected in samples from 4 wells; and alachlor was detected in 1 well. None of the detected pesticide concentrations exceeded the maximum contaminant level or health advisory level set by the U.S. Environmental Protection Agency. Wastewater compounds were detected in 28 of 45 groundwater samples. Of the 20 wastewater compounds detected, 11 compounds were from household chemicals, 3 compounds were hydrocarbons, 2 compounds were industrial chemicals, 2 compounds were pesticides, 1 compound was of animal source, and 1 compound was a detergent compound. The most frequently detected wastewater compound was phenol, which was detected in 23 wells. N,N-diethyl-meta-toluamide (DEET) was detected in water samples from 5 wells. Benzophenone, ethanol- 2-butoxy-phosphate, and tributylphosphate were detected in water samples from 3 wells. Fertilizer was determined to be the possible source of nitrate in samples from 13 of 45 wells sampled, with a15N values ranging from 0.43 to 3.46 permil. The possible source of nitrate for samples from the greatest number of wells (22 wells) was from mixed sources of nitrate from fertilizer, septic or manure, or natural sources. Mixed nitrate sources had a 15N values ranging from 0.25 to 9.83 permil. Septic or manure was determined as the possible source of nitrate in samples from 2 wells. Natural sources were determined to be the possible source of nitrate in samples from 7 wells, with a 15N values ranging from 0.83 to 9.44 permil.

Scientific Investigations Report↗
USGS2003

Percentile distributions of median nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorus concentrations in Oklahoma streams, 1973-2001

Nutrients are one of the primary causes of water-quality impairments in streams, lakes, reservoirs, and estuaries in the United States. The U.S. Environmental Protection Agency has developed regional-based nutrient criteria using ecoregions to protect streams in the United States from impairment. However, nutrient criteria were based on nutrient concentrations measured in large aggregated nutrient ecoregions with little relevance to local environmental conditions in states. The Oklahoma Water Resources Board is using a dichotomous process known as Use Support Assessment Protocols to define nutrient criteria in Oklahoma streams. The Oklahoma Water Resources Board is modifying the Use Support Assessment Protocols to reflect nutrient informa-tion and environmental characteristics relevant to Oklahoma streams, while considering nutrient information grouped by geographic regions based on level III ecoregions and state boundaries. Percentile distributions of median nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorous concentrations were calculated from 563 sites in Oklahoma and 4 sites in Arkansas near the Oklahoma and Arkansas border to facilitate development of nutrient criteria for Oklahoma streams. Sites were grouped into four geographic regions and were categorized into eight stream categories by stream slope and stream order. The 50th percentiles of median nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorus concentrations were greater in the Ozark Highland ecoregion and were less in the Ouachita Mountains ecoregion when compared to other geographic areas used to group sites. The 50th percentiles of median concentrations of nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorus were least in first, second, and third order streams. The 50th percentiles of median nitrite plus nitrate as nitrogen, total nitrogen and total phosphorus concentrations in the Ozark Highland and Ouachita Mountains ecoregions were least in first, second, and third order streams with streams slopes greater than 17 feet per mile. Nitrite plus nitrate as nitrogen and total nitrogen criteria determined by the U.S. Environmental Protection Agency for the Ozark Highland ecoregion were less than the 25th percentiles of median nitrite plus nitrate as nitrogen, total nitrogen, and total phosphorus concentrations in the Ozark Highland ecoregion calculated for this report. Nitrite plus nitrate as nitrogen and total nitrogen criteria developed by the U.S. Environmental Protection Agency for the Ouachita Mountains ecoregion were similar to the 25th percentiles of median nitrite plus nitrate as nitrogen and total nitrogen concentrations in the Ouachita Mountains ecoregion calculated for this report. Nitrate as nitrogen and total phosphorus concentrations currently (2002) used in the Use Support Assessment Protocols for Oklahoma were greater than the 75th percentiles of median nitrite plus nitrate as nitrogen and total phosphorus concentrations calculated for this report.

Oklahoma↗
USGS2002

Environmental Characteristics and Geographic Information System Applications for the Development of Nutrient Thresholds in Oklahoma Streams

The U.S.Environmental Protection Agency has developed nutrient criteria using ecoregions to manage and protect rivers and streams in the United States. Individual states and tribes are encouraged by the U.S. Environmental Protection Agency to modify or improve upon the ecoregion approach. The Oklahoma Water Resources Board uses a dichotomous process that stratifies streams using environmental characteristics such as stream order and stream slope. This process is called the Use Support Assessment Protocols, subchapter15. The Use Support Assessment Protocols can be used to identify streams threatened by excessive amounts of nutrients, dependant upon a beneficial use designation for each stream. The Use Support Assessment Protocols, subchapter 15 uses nutrient and environmental characteristic thresholds developed from a study conducted in the Netherlands, but the Oklahoma Water Resources Board wants to modify the thresholds to reflect hydrologic and ecological conditions relevant to Oklahoma streams and rivers. Environmental characteristics thought to affect impairment from nutrient concentrations in Oklahoma streams and rivers were determined for 798 water-quality sites in Oklahoma. Nutrient, chlorophyll, water-properties, and location data were retrieved from the U.S. Environmental Protection Agency STORET database including data from the U.S. Geological Survey, Oklahoma Conservation Commission, and Oklahoma Water Resources Board. Drainage-basin area, stream order, stream slope, and land-use proportions were determined for each site using a Geographic Information System. The methods, procedures, and data sets used to determine the environmental characteristics are described.

Water-Resources Investigations Report↗