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James R. Hein

Publications and source records attributed to James R. Hein.

86 records · Page 5Linked to original sources
USGS1990

Eocene diatom chert from Adak Island, Alaska

Bedded quartz cherts that contain recognizable diatoms are rare in the geologic record and are described here for the first time. The Eocene Andrew Lake Formation on Adak Island, Alaska consists of about 800 m of sedimentary and volcanogenic rocks. Quartz cherts containing diatoms occur in the upper part of the Andrew Lake Formation and crop out on the northern part of the island. The quartz chert formed at about 70 degrees C as determined by its oxygen isotopic composition. The diatoms were preserved in the chert because early and rapid alteration of ubiquitous volcanic glass in the section released silica and saturated the pore waters with respect to opal-A. Then, temperature rapidly increased with burial and the pore waters became undersaturated with respect to opal-A (biogenic silica), which occurred at a temperature greater than that needed to convert opal-CT to quartz. At this stage, delicate species of diatoms dissolved and quartz precipitated around the remaining more robust diatoms, forming diatom theft. Subsequently, grain-growth occurred and quartz replaced the frustules on a very fine scale.

Alaska↗
USGS1989

Geochemistry and diagenesis of Miocene lacustrine siliceous sedimentary and pyroclastic rocks, Mytilinii basin, Samos Island, Greece

A Late Miocene non-marine stratigraphic sequence composed of limestone, opal-CT-bearing limestone, porcelanite, marlstone, diatomaceous marlstone, dolomite, and tuffite crops out on eastern Samos Island. This lacustrine sequence is subdivided into the Hora Beds and the underlying Pythagorion Formation. The Hora Beds is overlain by the clastic Mytilinii series which contains Turolian (Late Miocene) mammalian fossils. The lacustrine sequence contains volcanic glass and the silica polymorphs opal-A, opal-CT, and quartz. Volcanic glass predominantly occurs in tuffaceous rocks from the lower and upper parts of the lacustrine sequence. Opal-A (diatom frustules) is confined to layers in the upper part of the Hora Beds. Beds rich in opal-CT underlie those containing opal-A. The occurrence of opal-CT is extensive, encompassing the lower Hora Beds and the sedimentary rocks and tuffs of the Pythagorion Formation. A transition zone between the opal-A and opal-CT zones is identified by X-ray diffraction patterns that are intermediate between those of opal-CT and opal-A, perhaps due to a mixture of the two polymorphs. Diagenesis was not advanced enough for opal-CT to transform to quartz or for volcanic glass to transform to opal-C. Based on geochemical and mineralogical data, we suggest that the rate of diagenetic transformation of opal-A to opal-CT was mainly controlled by the chemistry of pore fluids. Pore fluids were characterized by high salinity, moderately high alkalinity, and high magnesium ion activity. These pore fluid characteristics are indicated by the presence of evaporitic salts (halite, sylvite, niter), high boron content in biogenic silica, and by dolomite in both the opal-A and opal-CT-bearing beds. The absence of authigenic K-feldspar, borosilicates, and zeolites also support these pore fluid characteristics. Additional factors that influenced the rate of silica diagenesis were host rock lithology and the relatively high heat flow in the Aegean region from Miocene to Holocene.

Samos Island↗
USGS1985

Ferromanganese crusts from Necker Ridge, Horizon Guyot and S.P. Lee Guyot: Geological considerations

Necker Ridge, Horizon Guyot and S.P. Lee Guyot in the Central Pacific were sampled, seismically surveyed, and photographed by bottom cameras in order to better understand the distribution, origin, and evolution of ferromanganese crusts. Necker Ridge is over 600 km long with a rugged crest, pods of sediment to 146 m thick, slopes that average 12° to 20°, and debris aprons that cover some of the lower flanks. Substrate lithologies are mostly hyaloclastite, volcaniclastic breccia, and minor alkalic basalt. Horizon Guyot, 300 km long and 75 km wide, is capped by at least 160 m of sediment, which buries stepped terraces. Substrate lithologies are similar to those on Necker Ridge, although previous workers sampled much tholeiitic basalt on Horizon. S.P. Lee Guyot, 125 km long and 80 km wide, is capped by at least 300 m of sediment, and contains talus aprons along its lower flanks. Ferromanganese-encrusted rocks were recovered in every dredge and are thickest on Necker Ridge. Crust thicknesses average about 2.5, 1.5, and 0.8 cm for Necker, Horizon, and S.P. Lee, respectively. Crusts range from smooth or porous surfaces to knobby and botryoidal. The entire crust is laminated, however, two distinct layers commonly exist, separated by a paper-thin layer of phosphorite. The dominant mineral of all crusts is vernadite (δ-MnO 2 ), while quartz, feldspar, apatite, and, in three rocks todorokite, are minor phases. Quartz and feldspar decrease with decreasing latitude of occurrence, and is suggested to be related to eolian input. On the average, apatite also increases within the crusts with decreasing latitude of occurrence, which may be related to high biological productivity in the zone of equatorial upwelling. Phosphorite substrates are more abundant on Necker Ridge and S.P. Lee Guyot than they are on Horizon Guyot. Seamount ferromanganese nodules are distinct from abyssal nodules in their chemistry and internal structure.

Marine Geology↗
USGS1981

Petrographic and chemical characteristics of pyrite-marcasite mineralization in hole 465A, southern Hess Rise

Core recovered from Hess Rise contains concentrations of pyrite, marcasite, and barite in the lowermost meter of limestone (Unit II) and in the brecciated upper part of the underlying volcanic basement (Unit HI). Petrographic and chemical data indicate that the sulfide-barite assemblage in the limestone is mainly a product of low-temperature diagenetic processes. The iron-sulfide phases are biogenic and their concentrations mark the diffusion of sea water sulfate through sedimentary horizons containing abundant organic matter and mafic, glassy volcanogenic detritus. There is some evidence, however, that elevated temperatures augmented or intensified the synsedimentary diagenetic process.

Initial reports of the Deep Sea Drilling Project↗
USGS1980

Bibliography of fine-grained siliceous deposits

This bibliography was compiled under the auspices of the International Geologic Correlations Project's (IGCP) Research Group 115, "Siliceous Deposits of the Pacific Region"; IGCP is sponsored by UNESCO and the International Union of Geological Sciences (IUGS). Research Group 115 was originally proposed to IGCP in 1974 by Professor Azuma Iijima, University of Tokyo, and is now headed by James R. Hein, U.S. Geological Survey. Cooperative efforts by 86 members from 17 countries help in accomplishing Research Group 115's objectives of correlating sedimentary processes of siliceous deposits in the Pacific Basin and neighboring geosynclinal areas by means of stratigraphy, sedimentology, geochemisty, and paleontology. These correlations will allow us to estimate the geochemical silica budget in the Earth's crust; to estimate the production of silica in the marine environment through geologic time; to formulate a general rule on sedimentation of siliceous deposits in geosynclines; to increase understanding of the development of circum-Pacific orogenic belts; and to obtain basic methods to evaluate siliceous deposits of economic interest. The group agreed to focus on fine-grained siliceous deposits (cherts, siliceous shales, diatomites, and the like) and to exclude quartz sand deposits and quartzose sandstones.

Open-File Report↗
USGS1979

Clay mineralogy, fine-grained sediment dispersal, and inferred current patterns, lower Cook Inlet and Kodiak shelf, Alaska

Because lower Cook Inlet and Kodiak shelf are being explored and developed for their petroleum resources, it is essential for environmental reasons to understand the sediment dispersal routes and current patterns. The Susitna River flows into upper Cook Inlet and is the source of clay minerals in Holocene deposits found in western lower Cook Inlet. The Copper River, in the northern Gulf of Alaska, provides clay minerals to the Kodiak shelf and southeastern lower Cook Inlet. In addition, crosion of local bedrock outcrops on the shelf produces some clays that are deposited on the Kodiak shelf. Current patterns can be inferred from the clay-mineral distribution pattern. This is true even if the clay-size fraction is a minor sediment component, and in areas where coarse-grained relict deposits occur. Some potential dangers from offshore petroleum development include: (1) rapid and complete mixing of Cook Inlet waters, (2) adsorption of pollutants by clay deposited in quiet bays, and (3) ion-exchange and adsorption of chemical pollutants on clays that are part of the suspended sediment load in lower Cook Inlet.

Alaska↗