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James R. Budahn

Publications and source records attributed to James R. Budahn.

At least 19 recordsLinked to original sources

Ibex Hollow Tuff from ca. 12 Ma supereruption, southern Idaho, identified across North America, eastern Pacific Ocean, and Gulf of Mexico

The Ibex Hollow Tuff, 12.08 ± 0.03 Ma ( 40 Ar/ 39 Ar), is a widespread tephra layer erupted from the Bruneau-Jarbidge volcanic field of southern Idaho. Tephra from this eruption was deposited across much of western and central North America and adjacent ocean areas. We identified the Ibex Hollow Tuff at Trapper Creek, Idaho, near its eruption site, and at 15 distal sites, from the Pacific Ocean to the Gulf of Mexico, by the chemical composition of its glass shards, using electron-microprobe analysis, instrumental neutron activation analysis, and laser-ablation–inductively coupled plasma–mass spectrometry. By these methods, we distinguished the Ibex Hollow Tuff from overlying and underlying tephra layers near its source and at distal sites. Fluvially reworked Ibex Hollow Tuff ash was transported by the ancestral Mississippi River drainage from the interior of the North American continent to the Gulf of Mexico, where it is present within an ~50-m-thick deposit in marine sediments in the subsurface. The minimum fallout area covered by the ash is ~2.7 million km 2 , with a minimum volume of ~800 km 3 , and potential dispersal farther to the north and northeast. The areal distribution for the Ibex Hollow Tuff is similar to that of the Lava Creek B (0.63 Ma) supereruption. The Ibex Hollow Tuff represents a unique chronostratigraphic marker allowing a synoptic view of paleoenvironments at a virtual moment in time across a large terrestrial and marine region. The Ibex Hollow Tuff is also an important marker bed for North American Land Mammal Ages, and it coincides with climatic cooling in the middle to late Miocene documented in marine cores.

Gulf of Mexico, Pacific Ocean

Long-term African dust delivery to the eastern Atlantic Ocean from the Sahara and Sahel regions: Evidence from Quaternary paleosols on the Canary Islands, Spain

Africa is the most important source of dust in the world today and dust storms from that continent frequently deposit sediment on the nearby Canary Islands. Many investigators have inferred African dust inputs to Canary Islands paleosols based only on the presence of quartz. However, some local rocks do contain this mineral, so quartz alone is insufficient proof of dust deposition. Further, it is not known whether the Sahara Desert or the Sahel region is more important as a dust source. We address these issues by study of sequences of Pleistocene aeolian sands on the islands of Lanzarote and Fuerteventura. Aeolian sands are composed mostly of marine carbonate minerals and locally derived volcanic minerals. They date from the early-middle Pleistocene to the Holocene. Trace element geochemistry shows that the soils formed from both locally derived basalt and African dust. Major element geochemistry and clay mineralogy indicate that dust additions to the Canary Islands likely come from both the Sahara and Sahel. Dust delivered from the Sahel indicates that droughts in that region have had a history extending through much of the Quaternary. Accretionary-inflationary profile development, from dust accretion, is evident in the upward growth of Canary Islands paleosols.

Quaternary Science Reviews

New geochemical evidence for the origin of North America's largest dune field, the Nebraska Sand Hills, central Great Plains, USA

The Nebraska Sand Hills region is the largest dune field in North America and has diverse aeolian landforms. It has been active during both the late Pleistocene and late Holocene. Despite decades of study, the source of sediment for this large sand sea is still controversial. Here we report new trace element compositions of aeolian sand that are compared to four hypothesized sediment sources, Tertiary rocks of the Arikaree Group and Ogallala Group, unconsolidated sands of Pliocene age, and Platte River system sands. All four potential sources have a mineralogy that is similar to the Nebraska Sand Hills. K/Rb, K/Ba, Sc-Th-La, Eu/Eu*, La N /Yb N , As/Sb, and Fe/Sc values show, however, that Pliocene sediments and sands from the Platte River system are not likely sources. The Arikaree Group could be a minor contributor, but sands from the Ogallala Group appear to have the best compositional fit to the Nebraska Sand Hills. Although past studies have proposed the Ogallala Group as an important sand source, the hypothesis has been questioned, because the unit is well cemented by calcrete in its upper part. However, examination of the landscape upwind of the Nebraska Sand Hills shows that the Ogallala Group, where it occurs at the land surface, is highly dissected in much of this region, which makes sand-sized particles available for aeolian entrainment whenever drought conditions diminish a protective vegetation cover.

Nebraska

The antiquity of the Sahara Desert: New evidence from the mineralogy and geochemistry of Pliocene paleosols on the Canary Islands, Spain

The Sahara is the largest warm desert in the world, but its age has been controversial, with estimates ranging from Miocene to Holocene. Mineralogical and geochemical data show that paleosols of Pliocene to mid-Pleistocene age on Fuerteventura and Gran Canaria in the Canary Islands have developed in part from inputs of dust from Africa. These paleosols contain quartz and mica, minerals that are abundant in African dust but are rare in the basaltic rocks that dominate the Canary Islands. Trace elements with minimal mobility, Sc, Cr, Hf, Th, and Ta as well as the rare earth elements, show that paleosols have compositions that are intermediate between those of local rocks and African-derived dust. Thus, results reported here and in a recently published study by others indicate that 9 paleosols record delivery of African dust to the Canary Islands between ~4.8–2.8 Ma, ~3.0–2.9 Ma, ~2.3–1.46 Ma, and ~0.4 Ma. A long-term paleosol record of African dust input agrees with deep-sea records off the coast of western Africa that imply increased dust fluxes to the eastern Atlantic Ocean at ~4.6 Ma. It is concluded that the Sahara Desert has been in existence as an arid-region dust source, at least intermittently, for much of the Pliocene and continuing into the Pleistocene.

Canary Islands

Origin of last-glacial loess in the western Yukon-Tanana Upland, central Alaska, USA

Loess is widespread over Alaska, and its accumulation has traditionally been associated with glacial periods. Surprisingly, loess deposits securely dated to the last glacial period are rare in Alaska, and paleowind reconstructions for this time period are limited to inferences from dune orientations. We report a rare occurrence of loess deposits dating to the last glacial period, ~19 ka to ~12 ka, in the Yukon-Tanana Upland. Loess in this area is very coarse grained (abundant coarse silt), with decreases in particle size moving south of the Yukon River, implying that the drainage basin of this river was the main source. Geochemical data show, however, that the Tanana River valley to the south is also a likely distal source. The occurrence of last-glacial loess with sources to both the south and north is explained by both regional, synoptic-scale winds from the northeast and opposing katabatic winds that could have developed from expanded glaciers in both the Brooks Range to the north and the Alaska Range to the south. Based on a comparison with recent climate modeling for the last glacial period, seasonality of dust transport may also have played a role in bringing about contributions from both northern and southern sources.

Alaska

A comprehensive survey of faults, breccias, and fractures in and flanking the eastern Española Basin, Rio Grande rift, New Mexico

A comprehensive survey of geologic structures formed in the Earth’s brittle regime in the eastern Española Basin and flank of the Rio Grande rift, New Mexico, reveals a complex and protracted record of multiple tectonic events. Data and analyses from this representative rift flank-basin pair include measurements from 53 individual fault zones and 22 other brittle structures, such as breccia zones, joints, and veins, investigated at a total of just over 100 sites. Structures were examined and compared in poorly lithified Tertiary sediments, as well as in Paleozoic sedimentary and Proterozoic crystalline rocks. Data and analyses include geologic maps; field observations and measurements; orientation, kinematic, and paleostress analyses; statistical examination of fault trace lengths derived from aeromagnetic data; mineralogy and chemistry of host and fault rocks; and investigation of fault versus bolide-impact hypotheses for the origin of enigmatic breccias found in the Proterozoic basement rocks. Fault kinematic and paleostress analyses suggest a record of transitional, and perhaps partitioned, strains from the Laramide orogeny through Rio Grande rifting. Normal faults within Tertiary basin-fill sediments are consistent with more typical WNW-ESE Rio Grande rift extension, perhaps decoupled from bedrock structures due to strength contrasts favoring the formation of new faults in the relatively weak sediments. Analyses of the fault-length data indicate power-law length distributions similar to those reported from many geologic settings globally. Mineralogy and chemistry in Proterozoic fault-related rocks reveal geochemical changes tied to hydrothermal alteration and nearly isochemical transformation of feldspars to clay minerals. In sediments, faulted minerals are characterized by mechanical entrainment with minor secondary chemical changes. Enigmatic breccias in rift-flanking Proterozoic rocks are autoclastic and isochemical with respect to their protoliths and exist near shatter cones believed to be related to a previously reported pre-Pennsylvanian impact event. A weak iridium anomaly is associated with the breccias as well as adjacent protoliths, thus an impact shock wave cannot be ruled out for their origin. Major fault zones along the eastern rift-flank mountain front are discontinuous and unlikely to impede regional groundwater flow into Española Basin aquifers. The breccia bodies are not large enough to constitute aquifers, and no fault- or breccia-related geochemical anomalies were identified as potential contamination sources for ground or surface waters. The results of this work provide a broad picture of structural diversity and tectonic evolution along the eastern flank of the central Rio Grande rift and the adjacent Española Basin representative of the rift as a whole and many rifts worldwide.

New Mexico

Rare earth mineral potential in the southeastern U.S. Coastal Plain from integrated geophysical, geochemical, and geological approaches

We combined geophysical, geochemical, mineralogical, and geological data to evaluate the regional presence of rare earth element (REE)−bearing minerals in heavy mineral sand deposits of the southeastern U.S. Coastal Plain. We also analyzed regional differences in these data to determine probable sedimentary provenance. Analyses of heavy mineral separates covering the region show strong correlations between thorium, monazite, and xenotime, suggesting that radiometric equivalent thorium (eTh) can be used as a geophysical proxy for those REE-bearing minerals. Airborne radiometric data collected during the National Uranium Resource Evaluation (NURE) program cover the southeastern United States with line spacing varying from ∼2 to 10 km. These data show eTh highs over Cretaceous and Tertiary Coastal Plain sediments from the Cape Fear arch in North Carolina to eastern Alabama; these highs decrease with distance from the Piedmont. Quaternary sediments along the modern coasts show weaker eTh anomalies, except near coast-parallel ridges from South Carolina to northern Florida. Prominent eTh anomalies are also observed over large riverbeds and their floodplains, even north of the Cape Fear arch where surrounding areas are relatively low. These variations were verified using ground geophysical measurements and sample analyses, indicating that radiometric methods are a useful exploration tool at varying scales. Further analyses of heavy mineral separates showed regional differences, not only in concentrations of monazite, but also of rutile and staurolite, and in magnetic susceptibility. The combined properties suggest the presence of subregions where heavy mineral sediments are primarily sourced from high-grade metamorphic, low-grade metamorphic, or igneous terrains, or where they represent a mixing of these sources. Comparisons between interpreted sources of heavy mineral sands near the Fall Line and igneous and metamorphic Piedmont and Blue Ridge units showed a strong correspondence with rocks closest to the Fall Line and poor correspondence with rocks farther inland. This strongly suggests that the primary source of those heavy minerals, especially monazite, is the rocks that formed the rocky coast that was present during opening of the Atlantic Ocean, which in turn indicates the importance of coastal processes in forming heavy mineral sand concentrations. Furthermore, narrow radiometric eTh and K anomalies are associated with major rivers, indicating limited spatial influence of fluvial processes. Later coastal plain sediment deposition appears to have involved reworking of sediments, providing an “inheritance” of the rocky coast composition that persists for some distance from the Fall Line. However, this inheritance is reduced with distance, and sediments within ∼100 km of the coast in Georgia and Florida exhibit properties indicative of mixing from multiple sources.

GSA Bulletin

Geochemical evidence for seasonal controls on the transportation of Holocene loess, Matanuska Valley, southern Alaska, USA

Loess is a widespread Quaternary deposit in Alaska and loess accretion occurs today in some regions, such as the Matanuska Valley. The source of loess in the Matanuska Valley has been debated for more than seven decades, with the Knik River and the Matanuska River, both to the east, being the leading candidates and the Susitna River, to the west, as a less favorable source. We report here new stratigraphic, mineralogic, and geochemical data that test the competing hypotheses of these river sources. Loess thickness data are consistent with previous studies that show that a source or sources lay to the east, which rules out the Susitna River as a source. Knik and Matanuska River silts can be distinguished using Sc–Th–La, La N /Yb N vs. Eu/Eu ∗ , Cr/Sc, and As/Sb. Matanuska Valley loess falls clearly within the range of values for these ratios found in Matanuska River silt. Dust storms from the Matanuska River are most common in autumn, when river discharge is at a minimum and silt-rich point bars are exposed, wind speed from the north is beginning to increase after a low-velocity period in summer, snow depth is still minimal, and soil temperatures are still above freezing. Thus, seasonal changes in climate and hydrology emerge as critical factors in the timing of aeolian silt transport in southern Alaska. These findings could be applicable to understanding seasonal controls on Pleistocene loess accretion in Europe, New Zealand, South America, and elsewhere in North America.

Alaska

First steps of integrated spatial modeling of titanium, zirconium, and rare earth element resources within the Coastal Plain sediments of the southeastern United States

The Coastal Plain of the southeastern United States has extensive, unconsolidated sedimentary deposits that are enriched in heavy minerals containing titanium, zirconium, and rare earth element resources. Areas favorable for exploration and development of these resources are being identified by geochemical data, which are supplemented with geological, geophysical, hydrological, and geographical data. The first steps of this analysis have been completed. The concentrations of lanthanum, yttrium, and titanium tend to decrease as distance from the Piedmont (which is the likely source of these resources) increases and are moderately correlated with airborne measurements of equivalent thorium concentration. The concentrations of lanthanum, yttrium, and titanium are relatively high in those watersheds that adjoin the Piedmont, south of the Cape Fear Arch. Although this relation suggests that the concentrations are related to the watersheds, it may be simply an independent regional trend. The concentration of zirconium is unrelated to the distance from the Piedmont, the equivalent thorium concentration, and the watershed. These findings establish a foundation for more sophisticated analyses using integrated spatial modeling.

Open-File Report

Potential metal recovery from waste streams

‘Waste stream’ is a general term that describes the total flow of waste from homes, businesses, industrial facilities, and institutions that are recycled, burned or isolated from the environment in landfills or other types of storage, or dissipated into the environment. The recovery and reuse of chemical elements from waste streams have the potential to decrease U.S. reliance on primary resources and imports, and to lessen unwanted dispersion of some potentially harmful elements into the environment. Additional benefits might include reducing disposal or treatment costs and decreasing the risk of future environmental liabilities for waste generators. Elemental chemistry and mineralogical residences of the elements are poorly documented for many types of waste streams.

Conference Paper

Loess origin, transport, and deposition over the past 10,000 years, Wrangell-St. Elias National Park, Alaska

Contemporary glaciogenic dust has not received much attention, because most research has been on glaciogenic dust of the last glacial period or non-glaciogenic dust of the present interglacial period. Nevertheless, dust from modern glaciogenic sources may be important for Fe inputs to primary producers in the ocean. Adjacent to the subarctic Pacific Ocean, we studied a loess section near Chitina, Alaska along the Copper River in Wrangell-St. Elias National Park, where dust has been accumulating over the past ∼10,000 years. Mass accumulation rates for the fine-grained (<20 μm) fraction of this loess section are among the highest reported for the Holocene of high-latitude regions of the Northern Hemisphere. Based on mineralogy and geochemistry, loess at Chitina is derived from glacial sources in the Wrangell Mountains, the Chugach Mountains, and probably the Alaska Range. Concentrations of Fe in the silt-plus-clay fraction of the loess at Chitina are much higher than in all other loess bodies in North America and higher than most loess bodies on other continents. The very fine-grained (<2 μm) portion of this sediment, capable of long-range transport, is dominated by Fe-rich chlorite, which can yield Fe readily to primary producers in the ocean. Examination of satellite imagery shows that dust from the Copper River is transported by wind on a regular basis to the North Pacific Ocean. This Alaskan example shows that high-latitude glaciogenic dust needs to be considered as a significant Fe source to primary producers in the open ocean.

Alaska

Origin of the Sinai-Negev erg, Egypt and Israel: mineralogical and geochemical evidence for the importance of the Nile and sea level history

The Sinai–Negev erg occupies an area of 13,000 km 2 in the deserts of Egypt and Israel. Aeolian sand of this erg has been proposed to be derived from the Nile Delta, but empirical data supporting this view are lacking. An alternative source sediment is sand from the large Wadi El Arish drainage system in central and northern Sinai. Mineralogy of the Negev and Sinai dunes shows that they are high in quartz, with much smaller amounts of K-feldspar and plagioclase. Both Nile Delta sands and Sinai wadi sands, upstream of the dunes, also have high amounts of quartz relative to K-feldspar and plagioclase. However, Sinai wadi sands have abundant calcite, whereas Nile Delta sands have little or no calcite. Overall, the mineralogical data suggest that the dunes are derived dominantly from the Nile Delta, with Sinai wadi sands being a minor contributor. Geochemical data that proxy for both the light mineral fraction (SiO 2 /10–Al 2 O 3 + Na 2 O + K 2 O–CaO) and heavy mineral fraction (Fe 2 O 3 –MgO–TiO 2 ) also indicate a dominant Nile Delta source for the dunes. Thus, we report here the first empirical evidence that the Sinai–Negev dunes are derived dominantly from the Nile Delta. Linkage of the Sinai–Negev erg to the Nile Delta as a source is consistent with the distribution of OSL ages of Negev dunes in recent studies. Stratigraphic studies show that during the Last Glacial period, when dune incursions in the Sinai–Negev erg began, what is now the Nile Delta area was characterized by a broad, sandy, minimally vegetated plain, with seasonally dry anastomosing channels. Such conditions were ideal for providing a ready source of sand for aeolian transport under what were probably much stronger glacial-age winds. With the post-glacial rise in sea level, the Nile River began to aggrade. Post-glacial sedimentation has been dominated by fine-grained silts and clays. Thus, sea level, along with favorable climatic conditions, emerges as a major influence on the timing of dune activity in the Sinai–Negev erg, through its control on the supply of sand from the Nile Delta. The mineralogy of the Sinai–Negev dunes is also consistent with a proposed hypothesis that these sediments are an important source of loess in Israel.

Sinai-negev Erg

Accumulation of impact markers in desert wetlands and implications for the Younger Dryas impact hypothesis

The Younger Dryas impact hypothesis contends that an extraterrestrial object exploded over North America at 12.9 ka, initiating the Younger Dryas cold event, the extinction of many North American megafauna, and the demise of the Clovis archeological culture. Although the exact nature and location of the proposed impact or explosion remain unclear, alleged evidence for the fallout comes from multiple sites across North America and a site in Belgium. At 6 of the 10 original sites (excluding the Carolina Bays), elevated concentrations of various "impact markers" were found in association with black mats that date to the onset of the Younger Dryas. Black mats are common features in paleowetland deposits and typically represent shallow marsh environments. In this study, we investigated black mats ranging in age from approximately 6 to more than 40 ka in the southwestern United States and the Atacama Desert of northern Chile. At 10 of 13 sites, we found elevated concentrations of iridium in bulk and magnetic sediments, magnetic spherules, and/or titanomagnetite grains within or at the base of black mats, regardless of their age or location, suggesting that elevated concentrations of these markers arise from processes common to wetland systems, and not a catastrophic extraterrestrial impact event.

Proceedings of the National Academy of Sciences of

Soil genesis on the island of Bermuda in the Quaternary: the importance of African dust transport and deposition

The origin of terra rossa, red or reddish-brown, clay-rich soils overlying high-purity carbonate substrates, has intrigued geologists and pedologists for decades. Terra rossa soils can form from accumulation of insoluble residues during dissolution of the host limestones, addition of volcanic ash, or addition of externally derived, long-range-transported (LRT) aeolian particles. We studied soils and paleosols on high-purity, carbonate aeolianites of Quaternary age on Bermuda, where terra rossa origins have been debated for more than a century. Potential soil parent materials on this island include sand-sized fragments of local volcanic bedrock, the LRT, fine-grained (<20 &mu;m) component of distal loess from the lower Mississippi River Valley, and LRT dust from Africa. These parent materials can be characterized geochemically using trace elements that are immobile in the soil-forming environment. Results indicate that local volcanic bedrock on Bermuda has Sc-Th-La, Cr-Ta-Nd, and Eu/Eu*, La N /Yb N , Gd N /Yb N that can be distinguished from African dust and lower Mississippi River valley loess. Bermuda soils have Sc-Th-La, Cr-Ta-Nd, and Eu/Eu*, La N /Yb N , Gd N /Yb N that indicate derivation from a combination of LRT dust from Africa and local volcanic bedrock. Our results indicate that soils on islands in a very broad latitudinal belt of the western Atlantic margin have been influenced by African LRT dust inputs over much of the past &ndash;500 ka.

Journal of Geophysical Research

Geologic map of Big Bend National Park, Texas

The purpose of this map is to provide the National Park Service and the public with an updated digital geologic map of Big Bend National Park (BBNP). The geologic map report of Maxwell and others (1967) provides a fully comprehensive account of the important volcanic, structural, geomorphological, and paleontological features that define BBNP. However, the map is on a geographically distorted planimetric base and lacks topography, which has caused difficulty in conducting GIS-based data analyses and georeferencing the many geologic features investigated and depicted on the map. In addition, the map is outdated, excluding significant data from numerous studies that have been carried out since its publication more than 40 years ago. This report includes a modern digital geologic map that can be utilized with standard GIS applications to aid BBNP researchers in geologic data analysis, natural resource and ecosystem management, monitoring, assessment, inventory activities, and educational and recreational uses. The digital map incorporates new data, many revisions, and greater detail than the original map. Although some geologic issues remain unresolved for BBNP, the updated map serves as a foundation for addressing those issues. Funding for the Big Bend National Park geologic map was provided by the United States Geological Survey (USGS) National Cooperative Geologic Mapping Program and the National Park Service. The Big Bend mapping project was administered by staff in the USGS Geology and Environmental Change Science Center, Denver, Colo. Members of the USGS Mineral and Environmental Resources Science Center completed investigations in parallel with the geologic mapping project. Results of these investigations addressed some significant current issues in BBNP and the U.S.-Mexico border region, including contaminants and human health, ecosystems, and water resources. Funding for the high-resolution aeromagnetic survey in BBNP, and associated data analyses and interpretation, was from the USGS Crustal Geophysics and Geochemistry Science Center. Mapping contributed from university professors and students was mostly funded by independent sources, including academic institutions, private industry, and other agencies.

Texas

Chemistry of selected core samples, concentrate, tailings, and tailings pond waters: Pea Ridge iron (-lanthanide-gold) deposit, Washington County, Missouri

The Minerals at Risk and for Emerging Technologies Project of the U.S. Geological Survey (USGS) Mineral Resources Program is examining potential sources of lanthanide elements (rare earth elements) as part of its objective to provide up-to-date geologic information regarding mineral commodities likely to have increased demand in the near term. As part of the examination effort, a short visit was made to the Pea Ridge iron (-lanthanide-gold) deposit, Washington County, Missouri in October 2008. The deposit, currently owned by Wings Enterprises, Inc. of St. Louis, Missouri (Wings), contains concentrations of lanthanides that may be economic as a primary product or as a byproduct of iron ore production. This report tabulates the results of chemical analyses of the Pea Ridge samples and compares rare earth elements contents for world class lanthanide deposits with those of the Pea Ridge deposit. The data presented for the Pea Ridge deposit are preliminary and include some company data that have not been verified by the USGS or by the Missouri Department of Natural Resources, Division of Geology and Land Survey (DGLS), Geological Survey Program (MGS). The inclusion of company data is for comparative purposes only and does not imply an endorsement by either the USGS or MGS.

Missouri

Catalog of Mount St. Helens 2004-2007 dome samples with major- and trace-element chemistry

Sampling and analysis of eruptive products at Mount St. Helens is an integral part of volcano monitoring efforts conducted by the U.S. Geological Survey?s Cascades Volcano Observatory (CVO). The objective of our eruption sampling program is to enable petrological assessments of pre-eruptive magmatic conditions, critical for ascertaining mechanisms for eruption triggering and forecasting potential changes in eruption behavior. This report provides a catalog of near-vent lithic debris and new dome-lava collected during 34 intra-crater sampling forays throughout the October 2004 to October 2007 (2004-7) eruptive interval at Mount St. Helens. In addition, we present comprehensive bulk-rock geochemistry for a time-series of representative (2004-7) eruption products. This data, along with that in a companion report on Mount St. Helens 2004 to 2006 tephra by Rowe and others (2008), are presented in support of the contents of the U.S. Geological Survey Professional Paper 1750 (Sherrod and others, eds., 2008). Readers are referred to appropriate chapters in USGS Professional Paper 1750 for detailed narratives of eruptive activity during this time period and for interpretations of sample characteristics and geochemical data. The suite of rock samples related to the 2004-7 eruption of Mount St. Helens and presented in this catalog are archived at the David A. Johnson Cascades Volcano Observatory, Vancouver, Wash. The Mount St. Helens 2004-7 Dome Sample Catalogue with major- and trace-element geochemistry is tabulated in 3 worksheets of the accompanying Microsoft Excel file, of2008-1130.xls. Table 1 provides location and sampling information. Table 2 presents sample descriptions. In table 3, bulk-rock major and trace-element geochemistry is listed for 44 eruption-related samples with intra-laboratory replicate analyses of 19 dacite lava samples. A brief overview of the collection methods and lithology of dome samples is given below as an aid to deciphering the dome sample catalog. This is followed by an explanation of the categories of sample information (column headers) in Tables 1 and 2. A summary of the analytical methods used to obtain the geochemical data in this report introduces the presentation of major- and trace-element geochemistry of 2004-7 Mount St. Helens dome samples in table 3. Intra-laboratory results for the USGS AGV-2 standard are presented (tables 4 and 5), which demonstrate the compatibility of chemical data from different sources.

Open-File Report

Determination of premining geochemical background and delineation of extent of sediment contamination in Blue Creek downstream from Midnite Mine, Stevens County, Washington

Geochemical and radionuclide studies of sediment recovered from eight core sites in the Blue Creek flood plain and Blue Creek delta downstream in Lake Roosevelt provided a stratigraphic geochemical record of the contamination from uranium mining at the Midnite Mine. Sediment recovered from cores in a wetland immediately downstream from the mine site as well as from sediment catchments in Blue Creek and from cores in the delta in Blue Creek cove provided sufficient data to determine the premining geochemical background for the Midnite Mine tributary drainage. These data provide a geochemical background that includes material eroded from the Midnite Mine site prior to mine development. Premining geochemical background for the Blue Creek basin has also been determined using stream-sediment samples from parts of the Blue Creek, Oyachen Creek, and Sand Creek drainage basins not immediately impacted by mining. Sediment geochemistry showed that premining uranium concentrations in the Midnite Mine tributary immediately downstream of the mine site were strongly elevated relative to the crustal abundance of uranium (2.3 ppm). Cesium-137 (137Cs) data and public records of production at the Midnite Mine site provided age control to document timelines in the sediment from the core immediately downstream from the mine site. Mining at the Midnite Mine site on the Spokane Indian Reservation between 1956 and 1981 resulted in production of more than 10 million pounds of U3O8. Contamination of the sediment by uranium during the mining period is documented from the Midnite Mine along a small tributary to the confluence of Blue Creek, in Blue Creek, and into the Blue Creek delta. During the period of active mining (1956?1981), enrichment of base metals in the sediment of Blue Creek delta was elevated by as much as 4 times the concentration of those same metals prior to mining. Cadmium concentrations were elevated by a factor of 10 and uranium by factors of 16 to 55 times premining geochemical background determined upstream of the mine site. Postmining metal concentrations in sediment are lower than during the mining period, but remain elevated relative to premining geochemical background. Furthermore, the sediment composition of surface sediment in the Blue Creek delta is contaminated. Base-metal contamination by arsenic, cadmium, lead, and zinc in sediment in the delta in Blue Creek cove is dominated by suspended sediment from the Coeur d?Alene mining district. Uranium contamination in surface sediment in the delta of Blue Creek cove extends at least 500 meters downstream from the mouth of Blue Creek as defined by the 1,290-ft elevation boundary between lands administered by the National Park Service and the Spokane Indian Tribe. Comparisons of the premining geochemical background to sediment sampled during the period the mine was in operation, and to the sediment data from the postmining period, are used to delineate the extent of contaminated sediment in Blue Creek cove along the thalweg of Blue Creek into Lake Roosevelt. The extent of contamination out into Lake Roosevelt by mining remains open.

Washington