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James M. McNeal

Publications and source records attributed to James M. McNeal.

5 recordsLinked to original sources
USGS2015

Geochemistry and occurrence of selenium: An overview

Selenium (Se) is both beneficial and toxic to animals, plants, and humans. Consequently, it is imperative to know its concentration in the environment and to understand the processes controlling its distribution. Determinations of Se concentrations in a variety of materials indicate that Se is widely distributed throughout the environment. The processes responsible for its distribution include volcanic activity, the burning of fossil fuels, the weathering of rocks and soils, groundwater transport, precipitation of minerals, adsorption, chemical or bacterial reduction and oxidation, and metabolic uptake and release by plants and animals. The importance of a particular process in controlling the distribution of Se is intimately linked to the speciation of Se, which is controlled by the pH and redox conditions of the environment. Selenium can exist as selenide (Se 2− ), elemental Se (Se 0 ), selenite (SeO 2− 3 ), and selenate (SeO 2− 4 ). Each oxidation state exhibits different chemical behavior. Selenide and elemental Se occur in acidic, reducing, and organic-rich environments. Metal selenides, Se-sulfides, and elemental Se are insoluble, and therefore biologically unavailable. For the pH and redox conditions of most soil and aquatic environments, SeO 2− 3 and SeO 2− 4 ; should be the dominant forms of Se. Selenite is immobilized by adsorption onto particles, particularly Fe oxyhydroxides. Selenate is highly mobile and biologically available because of the solubility of its salts and its weak adsorption by particles. Microbial action can change the speciation of Se through oxidation or reduction, or through the formation of organic Se compounds.

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USGS2002

Strategic vision for the U. S. Geological Survey in the Great Lakes-St. Lawrence Region, 2001-2010

The U.S. Geological Survey's (USGS) strategic vision for the Great Lakes-St. Lawrence Region is that of a healthy ecosystem, whose ecological integrity and economic health are nurtured and sustained through sound resource-management decisions based on reliable, timely, and objective scientific information and data. The USGS is a leader in providing reliable, relevant, timely, and objective scientific data and information at local, statewide, regional, national, and international scales to assist in the management and restoration of the natural resources in the Great Lakes-St. Lawrence Region. The mission of the USGS in the Great Lakes-St. Lawrence Region is to provide natural science information to the broad community of policymakers, resource managers, regulators, scientists, and private citizens who contribute to informed decisions concerning natural-resource management practices and ecosystem quality and integrity. The strategic vision for the USGS in the Great Lakes-St. Lawrence Region is a plan to address complex issues that require integrated natural-science information. The strategic vision describes how the USGS will coordinate existing programs and draw upon the strengths of the entire organization. It provides the framework for long-term coordination and integration of USGS Programs and activities over the next decade (2001-10). The strategic vision describes the role of the USGS in the Great Lakes-St. Lawrence Region, the coordination of activities within and outside the Bureau and Department of Interior, and interactions between the USGS and its cooperators, partners, and stakeholders in the Region.

Great Lakes-St. Lawrence region↗
USGS1993

Understanding our fragile environment; Lessons from geochemical studies

An understanding of our fragile environment can begin with a recognition of the importance of certain elements, commonly called "minerals substances" (such as iron and zinc), in the lives of humans and animals and in the soils that support plants. This recognition is well deserved because these elements are essential for the life or optimum health of an organism. Some elements such as carbon, hydrogen, oxygen, magnesium, potassium, and phosphorus are required in relatively large amounts by organisms. However, others are required in smaller quantities; these are referred to as trace elements. Diseases have been related to the deficiency of about 20 elements in animals and humans and to the deficiency of approximately 13 elements in plants. At the same time, if these and other elements occur in quantities great enough, toxicity can result. An element, or any substance, that occurs in the environment and contains concentrations above what are considered to be background levels may be considered a contaminant. When contaminants occur at levels that are potentially harmful to organisms, they are labeled as hazards. Often the quantitative difference between essential amounts and toxic concentrations of these elements is very small. For example, the trace element selenium is required at a level of no less than 0.4 ppm in the diet of cattle but can be toxic at levels greater than approximately 4ppm. Elements that are required for survival by animals and plants are termed essential, while those not required are nonessential. Trace essential elements such as fluorine, copper, selenium, molybdenum, and others listed in the table on page 1 can be hazardous to life forms if present at high levels. Nonessential heavy metals such as arsenic, lead, mercury, cadmium, and chromium are usually toxic to organisms at much lower levels than trace essential elements. Depending on the association that these nonessential elements may form with natural geologic materials such as organic matter, other elements or minerals, and adsorbers (such as clays), these elements can range from being safe to being extremely toxic. The elemental composition of plants, animals, and humans correlates with the geologic makeup of the Earth, and life has evolved reflecting these natural occurrences. The science of environmental geochemistry examines the interrelationship of life with the physical and chemical Earth.

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