Geology topics
James L. Bischoff
Publications and source records attributed to James L. Bischoff.
Combined ESR/U-series chronology of Acheulian hominid-bearing layers at Trinchera Galería site, Atapuerca, Spain
The Sierra de Atapuerca, northern Spain, is known from many prehistoric and palaeontological sites documenting human prehistory in Europe. Three major sites, Gran Dolina, Galería and Sima del Elefante, range in age from the oldest hominin of Western Europe dated to 1.1 to 1.3 Ma (millions of years ago) at Sima del Elefante to c.a. 0.2 Ma on the top of the Galería archaeological sequence. Recently, a chronology based on luminescence methods (Thermoluminescence [TL] and Infrared Stimulated Luminescence [IRSL]) applied to cave sediments was published for the Gran Dolina and Galería sites. The authors proposed for Galería an age of 450 ka (thousands of years ago) for the units lower GIII and GII, suggesting that the human occupation there is younger than the hominid remains of Sima de los Huesos (>530 ka) around 1 km away. In this paper, we present new results obtained by combined Electron Spin Resonance/Uranium-series (ESR/U-series) dating on 20 herbivorous teeth from different levels at the Galería site. They are in agreement with the TL results for the upper part of the stratigraphic sequence (GIV and GIIIb), in the range of between 200 and 250 ka. But for the GIIIa to GIIb levels, the TL ages become abruptly older by 200 ka while ESR ages remain relatively constant. Finally, the TL and ESR data agree in the lowest part of the section (GIIa); both fall in the range of around 350–450 ka. Our results suggest a different interpretation for the GII, GIII and GIV units of Galería and the upper part of Gran Dolina (TD10 and TD11) than obtained by TL. The ESR/U-series results are supported by a Bayesian analysis, which allows a better integration between stratigraphic information and radiometric data.
Environmental, depositional and cultural changes in the upper Pleistocene and early Holocene; the Cinglera del Capello Sequence (Capellades, Spain)
The correlation between environmental and cultural changes is one of the primary archeological and paleoanthropological research topics. Analysis of ice and marine cores has yielded a high-resolution record of millennial-scale changes during the Late Pleistocene and Holocene eras. However, cultural changes are documented in low-resolution continental deposits; thus, their correlation with the millennial-scale climatic sequence is often difficult. In this paper, we present a rare occurrence in which a thick archeological sequence is associated with a high-resolution environmental record. The Cinglera del Capello is a tufa-draped cliff located in the northeastern Iberian Peninsula, 50 km west of Barcelona. This cliff harbors several rock-shelters with Late Pleistocene and Early Holocene deposits. Together, the deposits of four rock-shelters span from 7000 to 70,000 years ago and provide a high-resolution record of the environmental and human dynamics during this timespan. This record allows the correlation of the cultural and environmental changes. The multiproxy approach to the Cinglera evidence indicates that the main cultural stages of the Late Pleistocene and Early Holocene (Middle Paleolithic, Upper Paleolithic and Mesolithic) are associated with significant changes in the environmental and depositional contexts.
Evidence for deposition of 10 million tonnes of impact spherules across four continents 12,800 y ago
Airbursts/impacts by a fragmented comet or asteroid have been proposed at the Younger Dryas onset (12.80 ± 0.15 ka) based on identification of an assemblage of impact-related proxies, including microspherules, nanodiamonds, and iridium. Distributed across four continents at the Younger Dryas boundary (YDB), spherule peaks have been independently confirmed in eight studies, but unconfirmed in two others, resulting in continued dispute about their occurrence, distribution, and origin. To further address this dispute and better identify YDB spherules, we present results from one of the largest spherule investigations ever undertaken regarding spherule geochemistry, morphologies, origins, and processes of formation. We investigated 18 sites across North America, Europe, and the Middle East, performing nearly 700 analyses on spherules using energy dispersive X-ray spectroscopy for geochemical analyses and scanning electron microscopy for surface microstructural characterization. Twelve locations rank among the world’s premier end-Pleistocene archaeological sites, where the YDB marks a hiatus in human occupation or major changes in site use. Our results are consistent with melting of sediments to temperatures >2,200 °C by the thermal radiation and air shocks produced by passage of an extraterrestrial object through the atmosphere; they are inconsistent with volcanic, cosmic, anthropogenic, lightning, or authigenic sources. We also produced spherules from wood in the laboratory at >1,730 °C, indicating that impact-related incineration of biomass may have contributed to spherule production. At 12.8 ka, an estimated 10 million tonnes of spherules were distributed across ∼50 million square kilometers, similar to well-known impact strewnfields and consistent with a major cosmic impact event.
Chemistry of hydrothermal solutions from the southern Juan de Fuca Ridge
Fluids from three vent fields on the southern Juan de Fuca Ridge were sampled in September 1984 using the DSRV Alvin. The fluids are uniquely high in both chloride, which ranges up to twice the seawater value, and in metal content. Simple vapor-liquid phase separation could not have produced both the high chlorinity and gas concentrations observed in these fluids. The cause of the elevated chlorinity can not be uniquely identified but may be the result of either or a combination of two processes: (1) subsurface formation of a degassed brine and subsequent mixing of a small amount of this brine with a hydrothermal seawater which has not undergone a phase separation and (2) dissolution of a chloride-rich phase combined with a possible small loss of gas during sampling procedures. Although measured temperatures were all less than 300°C, quartz geothermometry suggests that the fluids have equilibrated at greater than 340°C. Quartz geobarometry is also in agreement with geophysical estimates of depth to the local magma chamber.
Very high-temperature impact melt products as evidence for cosmic airbursts and impacts 12,900 years ago
It has been proposed that fragments of an asteroid or comet impacted Earth, deposited silica-and iron-rich microspherules and other proxies across several continents, and triggered the Younger Dryas cooling episode 12,900 years ago. Although many independent groups have confirmed the impact evidence, the hypothesis remains controversial because some groups have failed to do so. We examined sediment sequences from 18 dated Younger Dryas boundary (YDB) sites across three continents (North America, Europe, and Asia), spanning 12,000 km around nearly one-third of the planet. All sites display abundant microspherules in the YDB with none or few above and below. In addition, three sites (Abu Hureyra, Syria; Melrose, Pennsylvania; and Blackville, South Carolina) display vesicular, high-temperature, siliceous scoria-like objects, or SLOs, that match the spherules geochemically. We compared YDB objects with melt products from a known cosmic impact (Meteor Crater, Arizona) and from the 1945 Trinity nuclear airburst in Socorro, New Mexico, and found that all of these high-energy events produced material that is geochemically and morphologically comparable, including: (i) high-temperature, rapidly quenched microspherules and SLOs; (ii) corundum, mullite, and suessite (Fe 3,/sup>Si), a rare meteoritic mineral that forms under high temperatures; (iii) melted SiO 2 glass, or lechatelierite, with flow textures (or schlieren) that form at > 2,200 °C; and (iv) particles with features indicative of high-energy interparticle collisions. These results are inconsistent with anthropogenic, volcanic, authigenic, and cosmic materials, yet consistent with cosmic ejecta, supporting the hypothesis of extraterrestrial airbursts/impacts 12,900 years ago. The wide geographic distribution of SLOs is consistent with multiple impactors.
Evidence from central Mexico supporting the Younger Dryas extraterrestrial impact hypothesis
We report the discovery in Lake Cuitzeo in central Mexico of a black, carbon-rich, lacustrine layer, containing nanodiamonds, microspherules, and other unusual materials that date to the early Younger Dryas and are interpreted to result from an extraterrestrial impact. These proxies were found in a 27-m-long core as part of an interdisciplinary effort to extract a paleoclimate record back through the previous interglacial. Our attention focused early on an anomalous, 10-cm-thick, carbon-rich layer at a depth of 2.8 m that dates to 12.9 ka and coincides with a suite of anomalous coeval environmental and biotic changes independently recognized in other regional lake sequences. Collectively, these changes have produced the most distinctive boundary layer in the late Quaternary record. This layer contains a diverse, abundant assemblage of impact-related markers, including nanodiamonds, carbon spherules, and magnetic spherules with rapid melting/quenching textures, all reaching synchronous peaks immediately beneath a layer containing the largest peak of charcoal in the core. Analyses by multiple methods demonstrate the presence of three allotropes of nanodiamond: n-diamond, i-carbon, and hexagonal nanodiamond (lonsdaleite), in order of estimated relative abundance. This nanodiamond-rich layer is consistent with the Younger Dryas boundary layer found at numerous sites across North America, Greenland, and Western Europe. We have examined multiple hypotheses to account for these observations and find the evidence cannot be explained by any known terrestrial mechanism. It is, however, consistent with the Younger Dryas boundary impact hypothesis postulating a major extraterrestrial impact involving multiple airburst(s) and and/or ground impact(s) at 12.9 ka.
Carbon sequestration via reaction with basaltic rocks: geochemical modeling and experimental results
Basaltic rocks are potential repositories for sequestering carbon dioxide (CO 2 ) because of their capacity for trapping CO 2 in carbonate minerals. We carried out a series of thermodynamic equilibrium models and high pressure experiments, reacting basalt with CO 2 -charged fluids over a range of conditions from 50 to 200 °C at 300 bar. Results indicate basalt has a high reactivity to CO 2 acidified brine. Carbon dioxide is taken up from solution at all temperatures from 50 to 200 °C, 300 bar, but the maximum extent and rate of reaction occurs at 100 °C, 300 bar. Reaction path simulations utilizing the geochemical modeling program CHILLER predicted an equilibrium carbonate alteration assemblage of calcite, magnesite, and siderite, but the only secondary carbonate identified in the experiments was a ferroan magnesite. The amount of uptake at 100 °C, 300 bar ranged from 8% by weight for a typical tholeite to 26% for a picrite. The actual amount of CO2 uptake and extent of rock alteration coincides directly with the magnesium content of the rock suggesting that overall reaction extent is controlled by bulk basalt Mg content. In terms of sequestering CO 2 , an average basaltic MgO content of 8% is equivalent to 2.6 × 10 8 metric ton CO 2 /km 3 basalt.
Mass spectrometric U-series dating of the Chaoxian hominin site at Yinshan, eastern China
The fossils of Chaoxian hominin, widely accepted as representing archaic Homo sapiens in eastern China, were recovered from the middle or slightly higher levels of Layer 2 deposits of a collapsed cave at Yinshan, Anhui Province. Results of mass spectrometric U-series dating of intercalated speleothem calcites are presented. Based mainly on four broadly coeval calcite samples, the hominin fossils should be bracketed in the range of 310–360 ka or somewhat older. These ages are much older than the previous estimate at 160–200 ka based on the U-series dating of fossil teeth and bones, and may be cited as supporting evidence for an earlier H. erectus –archaic H. sapiens interface in China.
Ancient earthquakes from archaeoseismic evidence during the Visigothic and Islamic periods in the archaeological site of “Tolmo de Minateda” (SE Spain)
The ruins of the ancient settlement of “El Tolmo de Minateda” are one of the best representative archaeological sites within the Albacete Province (SE Spain), characterized by a well-preserved record for the last ~3800 yr. The present ruins record an almost continuous of occupation from the Late Bronze Age (Iberian Culture, from ca. third century B.C.) to the High Middle Ages, including intervening and successive Roman, Visigoth, and Muslim city remains. The eventual Muslim settlement was abruptly abandoned and destroyed during the ninth–tenth centuries A.D., leaving a lack of any archaeological evidence of war or decay. Another previous anomalous archaeological episode of abrupt city abandonment and destruction is recorded during the Visigothic Period (seventh century). The archaeological record of this city supports evidence for earthquake damage linked to both periods of city abandonment and destruction, including oriented collapse of walls, watchtowers, and columns, oriented cracking of walls and column drums, as well as in situ broken pottery, abrupt abandonment of kilns, and anomalous sedimentary infilling of canals and water-supply facilities. Additionally, large-scale rockfalls containing Visigothic carved tombs are also apparently associated with both episodes, constituting one of the few instances of combined geoarchaeological evidence of earthquake ground effects ever reported. As a means of testing the theoretical archaeoseismic potential of this site, we obtained an archaeoseismic quality factor (AQF) value of 0.074.
High-resolution U-series dates from the Sima de los Huesos hominids yields 600 +∞ -66 : implications for the evolution of the early Neanderthal lineage
The Sima de los Huesos site of the Atapuerca complex near Burgos, Spain contains the skeletal remains of at least 28 individuals in a mud-breccia underlying an accumulation of the Middle Pleistocene cave bear (Ursus deningeri). We report here on new high-precision dates on the recently discovered speleothem SRA-3 overlaying human bones within the Sima de los Huesos. Earlier analyses of this speleothem by TIMS (thermal-ionization mass-spectrometry) showed the lower part to be indistinguishable from internal isotopic equilibrium at the precision of the TIMS instrumentation used, yielding minimum age of 350 kyr (kyr = 103 yr before present). Reanalysis of six samples of SRA-3 by inductively-coupled plasma-multicollector mass-spectrometry (ICP-MS) produced high-precision analytical results allowing calculation of finite dates. The new dates cluster around 600 kyr. A conservative conclusion takes the lower error limit ages as the minimum age of the speleothem, or 530 kyr. This places the SH hominids at the very beginnings of the Neandertal evolutionary lineage.
Geochemistry of sediments in cores and sediment traps from Bear Lake, Utah and Idaho
The present study of Bear Lake began in 1998. Initially, the study utilized sediments from three long cores (up to 5 m) previously collected in 1996 and short cores (up to 40 cm) collected in 1998. The short cores were specifically acquired to preserve the uppermost layers of sediment that may have been lost in the long cores. In addition, three arrays of sediment traps were deployed during the summer of 1998, and sediment from these traps was collected during the summers of 1999 and 2000 (see Dean and others, 2005, for core and sediment trap locations). The cores and sediment traps were sampled, and splits were distributed to various investigators for analyses of a wide variety of sediment parameters. The chemical composition of the acid-soluble component of the sediments is presented in this report. HCl or HNO3 treatment of the sediment quantitatively dissolves the authigenic component of the sediment, a component that includes carbonates, sulfates, and iron-mono sulfides. In the case of Bear Lake, CaCO3 is the major component of the sediment today and for most of the Holocene (Dean and others 2005). The chemical composition of the acid-soluble fraction gives important information on this component and, therefore, insight into the chemical conditions of the lake at the time of carbonate deposition.
The springs of Lake Pátzcuaro: chemistry, salt-balance, and implications for the water balance of the lake
Lake Pa??tzcuaro, the center of the ancient Tarascan civilization located in the Mexican altiplano west of the city of Morelia, has neither river input nor outflow. The relatively constant lake-salinity over the past centuries indicates the lake is in chemical steady state. Springs of the south shore constitute the primary visible input to the lake, so influx and discharge must be via sub-lacustrine ground water. The authors report on the chemistry and stable isotope composition of the springs, deeming them representative of ground-water input. The springs are dominated by Ca, Mg and Na, whereas the lake is dominated by Na. Combining these results with previously published precipitation/rainfall measurements on the lake, the authors calculate the chemical evolution from spring water to lake water, and also calculate a salt balance of the ground-water-lake system. Comparing Cl and ??18O compositions in the springs and lake water indicates that 75-80% of the spring water is lost evaporatively during evolution toward lake composition. During evaporation Ca and Mg are lost from the water by carbonate precipitation. Each liter of spring water discharging into the lake precipitates about 18.7 mg of CaCO3. Salt balance calculations indicate that ground water input to the lake is 85.9??106 m3/a and ground water discharge from the lake is 23.0??106 m3/a. Thus, the discharge is about 27% of the input, with the rest balanced by evaporation. A calculation of time to reach steady-state ab initio indicates that the Cl concentration of the present day lake would be reached in about 150 a. ?? 2004 Elsevier Ltd. All rights reserved.
New U-series dates at the Caune de l'Arago, France
In the beginning of the 1980s, the Caune de l'Arago was the focus of an interdisciplinary effort to establish the chronology of the Homo heidelbergensis (Preneandertals) fossils using a variety of techniques on bones and on speleothems. The result was a very large spread of dates particularly on bone samples. Amid the large spread of results, some radiometric data on speleothems showed a convergence in agreement with inferences from faunal studies. We present new U-series results on the stalagmitic formation located at the bottom of Unit IV (at the base of the Upper Stratigraphic Complex). Samples and splits were collaboratively analyzed in the four different laboratories with excellent interlaboratory agreement. Results show the complex sequence of this stalagmitic formation. The most ancient part is systematically at internal isotopic equilibrium (>350 ka) suggesting growth during or before isotopic stage 9, representing a minimum age for the human remains found in Unit III of the Middle Stratigraphical Complex which is stratigraphically under the basis of the studied stalagmitic formation. Overlaying parts of the speleothem date to the beginning of marine isotope stages 7 and 5. ?? 2003 Elsevier Science Ltd. All rights reserved.
Determination of sulfate in seawater and natural brines by 133Ba and membrane dialysis
Dissolved sulfate is determined by precipitation with the radioisotope 133 Ba and counting of the precipitate on a scintillation counter. Precipitation is carried out in dialysis bags; excess 133 Ba is removed via diffusion by soaking the bags in distilled water for 12 h, and the bags are then placed directly in the well of the scintillation counter. The procedure eliminates previous errors caused by washing and transferring of the precipitate and permits analysis of 0.5–3,000 µ g·ml −1 sulfate in a 1.0-ml sample. The detection limit is increased by simply increasing the sample volume up to 5.0 ml. The technique is interference-free in natural waters ranging from freshwater to brines of 1.5 times the salinity of seawater.
A 2000-year-long record of climate from the Gulf of California
No abstract available.
Core OL-92 from Owens Lake: Project rationale, geologic setting, drilling procedures, and summary
Several lines of evidence indicated that Owens Lake, a now-dry lake in southeast California, would probably yield a continuous and climatically informative sedimentary record. Also, the details of modern climate and runoff in the area are exceptionally well known, providing a firm basis for interpreting various types of evidence from a core in terms of past climates. Drilling was carried out in early 1992 to retrieve this record. The resulting core, OL-92, was taken from the south-central part of the lake (lat 36°22.85′ N, long 117°57.95′ W). Lake surface elevation at the drill site is 1,085 m. The core’s length is 322.86 m, recovery was ~80%, and the age of its basal sediments is ~800 ka. Study of the core has revealed lithologic, chemical, mineralogic, geophysical, and paleontologic evidence that reflects alternating periods of high- and low-volume runoff into Owens Lake. This volume presents these studies and summarizes their paleoclimatic significance.
Synthesis of the paleoclimatic record from Owens Lake core OL-92
During much of the late Quaternary, Owens Lake overflowed into one or more of four successively lower-elevation basins. Most of the water came from the high, eastern slopes of the southern Sierra Nevada, and changes in the volumes of that water reflect a dominant climatic cycle of ~100 k.y. Variations in the inflow to, and outflow from, Owens Lake since ca. 800 ka left biological, chemical, mineralogical, and geophysical evidence in the sediments of those changes. Biological evidence includes fossil ostracodes, diatoms, fish, and mollusks (and δ 18 O data from their shells) which indicate fresh or brackish lake water on the basis of their modern habitats. Fossil pollens indicate ~20 regional vegetation cycles during the same period. Chemical evidence of high inflow and, commonly, outflow volumes is provided by the low inorganic- and organic-C content of some sediments, reflecting short lake-water residence times; long residence times produced higher and more variable quantities of these components. Mineralogical variations in illite/smectite ratios indicate changes in weathering processes and glacial comminution. High magnetic susceptibility correlates with other criteria that indicate high runoff. Between 810 ka and 645 ka, Owens Lake was fresh, several meters deep, and depositing silt with a few beds of sand; it supported a flora and fauna now found in fresh, sometimes very cool, waters. (Note that most geologic ages describing the OL-92 chronology have been rounded to the nearest 5 or 10 ka.) A shallow-but-freshwater lake may have been the result of accelerated sedimentation during an earlier (>800 ka) glaciation in the Sierra Nevada, choking the basin with sediment nearly to its spillway level. Between 645 ka and 450 ka, the lake was probably even shallower, depositing beds of coarse to fine sand, but overflowing periodically allowing its water to remain fresh. Between 450 ka and 5 ka, Owens Lake was mostly deep, alternating between spilling and being closed part of the time. It deposited silt and clay on its floor, yet underwent detectable variations in salinity caused by climate changes; this part of the record is the most easily interpreted and constitutes the main basis for comparing this paleoclimatic record with other long records. From 5 ka to A.D. 1913, when the Owens River was diverted into an aqueduct, Owens Lake was shallow (~2 m to ~15 m), moderately saline (~5% to <15% salts), and depositing oolites. After 1913, the lake desiccated. Comparison of the Owens Lake water-depth record with that of Searles Lake, two-basins downstream during much of late Pleistocene time, shows that they underwent similar responses to climate, but sedimentation changes documenting those responses commenced thousands of years apart, apparently because changes in precipitation volumes occurred gradually. Owens Lake, at the base of high mountains, was the first to reflect increasing amounts of regional precipitation; Searles, in a more arid environment, was the first to reflect decreasing amounts of precipitation. Devils Hole, 150 km east of Owens Lake, has a well dated isotopic-temperature record that resembles the Owens Lake-depth record. Marine records of Pleistocene glacial fluctuations, which measure high-latitude ice-sheet volumes and thus both precipitation and temperature at those latitudes, also resemble the Owens Lake history. There are, however, differences between the ages of the maxima and minima of climatic events as reconstructed from the Owens Lake core and similar-appearing inflections in the other two records; the differences range from 0 to 33 k.y. and average ~15 k.y. The question arises whether the differences between those ages are results of errors in the time-scale used for the Owens Lake record, or were there significant differences in the times when atmospheric climate change began to affect its different elements. The three records compared here are measurements of different elements and combinations of elements in two latitude belts: the deep-sea marine records measure combinations of temperature and precipitation that determined global ice volumes (at mostly high latitudes), the Devils Hole record measures atmospheric temperatures (in its mid-latitude region), and the Owens Lake record measures effective precipitation (in the same mid-latitude region).