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James C. Zachos

Publications and source records attributed to James C. Zachos.

6 recordsLinked to original sources

Calcareous nannofossil assemblage changes in the Surprise Hill core and their implications for floral response to the Paleocene-Eocene Thermal Maximum across the Salisbury Embayment of Virginia, USA

We present Paleocene-Eocene calcareous nannofossil biostratigraphy and paleoecology for the Surprise Hill core, U.S. Atlantic Coastal Plain, Virginia. Calcareous nannofossil datums ranging from Zone NP3 to NP14 were identified. The Danian-aged Brightseat Formation rests unconformably atop the Lower Cretaceous Potomac Group at 211.4 m and disconformably underlies the Aquia Formation at 208.8 m. The absence of Zone NP7 suggests a hiatus is present in the Aquia Formation (Zones NP5 – NP9a). The contact between the Marlboro Clay and the overlying Nanjemoy Formation (Zones NP10 – NP14) at 189.5 m is truncated. The Paleocene-Eocene transition is marked by a shift from glauconitic sands of the Aquia Formation to pelitic muds of the Marlboro Clay at 202.7 m. A 3–3.5‰ negative δ 13 C excursion of benthic foraminifer and a thin dissolution interval (201.6–202.5 m) are recorded in the basal Marlboro Clay. Nannofossil response to the Paleocene-Eocene Thermal Maximum (PETM) include (1) a bloom in taxa with affinities for changing salinity conditions just prior to the PETM basin wide ( Hornibrookina australis arca ), (2) a decline in taxa with ecological affinities for cool, eutrophic waters ( Chiasmolithus bidens ) during PETM, (3) fluctuations in mesotrophic to eutrophic, opportunistic taxa (e.g., Neochiastozygus junctus ) during PETM, (4) successive turnovers in species of Toweius spp. during core-PETM and its recovery. Our findings suggest that overall nannofossil assemblages in the southernmost portion of the Salisbury Embayment responded similarly to assemblages from South Dover Bridge, but had differing response to local changes in nearshore paleoecology.

Maryland, Virginia

Astrochronology of the Paleocene-Eocene Thermal Maximum on the Atlantic Coastal Plain

The chronology of the Paleocene-Eocene Thermal Maximum (PETM, ~56 Ma) remains disputed, hampering complete understanding of the possible trigger mechanisms of this event. Here we present an astrochronology for the PETM carbon isotope excursion from Howards Tract, Maryland a paleoshelf environment, on the mid-Atlantic Coastal Plain. Statistical evaluation of variations in calcium content and magnetic susceptibility indicates astronomical forcing was involved and the PETM onset lasted about 6 kyr. The astrochronology and Earth system modeling suggest that the PETM onset occurred at an extreme in precession during a maximum in eccentricity, thus favoring high temperatures, indicating that astronomical forcing could have played a role in triggering the event. Ca content data on the paleo-shelf, along with other marine records, support the notion that a carbonate saturation overshoot followed global ocean acidification during the PETM.

Delaware, Maryland, New Jersey, Virginia

Surface ocean warming and acidification driven by rapid carbon release precedes Paleocene-Eocene Thermal Maximum

The Paleocene-Eocene Thermal Maximum (PETM) is recognized by a major negative carbon isotope (δ 13 C) excursion (CIE) signifying an injection of isotopically light carbon into exogenic reservoirs, the mass, source, and tempo of which continue to be debated. Evidence of a transient precursor carbon release(s) has been identified in a few localities, although it remains equivocal whether there is a global signal. Here, we present foraminiferal δ 13 C records from a marine continental margin section, which reveal a 1.0 to 1.5‰ negative pre-onset excursion (POE), and concomitant rise in sea surface temperature of at least 2°C and a decline in ocean pH. The recovery of both δ 13 C and pH before the CIE onset and apparent absence of a POE in deep-sea records suggests a rapid (< ocean mixing time scales) carbon release, followed by recovery driven by deep-sea mixing. Carbon released during the POE is therefore likely more similar to ongoing anthropogenic emissions in mass and rate than the main CIE.

Science Advances

Evidence for shelf acidification during the onset of the Paleocene-Eocene Thermal Maximum

A transect of paleoshelf cores from Maryland and New Jersey contains a ~0.19 m to 1.61 m thick interval with reduced percentages of carbonate during the onset of the Paleocene-Eocene Thermal Maximum (PETM). Outer paleoshelf cores are barren of nannofossils and correspond to two minor disconformities. Middle paleoshelf cores contain a mixture of samples devoid of nannofossils and those with rare specimens characterized by significant dissolution (i.e., etching). The magnitude of the decrease in carbonate cannot be explained by dilution by clastic material or dissolution resulting from the oxidation of organic matter during early diagenesis. The observed preservation pattern implies a shoaling of the calcite compensation depth (CCD) and lysocline to the middle shelf. This reduced carbonate interval is observed during the onset of the PETM on other continental margins raising the possibility that extreme shoaling of the CCD and lysocline was a global signal which is more significant than in previous estimates for the PETM. An alternative scenario is that shoaling was restricted to the northwest Atlantic, enhanced by regional and local factors (eutrophication from rivers, microbial activity associated with warming) that exacerbated the impact of acidification on the shelf.

Maryland, New Jersey

Paleocene–Eocene Thermal Maximum prolonged by fossil carbon oxidation

A hallmark of the rapid and massive release of carbon during the Palaeocene–Eocene Thermal Maximum is the global negative carbon isotope excursion. The delayed recovery of the carbon isotope excursion, however, indicates that CO 2 inputs continued well after the initial rapid onset, although there is no consensus about the source of this secondary carbon. Here we suggest this secondary input might have derived partly from the oxidation of remobilized sedimentary fossil carbon. We measured the biomarker indicators of thermal maturation in shelf records from the US Mid-Atlantic coast, constructed biomarker mixing models to constrain the amount of fossil carbon in US Mid-Atlantic and Tanzania coastal records, estimated the fossil carbon accumulation rate in coastal sediments and determined the range of global CO 2 release from fossil carbon reservoirs. This work provides evidence for an order of magnitude increase in fossil carbon delivery to the oceans that began ~10–20 kyr after the event onset and demonstrates that the oxidation of remobilized fossil carbon released between 10 2 and 10 4 PgC as CO 2 during the body of the Palaeocene–Eocene Thermal Maximum. The estimated mass is sufficient to have sustained the elevated atmospheric CO 2 levels required by the prolonged global carbon isotope excursion. Even after considering uncertainties in the sedimentation rates, these results indicate that the enhanced erosion, mobilization and oxidation of ancient sedimentary carbon contributed to the delayed recovery of the climate system for many thousands of years.

Nature Geoscience