Geology topics

James B. Paces

Publications and source records attributed to James B. Paces.

At least 19 recordsLinked to original sources

USGS2025

Two million years of climate-driven cave-sediment aggradation and valley incision in the southern Ozark Plateau from Fitton Cave, northern Arkansas, USA

Landscape evolution in karst terrains affects both subterranean and surface settings. For better understanding of controlling processes and connections between the two, multiple geochronometers were used to date sediments and speleothems in upper-level passages of Fitton Cave adjacent to the Buffalo River, northern Arkansas, within the southern Ozark Plateau. Burial cosmogenic-nuclide dating of coarse sediments indicates that gravel pulses washed into upper passages at 2.2 Ma and 1.25 Ma. These represent the oldest epigenetic cave deposits documented in this region. Associated sands and clay-rich sediments mostly have reversed magnetic polarity and thermally transferred optically stimulated luminescence dates of 1.2 to 1.0 Ma. Abandonment of these upper passages began before 0.72 Ma, when coarse sediment was deposited in a passage incised below older sediment. Maximum U-series dates of 0.7–0.4 Ma for flowstones capping clastic deposits mark the stabilization of older sediments and a change to vadose conditions that allowed post–0.4 Ma stalagmite growth. Resulting valley incision rates since 0.85 Ma are estimated at 27 m/Ma. Coarse cave-sediment pulses correlate to Laurentide glacial tills about 300 km to the north, suggesting climate influence on periglacial sediment production. Dated cave sediments also may correlate with undated older strath terraces preserved at similar heights above the Buffalo River.

Arkansas↗

USGS2024

Radiogenic strontium- and uranium-isotope tracers of water-rock interactions and hydrothermal flow in the Upper Geyser Basin, Yellowstone Plateau Volcanic Field, USA

Natural radiogenic isotopes (primarily 87 Sr/ 86 Sr) from hot springs in the Upper Geyser Basin of the Yellowstone Plateau volcanic field and associated rocks were used to evaluate groundwater flow patterns, water-rock reactions, and the extent of mixing between various groundwater sources. Thermal waters have very low uranium concentrations and 234 U/ 238 U activity ratios near 1.0, which limit their utility as tracers in this reducing setting. Thermal waters have higher Sr concentrations (<22 ng/g) and a wide range of 87 Sr/ 86 Sr values that vary both temporally at individual discharge sites and between adjacent springs, indicating that conduits tap different subsurface reservoirs to varying degrees. Sr from local rhyolites have 87 Sr/ 86 Sr compositions that bound the range of values observed in groundwater throughout the basin. Non-boiling springs on the west flank of the basin discharge water with low 87 Sr/ 86 Sr consistent with flow through young volcanic rocks exposed at the surface. Boiling springs in the central basin have higher 87 Sr/ 86 Sr values reflecting interactions with older, more radiogenic volcanic rocks. Variability in upwelling thermal waters requires mixing with a low 87 Sr/ 86 Sr component derived from young lava or glacial sediments, or more likely, from deeper sources of hot groundwater circulating through buried Lava Creek Tuff having intermediate 87 Sr/ 86 Sr. Isotope data constrain basin-wide output of thermal water to 110–140 kg·s −1 . Results underscore the utility of radiogenic Sr isotopes as valuable tracers of hydrothermal flow patterns and improve the understanding of temperature-dependent water-rock reactions in one of the largest continental hydrothermal systems on Earth.

Wyoming↗

USGS2024

Clumped isotopes record a glacial-interglacial shift in seasonality of soil carbonate accumulation in the San Luis Valley, southern Rocky Mountains, USA

Clumped isotope paleothermometry using pedogenic carbonates is a powerful tool for investigating past climate changes. However, location-specific seasonal patterns of precipitation and soil moisture cause systematic biases in the temperatures they record, hampering comparison of data across large areas or differing climate states. To account for biases, more systematic studies of carbonate forming processes are needed. We measured modern soil temperatures within the San Luis Valley of the Rocky Mountains and compared them to paleotemperatures determined using clumped isotopes. For Holocene-age samples, clumped isotope results indicate carbonate accumulated at a range of temperatures with site averages similar to the annual mean. Paleotemperatures for late Pleistocene-age samples (ranging 19–72 ka in age) yielded site averages only 2°C lower, despite evidence that annual temperatures during glacial periods were 5–9°C colder than modern. We use a 1D numerical model of soil physics to support the idea that differences in hydrologic conditions in interglacial versus glacial periods promote differences in the seasonal distribution of soil carbonate accumulation. Model simulations of modern (Holocene) conditions suggest that soil drying under low soil p CO 2 favors year-round carbonate accumulation in this region but peaking during post-monsoon soil drying. During a “glacial” simulation with lowered temperatures and added snowpack, more carbonate accumulation shifted to the summer season. These experiments show that changing hydrologic regimes could change the seasonality of carbonate accumulation, which in this study blunts the use of clumped isotopes to quantify glacial-interglacial temperature changes. This highlights the importance of understanding seasonal biases of climate proxies for accurate paleoenvironmental reconstruction.

Colorado, new Mexico↗

USGS2024

Travertine records climate-induced transformations of the Yellowstone hydrothermal system from the late Pleistocene to the present

Chemical changes in hot springs, as recorded by thermal waters and their deposits, provide a window into the evolution of the postglacial hydrothermal system of the Yellowstone Plateau Volcanic Field. Today, most hydrothermal travertine forms to the north and south of the ca. 631 ka Yellowstone caldera where groundwater flow through subsurface sedimentary rocks leads to calcite saturation at hot springs. In contrast, low-Ca rhyolites dominate the subsurface within the Yellowstone caldera, resulting in thermal waters that rarely deposit travertine. We investigated the timing and origin of five small travertine deposits in the Upper and Lower Geyser Basins to understand the conditions that allowed for travertine deposition. New 230 Th-U dating, oxygen (δ 18 O), carbon (δ 13 C), and strontium ( 87 Sr/ 86 Sr) isotopic ratios, and elemental concentrations indicate that travertine deposits within the Yellowstone caldera formed during three main episodes that correspond broadly with known periods of wet climate: 13.9−13.6 ka, 12.2−9.5 ka, and 5.2−2.9 ka. Travertine deposition occurred in response to the influx of large volumes of cold meteoric water, which increased the rate of chemical weathering of surficial sediments and recharge into the hydrothermal system. The small volume of intracaldera travertine does not support a massive postglacial surge of CO 2 within the Yellowstone caldera, nor was magmatic CO 2 the catalyst for postglacial travertine deposition.

Wyoming↗

USGS2023

Evaluation of hydrologic processes in the eastern Snake River Plain aquifer using uranium and strontium isotopes, Idaho National Laboratory, eastern Idaho

Waste constituents discharged to the eastern Snake River Plain aquifer at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) pose risks to the water quality of the aquifer. To understand these risks, the U.S. Geological Survey, in cooperation with the DOE, is conducting geochemical studies to better understand the hydrologic processes at the INL that affect the movement of groundwater and waste constituents. In this study, we used natural uranium ( 234 U/ 238 U) and strontium ( 87 Sr/ 86 Sr) isotope ratios of surface water and groundwater to identify the sources of water, the mixing of different source waters, and the flow directions in the shallow part (upper 250 feet) of the aquifer at the INL. Samples were collected from 17 sites at and near the INL that represent the source-water contributions to the aquifer. These source-water sites included surface water, regional groundwater, and springs. Groundwater samples from 63 sites were collected at and near the INL. For all sites, sample collection dates ranged from 1979 to 2019, but groundwater samples collected at the INL are representative of wet climate cycles when the Big Lost River (BLR) was flowing onto the INL. The 234 U/ 238 U activity ratios and 87 Sr/ 86 Sr from groundwater at the INL were plotted on graphs within ternary mixing webs in which the three end members of the mixing web represented specific sources of recharge. The large number of sources of recharge required numerous mixing webs, representing various geographic locations at the INL, so that each mixing web represented an area with just three sources of recharge. Considerations for determining the sources of recharge to groundwater sites included chemical signatures in addition to 234 U/ 238 U and 87 Sr/ 86 Sr, hydrologic context, and geographic location. The mixing webs were used to estimate the percentage of recharge from specific sources to groundwater at wells. The results of this study identified groundwater from the Lemhi Range as a source of recharge to the INL, which was a previously unsuspected source of recharge. The estimated spatial distribution of recharge from the BLR and groundwater from the Lost River Range also decreased and increased, respectively, relative to the spatial distribution estimated from an earlier study. Upwelling geothermal water was identified at only one well, which indicates that the upward movement of deep groundwater to the shallow part of the aquifer is largely nonexistent. Mixing between surface water and groundwater, different groundwater recharge sources, or both is ubiquitous at the INL. Mixing of water fully explains the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr in groundwater at the INL and thus renders unnecessary the hypothesis that fast and slow flow zones at the INL are required to explain the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr.

Idaho↗

USGS2023

Strontium isotope chronostratigraphic age of a sirenian fossil site on Santa Rosa Island, Channel Islands National Park, California

Fossils in the order Sirenia (family Dugongidae) from Santa Rosa Island, part of Channel Islands National Park in southern California, provide rare temporal and spatial links between earlier and later evolutionary forms of dugongids, and add information about their dispersal into the northeastern Pacific region. Marine sedimentary rocks containing these fossils have characteristics of both the late Oligocene to middle Miocene Vaqueros Sandstone and the early to middle Miocene Rincon formation observed elsewhere. To determine a more precise age of the fossils, marine invertebrate shells were collected from the same exposures as the sirenian fossils for chronostratigraphic assessment using strontium isotope compositions and the well-calibrated seawater strontium evolution curve. Shells used for analysis were from bivalve mollusks ( Pycnodonte sp. [oyster] and Lyropecten sp. [scallop]) and crustaceans ( Balanus sp. [barnacle]). Results show a wide range of 87 Sr/ 86 Sr values, indicating that shell materials experienced varying degrees of diagenetic alteration. Strontium concentrations and 87 Sr/ 86 Sr values in subsamples of Pycnodonte shell show correlations between original shell material and a secondary component having lower strontium concentrations and less radiogenic (lower) 87 Sr/ 86 Sr. In contrast, all Lyropecten shell analyses yielded a uniform 87 Sr/ 86 Sr value (0.708440±0.000010 [2× standard deviation]) over a wide range of strontium concentrations (around 900 to 1,800 micrograms per gram [μg/g]). Results for Balanus shell subsamples show a range of strontium compositional behavior between the other two types of shell. Acetic acid leachates of sandy matrix confirm that diagenetic fluids had low 87 Sr/ 86 Sr values consistent with the least radiogenic values in Pycnodonte subsamples. A simple mixing model between two calcite end-members can explain observed Pycnodonte data, although actual diagenetic processes likely involved secondary dissolution/reprecipitation or strontium ion exchange between shell material and pore fluid. Data indicate that only Lyropecten subsamples have retained their original 87 Sr/ 86 Sr compositions, resulting in a best-estimate age of 20.08±0.11 million years ago (Ma) (±95-percent confidence interval [CI]). Although Dugongidae fossils have been found in Miocene and younger sediments along the west coast of North America, the Santa Rosa Island specimens represent some of the earliest and most accurately dated sirenian fossils in the region. Chronostratigraphic results also constrain the timing of the transgressional processes represented by shallow-water (Vaqueros Sandstone) to deep-water (Rincon formation) depositional environments.

California↗

USGS2023

Climate-driven mid- to late Holocene hydrologic evolution of arid wetlands documented by strontium, uranium, and oxygen isotopes from Lower Pahranagat Lake, southern Nevada, USA

Lacustrine carbonates in a 12.4-m-long core from Lower Pahranagat Lake (LPAH), southern Nevada, indicate that radiogenic isotopes of Sr and U ( 87 Sr/ 86 Sr and 234 U/ 238 U) preserve evidence of past variations in water sources and evolving hydrologic conditions. Sr and U isotope compositions in LPAH carbonates fall within the range defined by the three primary groundwater sources in Pahranagat Valley and reflect variable mixtures of those sources since the mid-Holocene. Compositions in the oldest sample (5.78 ka) closely match modern compositions of modern discharge from nearby springs, indicating that LPAH water was derived almost exclusively from the local volcanic aquifer. By ca. 5.3–5.2 ka, LPAH water compositions shifted sharply towards isotopic compositions observed in groundwater from the regional carbonate aquifer, indicating a marked increase in surface flow from high-volume springs discharging from the carbonate aquifer to the north. Sediments deposited between 3.08–1.06 ka indicate reduced contributions from the regional aquifer. A comparison of uranium- and oxygen-isotope values in LPAH carbonates suggests that wetter climate conditions favor increased supply from deeper, regional carbonate aquifers compared to drier conditions when contributions from shallower, local volcanic aquifers were more important.

Nevada↗

USGS2023

Geologic map and hydrogeologic investigations of the upper Santa Cruz River basin, southern Arizona

This report includes an updated geologic map and cross sections of the upper Santa Cruz River basin, southern Arizona. The map and cross sections describe the geometry, thickness, and structure of the Miocene to Holocene units which form the main aquifers in the basin. The report also includes results of new hydrogeologic studies including (1) mapping and defining depth to bedrock based on geophysical data in the map area to better define the geometry and structure of the basin aquifers, (2) describing newly recognized hydrologically significant faults in the Peck Canyon and Sopori Wash areas, and (3) evaluating groundwater sources and hydrogeology of the Potrero Creek wetlands.

Arizona↗

USGS2022

The Coles Hill uranium deposit, Virginia, USA: Geology, geochemistry, geochronology, and genetic model

The Coles Hill uranium deposit with an indicated resource of about 130 million lbs. of U 3 O 8 is the largest unmined uranium deposit in the United States. The deposit is hosted in the Taconian (approximately 480 – 450 Ma) Martinsville igneous complex, which consists of the Ordovician Leatherwood Granite (granodiorite) and Silurian Rich Acres Formation (diorite). The host rock was metamorphosed to orthogneiss during the Alleghanian orogeny (approximately 325 – 260 Ma) when it also underwent dextral strike-slip movement along the Brookneal shear zone. During the Triassic, extensional tectonics led to the development of the Dan River Basin that lies east of Coles Hill. The mineralized zone is hosted in brittle structures in the footwall of the Triassic Chatham fault that forms the western edge of the basin. Within brittle fracture zones, uranium silicate and uranium-bearing fluorapatite with traces of brannerite form veins and breccia fill with chlorite, quartz, calcite, titanium oxide, pyrite, and calcite. Uranium silicates also coat and replace primary titanite, zircon, ilmenite, and sulfides. Sodium metasomatism preceded and accompanied uranium mineralization, pervasively altering host rock, and forming albite from primary feldspar, depositing limpid albite rims on feldspar, altering titanite to titanium oxide and calcite and forming riebeckite. Various geothermometers suggest temperatures of less than approximately ~200°C during mineralization. In situ U-Pb analyses of titanite, Ti-oxide, and apatite, and Rb/Sr and U/Pb isotope-systematics of whole rock samples resolve the timing of geologic processes affecting Coles Hill. The host Leatherwood granite containing primary euhedral titanite is dated at 450 – 445 Ma, in agreement with previously obtained ages from zircon in the Martinsville igneous complex. A regional metamorphic event at 330 – 310 Ma formed anhedral titanite and some apatite, re-equilibrated whole rock Rb/Sr and U-Pb isotopes and is interpreted to have coincided with movement along the Brookneal shear zone. During shearing and metamorphism primary refractory uranium-bearing minerals including titanite, zircon, and uranothorite were recrystallized and uranium was liberated and incorporated locally into hematite, clay, and other fine-grained minerals. Uranium mineralization was accompanied by a metasomatic episode between 250 and 200 Ma that reset the Rb-Sr and U-Pb isotope systems, forming titanite and apatite that are associated and in places intimately intergrown with uranium silicate dating mineralization. This event coincides with rifting that formed the Dan River Basin and was a precursor to the breakup of Pangea. Based on the close spatial and temporal association of uranium with apatite, we conclude that uranium was carried as a uranyl-phosphate complex. The release of calcium during sodium metasomatic alteration of primary calcic feldspar and titanite in the host rock initiated successive reactions in which uranium and phosphate in mineralizing fluids combined with calcium to form U-enriched fluorapatite. Excess uranium was locally reduced by coupled redox reactions involving ferrous iron and sulfide minerals in the host rock, forming uranium silicates. Based on the deposit mineralogy, oxygen isotope geochemistry and trace element characteristics of uranium silicate and gangue minerals the primary mineralizing fluids likely included connate and/or meteoric water sourced from the local Dan River Basin. High heat flow related to Mesozoic rifting may have driven these (P-Na-F-rich) brines through local aquifers and into basin margin faults, transporting uranium from the basin or mobilizing uranium from previously formed U-minerals in the Brookneal shear zone, or from U-enriched older basement rock.

Virginia↗

USGS2021

Geomorphic history of Lake Manix, Mojave Desert, California: Evolution of a complex terminal lake basin

The US Environmental Protection Agency's short-term freshwater effluent test methods include a fish ( Pimephales promelas ), a cladoceran ( Ceriodaphnia dubia ), and a green alga ( Raphidocelis subcapitata ). There is a recognized need for additional taxa to accompany the three standard species for effluent testing. An appropriate additional taxon is unionid mussels because mussels are widely distributed, live burrowed in sediment and filter particles from the water column for food, and exhibit high sensitivity to a variety of contaminants. Multiple studies were conducted to develop a relevant and robust short-term test method for mussels. We first evaluated the comparative sensitivity of two mussel species ( Villosa constricta and Lampsilis siliquoidea ) and two standard species ( P. promelas and C. dubia ) using two mock effluents prepared by mixing ammonia and five metals (cadmium, copper, nickel, lead, and zinc) or a field-collected effluent in 7-day exposures. Both mussel species were equally or more sensitive (more than two-fold) to effluents compared with the standard species. Next, we refined the mussel test method by first determining the best feeding rate of a commercial algal mixture for three age groups (1, 2, and 3 weeks old) of L. siliquoidea in a 7-day feeding experiment, and then used the derived optimal feeding rates to assess the sensitivity of the three ages of juveniles in a 7-day reference toxicant (sodium chloride [NaCl]) test. Juvenile mussels grew substantially (30%–52% length increase) when the 1- or 2-week-old mussels were fed 2 ml twice daily and the 3-week-old mussels were fed 3 ml twice daily. The 25% inhibition concentrations (IC25s) for NaCl were similar (314–520 mg Cl/L) among the three age groups, indicating that an age range of 1- to 3-week-old mussels can be used for a 7-day test. Finally, using the refined test method, we conducted an interlaboratory study among 13 laboratories to evaluate the performance of a 7-day NaCl test with L. siliquoidea . Eleven laboratories successfully completed the test, with more than 80% control survival and reliable growth data. The IC25s ranged from 296 to 1076 mg Cl/L, with a low (34%) coefficient of variation, indicating that the proposed method for L. siliquoidea has acceptable precision. Environ Toxicol Chem 2021;40:3392–3409. © 2021 SETAC

California↗

USGS2020

Hydrothermal activity in the southwest Yellowstone Plateau Volcanic Field

In the past two decades, the U.S. Geological Survey and the National Park Service have studied hydrothermal activity across the Yellowstone Plateau Volcanic Field (YPVF) to improve the understanding of the magmatic-hydrothermal system and to provide a baseline for detecting future anomalous activity. In 2017 and 2018 we sampled water and gas over a large area in the southwest YPVF and used Landsat 8 thermal infrared data to estimate radiative heat flow. Most of the thermal activity in this region is in close proximity to the Yellowstone Caldera boundary. Springs and fumaroles discharge from a variety of lithologies including some of the youngest rhyolites in the YPVF. Gas compositions and helium isotope ratios of most samples resemble those in other parts of the YPVF. The waters have meteoric origins and tritium was detected in several samples. Thermal waters from some areas have compositions that plot along a line connecting thermal and non-thermal water endmember compositions. The thermal water endmember equilibrated at 160-170 °C, lower than waters in Yellowstone’s geyser basins. Heat discharged by springs and fumaroles originates from within the Yellowstone Caldera and is transported laterally by advection, mainly along the base of rhyolite flows that cover the inferred caldera boundaries.

Yellowstone National Park↗

USGS2020

Dating silica sinter (geyserite): A cautionary tale

We describe a new effort to date hydrothermal silica sinter deposits (geyserite) from the Upper Geyser Basin of Yellowstone National Park using 14C of co-deposited organic matter, U-series and cosmogenic 10Be methods. A majority of the samples were collected from stratigraphic sections, mainly at Riverside, Giant, and Castle Geysers. Ages obtained from 41 14C analyses range from modern to 12.1 cal ka BP. Nearly all the 14C ages show inconsistencies with their stratigraphic positions, and several replicate 14C analyses from the same sample result in significantly different ages. The δ13C values of the organic material in the sinter range from -26.6‰ to -12.7‰. The more enriched values are attributed to microbial fixation of dissolved inorganic carbon (DIC), which has heavier δ13C values and is 14C-depleted relative to atmospheric CO2, leading to apparent older ages. U-series analyses on 4 samples yielded ages between 2.2 and 7.4 ka. Large 230Th/U age uncertainties in the sinter, due to low uranium concentrations along with elevated 232Th and associated initial 230Th, make these ages imprecise for use on Holocene deposits. A single cosmogenic 10Be exposure age of 596±18 ka is considerably older than the age of underlying rhyolite and is thus unreliable. This apparent old age results from contamination by meteoric 10Be trapped in the opal that overprints the very small amount of cosmogenic 10Be. By presenting the problems we encountered and discussing their probable cause, this paper highlights the difficulty in obtaining reliable, high-precision geochronological data necessary to use sinter deposits as paleoenvironmental and paleo-hydrothermal archives.

Wyoming↗

USGS2019

Pleistocene lakes and paleohydrologic environments of the Tecopa basin, California: Constraints on the drainage integration of the Amargosa River

The Tecopa basin in eastern California was a terminal basin that episodically held lakes during most of the Quaternary until the basin and its modern stream, the Amargosa River, became tributary to Death Valley. Although long studied for its sedimentology, diagenesis, and paleomagnetism, the basin’s lacustrine and paleoclimate history has not been well understood, and conflicting interpretations exist concerning the relations of Tecopa basin to the Amargosa River and to pluvial Lake Manly in Death Valley. Previous studies also did not recognize basinwide tectonic effects on lake-level history. In this study, we focused on: (1) establishing a chronology of shoreline deposits, as the primary indicator of lake-level history, utilizing well-known ash beds and new uranium-series and luminescence dating; (2) using ostracodes as indicators of water chemistry and water source(s); and (3) correlating lake transgressions to well-preserved fluvial-deltaic sequences. During the early Pleistocene, the Tecopa basin hosted small shallow lakes primarily fed by low-alkalinity water sourced mainly from runoff and (or) a groundwater source chemically unlike the modern springs. The first lake that filled the basin occurred just prior and up to the eruption of the 765 ka Bishop ash during marine isotope stage (MIS) 19; this lake heralded the arrival of the Amargosa River, delivering high-alkalinity water. Two subsequent lake cycles, coeval with MIS 16 (leading up to eruption of 631 ka Lava Creek B ash) and MIS 14 and (or) MIS 12, are marked by prominent accumulations of nearshore and beach deposits. The timing of the youngest of these three lakes, the High lake, is constrained by a uranium-series age of ca. 580 ± 120 ka on tufa-cemented beach gravel and by estimates from sedimentation rates. Highstand deposits of the Lava Creek and High lakes at the north end of the basin are stratigraphically tied to distinct sequences of fluvial-deltaic deposits fed by alkaline waters of the Amargosa River. The High lake reached the highest level achieved in the Tecopa basin, and it may have briefly discharged southward but did not significantly erode its threshold. The High lake was followed by a long hiatus of as much as 300 k.y., during which there is evidence for alluvial, eolian, and groundwater-discharge deposition, but no lakes. We attribute this hiatus, as have others, to blockage of the Amargosa River by an alluvial fan upstream near Eagle Mountain. A final lake, the Terminal lake, formed when the river once again flowed south into Tecopa basin, but it was likely short-lived due to rapid incision of the former threshold south of Tecopa. Deposits of the Terminal lake are inset below, and are locally unconformable on, deposits of the High lake and the nonlacustrine deposits of the hiatus. The Terminal lake reached its highstand at ca. 185 ± 21 ka, as dated by infrared-stimulated luminescence on feldspar in beach sand, a time coincident with perennial lake mud and alkaline-tolerant ostracodes in the Badwater core of Lake Manly during MIS 6. A period of stillstand occurred as the Terminal lake drained when the incising river encountered resistant Stirling Quartzite near the head of present-day Amargosa Canyon. Our studies significantly revise the lacustrine and drainage history of the Tecopa basin, show that the MIS 6 highstand was not the largest lake in the basin as previously published (with implications for potential nuclear waste storage at Yucca Mountain, Nevada), and provide evidence from shoreline elevations for ∼20 m of tectonic uplift in the northern part of the basin across an ENE-trending monoclinal flexure.

California↗

USGS2019

300,000 yr history of water-table fluctuations at Wind Cave, South Dakota, USA—Scale, timing, and groundwater mixing in the Madison Aquifer

Deposits of calcite coating the lower passages of Wind Cave in the southern Black Hills of South Dakota were precipitated under phreatic conditions. Data from samples associated with a new cave survey and hydrologic studies indicate that past water tables within Wind Cave reached a maximum height of 45 m above modern levels but were mostly confined to 25 m or less. Uranium-series ages for basal layers deposited on weathered wall rock indicate subaerial conditions in this part of the cave persisted between 1000 and 300 ka. Ages and elevations of wall coatings and cave rafts establish a 300,000 yr paleohydrograph indicating that water-table highstands occurred during interglacial or interstadial-to-early glacial periods and lowstands occurred during full-glacial and stadial episodes. Isotopes of Sr, U, C, and O from dated calcite samples were obtained to evaluate potential shifts in paleo-groundwater composition. For comparison, Sr and U isotopic compositions were determined for modern groundwater from 18 sites previously classified into five hydrogeologic domains. Isotope data for different domains tend to cluster in separate fields, although several fields overlap. Compositions of Calcite Lake (informal name) water reflect modern recharge to shallow aquifers. In contrast, speleothem data indicate that paleo-groundwater highstands were not supported by increased infiltration associated with local recharge, or by upwelling from deeper Proterozoic sources. Instead, cave water was similar to deeper, warmer groundwater from the Madison Aquifer discharging at modern artesian springs flanking the southern Black Hills. Highstands were likely influenced by large-scale hydraulic processes associated with recharge to the Madison Aquifer under the Laurentide ice sheet on the northeast side of the Williston Basin, causing increased hydrostatic pressures in confined aquifers on the south side of the basin.

South Dakota↗

USGS2019

Calcrete uranium deposits in the Southern High Plains, USA

The Southern High Plains (SHP) is a new and emerging U.S. uranium province. Here, uranyl vanadates form deposits in Pliocene to Pleistocene sandstone, dolomite, and limestone. Fifteen calcrete uranium occurrences are identified; two of these, the Buzzard Draw and Sulfur Springs Draw deposits, have combined in-place resources estimated at about 4 million pounds of U 3 O 8 . Ore minerals carnotite and finchite are hosted in dolomite at the Sulfur Springs Draw deposit, with accessory fluorite, celestine, smectite/illite, autunite, and strontium carbonate. Host carbonate at the Sulfur Springs Draw deposit is ∼190 ka and mineralization mobilized as recently as 3.8 ka. Ash collected near the deposit is 631 ka and erupted from the Yellowstone caldera complex. The Triassic Dockum Group that contains sandstone-hosted uranium deposits throughout the region and underlies the SHP is a potential source for uranium and vanadium. Regional uplift and dissection reintroduced oxygenated groundwater into the Dockum Group, mobilizing uranium. Additional uranium may have been contributed to groundwater by weathering of volcanic ash in Pliocene and Pleistocene host rocks. The locations of the uranium occurrences are mostly in modern drainage systems in the southeast portion of the SHP. Modelling of modern groundwater in the SHP carried out in a parallel study shows that a single fluid could form carnotite through evaporation, and that fluids of the requisite composition are more prevalent in the southern portion of the SHP. The southeastern portion of the SHP hosts more uranium occurrences due to a variety of factors including (1) upward transport of groundwater and connectivity between source and host rock, (2) higher uranium and vanadium content of groundwater, (3) higher rates of groundwater recharge in this region to drive the mineralizing system, and (4) shallower groundwater facilitating surface evaporation. Ongoing erosion of host rocks challenges preservation of deposits and may limit their size.

Southern High Plains↗

USGS2019

Middle Pleistocene formation of the Rio Grande Gorge, San Luis Valley, south-central Colorado and north-central New Mexico, USA: Process, timing, and downstream implications

The Rio Grande is the fourth longest river in North America extending over 3,000 km from the Rocky Mountains to the Gulf of Mexico. The Pleistocene evolution of this river from individual subbasins into a coalesced fluvial system has been long debated. Herein, we constrain the middle Pleistocene evolution of the northernmost and largest Rio Grande basin, the San Luis basin, and the timing of incision of the Rio Grande Gorge, based on new geologic mapping, 3 He surface exposure dating, and U-series dating on pedogenic carbonates. 3 He dating of shoreline deposits of closed basin Lake Alamosa and fluvially scoured bedrock along the Rio Grande gorge rim indicate the San Luis basin was connected with southerly Rio Grande basins and progressively incised since ∼400 ka. Waning tectonic activity, coupled with the hydrologic response to intensified middle Pleistocene glaciation, drove southward spillover of Lake Alamosa ∼400 ka, expanding the river's drainage basin by nearly 24,000 km 2 , and adding recharge areas in the high-altitude, glaciated San Juan, Tusas, and Sangre de Cristo Mountains. Geologic barriers to streamflow on the Taos Plateau were breached and basin tributary drainages were integrated and inset into their present canyons ∼250-200 ka, with approximately 120 m of incision during ∼400-200 ka. Previous work demonstrates that southerly streamflow through basins south of the SLB terminated into a large, rift-related bolson complex until the middle Pleistocene, and most axial Rio Grande river incision has occurred since 630 ka. We propose that middle Pleistocene integration of the SLB was the major geomorphic event that eroded Plio-Pleistocene tectonic and volcanic barriers and re-established flow of the Rio Grande from the Rocky Mountains to the Gulf of Mexico.

Colorado, New Mexico↗

USGS2019

Multivariate analysis of hydrochemical data for Jewel Cave, Wind Cave, and surrounding areas

Jewel Cave National Monument and Wind Cave National Park in South Dakota contain two of the six longest caves worldwide. These caves contain subterranean lakes that are important points of intersection between the water table of the Madison aquifer and the caves. During 2015 to 2017, several subterranean lakes were discovered in Jewel Cave, which previously was thought to be above the regional water table. The objectives of this study were to better understand the hydrology of the recently discovered lakes in Jewel Cave and to evaluate their relation or possible connection to similar subterranean lakes in Wind Cave. Both objectives align with National Park Service resource management purposes. Multivariate analysis, consisting of principal component analysis (PCA), cluster analysis, and end member mixing, was applied to hydrochemical data for 70 sites within and surrounding Jewel Cave and Wind Cave. Hydrochemical data consisted of the contents of major ions (Ca, Mg, Na, HCO3, Cl, Si, SO4), arsenic (As), strontium (Sr), uranium (U), stable isotopes of oxygen and hydrogen (δ18O, δ2H), radiogenic isotope ratios of strontium and uranium (87Sr/86Sr and 234U/238U), pH, and electrical conductivity (EC) in water samples. Five hydrogeologic domains were identified on the basis of PCA and cluster analysis for the area encompassing Jewel Cave and Wind Cave in the southern Black Hills. The Artesian 1 and Artesian 2 domains represent primarily artesian springs and surrounding groundwater, the East and West domains represent areas where Madison and Minnelusa aquifer rocks are at or near the land surface, and the Precambrian domain represents the Precambrian aquifer. Multivariate analysis indicates that the Jewel Cave area is part of the West domain and that Wind Cave is part of the East domain. End member mixing was applied to estimate that groundwater in the Jewel Cave area primarily was derived from the West domain and secondarily from the Precambrian domain. Jewel Cave and Wind Cave contain lakes that are well connected to regional groundwater flow in the Madison aquifer.

South Dakota↗

USGS2018

Geologic map of the Fort Morgan 7.5' quadrangle, Morgan County, Colorado

The Fort Morgan 7.5′ quadrangle is located on the semiarid plains of northeastern Colorado, along the South Platte River corridor where the river has incised into Upper Cretaceous Pierre Shale. The Pierre Shale is largely covered by surficial deposits that formed from alluvial, eolian, and hillslope processes operating in concert with environmental changes from the late Pliocene to the present. The South Platte River, originating high in the Colorado Rocky Mountains, has played a major role in shaping surficial geology in the map area, which is several tens of kilometers downstream from where headwater tributaries join the river. Recurrent glaciation (and deglaciation) of basin headwaters has affected river discharge and sediment supply far downstream, influencing deposition of alluvium and river incision in the Fort Morgan quadrangle. Distribution and characteristics of the alluvial deposits indicate that during the Pleistocene the course of the river within the map area shifted progressively southward as it incised, and by late middle Pleistocene the river was south of its present position, cutting and filling a deep paleochannel near the south edge of the quadrangle. The river shifted back to the north during the late Pleistocene. Kiowa and Bijou Creeks are unglaciated tributaries originating in the Colorado Piedmont east of the Front Range that also have played a major role in shaping surficial geology of the map area. Periodically during the late Pleistocene, major flood events on these tributaries deposited large volumes of sediment at and near their confluences, forming a broad, low-gradient fan composed of sidestream alluvium that could have occasionally dammed the river for short periods of time. Wildcat Creek, also originating on the Colorado Piedmont, and the small drainage of Cris Lee Draw dissect the map area north of the river. Eolian sand deposits of the Sterling (north of river) and Fort Morgan (south of river) dune fields cover much of the quadrangle and record past episodes of sand mobilization during times of prolonged drought. With the onset of irrigation and damming during historical times, the South Platte River has changed from a broad, shallow, and sandy braided river with highly variable seasonal discharge to a much narrower, deeper river with braided-meandering transition morphology and more uniform discharge.

Colorado↗