Zinc- and Y-group-bearing senaite from St Peters Dome, and new data on senaite from Dattas, Minas Gerais, Brazil
A Zn- and Y-group-bearing senaite, formulated as AM 21 O 38 (Pb 0.63 Na 0.46 Ba 0.11 ) Σ1.20 (Ti 14.64 Zn 1.74 Y‒group REE 0.70 Mn 0.38 Nb 0.20 Sn 0.03 Zr 0.03 Th 0.02 ) Σ20.9 O 38 , a member of the crichtonite group, is a newly characterized phase associated with murataite at the St Peters Dome area, Colorado. The Zn- and Y-group-bearing senaite is uranium-free and nonmetamict, but otherwise is comparable to known senaites and davidites in X-ray diffraction pattern, symmetry, and structure. The REE distribution shows a strong dominance of Y and the Y-group REE which are present in M (1). Megascopically, the mineral is black, submetallic, and opaque; in polished section it appears to be white and moderately bright compared with murataite. Cleavage is absent but twinning on {52 0} is present. Senaite and hitherto unreported zinc-bearing senaite from Dattas, Diamantina, Minas Gerais, Brazil, have the following respective structural formulas as determined by electron microprobe: (Pb 0.76 Sr 0.20 La 0.08 Ce 0.07 Ba 0.04 ) Σ1.15 (Ti 12.89 Mn 0.88 Y 0.59 Zn 0.12 Mg 0.07 Nb 0.03 Cr 0.02 Th 0.02 ) Σ20.61 O 38 and (Pb 0.89 Ba 0.15 Ce 0.02 Sr 0.02 ) Σ1.08 (Ti 14.57 Zn 1.76 Na 0.63 Mn 0.50 Y 0.28 Nb 0.14 Mg 0.04 Cr 0.02 ) Σ20.83 O 38