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Geology topics

J.J. Irwin

Publications and source records attributed to J.J. Irwin.

4 recordsLinked to original sources
USGS1992

Brine history indicated by argon, krypton, chlorine, bromine, and iodine analyses of fluid inclusions from the Mississippi Valley type lead-fluorite-barite deposits at Hansonburg, New Mexico

Argon, krypton, chlorine, bromine, and iodine were measured in a homogeneous population of high-salinity hydrothermal fluid inclusions from the Tertiary-age Mississippi Valley-type (MVT) lead-fluorite-barite deposits at Hansonburg, New Mexico to establish new types of evidence for the history of both the fluid and the major dissolved salts. Noble gases and halogens in fluid inclusions containing 10 −10 –10 −9 L of brine ( Cl= 3 molal) were analyzed by laser microprobe noble-gas mass spectrometry ( lmngms ) on neutron-irradiated samples. The concentrations of 36 Ar ( 4.7 × 10 −8 molal) and 84 Kr 1.8 × 10 −9 molal) in the fluid inclusions are equal to those of fresh surface waters in equilibrium with air at approximately 20 ± 5 °. The mole ratios of Br/Cl ( 1.2 × 10 −4 ) and I/Cl ( 1–2 × 10 −6 ) are among the lowest measured in any natural waters, similar to those of modern brines formed by dissolution of Permian NaCl-bearing evaporites in southeast New Mexico. 40 Ar/ 36 Ar ratios (600) are twice that of air, and indicate that the fluid inclusions had excess radiogenic 40 Ar ( 1.4 × 10 −5 molal) when trapped. The amount of excess 40 Ar appears to be too large to have been acquired with Cl by congruent dissolution of halite-bearing evaporites, and possibly too small to have been acquired with Pb by congruent dissolution of granitic basement rocks with Proterozoic K Ar ages. From the lmngms data, combined with published Pb and S isotope data, we infer the following sequence of events in the history of the Hansonburg MVT hydrothermal brine: (1) the brine originated as relatively dilute meteoric water, and it did not gain or lose atmospheric Ar or Kr after recharge; (2) the originally dilute fluid acquired the bulk of its Cl and sulfate in the subsurface after recharge by dissolving halite-bearing Permian? marine evaporites; (3) the high salinity brine then acquired most of its Pb and excess radiogenic 40 Ar from interactions with aquifer rocks other than evaporites, possibly clastic sedimentary rocks or basement rocks with Phanerozoic K Ar “ages”; and (4) the brine deposited fluorite without having boiled or degassed.

Earth and Planetary Science Letters↗
USGS1992

Laser microprobe analyses of noble gas isotopes and halogens in fluid inclusions: Analyses of microstandards and synthetic inclusions in quartz

Ar, Kr, Xe, Cl, Br, I, and K abundances and isotopic compositions have been measured in microscopic fluid inclusions in minerals by noble gas mass spectrometry following neutron irradiation and laser extraction. The laser microprobe noble gas mass spectrometric (LMNGMS) technique was quantified by use of microstandards, including air-filled capillary tubes, synthetic basalt glass grains, standard hornblende grains, and synthetic fluid inclusions in quartz. Common natural concentrations of halogens (Cl, Br, and I) and noble gases (Ar and Kr) in trapped groundwaters and hydrothermal fluids can be analyzed simultaneously by LMNGMS in as little as 10 −11 L of inclusion fluid, with accuracy and precision to within 5–10% for element and isotope ratios. Multicomponent element and isotope correlations indicate contaminants or persistent reservoirs of excess Xe and/or unfractionated air in some synthetic and natural fluid inclusion samples. LMNGMS analyses of natural fluid inclusions using the methods and calibrations reported here may be used to obtain unique information on sources of fluids, sources of fluid salinity, mixing, boiling (or unmixing), and water-rock interactions in ancient fluid flow systems.

Geochimica et Cosmochimica Acta↗
USGS1992

Laser microprobe analyses of Cl, Br, I, and K in fluid inclusions: Implications for sources of salinity in some ancient hydrothermal fluids

The relative concentrations of Cl, Br, I, and K in fluid inclusions in hydrothermal minerals were measured by laser microprobe noble gas mass spectrometry on irradiated samples containing 10 −10 to 10 −8 L of fluid. Distinctive halogen signatures indicate contrasting sources of fluid salinity in fluid inclusions from representative “magmatic” (St. Austell), “metamorphic” (Alleghany), and “geothermal” (Creede, Salton Sea) aqueous systems. Br/Cl mol ratios are lowest at Salton Sea (0.27–0.33 × 10 −3 ), where high salinities are largely due to halite dissolution; intermediate at St. Austell (0.85 × 10 −3 ), possibly representative of magmatic volatiles; and highest (near that of seawater) at Creede (1.5–2.1 × 10 −3 ) and Alleghany (1.2–2.4 × 10 −3 ), where dissolved halogens probably were leached from volcanic and (or) nonevaporitic sedimentary rocks. I C1 "> IC1 mol ratios are lowest (near that of seawater) at Creede (1–14 × 10 −6 ), possibly because organisms scavenged I during low temperature recharge; intermediate at Salton Sea (24–26 × 10 −6 ) and St. Austell (81× 10 −6 ); and highest at Alleghany (320–940 × 10 −6 ), probably because the fluids interacted with organic-rich sediments at high temperatures before being trapped. K Cl "> KCl mol ratios indicate disequilibrium with respect to hypothetical feldspathic alkali-Al-silicate mineral buffers at fluid inclusion trapping temperatures at Creede, and large contributions of (Na, K)-bicarbonate to total fluid ionic strength at Alleghany. Significant variations in Cl/Br/I/K ratios among different fluid inclusion types are correlated with previously documented mineralization stages at Creede, and with the apparent oxidation state of dissolved carbon at Alleghany. The new data indicate that Cl/ Br/I ratios in hydrothermal fluid inclusions vary by several orders of magnitude, as they do in modern surface and ground waters. This study demonstrates that halogen signatures of fluid inclusions determined by microanalysis yield important information about sources of fluid salinity and provide excellent definition of fluid reservoirs and tracers of flow and interaction in ancient hydrothermal systems.

Geochimica et Cosmochimica Acta↗