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J. R. O’Neil

Publications and source records attributed to J. R. O’Neil.

At least 37 records · Page 2Linked to original sources
USGS1980

Stable isotope and fluid inclusion studies of carbonate deposits from the Tolfa Mountains mining district (Latium, central Italy)

Carbon and oxygen isotope analyses were made of representative samples of calcite and quartz from the carbonate deposits in the Tolfa Mountains mining district. Measurements were also made of hydrogen isotope compositions, filling temperatures and salinities of fluid inclusions in these minerals. There are three stages of mineralization at Tolfa. In stage I, characterized by calc-silicate hornfels, the carbonates have relatively high ?? 18O values of 14.5 to 21.6 suggesting a rather low water/rock ratio. ??13C values of -0.3 to 2.1 indicate that appreciable decarbonation or introduction of deep-seated carbon did not occur. Stage II is marked by phanerocrystalline carbonates; ?? 18O values of 13.1 to 20.0 and ??13C values of 0.7 to 5.0 identify them as hydrothermal veins rather than marbles. ?? D values of -56 to -50 for inclusion fluids suggest a possible magmatic component to the hydrothermal fluid. Filling temperatures of coarse-grained samples of Calcite II are 309?? to 362?? C with a salinity range of 5.3 to 7.1 weight percent NaCl. Calculated ??18O values of 11-12 for these fluids are again indicative of low water/rock ratios. The sparry calcites of stage III have ??18O and ??13C values of 8.1 to 12.9 and -1.7 to 3.2, respectively. ?? D values of inclusion fluids are -40 to -33, clearly heavier than in earlier stages and similar to values of modern local ground waters. A salinity measurement of <0.1 weight percent NaCl in a sample of Calcite III is compatible with a relatively unaltered ground water origin for this fluid. Precipitation of the sparry calcite took place at much lower temperatures, around 160?? C. For quartz, ??18O values of 9.3 to 12.4 and ?? D values for inclusions of -53 to -28 are consistent with its late occurrence and paragenetic link with associated carbonates. ?? 1980 Springer-Verlag.

Mineralium Deposita↗
USGS1980

Stable isotope variations in the Quaternary epithermal calcite-fluorite deposit at Monte delle Fate near Cerveteri (Latium, central Italy)

Carbon, oxygen and hydrogen isotope variations have been measured in samples from the epithermal fluorite vein deposit at Monte delle Fate, Latium. The ranges in ?? 13C and ??18O of calcite are -1.3 to 3.4 and 9.5 to 17.3, respectively. ??D values of water extracted from fluid inclusions are -49 to -39 for calcite and -41 to -34 for fluorite. Fluid inclusion filling temperatures (225??-240??C) and salinites (3.75) are nearly the same for both fluorite and sparry calcite. An elongated form of calcite, of minor abundance, precipitated at lower temperatures. The data indicate that (1) the CO2 involved in the mineralization was provided by the local marine limestones, (2) the waters were meteoric in origin and underwent an 18O shift of ??? 10 permil by exchange with marine country rocks, and (3) all geochemical features can be explained by the action of two hydrothermal fluids. Hot brines recently discovered in the Cesano geothermal area, 30 km to the east, have temperatures and some chemical characteristics similar to the hydrothermal fluids at Monte delle Fate. ?? 1980 Springer-Verlag.

Mineralium Deposita↗
USGS1978

Present day serpentinization in New Caledonia, Oman and Yugoslavia

Geochemical evidence for modern low-temperature serpentinization has been found in three new localities. Apparently the low-temperature reactions are a common mode of formation of the lizardite-chrysotile and brucite assemblage. Possibly the 18O content of serpentine formed at low temperatures is in part inherited from the pyroxene and olivine. ?? 1978.

Geochimica et Cosmochimica Acta↗
USGS1977

Stable isotopes in mineralogy

Stable isotope fractionations between minerals are functions of the fundamental vibrational frequencies of the minerals and therefore bear on several topics of mineralogical interest. Isotopic compositions of the elements H, C, O, Si, and S can now be determined routinely in almost any mineral. A summary has been made of both published and new results of laboratory investigations, analyses of natural materials, and theoretical considerations which bear on the importance of temperature, pressure, chemical composition and crystal structure to the isotopic properties of minerals. It is shown that stable isotope studies can sometimes provide evidence for elucidating details of crystal structure and can be a powerful tool for use in tracing the reaction paths of mineralogical reactions. ?? 1977 Springer-Verlag.

Physics and Chemistry of Minerals↗
USGS1977

Oxygen and hydrogen isotope compositions as indicators of granite genesis in the New England Batholith, Australia

Oxygen and hydrogen isotope studies of a number of granite suites and mineral separates from the New England Batholith indicate that ??O18 can be used to discriminate the major granite protoliths. The granite suites previously subdivided on the basis of mineralogical and geochemical criteria into S-type (sedimentary) and I-type (igneous) have ??O18 values consistently higher in the S-type granites (10.4-12.5) than in the spatially related I-type plutons (7.7-9.9). There appears to be a systematic variation in ??O18 from the most S-type to the most I-type granites, the dividing point between the two occuring at ??O18 equal to 10. A group of leucocratic granites that form about half of the batholith and difficult to classify mineralogically and geochemically is found to have low ??O18 values (6.4-8.1), suggesting an affinity to the most I-type granites. A single leucogranite pluton with minor muscovite has a ??O18 of 9.6 which is significantly higher than other leucogranites indicating a different origin perhaps involving amphibole fractionation. The behavior of ??D in the plutonic rocks is much less systematic than ??O18. Excluding samples collected adjacent to major faults, the ??D values show a rough positive correlation with water content similar to, but less pronounced than, the trend previously observed in the Berridale Batholith, southeastern Australia. This relation is considered to reflect an interaction between meteoric water and the granites, the largest effect being observed in samples with the least amount of water. Of note is the generally lower ??D values of the upper Paleozoic New England Batholith compared with the Silurian Berridale Batholith. This difference may be related to a near equatorial paleolatitude of 22 ??S in the Silurian and near polar paleolatitudes in the late Carboniferous that have been inferred for these regions. Granite samples collected from near major faults, and one ignimbrite sample of rhyodacite composition, have very low ??D values (less than -120) suggesting a much greater degree of interaction with meteoric water. ?? 1977 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1977

Stable isotope studies of metasomatic Ca-Fe-Al-Si skarns and associated metamorphic and igneous rocks, Osgood Mountains, Nevada

Garnet-pyroxene skarns were formed 90 m.y. B.P. in the Osgood Mountains at or near contacts of grandiorite with calcareous rocks of the Cambrian Preble Formation. The metasomatic replacement followed contact metamorphic recrystallization of the Preble. The sources, temperature, and variation in H2O/CO2 ratios of the metasomatic fluid are interpreted from 269 analyses of oxygen, carbon, hydrogen, and sulfur isotopes in whole rocks, minerals and inclusion fluids. Skarns formed in three mineralogical stages. Oxygen isotope data indicate that temperatures during the crystallization of garnet, pyroxene and wollastonite (Stage I) were least 550 ?? C, and that the metasomatic fluid had an {Mathematical expression} ??? 0.035 in the massive skarns, and ??? 0.12 in vein skarns up to 3 cm thick. Pore fluids in isotopic equilibrium with garnet in calc-silicate metamorphic rocks, on the other hand, had {Mathematical expression} ??? 0.15. The metasomatic fluids of Stage I were derived primarily from the crystallizing magma. The isotopic composition of magmatic water was ??18O =+9.0, ??D= -30 to -45. Oxygen isotope temperatures of greater than 620 ?? C were determined for the granodiorite. Isotopic and chemical equilibria between mineral surfaces and the metasomatic fluid were approached simultaneously in parts of the skarn several meters or more apart, while isotopic and chemical disequilibria (i.e. zoning) have been preserved between 20 to 40 ??m-thick zones in grandite garnet. More Fe-, or andradite-rich garnet crystallized in more H2O-rich C-O-H fluids ( {Mathematical expression} ??? 0.01) than present with grossularite-rich garnet ( {Mathematical expression}??? 0.035). Stage II was marked by the replacement of garnet and pyroxene by quartz, amphibole, plagioclase, epidote, magnetite, and calcite. Many of the replacement reactions took place over a relatively narrow range in temperature (480-550 ?? C), as indicated by 18O fractionations between quartz and amphibole. Meteoric water comprised 20 to 50% of the metasomatic fluid during Stage II. Calcite was formed along with pyrite, minor pyrrhotite, and chalcopyrite during Stage III, although the crystallization of pyrite and calcite had begun earlier, during Stages I and II, respectively. Carbon and sulfur isotope compositions of calcite and pyrite indicate a magmatic source for most of the C and S in the metasomatic fluids of Stage III. By the end of Stage III, meteoric water constituted as much as 100% of the metasomatic fluid. Minerals from grandiorite and skarn do not show large depletions in 18O because the oxygen isotope composition of the metasomatic fluid was buffered by the calcareous wall rocks and the grandiorite. Meteoric water in the vicinity of the Osgood Mountains during the Late Crectaceous (??18Ocale. ??? -14.0, ??D = - 107) was slightly enriched in 18O and D relative to present-day meteoric water (??18O = 15.9, ??D = - 117) ?? 1977 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1976

Equilibrium-disequilibrium relations in the Monte Rosa Granite, Western Alps: Petrological, Rb-Sr and stable isotope data

Nine samples from the Monte Rosa Granite have been investigated by microscopic, X-ray, wet chemical, electron microprobe, stable isotope and Rb-Sr and K-Ar methods. Two mineral assemblages have been distinguished by optical methods and dated as Permian and mid-Tertiary by means of Rb-Sr age determinations. The Permian assemblage comprises quartz, orthoclase, oligoclase, biotite, and muscovite whereas the Alpine assemblage comprises quartz, microcline, albite+epidote or oligoclase, biotite, and phengite. Disequilibrium between the Permian and Alpine mineral assemblages is documented by the following facts: (i) Two texturally distinguishable generations of white K-mica are 2 M muscovite (Si=3.1–3.2) and 2 M or 3 T phengite (Si=3.3–3.4). Five muscovites show Permian Rb-Sr ages and oxygen isotope fractionations indicating temperatures between 520 and 560 ° C; however, K-Ar ages are mixed or rejuvenated. Phengite always shows mid-Tertiary Rb-Sr ages, (ii) Two biotite generations can be recognized, although textural evidence is often ambiguous. Three out of four texturally old biotites show mid-Tertiary Rb-Sr cooling ages while the oxygen isotopic fractionations point to Permian, mixed or Alpine temperatures, (iii) Comparison of radiogenic and stable isotope relations indicates that the radiogenic isotopes in the interlayer positions of the micas were mobilized during Alpine time without recrystallization, that is, without breaking Al-O or Si-O bonds. High Ti contents in young muscovites and biotites also indicate that the octahedral (and tetrahedral) sites remained undisturbed during rejuvenation. (iv) “Isotopic reversals” in the order of O 18 enrichment between K-feldspar and albite exist. Arguments for equilibrium during Permian time are meagre because of Alpine overprinting effects. Texturally old muscovites show high temperatures and Permian Rb-Sr ages in concordancy with Rb-Sr whole rock ages. For the tectonically least affected samples, excellent concordance between quartz-muscovite and quartz-biotite “Permian temperatures” implies oxygen isotope equilibrium in Permian time which was undisturbed during Alpine metamorphism. Arguments for equilibrium during the mid-Tertiary metamorphism are as follows: (i) Mid-Tertiary Rb-Sr mineral isochrons of up to six minerals exist, (ii) Oxygen isotope temperatures of coexisting Alpine phengites and biotites are concordant. The major factor for the adjustment of the Permian assemblages to Alpine conditions was the degree of Alpine tectonic overprinting rather than the maximum temperatures reached during the mid-Tertiary Alpine metamorphism. The lack of exchange with externally introduced fluid phases in the samples least affected by tectonism indicates that the Monte Rosa Granite “stewed in its own juices”. This seems to be the major cause for the persistence of Permian ages and corresponding temperatures.

Contributions to Mineralogy and Petrology↗
USGS1976

Hydrogen and oxygen isotope exchange reactions between clay minerals and water

The extent of hydrogen and oxygen isotope exchange between clay minerals and water has been measured in the temperature range 100–350° for bomb runs of up to almost 2 years. Hydrogen isotope exchange between water and the clays was demonstrable at 100°. Exchange rates were 3–5 times greater for montmorillonite than for kaolinite or illite and this is attributed to the presence of interlayer water in the montmorillonite structure. Negligible oxygen isotope exchange occurred at these low temperatures. The great disparity in D and O 18 exchange rates observed in every experiment demonstrates that hydrogen isotope exchange occurred by a mechanism of proton exchange independent of the slower process of O 18 exchange. At 350° kaolinite reacted to form pyrophyllite and diaspore. This was accompanied by essentially complete D exchange but minor O 18 exchange and implies that intact structural units in the pyrophyllite were inherited from the kaolinite precursor.

Geochimica et Cosmochimica Acta↗
USGS1975

Arctic palaeosalinities during late Cainozoic time

DURING the late Cainozoic, alternations between interglacial and glacial conditions, manifested by waning and waxing of continental ice sheets coincided with the rise and fall of seawater temperatures. Our palaeontological and oxygen isotope data indicate that although the major oceans and low latititude seas underwent large temperature variations, ∼ 5–10 °C, Arctic water temperatures remained near freezing point for at least the past 3 Myr, the time interval represented by the longest studied cores. We have determined palaeotemperatures from the ratio of left to right coiling Globigerina pachyderma 1–3 and calculated palaeosalinities using the oxygen isotope palaeotemperature expression of Epstein et al. 4 .

Nature↗
USGS1973

Stable isotope and chemical relations during mineralization in the Bodie mining district, Mono County, California

Stable isotope and chemical relations have been determined in a typical epithermal Au-Ag deposit located in the Bodie mining district of California. Analyses were made of altered host rocks, vein minerals, alteration clays, fluid inclusions, modern spring waters, and unaltered rocks of the area.The results indicate that a hydrothermal convection system was set up by the interaction of a cooling shallow intrusion and local meteoric water. The water traveled to depth where it picked up ore constituents and SiO 2 , K, and Rb, without significant shifts in the stable isotope ratios of the water. The altered rocks have equilibrated to various degrees with an ore fluid of constant K/Rb, O 18 /O 16 and D/H ratios. Deposition of ore took place over the approximate temperature range 215 degrees -245 degrees . From C 13 /C 12 ratios of minor calcite, a volcanic source of CO 2 is postulated. The chemical and isotope composition of the ore fluid is strikingly similar to that of modern spring waters in the area.All ore deposition at Bodie took place from essentially isotopically unaltered ground water with delta O 18 = -13ppm and delta D = -98ppm.

California↗
USGS1973

Silica-carbonate alteration of serpentine: Wall rock alteration in mercury deposits of the California Coast Ranges

Chemical, isotopic, and thermodynamic properties have been measured of CO 2 -rich ground waters in the central California Coast Ranges. The acidic CO 2 -rich waters react with serpentine to form silica-carbonate rock, the host rock of many mercury deposits in the Coast Range of California. In part the waters are of a metamorphic origin and in part the waters are locally derived meteoric waters. The CO 2 is entirely derived from metamorphic reactions at depth. Depending on the relative importance of several reactions, the relative abundances of silica and carbonate minerals vary in the silica-carbonate rock. If the CO 2 -rich fluids react directly with peridotite or dunite, massive magnesite deposits may form. © 1973 Society of Economic Geologists, Inc.

California↗
USGS1973

18O 16O ratios in cherts associated with the saline lake deposits of East Africa

The cherts formed from sodium silicate precursors in East African saline, alkaline lakes have δ 18 O values ranging from 31.1 to 44.1. The δ 18 O values correlate in general with lake salinities as inferred from geologic evidence, indicating that most chert was formed from its precursor in contact with lake water trapped at the time of deposition. A few of the analyzed cherts probably formed in contact with dilute meteoric water. From the widely varying δ 18 O values we conclude that precursors were transformed to chert in fluids of widely varying salinity and a Na + /a H + ratio.

Earth and Planetary Science Letters↗
USGS1972

Metamorphic assemblages and the direction of flow of metamorphic fluids in four instances of serpentinization

Fluids related to Serpentinization are of at least three types. The first reported (Barnes and O'Neil, 1969) is a fluid of local meteoric origin, the chemical and thermodynamic properties of which are entirely controlled by olivine, orthopyroxene, brucite, and serpentine reactions. It is a Ca +2 -OH −1 type and is shown experimentally to be capable of reacting with albite to yield calcium hydroxy silicates. Rodingites may form where the Ca +2 -OH −1 type waters flow across the ultramafic contact and react with siliceous country rock. The second type of fluid has its chemical composition largely controlled before it enters the ultramafic rocks, but reactions within the ultramafic rocks fix the thermodynamic properties by reactions of orthopyroxene, olivine, calcite, brucite, and serpentine. The precipitation of brucite from this fluid clearly shows that fluid flow allows reaction products to be deposited at a distance from the point of solution. Thus, textural evidence for volume relations during Serpentinization may not be valid. The third type of fluid has its chemical properties fixed in part before the reactions with ultramafic rocks, in part by the reactions of orthopyroxene, olivine, and serpentine and in part by reactions with siliceous country rock at the contact. The reactions of the ultramafic rock and country rock with the fluid must be contemporaneous and require flow to be along the contact. This third type of fluid is grossly supersaturated with talc and tremolite, both found along the contact. The occurrence of magadiite, kenyaite, mountainite, and rhodesite along the contact is probably due to a late stage low-temperature reaction of fluids of the same thermodynamic properties as those that formed the talc and tremolite at higher temperatures. Oxygen isotope analyses of some of these minerals supports this conclusion. Rodingites form from Ca +2 -rich fluids flowing across the contact; talc and tremolite form from silica-rich fluids flowing along the contact. Isotopic analyses of the fluids indicate varied origins including unaltered local meteoric water and connate water. Complexion Spring water may be a sample of only slightly altered Jurassic or Cretaceous sea water.

Contributions to Mineralogy and Petrology↗
USGS1971

C13 and O18 compositions in some fresh-water carbonates associated with ultramafic rocks and serpentinites: Western United States

All carbonates associated with the ultramafic rocks and serpentinites of the western United States are shown by their stable isotope ratios to be of near-surface, low-temperature origin. These include vein materials that have been previously classified as hydrothermal. New laboratory and natural data were obtained on the equilibrium isotope relations between hydromagnesite and water. The origins of travertines in the ultramafic area are easily distinguished on the basis of their stable isotope ratios. The extremely heavy isotope ratios of nesquehonites suggest an intricate evaporating-film mechanism of formation.

Geochimica et Cosmochimica Acta↗
USGS1971

Calcium-magnesium carbonate solid solutions from Holocene conglomerate cements and travertines in the Coast Range of California

Two calcium-magnesium carbonate solid solutions form Holocene travertines and conglomerate cements in fresh water stream channels of the Coast Range of California. Calcite does not yield the {015} diffraction maximum. The {006} diffraction maximum is lacking over most of the range of composition of calcite. Calcite has compositions from CaCO 3 to Ca 0.5 Mg 0.5 CO 3 . Dolomite yields both the {006} and {015} diffraction maxima over its entire composition range, Ca 0.6 Mg 0.4 CO 3 to Ca 0.5 Mg 0.5 CO 3 . The Ca-Mg carbonates form in isotopic equilibrium and thermodynamic disequilibrium from dispersion of Ca 2+ -rich water into CO 3 2− -rich water within the alluvium. The stable isotope data suggest that all the Mg-rich carbonates are primary precipitates and not a result of Mg-substitution in precursor CaCO 3 . There is a correlation between δC 13 and Mg content of the carbonates which predicts a 5%. fractionation of C 13 between dolomite and calcite at sedimentary temperatures. C 14 is incorporated in Ca-Mg carbonates forming from C 13 -poor meteoric waters and C 13 -rich waters from Cretaceous sediments. C 14 ages of the Ca-Mg carbonates are apparent, and cannot be corrected to absolute values. Solution rates of calcite decrease with increasing MgCO 3 content; dolomite dissolves slower than any calcite.

California↗
USGS1971

A Cuban tektite

A large tektite from Cuba is classified with other North American tektites on the basis of its age. The major-element chemistry, oxygen isotopic composition, refractive index and density of the Cuban tektite are within the ranges exhibited by bediasites.

Geochimica et Cosmochimica Acta↗