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Geology topics

J. R. Clark

Publications and source records attributed to J. R. Clark.

At least 19 recordsLinked to original sources
USGS1986

Electrothermal atomisation atomic absorption conditions and matrix modifications for determining antimony, arsenic, bismuth, cadmium, gallium, gold, indium, lead, molybdenum, palladium, platinum, selenium, silver, tellurium, thallium and tin following back-extraction of organic aminohalide extracts

A multi-element organic-extraction and back-extraction procedure, that had been developed previously to eliminate matrix interferences in the determination of a large number of trace elements in complex materials such as geological samples, produced organic and aqueous solutions that were complex. Electrothermal atomisation atomic absorption conditions and matrix modifications have been developed for 13 of the extracted elements (Ag, As, Au, Bi, Cd, Ga, In, Pb, Sb, Se, Sn, Te and Tl) that enhance sensitivity, alleviate problems resulting from the complex solutions and produce acceptable precision. Platinum, Pd and Mo can be determined without matrix modification directly on the original unstripped extracts.

Journal of Analytical Atomic Spectrometry↗
USGS1985

Mineral resource potential map of the Fossil Ridge Wilderness Study Area, Gunnison County, Colorado

Parts of the Fossil Ridge Wilderness Study Area have a high resource potential for gold and silver in small deposits, uranium in medium-size deposits, and high-calcium limestone in large deposits. Parts have a moderate to high potential for uranium, thorium, and light rare-earth elements in small- to medium-size deposits, a moderate potential for copper, lead, and zinc in small deposits, a low potential for molybdenum in small deposits, and an unknown potential for molybdenum in deposits of unknown size. Parts of the area have a low potential for cobalt, chromium, tungsten, beryllium, boron, and tin in small deposits. And, depending on the extraction of precious metals, parts of the area could have a low potential for arsenic in small deposits. Tungsten, rare-earth elements, and tin could not be considered resources except for coexisting base metals, thorium, and uranium. Areas that immediately adjoin the Fossil Ridge Wilderness Study Area have a high potential for molybdenum in large deposits, lead in medium-size deposits, and zinc -in small- to medium-size deposits. Depending on the extraction of base metals, parts of the adjoining areas could have a low resource potential for bismuth and cadmium as byproducts in medium-size deposits.

Colorado↗
USGS1977

A crystal-chemical classification of borate structures with emphasis on hydrated borates

The rules governing formation of hydrated borate polyanions that were proposed by C.L. Christ in 1960 are critically reviewed and new rules added on the basis of recent crystal structure determinations. Principles and classifications previously published by others are also critically reviewed briefly. The fundamental building blocks from which borate polyanions can be constructed are defined on the basis of the number n of boron atoms, and the fully hydrated polyanions are illustrated. Known structures are grouped accordingly, and a shorthand notation using n and symbols ?? = triangle, T = tetrahedron is introduced so that the polyanions can be easily characterized. For example, 3:??+2T describes [B3O3(OH)5]2-. Correct structural formulas are assigned borates with known structures whereas borates of unknown structure are grouped separately. ?? 1977 Springer-Verlag.

Physics and Chemistry of Minerals↗
USGS1972

Atomic displacements in ferroelectric trigonal and orthorhombic boracite structures

New crystal-structure refinements of Pca 2 1 boracite, Mg 3 ClB 7 O 13 , and R ϵ c ericaite, Fe 2.4 Mg 0.6 ClB 7 O 13 , show that some boron and oxygen atoms are involved in the ‘ferro’ transitions as well as the metal and halogen atoms. The atomic displacements associated with the polarity changes are as large as 0.6Å.

Solid State Communications↗
USGS1970

Lunar clinopyroxenes: Chemical composition, structural state, and texture

Single-crystal x-ray diffraction, microprobe, optical and electron optical examinations of clinopyroxenes from Apollo 11 lunar samples 10003, 10047, 10050, and 10084 show that generally the crystals are composed of (001) augite-pigeonite intergrowths in varying ratios. Transmission electron micrographs reveal abundant exsolution lamellae, many only 60 Å thick. In addition to the phase inhomogeneities, primary chemical inhomogeneities are clearly demonstrated. There are reciprocal relationships between calcium and iron and between Ti 4+ + 2Al and R 2+ + 2Si. Our evidence suggests that a chemically inhomogeneous subcalcic C 2/ c augite was the only primary pyroxene from which pigeonite later exsolved.

Science↗
USGS1970

Crystallography of some lunar plagioclases

Crystals of calcic bytownite from type B rocks have space group I1 with c ≈ 14 angstroms. Bytownite crystals from type A rocks are more sodic and have space group C1, c ≈ 7 angstroms. Cell parameters of eight bulk feldspar separates from crystalline rocks indicate that the range of angle gamma is about 23 times the standard error of measurement, and its value might be useful for estimation of composition. Cell parameters of seven ilmenites are close to those of pure FeTiO 3 .

Science↗
USGS1968

Bonding in eight ordered clinopyroxenes isostructural with diopside

Bond distances and angles in isostructural, ordered clinopyroxenes are compared for eight compositions, based on five new and three published crystal-structure refinements from X-ray diffraction data. Unit-cell parameters and configuration of the silicate chains are directly correlated with cation composition and distribution in the M2 and M1 sites.

Contributions to Mineralogy and Petrology↗
USGS1966

Eclogitic pyroxenes, ordered with P2 symmetry

X-ray diffraction crystal-structure analysis of omphacite from eclogite, Tiburon Peninsula, Marin County, California, shows that this clinopyroxene has P 2 symmetry with a nearly ordered distribution of the multiple cation content defined by its approximate formula: (Na 0.5 Ca 0.5 ) (Mg 0.4 Fe 2 + 0.1 Al 0.4 Fe 3 + 0.1 )Si 2 O 6 . Na+ and Ca 2+ tend to assume alternate locations in the structure, and (Mg,Fe 2+ ) octahedra alternate with Al 3+ or (Al,F 3+ ) octahedra in chains along c .

California↗