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J. L. Bischoff

Publications and source records attributed to J. L. Bischoff.

At least 55 records · Page 3Linked to original sources

Uranium-series dating of the Mousterian occupation at Abric Romani, Spain

The precise evolutionary position of the Neanderthal people continues to be a major uncertainty in human evolution. Their origin and their relationship to anatomically modern people are unclear and are clouded by poor chronology. Lithic artefacts of the Mousterian type, found throughout Europe and the Mediterranean Basin, are believed to be the tool kit of the Neanderthals, but dates within Mousterian-bearing deposits are extremely rare. We report here on 20 high-quality uranium-series dates from Mousterian beds at Abric Romani, a rock shelter near Barcelona, Spain. The dates range from 39 to 60 kyr before present ( BP ) in an orderly stratigraphic succession and provide precise chronological control on an important Mousterian archaeological site.

Nature↗

Phase relations and adiabats in boiling seafloor geothermal systems

Observations of large salinity variations and vent temperatures in the range of 380–400°C suggest that boiling or two-phase separation may be occurring in some seafloor geothermal systems. Consideration of flow rates and the relatively small differences in density between vapors and liquids at the supercritical pressures at depth in these systems suggests that boiling is occurring under closed-system conditions. Salinity and temperature of boiling vents can be used to estimate the pressure-temperature point in the subsurface at which liquid seawater first reached the two-phase boundary. Data are reviewed to construct phase diagrams of coexisting brines and vapors in the two-phase region at pressures corresponding to those of the seafloor geothermal systems. A method is developed for calculating the enthalpy and entropy of the coexisting mixtures, and results are used to construct adiabats from the seafloor to the P-T two-phase boundary. Results for seafloor vents discharging at 2300 m below sea level indicate that a 385°C vent is composed of a brine (7% NaCl equivalent) in equilibrium with a vapor (0.1% NaCl). Brine constitutes 45% by weight of the mixture, and the fluid first boiled at approximately 1 km below the seafloor at 415°C, 330 bar. A 400°C vent is primarily vapor (88 wt.%, 0.044% NaCl) with a small amount of brine (26% NaCl) and first boiled at 2.9 km below the seafloor at 500°C, 520 bar. These results show that adiabatic decompression in the two-phase region results in dramatic cooling of the fluid mixture when there is a large fraction of vapor.

Earth and Planetary Science Letters↗

Oxidation state of marine manganese nodules

Analyses of the bulk oxidation state of marine manganese nodules indicates that more than 98% of the Mn in deep ocean nodules is present as Mn(IV). The samples were collected from three quite different areas: the hemipelagic environment of the Guatemala Basin, the pelagic area of the North Pacific, and seamounts in the central Pacific. Results of the study suggest that todorokite in marine nodules is fully oxidized and has the following stoichiometry: (K, Na, Ca, Ba) .33 (Mg, Cu, Ni) .76 Mn 5 O 22 (H 2 O) 3.2 .

Geochimica et Cosmochimica Acta↗

Holocene age of the Yuha burial: Direct radiocarbon determinations by accelerator mass spectrometry

The view that human populations may not have arrived in the Western Hemisphere before about 12,000 radiocarbon yr BP1,2 has been challenged by claims of much greater antiquity for a small number of archaeological sites and human skeleton samples. One such site is the Homo sapiens sapiens cairn burial excavated in 1971 from the Yuha desert, Imperial County, California3-5. Radiocarbon analysis of caliche coating one of the bones of the skeleton yielded a radiocarbon age of 21,500??1,000 yr BP4, while radiocarbon and uranium series analyses of caliche coating a cairn boulder yielded ages of 22,125??400 and 19,000??3,000 yr BP, respectively5. The late Pleistocene age assignment to the Yuha burial has been challenged by comparing the cultural context of the burial with other cairn burials in the same region6, on the basis of the site's geomorphological context and from radiocarbon analyses of soil caliches. 7,8 In rebuttal, arguments in defence of the original age assignment have been presented9,10 as well as an amino acid racemization analysis on the Yuha skeleton indicating an age of 23,600??2,600 yr BP11. The tandem accelerator mass spectrometer at the University of Arizona has now been used to measure the ratio of 14C/13C in several organic and inorganic fractions of post-cranial bone from the Yuha H. sapiens sapiens skeleton. Isotope ratios from six chemical fractions all yielded radiocarbon ages for the skeleton of less than 4,000 yr BP. These results indicate that the Yuha skeleton is of Holocene age, in agreement with the cultural context of the burial, and in disagreement with the previously assigned Pleistocene age of 19,000-23,000 yr. ?? 1984 Nature Publishing Group.

Nature↗

Hydrothermal alteration of graywacke and basalt by 4 m NaCl

Separate experiments at 350 degrees C and 500 bars at a rock/fluid ratio of 1/10. Illite, dolomite, and quartz amounting to 67 percent of the original graywacke, were converted to albite and smectite. The rock gained Na and released Ca, K, heavy metals, and CO 2 to solution. In sharp contrast, the reaction of 4 m NaCl with basalt produced only minor alteration. Albitization of graywacke produces H (super +) whereas albitization of basalt apparently consumes H (super +) . All experiments to date that have reacted basalt with sea water, natural brine, and fully saturated NaCl over a variety of conditions have been unsuccessful in producing a spilite alteration assemblage.

Economic Geology↗

The aluminosilicate fraction of North Pacific manganese nodules

Nine nodules collected from throughout the deep North Pacific were analyzed for their mineralogy and major-element composition before and after leaching with Chester-Hughes solution. Data indicate that the mineral phillipsite accounts for the major part (> 75%) of the aluminosilicate fraction of all nodules. It is suggested that formation of phillipsite takes place on growing nodule surfaces coupled with the oxidation of absorbed manganous ion. All the nodules could be described as ternary mixtures of amorphous iron fraction (Fe-Ti-P), manganese oxide fraction (Mn-Mg Cu-Ni), and phillipsite fraction (Al-Si-K-Na), these fractions accounting for 96% of the variability of the chemical composition.

Geochimica et Cosmochimica Acta↗

Experimental seawater-basalt interaction at 300°C, 500 bars, chemical exchange, secondary mineral formation and implications for the transport of heavy metals

Seawater and NaCl solutions were reacted with basalt (basalt glass and diabase) for several months at 300&deg;C, 500 bars and a water/rock ratio of 10. During reaction, seawater was significantly modified, increasing in Ca, H 2 S, CO 2 . SiO 2 , K. Fe, Mn. Ba, Al and H + , and decreasing in Mg and SO 4 . Basalt glass was completely replaced by smectite, wairakite, anhydrite and hematite, and diabase was partially replaced by mixed layered smectite-chlorite, anhydrite and magnetite (?). Diabase was altered more slowly than basalt glass and the corresponding changes in seawater chemistry were less pronounced. Basalt glass reacted with a 0.45 m NaCl solution resulted in the formation of smectite, albite. truscottite and wairakite. Solutions from this experiment were characterized by a relatively high pH and dominated by Ca for Na exchange reactions. At no point in this experiment were heavy metals solubilized, in contrast to the seawater experiments. This behavior illustrates the fundamental importance of seawater chemistry to heavy-metal solubility; that is, the removal of Mg from seawater generates acidity which maintains heavy metals in solution. Apparently seawater chlorinity is not capable of enhancing heavy-metal solubility by chloride complexing. Seafloor heavy-metal deposits can result from the following: Seawater-basalt interaction at moderate temperature (&sim;-300&deg;C and high effective water/rock ratios; or at relatively high temperatures (&sim;-400&deg;C) and low (e.g.< 10) water/rock ratios.

Geochimica et Cosmochimica Acta↗

Uranium series dating of human skeletal remains from the Del Mar and Sunnyvale sites, California

Uranium series analyses of human bone samples from the Del Mar and Sunnyvale sites indicate ages of 11,000 and 8,300 years, respectively. The dates are supported by internal concordancy between thorium-230 and protactinium-231 decay systems. These ages are significantly younger than the estimates of 48,000 and 70,000 years based on amino acid racemization, and indicate that the individuals could derive from the population waves that came across the Bering Strait during the last sea-level low.

California↗

A high-temperature hydrothermal deposit on the seabed at a Gulf of California spreading center ( Guaymas Basin).

A submersible dive on a turbidite-covered spreading axis in Guaymas Basin photographed and sampled extensive terraces and ledges of talc. The rock contains siliceous microfossils, smectite, and euhedral pyrrhotite as well as rather pure iron-rich talc. S and O isotopes indicate precipitation around a hydrothermal vent, at about 2800C. - Authors

Earth and Planetary Science Letters↗

Geothermal system at 21°N, East Pacific Rise: physical limits on geothermal fluid and role of adiabatic expansion

Pressure-volume-temperature relations for water at the depth of the magma chamber at 21 &deg; N on the East Pacific Rise suggest that the maximum subsurface temperature of the geothermal fluid is about 420 &deg; C. Both the chemistry of the discharging fluid and thermal balance considerations indicate that the effective water/rock ratios in the geothermal system are between 7 and 16. Such low ratios preclude effective metal transport at temperatures below 350 &deg; C, but metal solubilization at 400 &deg; C and above is effective even at such low ratios. It is proposed that the 420 &deg; C fluid ascends essentially adiabatically and in the process expands, cools, and precipitates metal sulfides within the upper few hundred meters of the sea floor and on the sea floor itself.

Science↗

Temperature calibration of amino acid racemization: Age implications for the Yuha skeleton

D/L of aspartic acid ranged from 0.52 to 0.56 for femur samples of the Yuha skeleton. Subsurface temperature measurements made at the burial site indicate average annual temperature is 18°C and diagenetic temperature is 21.6°C. These data and a relation derived for the dependence of the aspartic acid rate constant on diagenetic temperature indicate an age of 23,600. The result is consistent with 14 C and 230 Th dating of calcrete found coating the bones.

Earth and Planetary Science Letters↗

Low temperature basalt alteration by sea water: an experimental study at 70°C and 150°C

Basaltic glass and diabase were reacted with seawater at 70&deg;C at 1 bar and 150&deg;C at 500 bars to determine fluid composition and alteration mineralogy. All experiments were performed at a water/ rock mass ratio of 10. The changes in seawater chemistry depended on temperature and crystallinity of the basalt. The experiment at 70&deg;C produced a slight but continuous loss of Mg, Na and K and enrichment of Ca and SiO 2 in the seawater while pH decreased slowly. At 150&deg;C, in contrast, Mg and SO 4 were quickly and quantitatively removed while Ca, SiO 2 , Na, K, Fe, Mn and Ba were added to the seawater. pH rose to values between 5.5 and 6.5 after an initial drop to lower values. Basalt glass reacted more extensively at 150&deg;C than diabase. Smectite was the major alteration product (iron-rich saponite) at 150&deg;C for both the glass and diabase experiments. Smectite from the diabase experiment was well crystallized while that from the glass experiment was poorly crystallized. The smectites are similar to smectites found in altered oceanic ophiolitic basalts.

Geochimica et Cosmochimica Acta↗

Recent metalliferous sediment in the North Pacific manganese nodule area

Quaternary sediments cored in the northeast Pacific nodule area (DOMES site C, 14°N, 126°W) contain a significant amount of hydrothermal metalliferous mud. Water content, color, mineralogy, and chemical composition are analogous to metalliferous sediments of the subequatorial East Pacific Rise. Correction for contribution of pelagic clay indicates the metalliferous fraction to be about 40% of the sediment. SiO 2 and Mg are major components in the corrected composition, as they are for other metalliferous sediments similarly corrected from a variety of East Pacific Rise and DSDP metalliferous sediments. A correlation between Mg and SiO 2 for these corrected sediments could indicate a hydrothermal origin for a significant portion of the SiO 2 . Results from DSDP in the nodule area suggest that metalliferous globules are a ubiquitous minor component of the Clipperton Oceanic Formation, which underlies much of the Pacific ferromanganese nodule belt. This indicates that deposition of hydrothermal precipitates is not confined to spreading centers.

Earth and Planetary Science Letters↗

Hydrothermal transport of heavy metals by seawater: The role of seawater/basalt ratio

Seawater reacted with basaltic glass at 260°C and 500 bars under water-dominated conditions (50 : 1 water/rock ratio) efficiently leached and maintained heavy metals in solution. Cu, Zn, and Ba are transferred in significant proportions to the aqueous phase, while Fe and Mn attain concentrations of 45 and 20 ppm respectively as the basalt is completely made over to magnesian smectite. High metal solubility is a function of acidity maintained by large excess of dissolved Mg and equilibria with the alteration phase. Metal concentrations and relative proportions are consistent within limits required for metal-rich fluid which produced East Pacific Rise metalliferous sediments. Experiments mixing metal-bearing altered seawater and normal seawater were carried out as a qualitative indicator of sea-floor precipitation processes. Bulk composition of the precipitates are strongly influenced by mixing ratio. Precipitates range from silica-magnesium rich under low dilution by seawater to essentially pure ferric hydroxide under conditions of high dilution.

Earth and Planetary Science Letters↗

Ore transport and deposition in the Red Sea geothermal system: a geochemical model

Thermodynamic calculation of distribution of dissolved aqueous species in the Red Sea geothermal brine provides a model of ore transport and deposition in good agreement with observed accumulations of base metal sulfides, anhydrite, and barite. The Red Sea brine is recirculated seawater that acquires high salinity by low-temperature interaction with Miocene evaporites and is subsequently heated to temperatures in excess of 200°C by interaction with recent rift zone intrusive rocks. At temperatures up to 250°C, NaSO − 4 and MgSO 0 4 are the dominant sulfur-bearing species. H 2 S forms by inorganic sulfate reduction at the higher temperatures but is maintained at a uniform concentration of about 2 ppm by the strength of the sulfate complexes. Chloride complexes solubilize metals at the higher temperatures, and thus sulfide and metals are carried together into the Atlantis II Deep. Below 150°C, the brine becomes supersaturated with respect to chalcopyrite, sphalerite, galena, and iron monosulfide due to chloride-complex dissociation. Sulfide precipitation rates, based on the rate of brine influx, are in good agreement with measured sedimentation rates. Anhydrite precipitates as crystalline fissure infillings from high-temperature inflowing brine. Barite forms from partial oxidation of sulfides at the interface between the lower hot brine and the transitional brine layer.

Geochimica et Cosmochimica Acta↗

Antiquity of man in America indicated by radiometric dates on the Yuha burial site

MUCH evidence suggests that man was present in the Western Hemisphere before 12,000 yr ago, but the case has remained less than conclusive 1 . In some situations, the geological age of the site is reasonably well established but the association or nature of the artefacts is questionable 2,3 . In other cases, museum specimens of human bones dated by radiocarbon analysis of collagen lack desirable information concerning site location, geology, and stratigraphy even though the accuracy of their absolute ages seems valid 4–6 . We report here the results of radiometric dates of the Yuha burial site from Imperial County, California, for which the geology and stratigraphy have been documented and reported in detail.

Nature↗