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J. Castaing

Publications and source records attributed to J. Castaing.

2 recordsLinked to original sources

Prismatic slip of A12O3 single crystals below 1000°C in compression under hydrostatic pressure

Alumina single crystals were compressed perpendicular to the [0001] axis at a constant strain rate between 20° and 950°C. At r>200°C, failure was suppressed by_hydrostatic pressures of 500 to 1500 MPa. Prismatic slip {1120}〈1100〉 was deduced from optical observations of the lateral surfaces and from stress‐optical features in thin sections cut from the specimens. The critical resolved shear stress (CRSS) decreased rapidly with increasing temperature, from a maximum of ∼3000 MPa at 200°C (strain rate 2±10‐ −5 s −1 ). A simple linear law can be fitted with the logarithm of the CRSS as a function of temperature, up to 1800°C. The rate‐controlling mechanism for dislocation glide is likely to be either the Peierls barrier or barriers due to dissociation out of the glide plane.

Journal of the American Ceramic Society

Hydrogen defects in α-Al2O3 and water weakening of sapphire and alumina ceramics between 600°C and 1000°C: II. Mechanical properties

Hydrogen impurities in alumina have been introduced by hydrothermal annealing (see part I). In this paper, we report on reductions in the flow strength of α -Al 2 O 3 single crystals and polycrystals associated with hydrogen incorporation. Prior to deformation, α -Al 2 O 3 single crystal and ceramic specimens were annealed in the presence of supercritical water at 850° or 900°C, under 1500 MPa pressure. Sapphire and alumina ceramics were plastically deformed between 600° and 1000°C under 1500 MPa pressure, by the addition of a uniaxial stress. Flow stresses are reduced by a factor of two, due to the presence of water, for sapphire and large grain (30–50 μm) polycrystals, as a result of enhanced dislocation mobility. Flow stresses of fine-grained (3–5 μm) polycrystals are reduced by water by a factor of six. This large reduction in strength is attributed to a change in mechanism from dislocation glide under dry conditions to grain boundary sliding under hydrothermal conditions.

Acta Materialia