Geology topics

J. B. Shanley

Publications and source records attributed to J. B. Shanley.

36 records · Page 2Linked to original sources

USGS2004

Tracing sources of nitrate in snowmelt runoff using a high-resolution isotopic technique

The denitrifier method to determine the dual isotopic composition (??15N and ??18O) of nitrate is well suited for studies of nitrogen contributions to streams during runoff events. This method requires only 70 nmol of NO3- and enables high throughput of samples. We studied nitrate sources to a headwater stream during snowmelt by generating a high-temporal resolution dataset at the Sleepers River Research Watershed in Vermont, USA. In the earliest phase of runoff, stream NO3- concentrations were highest and stream discharge, NO3- concentrations, and ??18O of NO 3- generally tracked one another during diurnal melting. The isotopic composition of stream NO3- varied in-between atmospheric and groundwater NO 3- end members indicating a direct contribution of atmospherically-derived NO3- from the snow pack to the stream. During the middle to late phases of snowmelt, the source shifted toward soil NO3- entering the stream via shallow subsurface flow paths. Copyright 2004 by the American Geophysical Union.

Geophysical Research Letters↗

USGS2004

A biogeochemical comparison of two well-buffered catchments with contrasting histories of acid deposition

Much of the biogeochemical cycling research in catchments in the past 25 years has been driven by acid deposition research funding. This research has focused on vulnerable base-poor systems; catchments on alkaline lithologies have received little attention. In regions of high acid loadings, however, even well-buffered catchments are susceptible to forest decline and episodes of low alkalinity in streamwater. As part of a collaboration between the Czech and U.S. Geological Surveys, we compared biogeochemical patterns in two well-studied, well-buffered catchments: Pluhuv Bor in the western Czech Republic, which has received high loading of atmospheric acidity, and Sleepers River Research Watershed in Vermont, U.S.A., where acid loading has been considerably less. Despite differences in lithology, wetness, forest type, and glacial history, the catchments displayed similar patterns of solute concentrations and flow. At both catchments, base cation and alkalinity diluted with increasing flow, whereas nitrate and dissolved organic carbon increased with increasing flow. Sulfate diluted with increasing flow at Sleepers River, while at Pluhuv Bor the sulfate-flow relation shifted from positive to negative as atmospheric sulfur (S) loadings decreased and soil S pools were depleted during the 1990s. At high flow, alkalinity decreased to near 100 μeq L -1 at Pluhuv Bor compared to 400 μeq L -1 at Sleepers River. Despite the large amounts of S flushed from Pluhuv Bor soils, these alkalinity declines were caused solely by dilution, which was greater at Pluhuv Bor relative to Sleepers River due to greater contributions from shallow flow paths at high flow. Although the historical high S loading at Pluhuv Bor has caused soil acidification and possible forest damage, it has had little effect on the acid/base status of streamwater in this well-buffered catchment.

Water, Air, and Soil Pollution: Focus↗

USGS2002

Controls on old and new water contributions to stream flow at some nested catchments in Vermont, USA

Factors controlling the partitioning of old and new water contributions to stream flow were investigated for three events in four catchments (three of which were nested) at Sleepers River Research Watershed in Danville, Vermont. In the 1993 snowmelt period, two-component isotopic hydrograph separations showed that new water (meltwater) inputs to the stream ranged widely from 41 to 74%, and increased with catchment size (41 to 11 125 ha) (with one exception) and with open land cover (0-73%). Peak dissolved organic carbon concentrations and relative alkalinity dilution in stream water ranked in the same order among catchments as the new water fractions, suggesting that new water followed shallow flow paths. During the 1994 snowmelt, despite similar timing and magnitude of melt inputs, the new-water contribution to stream flow ranged only from 30 to 36% in the four catchments. We conclude that the uncommonly high and variable new water fractions in streamwater during the 1993 melt were caused by direct runoff of meltwater over frozen ground, which was prevalent in open land areas during the 1993 winter. In a high-intensity summer rainstorm in 1993, new water fractions were smaller relative to the 1993 snowmelt, ranging from 28 to 46%, but they ranked in the identical catchment order. Reconciliation of the contrasting patterns of new-old water partitioning in the three events appears to require an explanation that invokes multiple processes and effects, including: 1 topographically controlled increase in surface-saturated area with increasing catchment size; 2 direct runoff over frozen ground; 3 low infiltration in agriculturally compacted soils; 4 differences in soil transmissivity, which may be more relevant under dry antecedent conditions. These data highlight some of the difficulties faced by catchment hydrologists in formulating a theory of runoff generation at varying basin scales. Copyright ?? 2002 John Wiley and Sons, Ltd.

Hydrological Processes↗

USGS2000

Dissolved organic nitrogen budgets for upland, forested ecosystems in New England

Relatively high deposition of nitrogen (N) in the northeastern United States has caused concern because sites could become N saturated. In the past, mass-balance studies have been used to monitor the N status of sites and to investigate the impact of increased N deposition. Typically, these efforts have focused on dissolved inorganic forms of N (DIN = NH4-N + NO3-N) and have largely ignored dissolved organic nitrogen (DON) due to difficulties in its analysis. Recent advances in the measurement of total dissolved nitrogen (TDN) have facilitated measurement of DON as the residual of TDN - DIN. We calculated DON and DIN budgets using data on precipitation and streamwater chemistry collected from 9 forested watersheds at 4 sites in New England. TDN in precipitation was composed primarily of DIN. Net retention of TDN ranged from 62 to 89% (4.7 to 10 kg ha-1 yr-1) of annual inputs. DON made up the majority of TDN in stream exports, suggesting that inclusion of DON is critical to assessing N dynamics even in areas with large anthropogenic inputs of DIN. Despite the dominance of DON in streamwater, precipitation inputs of DON were approximately equal to outputs. DON concentrations in streamwater did not appear significantly influenced by seasonal biological controls, but did increase with discharge on some watersheds. Streamwater NO3-N was the only fraction of N that exhibited a seasonal pattern, with concentrations increasing during the winter months and peaking during snowmelt runoff. Concentrations of NO3-N varied considerably among watersheds and are related to DOC:DON ratios in streamwater. Annual DIN exports were negatively correlated with streamwater DOC:DON ratios, indicating that these ratios might be a useful index of N status of upland forests.

Biogeochemistry↗

USGS1999

The effect of frozen soil on snowmelt runoff at Sleepers River, Vermont

Soil frost depth has been monitored at the Sleepers River Research Watershed in northeastern Vermont since 1984. Soil frost develops every winter, particularly in open fields, but its depth varies greatly from year to year in inverse relation to snow depth. During the 15 years of record at a benchmark mid-elevation open site, the annual maximum frost depth varied from 70 to 390 mm. We empirically tested the hypothesis that frozen soil prevents infiltration and recharge, thereby causing an increased runoff ratio (streamflow/(rain+snowmelt)) during the snowmelt hydrograph rise and a decreased runoff ratio during snowmelt recession. The hypothesis was not supported at the 111 km 2 W-5 catchment; there was no significant correlation of the runoff ratio with the seasonal maximum frost depth for either the pre-peak or post-peak period. In an analysis of four events, however, the presence of frost promoted a large and somewhat quicker response to rainfall relative to the no-frost condition, although snow cover caused a much greater time-to-peak regardless of frost status. For six years of flow and frost depth measured at the 59 ha agricultural basin W-2, the hypothesis appeared to be supported. The enhancement of runoff due to soil frost is evident on small plots and in extreme events, such as rain on frozen snow-free soil. In the northeastern USA and eastern Canada, the effect is often masked in larger catchments by several confounding factors, including storage of meltwater in the snowpack, variability in snowmelt timing due to elevational and aspect differences, interspersed forested land where frost may be absent, and the timing of soil thawing relative to the runoff peak.

Hydrological Processes↗

USGS1999

A hydrometric and geochemical approach to test the transmissivity feedback hypothesis during snowmelt

To test the transmissivity feedback hypothesis of runoff generation, surface and subsurface waters were monitored and sampled during the 1996 snowmelt at various topographic positions in a 41 ha forested headwater catchment at Sleepers River, Vermont. Two conditions that promote transmissivity feedback existed in the catchment during the melt period. First, saturated hydraulic conductivity increased toward land surface, from a geometric mean of 3.6 mm h-1 in glacial till to 25.6 mm h-1 in deep soil to 54.0 mm h-1 in shallow soil. Second, groundwater levels rose to within 0.3 m of land surface at all riparian sites and most hillslope sites at peak melt. The importance of transmissivity feedback to streamflow generation was tested at the catchment scale by examination of physical and chemical patterns of groundwater in near-stream (discharge) and hillslope (recharge/lateral flow) zones, and within a geomorphic hollow (convergent flow). The presence of transmissivity feedback was supported by the abrupt increase in streamflow as the water table rose into the surficial, transmissive zone; a flattening of the groundwater level vs. streamflow curve occurred at most sites. This relation had a clockwise hysteresis (higher groundwater level for given discharge on rising limb than at same discharge on falling limb) at riparian sites, suggesting that the riparian zone was the dominant source area during the rising limb of the melt hydrograph. Hysteresis was counterclockwise at hillslope sites, suggesting that hillslope drainage controlled the snowmelt recession. End member mixing analysis using Ca, Mg, Na, dissolved organic carbon (DOC), and Si showed that stream chemistry could be explained as a two-component mixture of groundwater high in base cations and an O-horizon/overland flow water high in DOC. The dominance of shallow flow paths during events was indicated by the high positive correlation of DOC with streamflow (r2 = 0.82). Despite the occurrence of transmissivity feedback, hillslope till and soil water were ruled out as end members primarily because their distinctive high-Si composition had little or no effect on streamwater composition. Till water from the geomorphic hollow had a chemistry very close to streamwater base flow, and may represent the base flow end member better than the more concentrated riparian groundwater. During snowmelt, streamwater composition shifted as this base flow was diluted - not by shallow groundwater from the hillslope, but rather by a more surficial O-horizon/overland flow water.Surface and subsurface waters were analyzed to test the transmissivity feedback of runoff generation during the 1996 snowmelt in a catchment at Sleepers River, Vermont. The importance of transmissivity feedback to stream flow generation was tested by examination of physical and chemical patterns of groundwater in near-stream and hillslope zones within a geomorphic hollow. End member mixing analysis of Ca, Mg, Na, dissolved organic carbon (DOC), and Si showed that stream chemistry could be explained as a two-component mixture of groundwater high in base cations and an O-horizon/overland flow water high in DOC. The dominance of shallow water paths during the events was indicated by the high positive correlation of DOC with streamflow (r2 = 0.82).

Journal of Hydrology↗

USGS1999

Riparian zone flowpath dynamics during snowmelt in a small headwater catchment

The hydrology of the near-stream riparian zone in upland humid catchments is poorly understood. We examined the spatial and temporal aspects of riparian flowpaths during snowmelt in a headwater catchment within the Sleepers River catchment in northern Vermont. A transect of 15 piezometers was sampled for Ca, Si, DOC, other major cations, and ??18O. Daily piezometric head values reflected variations in the stream hydrograph induced by melt and rainfall. The riparian zone exhibited strong upward discharge gradients. An impeding layer was identified between the till and surficial organic soil. Water solute concentrations increased toward the stream throughout the melt. Ca concentrations increased with depth and DOC concentrations decreased with depth. The concentrations of Ca in all piezometers were lower during active snowmelt than during post-melt low flow. Ca data suggest snowmelt infiltration to depth; however, only upslope piezometers exhibited snowmelt infiltration and consequent low ??18O values, while ??18O values varied less than 0.5% in the deep riparian piezometers throughout the study period. Ca and ??18O values in upslope piezometers during low streamflow were comparable to Ca and ??18O in riparian piezometers during high streamflow. The upland water Ca and ??18O may explain the deep riparian Ca dilution and consistent ??18O composition. The temporal pattern in Ca and ??18O indicate that upland water moves to the stream via a lateral displacement mechanism that is enhanced by the presence of distinct soil/textural layers. Snowmelt thus initiates the flux of pre-melt, low Ca upland water to depth in the riparian zone, but itself does not appear at depth in the riparian zone during spring melt. This is despite the coincident response of upland groundwater and stream discharge.The hydrology of the near-stream riparian zone in upland humid catchments is poorly understood. We examined the spatial and temporal aspects of riparian flowpaths during snowmelt in a headwater catchment within the Sleepers River catchment in northern Vermont. A transect of 15 piezometers was sampled for Ca, Si, DOC, other major cations, and ??18O. Daily piezometric head values reflected variations in the stream hydrograph induced by melt and rainfall. The riparian zone exhibited strong upward discharge gradients. An impeding layer was identified between the till and surficial organic soil. Water solute concentrations increased toward the stream throughout the melt. Ca concentrations increased with depth and DOC concentrations decreased with depth. The concentrations of Ca in all piezometers were lower during active snowmelt than during post-melt low flow. Ca data suggest snowmelt infiltration to depth; however, only upslope piezometers exhibited snowmelt infiltration and consequent low ??18O values, while ??18O values varied less than 0.5 per mil in the deep riparian piezometers throughout the study period. Ca and ??18O values in upslope piezometers during low streamflow were comparable to Ca and ??18O in riparian piezometers during high streamflow. The upland water Ca and ??18O may explain the deep riparian Ca dilution and consistent ??18O composition. The temporal pattern in Ca and ??18O indicate that upland water moves to the stream via a lateral displacement mechanism that is enhanced by the presence of distinct soil/textural layers. Snowmelt thus initiates the flux of pre-melt, low Ca upland water to depth in the riparian zone, but itself does not appear at depth in the riparian zone during spring melt. This is despite the coincident response of upland groundwater and stream discharge.

Journal of Hydrology↗

USGS1998

Factors controlling mercury transport in an upland forested catchment

Total mercury (Hg) deposition and input/output relationships were investigated in an 11-ha deciduous forested catchment in northern Vermont as part of ongoing evaluations of rig cycling and transport in the Lake Champlain basin. Atmospheric Hg deposition (precipitation + modeled vapor phase downward flux) was 425 mg ha-1 during the one-year period March 1994 through February 1995 and 463 mg ha-1 from March 1995 through February 1996. In the same periods, stream export of total Hg was 32 mg ha-1 and 22 mg ha-1, respectively. Thus, there was a net retention of Hg by the catchment of 92% the first year and 95% the second year. In the first year, 16.9 mg ha-1 or about half of the annual stream export, occurred on the single day of peak spring snowmelt in April. In contrast, the maximum daily export in the second year, when peak stream flow was somewhat lower, was 3.5 mg ha-1 during a January thaw. The fate of file Hg retained by this forested catchment is not known. Dissolved (< 0.22 ??m) Hg concentrations in stream water ranged from 0.5-2.6 ng L-1, even when total (unfiltered) concentrations were greater than 10 ng L-1 during high flow events. Total Hg concentrations in stream water were correlated with the total organic fraction of suspended sediment, suggesting the importance of organic material in Hg transport within the catchment. High flow events and transport with organic material may be especially important mechanisms for the movement of Hg through forested ecosystems.

Water, Air, & Soil Pollution↗

USGS1997

Streamwater chemistry and nutrient budgets for forested watersheds in New England: Variability and management implications

Chemistry of precipitation and streamwater and resulting input-output budgets for nutrient ions were determined concurrently for three years on three upland, forested watersheds located within an 80 km radius in central New England. Chemistry of precipitation and inputs of nutrients via wet deposition were similar among the three watersheds and were generally typical of central New England. In contrast, chemistry and nutrient outputs in streamwater varied dramatically between watersheds, with chemistries ranging from acidic to alkaline. Comparisons with data reported for 159 other upland, forested watersheds in central New England show that our study watersheds span the regional range likely to be encountered in stream chemistry. The regional variability stems in part from past natural disturbances such as wildfire, and variations in source of soil parent material. An approach is presented for predicting the important influence of glacial till on stream chemistry, including acid-base relationships, aluminum content, and nutrient outputs. Knowledge of streamwater chemistry and controlling factors can serve as an index of how terrestrial and aquatic ecosystems will respond to forest management activities and atmospheric deposition.

Forest Ecology and Management↗

USGS1995

Factors affecting water quality and net flux of solutes in two stream basins in the Quabbin Reservoir drainage basin, central Massachusetts, 1983-85

The factors that affect stream-water quality were studied at West Branch Swift River (Swift River), and East Branch Fever Brook (Fever Brook), two forested watersheds that drain into the Quabbin Reservoir, central Massachusetts, from December 1983 through August 1985. Spatial and temporal variations of chemistry of precipitation, surface water; and ground water and the linkages between chemical changes and hydrologic processes were used to identify the mechanisms that control stream chemistry. Precipitation chemistry was dominated by hydrogen ion (composite p.H 4.23), sulfate, and nitrate. Inputs of hydrogen and nitrate from pre- cipitation were almost entirely retained in the basins, whereas input of sulfate was approximately balanced by export by streamflow draining the basins. Both streams were poorly buffered, with mean pH near 5.7, mean alkalinity less than 30 microequivalents per liter, and sulfate concen- trations greater than 130 microequivalents per liter. Sodium and chloride, derived primarily from highway deicing salts, were the dominant solutes at Fever Brook. After adjustments for deicing salts, fluxes of base cations during the 21-month study were 2,014 and 1,429 equivalents per hectare in Swift River and Fever Brook, respectively. Base cation fluxes were controlled primarily by weathering of hornblende (Fever Brook) and plagioclase (Swift River). The overall weathering rate was greater in the Swift River Basin because easily weathered gabbro underlies one subbasin which comprises 11.2 percent of the total basin area but contributed about 77 percent of the total alkalinity. Alkalinity export was nearly equal in the two basins, however, because some alkalinity was generated in wetlands in the Fever Brook Basin through bacterial sulfate reduction coupled with organic-carbon oxidation.

Massachusetts↗

USGS1995

Effects of selective forest clearing fertilization, and liming on the hydrology and water quality of a small tributary to the Quabbin Reservoir, central Massachusetts

Effects of selective forest clearing on water yield and water quality were investigated in a 308-hectare basin that drains to Quabbin Reservoir Watershed in central Massachusetts. The experimental basin and a nearby 280-hectare control basin were studied together for comparison. Streamflow was measured continuously and water-quality samples were collected biweekly in both basins from February 1985 through September 1989. During the same period, measurements of precipitation quantity and ground- water levels were made and samples were collected for determination of precipitation and ground-water quality. After an initial monitoring period to establish baseline hydrology and water quality in both basins, an area of red pine and white pine forest in the experimental basin was cleared. From October 1986 until April 1987, 23.8 percent of the total basal area was removed by clearcutting and thinning. Part of the cleared area was converted to rye and other field grasses, and the remainder was allowed to regrow naturally. Fertilizer and lime were applied to part of the cleared area. An additional 8.3 percent of basal area was cleared in fall 1988. Despite differences in bedrock geology, topography, and amount of wetland area, pre- treatment hydrology and chemistry of the two basins were similar. Biogeochemical reactions of the dilute mixture of sulfuric and nitric acids in precipitation with soils and rocks in the basins resulted in moderately buffered calcium-magnesium bicarbonate-type streamwater. During high flows, sulfate concentrations increased and alkalinity decreased. Selective forest clearing resulted in a slight increase in water yield during the year in which the clearing took place, particularly during the spring high-flow period, but flows returned to normal thereafter. Concurrent increases in solute flux were primarily a function of the increased water flux. No major alterations to biogeochemical processes were induced by the forest clearing, nor were any effects from the fertilizer or liming activity observed. The minimal effect observed from the clearing was attributed primarily to the limited area that was cleared, and the location of the cleared area in the headwaters of the basin (away from the riparian zone).

Massachusetts↗

USGS1995

Chemical and isotopic evolution of a layered eastern U.S. snowpack and its relation to stream-water composition

The chemical, isotopic, and morphologic evolution of a layered snowpack was investigated during the winter of 1993-94 at Sleepers River Research Watershed in Danville, Vermont. The snowpack was monitored at two small basins: a forested basin at 525 m elevation, and an agricultural basin at 292 m elevation. At each site, the snowpack morphology was characterized and individual layers were sampled seven times during the season. Nitrate and 8d18O profiles in the snowpack remained relatively stable until peak accumulation in mid-March, except near the snow surface, where rain-on-snow events caused water and nitrate movement down to impeding ice layers. Subsequently, water and nitrate moved more readily through the ripening snowpack. As the snowpack evolved, combined processes of preferential ion elution, isotopic fractionation, and infiltration of isotopically heavy rainfall caused the pack to become depleted in solutes and isotopically enriched. The release of nitrate and isotopically depleted water was reflected in patterns of nitrate concentrations and ??18O of meltwater and stream water. Results supported data from the previous year which suggested that streamflow in the forested basin during snowmelt was dominated by groundwater discharge.

Biogeochemistry of seasonally snow-covered catchme↗

USGS1994

Effects of ion exchange on stream solute fluxes in a basin receiving highway deicing salts

At Fever Brook, a 1260-ha forested basin in central Massachusetts, highway deicing salt application increased the solute flux in streamflow by 120% above background flux (equivalent basis) during a 2-yr period. Attempts to isolate the nonsalt component of stream solute fluxes have commonly subtracted salt contributions based on the net Cl flux (Cl output in streamflow minus Cl input in precipitation). In these studies, any net Na flux in excess of the amount needed to balance the net Cl flux has been attributed to weathering. At Fever Brook, however, the net output of Na was less than the net output of Cl, suggesting a loss of Na within the basin. The Na sink was inferred to be cation exchange of Na for Ca and Mg in the soil. A method was developed to quantify the exchange based on a Na budget, which included an independent estimate of the Na flux from weathering. The amount of exchange was apportioned to Ca and Mg based on their relative concentrations in the stream. The background fluxes of Ca and Mg (i.e., those that would occur in the absence of deicing salts) were calculated by subtracting the amounts from ion exchange plus the much smaller direct contributions in deicing salts from the observed fluxes. Ion exchange and direct salt contributions increased the net output fluxes of Ca and Mg, each by 44% above background. In basins that receive deicing salts, failure to account for cation exchange thus may result in an underestimate of the flux of Na from weathering and overestimates of the fluxes of Ca and Mg from weathering.

Journal of Environmental Quality↗

USGS1994

Effects of storm paths on precipitation chemistry, and variations of within-storm chemistry during selected storms in central Massachusetts, 1986-87

Samples of precipitation from 31 storms were collected from October 1986 through December 1987 at a site near Quabbin Reservoir in central Massachusetts and were analyzed for pH, specific conductance, and concentrations of common chemical constituent. Twenty-four storms followed a conti- nental path west of the Appalachian Mountains. The remaining seven storms followed a coastal path east of the Appalachian Mountains along the Atlantic Coast. Precipitation from the continental storms was more acidic than precipitation from the coastal storms according to a nonparametric statistical com- parison. Because the continental storms had less volume, the loads of hydrogen ions and other common chemical constituents from both groups were not statistically different. The variability of within- storm precipitation chemistry was evaluated for 8 of the 31 storms. Seven of the storms showed evidence of suspended-particulate removal at levels between the cloud layer and the land surface during their early stages. The remaining storm, also the most acidic, showed evidence of suspended- particulate removal within the cloud layer as indicated by a relatively constant pH throughout the storm. Surface-air concentrations of sulfur dioxide and nitrogen dioxide before, during, and after each of the eight storms were compared to within-storm values of pH and precipitation. Seven of the storms were accompanied by decreased atmospheric concen- trations of both sulfur dioxide and nitrogen dioxide in the early stages of the storm. For three of the storms, atmospheric concentrations of sulfur dioxide and nitrogen dioxide were higher during the 24-hour period after the storm than the 24-hour period pre- ceding the storm. Particulates in precipitation samples were analyzed for three storms. Biotite was the predominant mineral in two of the storms. Other minerals detected were garnet, quartz, gypsum, hematite, epidote, ilmenite, eggonite, halite, rutile, and organic ash.

Water-Resources Investigations Report↗

USGS1993

Variations in aqueous sulfate concentrations at Panola Mountain, Georgia

Aqueous sulfate concentrations were measured in incident precipitation, canopy throughfall, stemflow, soil water, groundwater, and streamwater at three locations in a 41 ha forested watershed at Panola Mountain State Park in the Georgia Piedmont. To evaluate the variations in sulfate concentrations, sampling intensity was increased during storms by automated collection of surface water and by incremental subsampling of rainfall, throughfall, and soil solution. Canopy throughfall, stemflow, and runoff from a bedrock outcrop in the watershed headwaters were enriched in sulfate relative to incident precipitation due to washoff of dry deposition that accumulated between storms. Soil waters collected from zero-tension lysimeters at 15 cm and 50 cm below land surface also were enriched in sulfate relative to precipitation, groundwater and streamwater. Sulfate concentrations in groundwater and in streamwater at base flow varied in an annual sinusoidal pattern with winter maxima and summer minima. Stream discharge and groundwater levels varied in a similar annual pattern in phase with the sulfate concentrations. The temporal variability of sulfate concentrations at most groundwater sites was small relative to the spatial variability among groundwater sites. Streamwater sulfate concentrations during base flow were controlled by low-sulfate groundwater discharge. As flow increased, an increasing proportion of shallow, high-sulfate groundwater and soil water contributed to streamflow. The dominant control on stream sulfate concentration shifted from sulfate retention by adsorption in the mineral soil at base flow to mobilization of sulfate from the upper, organic-rich horizons of the soil at high flow.

Journal of Hydrology↗

USGS1992

Sulfate retention and release in soils at Panola Mountain, Georgia

Inorganic sulfate pools, sulfate sorption characteristics, and Fe and Al fractions were determined on soils at Panola Mountain, a 41-ha forested watershed in the Georgia Piedmont. Sulfate sorption properties of these soils fall along a continuum between two end members. The "low-adsorbing' end member comprises shallow soils (0-10 cm), with high water-soluble sulfate (Sw), low phosphate-extractable sulfate (Sp-w), high organic matter, low sulfate retention ability, and high sulfate adsorption reversibility. The "high-adsorbing' end member comprises deeper soils (>10 cm), with higher total native sulfate (mostly as Sp-w), low organic matter, high sulfate retention ability, and low sulfate adsorption reversibility. Sulfate retention was only weakly related to Fe and Al fractions, possibly because of inhibition of adsorption by organic matter. Sulfate concentrations in surface waters reflect the spatial distribution of soil sulfate retention properties. -from Author

Soil Science↗

USGS1989

Field measurements of dry deposition to spruce foliage and petri dishes in the Black Forest, F.R.G.

Dry deposition fluxes of Ca 2+ , Mg 2+ , K + , Mn 2+ , Pb 2+ and SO 2− 4 to spruce foliage and petri dishes were measured in two high-elevation sites ( > 900 m) in the southern Black Forest, F.R.G., during 12 periods (2–7 days, each) from mid-September to mid-November, 1983, In situ extraction of deposited material from small spruce branches allowed repeated use of the same foliar collecting surfaces for a direct comparison of deposition between periods. Fluxes were corrected for leaching of internally cycled constituents using factors determined from serial extraction experiments. The ratio of flux to petri dishes vs foliage ( P F "> PF ) was > 1.0 for Ca 2+ , Pb 2+ and SO 2− 4 , and somewhat < 1.0 but more constant for Mg 2+ . Temporal variations in dry deposition fluxes at an exposed site near the industrialized Rhine Valley correlated with variations in total air particulate concentrations at a nearby air quality station. Deposition rates were comparable in magnitude but different in temporal pattern at a remote site in the Black Forest interior. Fluxes at each site reached a minimum during the period of 4–9 November when a regional air inversion confined pollutants to the Rhine Valley below the study sites. High fluxes accompanied the inversion break-up.

Black Forest↗

USGS1988

Preliminary observations of streamflow generation during storms in a forested Piedmont watershed using temperature as a tracer

Variations in streamwater temperature at the outlet of a 41-ha forested watershed at Panola Mountain in the Georgia Piedmont indicate that the initial rapid hydrologic response is caused by a combination of groundwater discharge and channel interception of rainwater. A storm in May 1986 caused a rapid increase in discharge that was accompanied by a decrease in streamwater temperature and a rise in the water table level adjacent to the stream. The higher water table provided the hydraulic gradient necessary to increase the discharge of colder groundwater to the stream. Storms that occurred under very dry antecedent conditions in July 1986 and June 1987 caused a rapid hydrologic response but no change in water table level, indicating the response was caused by channel interception of rainwater. This conclusion was supported by increases in streamwater temperature in the June storm and by chemical changes in the July storm. When rainfall is sufficient, flow in the ephemeral part of the stream in the catchment headwaters generates a second and larger discharge peak that reflects the chemistry and temperature of runoff from a 3-ha granite outcrop in the headwaters; sulfate concentration and temperature increase and alkalinity decreases relative to prestorm conditions. The initial response, however, results from channel interception and groundwater discharge. Rapid rises in the water table level during some storms suggest that macropore flow may play a major role in the hydrologic response of the watershed to rainstorms.

Journal of Contaminant Hydrology↗