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Geology topics

J. A. Smith

Publications and source records attributed to J. A. Smith.

11 recordsLinked to original sources
USGS2023

A restructured Bayesian approach to estimate the abundance of a rare and invasive fish

Quantifying invasive species abundance informs management and control strategies. However, estimating abundance can be challenging, particularly when dealing with rare species early in the invasion process. Data generated from control strategies, such as removing invasive species, are usually not suited to conventional statistical modelling approaches. Hence, we developed a Bayesian model using data generated by a grass carp ( Ctenopharyngodon idella ) control program in the Sandusky River, Ohio (USA) for estimating the abundance of rare, invasive species. The model is a restructured N-mixture model modified to incorporate the data generating process (i.e., setting a trammel net to isolate a sampling area followed by boat-mounted electrofishing). Allowing the estimation of grass carp abundance from the species removal data, which had very few detections relative to the sampling effort. Our results indicated that the average number of grass carp present in the river at any one time did not change substantially from 2018 to 2020. The highest abundance estimates were in the lower and upper-middle segments of the river, suggesting possible recolonization from Lake Erie, and possibly other tributaries. Ultimately, the ability to use species-control data to estimate abundance provides important information for management, particularly for invasive ‘sleeper’ species in freshwater ecosystems.

Ohio↗
USGS2005

Sorption of aromatic organic pollutants to grasses from water

The influence of plant lipids on the equilibrium sorption of three aromatic solutes from water was studied. The plant-water sorption isotherms of benzene, 1,2-dichlorobenzene, and phenanthrene were measured over a large range of solute concentrations using sealed vessels containing water, dried plant material, and solute. The plant materials studied include the shoots of annual rye, tall fescue, red fescue, and spinach as well as the roots of annual rye. Seven out of eight sorption isotherms were linear with no evidence of competitive effects between the solutes. For a given plant type, the sorption coefficient increased with decreasing solute water solubility. For a given solute, sorption increased with increasing plant lipid content. The estimated lipid-water partition coefficients of individual solutes were found to be significantly greater than the corresponding octanol-water partition coefficients. This indicates that plant lipids are a more effective partition solvent than octanol for the studied aromatic compounds. As expected, the solute lipid-water partition coefficients were log-linearly related to the respective water solubilities. For the compounds studied, partitioning into the lipids is believed to be the primary sorption mechanism. ?? 2005 American Chemical Society.

Environmental Science & Technology↗
USGS2002

Effect of ten quaternary ammonium cations on tetrachloromethane sorption to clay from water

The mineral surface of Wyoming bentonite (clay) was modified by replacing inorganic ions by each of 10 quaternary ammonium compounds, and tetrachloromethane sorption to the modified sorbents from water was studied. Tetrachloromethane sorption from solution to clay modified with tetramethyl-, tetraethyl-, benzyltrimethyl-, or benzyltriethylammonium cations generally is characterized by relatively high solute uptake, isotherm nonlinearity, and competitive sorption (with trichloroethene as the competing sorbate). For these sorbents, the ethyl functional groups yield reduced sorptive capacity relative to methyl groups, whereas the benzyl group appears to have a similar effect on sorbent capacity as the methyl group. Sorption of tetrachloromethane to clay modified with dodecyldimethyl(2-phenoxyethyl)-, dodecyltrimethyl-, tetradecyltrimethyl-, hexadecyltrimethyl-, or benzyldimethylhexadecylammonium bromide is characterized by relatively low solute uptake, isotherm linearity, and noncompetitive sorption. For these sorbents, an increase in the size of the nonpolar functional group(s) causes an increase in the organic carbon normalized sorption coefficient (Koc). No measurable uptake of tetrachloromethane sorption by the unmodified clay or clay modified by ammonium bromide was observed.

Environmental Science & Technology↗
USGS1989

The role of catastrophic geomorphic events in central Appalachian landscape evolution

Catastrophic geomorphic events are taken as those that are large, sudden, and rare on human timescales. In the nonglaciated, low-seismicity central Appalachians, these are dominantly floods and landslides. Evaluation of the role of catastrophic events in landscape evolution includes assessment of their contributions to denudation and formation of prominent landscape features, and how they vary through space and time. Tropical storm paths and topographic barriers at the Blue Ridge and Allegheny Front create significant climatic variability across the Appalachians. For moderate floods, the influence of basin geology is apparent in modifying severity of flooding, but for the most extreme events, flood discharges relate mainly to rainfall characteristics such as intensity, duration, storm size, and location. Landslide susceptibility relates more directly to geologic controls that determine what intensity and duration of rainfall will trigger slope instability. Large floods and landslides are not necessarily effective in producing prominent geomorphic features. Large historic floods in the Piedmont have been minimally effective in producing prominent and persistent geomorphic features. In contrast, smaller floods in the Valley and Ridge produced erosional and depositional features that probably will require thousands of years to efface. Scars and deposits of debris slide-avalanches triggered on sandstone ridges recover slowly and persist much longer than scars and deposits of smaller landslides triggered on finer-grained regolith, even though the smaller landslides may have eroded greater aggregate volume. The surficial stratigraphic record can be used to extend the spatial and temporal limits of our knowledge of catastrophic events. Many prominent alluvial and colluvial landforms in the central Appalachians are composed of sediments that were deposited by processes similar to those observed in historic catastrophic events. Available stratigraphic evidence shows two scales of temporal variation: one related to Quaternary climate changes and a more-recent, higher-frequency variation due to rare events during the Holocene. In much of the central Appalachians, landforms related to Quaternary climate changes persist as the most prominent features, despite the modifying effects of late-Holocene catastrophic events.

Geomorphology↗
USGS1987

A review of surface-water sediment fractions and their interactions with persistent manmade organic compounds

This paper reviews the suspended and surficial sediment fractions and their interactions with manmade organic compounds. The objective of this review is to isolate and describe those contaminant and sediment properties that contribute to the persistence of organic compounds in surface-water systems. Most persistent, nonionic organic contaminants, such as the chlorinated insecticides and polychlorinated biphenyls (PCBs), are characterized by low water solubilities and high octanol-water partition coefficients. Consequently, sorptive interactions are the primary transformation processes that control their environmental behavior. For nonionic organic compounds, sorption is primarily attributed to the partitioning of an organic contaminant between a water phase and an organic phase. Partitioning processes play a central role in the uptake and release of contaminants by sediment organic matter and in the bioconcentration of contaminants by aquatic organisms. Chemically isolated sediment fractions show that organic matter is the primary determinant of the sorptive capacity exhibited by sediment. Humic substances, as dissolved organic matter, contribute a number of functions to the processes cycling organic contaminants. They alter the rate of transformation of contaminants, enhance apparent water solubility, and increase the carrying capacity of the water column beyond the solubility limits of the contaminant. As a component of sediment particles, humic substances, through sorptive interactions, serve as vectors for the hydrodynamic transport of organic contaminants. The capabilities of the humic substances stem in part from their polyfunctional chemical composition and also from their ability to exist in solution as dissolved species, flocculated aggregates, surface coatings, and colloidal organomineral and organometal complexes. The transport properties of manmade organic compounds have been investigated by field studies and laboratory experiments that examine the sorption of contaminants by different sediment size fractions. Field studies indicate that organic contaminants tend to sorb more to fine-grained sediment, and this correlates significantly with sediment organic matter content. Laboratory experiments have extended the field studies to a wider spectrum of natural particulates and anthropogenic compounds. Quantitation of isotherm results allows the comparison of different sediment sorbents as well as the estimation of field partition coefficients from laboratory-measured sediment and contaminant properties. Detailed analyses made on the basis of particle-size classes show that all sediment fractions need to be considered in evaluating the fate and distribution of manmade organic compounds. This conclusion is based on observations from field studies and on the variety of natural organic sorbents that demonstrate sorptive capabilities in laboratory isotherm experiments.

Circular↗