Search USGS⌕ Search

Geology topics

Isabelle K. Brownfield

Publications and source records attributed to Isabelle K. Brownfield.

9 recordsLinked to original sources
USGS2018

Uranoan thorite in lithophysal rhyolite - Topaz Mountain, Utah, U.S.A.

Uranoan thorite crystals have been found occurring as a sparse constituent in lithophysae in 6.1 to 6.8 Ma alkali rhyolite flows at Thomas Mountain, Utah, USA. The crystals are associated with sandidine, quartz, topaz, hematite, magnetite, and calcite; they are leek to dark grass green, transparent, well-formed, euhedral prisms, showing development of forms {100}, {101}, and {111}. The mineral is both optically isotropic, with a refractive index of 1.86(1), and X-ray amorphous, indicating its metamict state. Electron microprobe analysis yields: SiO 2 17.3, ThO 2 56.8, UO 2 25.4, total 99.5%, and a structural formula of (Th 0.72 U 0.31 ) Σ1.03 Si 0.97 O 4 . This appears to be the first reported occurrence of thorite in volcanic rocks of rhyolitic composition, and may account for part or all of the Th reported in alkali rhyolites and so-called ‘topaz-rhyolites’ of the western USA.

Utah↗
USGS2008

Petrology of the 2004-2006 Mount St. Helens lava dome -- implications for magmatic plumbing and eruption triggering

Eighteen years after dome-forming eruptions ended in 1986, and with little warning, Mount St. Helens began to erupt again in October 2004. During the ensuing two years, the volcano extruded more than 80×10 6 m 3 of gas-poor, crystal-rich dacite lava. The 2004-6 dacite is remarkably uniform in bulk-rock composition and, at 65 percent SiO 2 , among the richest in silica and most depleted in incompatible elements of the magmas erupted at Mount St. Helens during the past 500 years. Since shortly after the first spine of lava appeared, samples have been collected using a steel box dredge (“Jaws”) suspended 20-35 m below a helicopter and, occasionally, by hand sampling. As of the spring of 2006, 25 age-controlled samples have been collected from the seven spines of the new lava dome. Samples were obtained from both the interiors of spines and from their carapaces, which are composed of fault gouge and cataclasite 1-2 m thick. The dacite lava is crystal rich, with 40-50 percent phenocrysts. The groundmass is extensively crystallized to a cotectic assemblage of quartz, tridymite, and Na- and K-rich feldspar microlites, raising the total crystal content to more than 80 percent on a vesicle-free basis in all but the earliest erupted samples. Early samples and those collected from near the spine margin are more glassy and vesicular that those collected later and from the interior of the spines. Oxide thermobarometer determinations for the earliest erupted samples we collected cluster at temperatures of approximately 850&deg;C and at an oxygen fugacity one log unit above the nickel-nickel oxide (NNO) buffer curve. In contrast, samples from relatively glass-poor samples erupted in late 2004 and early 2005 have zoned oxides with apparent temperatures that range to greater than 950&deg;C. The higher temperatures in these microlite-rich rocks are attributed to latent heat evolved during extensive and rapid groundmass crystallization. Low volatile contents of matrix glasses and presence of tridymite and quartz in the high-silica rhyolite matrix glass indicate extensive shallow (<1 km) crystallization of the matrix, driven by degassing of water and solidifying the magma below the level of the vent. The mode of eruption of the dacite as a series of fault-gouge-mantled spines is explained by this process of extensive subvent degassing and solidification. Although the dacite from this eruption is more silica rich than 1980-86 dome rocks, most major and trace element concentrations of the 1980-86 and 2004-6 magma batches are similar, and magmatic gas emissions have been low and have had similar ratios to those of the 1980s, raising the possibility that the magma might be residual from the 1980–86 reservoir. However, titanium and chromium are enriched slightly relative to the most recent 1980-86 and Goat Rocks (A.D. 1800-1857) eruptive cycles, and heavy rare-earth-element abundances are slightly depleted relative to those erupted during the past 500 years at Mount St. Helens. These data suggest either addition of new gas-poor dacite magma or tapping of a region of the preexisting reservoir that was not erupted previously. A relatively low pressure of last phenocryst growth suggests that the magma was derived from near the apex of the Mount St. Helens magma reservoir at a depth of about 5 km. Viewed in the context of seismic, deformation, and gas-emission data, the petrologic and geochemical data can be explained by ascent of a geochemically distinct batch of magma into the apex of the reservoir during the period 1987-97, followed by upward movement of magma into a new conduit beginning in late September 2004. The question of new versus residual magma has implications for the long-term eruptive behavior of Mount St. Helens, because arrival of a new batch of dacitic magma from the deep crust could herald the beginning of a new long-term cycle of eruptive activity. It is also important to our understanding of what triggered the eruption and its future course. Two hypotheses for triggering are considered: (1) top-down fracturing related to the shallow groundwater system and (2) an increase in reservoir pressure brought about by recent magmatic replenishment. With respect to the future course of the eruption, similarities between textures and character of eruption of the 2004-6 dome and the long-duration (greater than 100 years) pre-1980 summit dome, along with the low eruptive rate of the current eruption, suggest that the eruption could continue sluggishly or intermittently for years to come.

Washington↗
USGS2005

Characterization and modes of occurrence of elements in feed coal and coal combustion products from a power plant utilizing low-sulfur coal from the Powder River Basin, Wyoming

The U.S. Geological Survey and the University of Kentucky Center for Applied Energy Research are collaborating with an Indiana utility company to determine the physical and chemical properties of feed coal and coal combustion products from a coal-fired power plant. The Indiana power plant utilizes a low-sulfur (0.23 to 0.47 weight percent S) and lowash (4.9 to 6.3 weight percent ash) subbituminous coal from the Wyodak-Anderson coal zone in the Tongue River Member of the Paleocene Fort Union Formation, Powder River Basin, Wyoming. Based on scanning electron microscope and X-ray diffraction analyses of feed coal samples, two mineral suites were identified: (1) a primary or detrital suite consisting of quartz (including beta-form grains), biotite, feldspar, and minor zircon; and (2) a secondary authigenic mineral suite containing alumino-phosphates (crandallite and gorceixite), kaolinite, carbonates (calcite and dolomite), quartz, anatase, barite, and pyrite. The primary mineral suite is interpreted, in part, to be of volcanic origin, whereas the authigenic mineral suite is interpreted, in part, to be the result of the alteration of the volcanic minerals. The mineral suites have contributed to the higher amounts of barium, calcium, magnesium, phosphorus, sodium, strontium, and titanium in the Powder River Basin feed coals in comparison to eastern coals. X-ray diffraction analysis indicates that (1) fly ash is mostly aluminate glass, perovskite, lime, gehlenite, quartz, and phosphates with minor amounts of periclase, anhydrite, hematite, and spinel group minerals; and (2) bottom ash is predominantly quartz, plagioclase (albite and anorthite), pyroxene (augite and fassaite), rhodonite, and akermanite, and spinel group minerals. Microprobe and scanning electron microscope analyses of fly ash samples revealed quartz, zircon, and monazite, euhedral laths of corundum with merrillite, hematite, dendritic spinels/ferrites, wollastonite, and periclase. The abundant calcium and magnesium mineral phases in the fly ash are attributed to the presence of carbonate, clay, and phosphate minerals in the feed coal and their alteration to new phases during combustion. The amorphous diffraction-scattering maxima or glass 'hump' appears to reflect differences in chemical composition of fly ash and bottom ash glasses. In Wyodak-Anderson fly and bottom ashes, the center point of scattering maxima is due to calcium and magnesium content, whereas the glass 'hump' of eastern fly ash reflects variation in aluminum content. The calcium- and magnesium-rich and alumino-phosphate mineral phases in the coal combustion products can be attributed to volcanic minerals deposited in peat-forming mires. Dissolution and alteration of these detrital volcanic minerals occurred either in the peat-forming stage or during coalification and diagenesis, resulting in the authigenic mineral suite. The presence of free lime (CaO) in fly ash produced from Wyodak-Anderson coal acts as a self-contained 'scrubber' for SO3, where CaO + SO3 form anhydrite either during combustion or in the upper parts of the boiler. Considering the high lime content in the fly ash and the resulting hydration reactions after its contact with water, there is little evidence that major amounts of leachable metals are mobilized in the disposal or utilization of this fly ash.

Scientific Investigations Report↗
USGS2002

Reconnaissance study of the geology of U.S. vermiculite deposits: Are asbestos minerals common constituents?

Unusually high incidences of asbestos-related mortality and respiratory disease in the small town of Libby, Montana, have been linked to amphibole mineral fibers intergrown with the vermiculite deposits mined and milled near the town from 1923 to 1990. A study conducted by the U.S. Agency for Toxic Substances and Disease Registry concluded that mortality due to asbestosis in Libby mine and mill workers and residents during 1979 to 1998 was much higher than expected for a similar Montana or United States population group. Recent medical testing of past and present mineworkers and residents of Libby showed lung abnormalities in nearly one-fifth of the adult study participants. The U.S. Environmental Protection Agency, under Superfund authority, is completing sampling and cleanup of asbestos-bearing materials in the mine, mill, and town sites. The U.S. Geological Survey is conducting a study, reviewed herein, to investigate the mineral content of other U.S. vermiculite deposits and to determine if the amphibole asbestos minerals like those found in the Libby deposits are common in other vermiculite deposits.

Montana↗
USGS1977

Rare earths, thorium, and other minor elements in sphene from some plutonic rocks in west-central Alaska

Sphene is an abundant accessory mineral in some abnormally radioactive plutonic rocks in west-central Alaska. Seven samples of sphene from four different areas in west-central Alaska contained from 20350 to 39180 parts per million total rare earths and 390 to 2000 ppm thorium. The lanthanide content in six of the seven sphenes is chiefly the light rare earths and is similar to that of crustal abundance; a seventh sphene from the Darby Mountains, however, contains above average amounts of the heavy rare earths. A comparison of the lanthanide distribution in sphene from several areas indicates that the structure of sphene will accommodate whatever lanthanides are available when the mineral crystallizes. The amount of thorium and rare earths in sphene is also affected by the presence of other accessory minerals. Sphene in rocks containing either allanite or zircon has a lower thorium content than in rocks that do not contain allanite or zircon. Sphene, because of its abundance, may contain the greater part of the rare earths and thorium in some of the plutonic rocks of west-central Alaska.

Alaska↗