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Irving A. Breger

Publications and source records attributed to Irving A. Breger.

At least 19 recordsLinked to original sources
USGS1983

Eastern Devonian shales: Organic geochemical studies, past and present

The Eastern Devonian shales are represented by a sequence of sediments extending from New York state, south to the northern regions of Georgia and Alabama, and west into Ohio and to the Michigan and Ilinois Basins. Correlatives are known in Texas. The shale is regionally known by a number of names: Chattanooga, Dunkirk, Rhinestreet, Huron, Antrim, Ohio, Woodford, etc. These shales, other than those in Texas, have elicited much interest because they have been a source of unassociated natural gas. It is of particular interest, however, that most of these shales have no associated crude oil, in spite of the fact that they have some of the characteristics normally attributed to source beds. This paper addresses some of the organic geochemical aspects of the kerogen in these shales, in relation to their oil generating potential. Past organic geochemical studies on Eastern Devonian shales will be reviewed. Recent solid state 13C NMR studies on the nature of the organic matter in Eastern Devonian shales show that Eastern Devonian shales contain a larger fraction of aromatic carbon in their chemical composition. Thus, despite their high organic matter contents, their potential as a petroleum source rock is low, because the kerogen in these shales is of a "coaly" nature and hence more prone to producing natural gas.

Conference Paper↗
USGS1981

Nuclear magnetic resonance studies of ancient buried wood-I. Observations on the origin of coal to the brown coal stage

Various wood fragments buried in sediments under anaerobic conditions for from 450 yr to approximately 8 Myr have been examined by solid-state 13C nuclear magnetic resonance. Cellulose and other carbohydrates, the major components of Holocene wood, have been shown to be gradually hydrolyzed or otherwise lost under the conditions of burial. Lignin structures, however, are preserved relatively unchanged and become concentrated by difference as the carbohydrates disappear. Thus, a fragment of coalified wood isolated from a Miocene brown coal was found to be still composed of approximately 75% lignin and 25% cellulose. On the basis of our observations, we suggest that coalification of woody tissue progresses directly from lignin to coal and that such coalification may be retarded until most of the cellulose disappears. ?? 1981.

Organic Geochemistry↗
USGS1970

Search for organic compounds in the lunar dust from the Sea of Tranquillity

A sample of lunar dust was examined for organic compounds. Carbon detected in concentrations of 157 micrograms per gram had a δ 13 C per mil (PDB) value of + 20. Treatment with hydrochloric acid yielded hydrocarbons of low molecular weight, suggesting the presence of carbides. The gas chromatogram of the acylated and esterified derivatives of the hydrolyzate was similar to that obtained for the Pueblito de Allende meteorite. There were no detectable amounts of extractable high-molecular-weight alkanes, aromatic hydrocarbons, isoprenoid hydrocarbons, normal alkanes, fatty acids, amino acids, sugars, or nucleic acid bases. Traces of porphyrins were found, perhaps arising from rocket exhaust materials.

Science↗
USGS1960

Extract ability of humic acid from coalified logs as a guide to temperatures in colorado plateau sediments

Coalified logs in Triassic and Jurassic sediments of the Colorado Plateau have been exposed to alkaline ground water. Extraction of humic acids under such conditions is temperature dependent. Study of residual humic acids in a suite of coalified logs has indicated that temperatures up to but not over 120° C prevailed in the sediments . This maximum temperature corresponds with that to be expected from geothermal gradient and estimated from mineralogic evidence.

Colorado↗
USGS1960

Diagenesis of metabolites and a discussion of the origin of petroleum hydrocarbons

Proteins and carbohydrates are rapidly degraded to compounds of no direct interest in the problem of the origin of petroleum. Lignin, if carried into marine basins in the form of humic substances, is probably the major progenitor of kerogen rather than the precursor of petroleum. Pigments are but minor contributors to petroleum. The fate of fatty acids in a marine environment is not completely understood. Although they may not be directly decarboxylated biochemically, it is shown how they can be converted into oxygenated or dehydrogenated acids more reactive than the parent compounds. Illustrations are also given for Diels-Alder reactions that could account for the formation from these compounds of the alicyclic and aromatic hydrocarbons in petroleum. It is most likely that crude oil is generated in sediments containing concentrations of lipids, the character of which governs the nature of the oil that is formed.

Geochimica et Cosmochimica Acta↗
USGS1960

Potentiometric titration and equivalent weight of humic acid

The “acid nature” of humic acid has been controversial for many years. Some investigators claim that humic acid is a true weak acid, while others feel that its behaviour during potentiometric titration can be accounted for by colloidal adsorption of hydrogen ions. The acid character of humic acid has been reinvestigated using newly-derived relationships for the titration of weak acids with strong base. Re-interpreting the potentiometric titration data published by Thiele and Kettner in 1953, it was found that Merck humic acid behaves as a weak polyelectrolytic acid having an equivalent weight of 150, a pK a of 6.8 to 7.0, and a titration exponent of about 4.8. Interdretation of similar data pertaining to the titration of phenol-formaldehyde and pyrogallol-formaldehyde resins, considered to be analogs for humic acid by Thiele and Kettner , leads to the conclusion that it is not possible to differentiate between adsorption and acid-base reaction for these substances.

Geochimica et Cosmochimica Acta↗
USGS1960

Equivalent weight of humic acid from peat

By means of discontinuous titration, the equivalent weight of humic acid isolated from a peat was found to increase from 144 to 183 between the third and fifty-second day after the humic acid was dissolved. Infra-red studies showed that the material had probably condensed with loss of carbonyl groups.

Geochimica et Cosmochimica Acta↗
USGS1959

Free-radical concentrations and other properties of pile-irradiated coals

Five coals reacted quite differently when they were exposed to pile-irradiation. Little or no change was found in free-radical content for the three coals of lowest carbon content, whereas the two coals of highest carbon content were found to have a considerable increase in free-radical content. The infrared spectra and the apparent hardness of the irradiated coals of higher carbon content indicate that polymerization occurred. Radiation of these coals in chemical reagents may promote reactivity.

Science↗
USGS1958

Isolation and identification of an ester from a crude oil

A dioctylphthalate has been isolated from a crude oil by means of adsorption column chromatography. The ester was identified by means of elemental analysis, refractive index, and its infra-red absorption spectrum. Saponification of the isolate and examination of the resultant alcohol by means of infrared absorption spectra led to the conclusion that the ester is a branched chain dioctylphthalate. This is the first reported occurrence of an ester in crude petroleum.

Geochimica et Cosmochimica Acta↗
USGS1955

Geochemistry and mineralogy of a uraniferous sub bituminous coal

A sample of subbituminous uraniferous coal from the Red Desert, Sweetwater County, Wyo., has been studied mineralogically. The coal contains gypsum (6 percent), kaolinite (1 percent), quartz (0.3 percent), calcite (trace), and limonite (trace). This suite of minerals and the absence of pyrite show that the coal has been subjected to weathering and oxidation. No uranium minerals have been found; mechanical fractionation has indicated that the uranium is associated with the organic constituents of the coal. The minerals that have been isolated contain 0.0006 percent uranium, a content that is to be expected for nonuraniferous sedimentary rocks. The organic components of the coal contain approximately 0.002 percent uranium. On the basis of material-balance calculations, the organic components carry 98 percent of the uranium in the coal. Batch extraction of the Wyoming coal with 6 N hydrochloric acid leads to the solution of almost 90 percent of its uranium. Recovery of uranium is independent of the particle size of the coal between - 4 and - 20 mesh, and is accompanied by the solution of approximately 70 percent of the inorganic constituents (ash) of the coal. The extract contains, together with uranium, a concentration of several elements such as manganese, cerium, and vanadium that are present in the coal. Fischer assays of this weathered coal from the Red Desert indicate a yield of 16.7 gallons of tar per ton. Yields of both tar and char are about 15 percent lower if the coal is first treated with 6 N hydrochloric acid to extract the uranium. It is suggested that uranium was introduced into the coal by means of ground water carrying soluble alkaline or alkaline-earth uranyl carbonate complexes. The mineral schroeckingerite-a similar complex-is found near this subbituminous coal in the Red Desert of Wyoming. These complexes, which are unstable in acid medium, release the uranyl ion (U02++), which may then react with organic constituents of the coal to form ionic uranyl-organic compounds that are insoluble above a pH of about 2.2. Preliminary data indicate that the uranium is associated with various humic components of the coal. The distribution of uranium among the components of the subbituminous coal from Wyoming is similar to the distribution in a lignite from South Dakota. There is no indication that uranium was introduced into or retained by the two coals by appreciably different geochemical processes. © 1955 Society of Economic Geologists, Inc.

Wyoming↗
USGS1955

Geochemistry and mineralogy of a uraniferous lignite [South Dakota]

Detailed studies have been carried out on a uraniferous lignite from the Mendenhall strip mine, Harding County, S. Dak. By means of heavy-liquid separations, a mineral-free concentrate of the lignite was obtained that contained 13.8 percent ash and 0.31 percent uranium in the ash. The minerals (gypsum 69 percent, jarosite 10 percent, quartz 2 percent, kaolinite and clay minerals 19 percent, and calcite trace) contain only 7 percent of the uranium in the original coal, indicating an association of the uranium with the organic components of the lignite.Batch extractions show that 88.5 percent of the uranium can be extracted from the lignite by two consecutive treatments with boiling 1 N hydrochloric acid. Continuous extraction with hot 6 N hydrochloric acid removes 98.6 percent of the uranium.Columns of coal were treated with water, 1 N hydrochloric acid, 6 N hydrochloric acid, and a solution of lanthanum nitrate. The experiment with lanthanum nitrate indicated that only 1.2 percent of the uranium in the coal is held by ion exchange. The elutriation experiments showed that the uranium is held in the coal as an organo-uranium compound or complex that is soluble at a pH of less than 2.18.A geochemical mechanism by which the uranium may have been introduced into and retained by the lignite is discussed.

South Dakota↗
USGS1955

Radioactive equilibrium in ancient marine sediments

Radioactive equilibrium in eight marine sedimentary formations has been studied by means of direct determinations of uranium, radium and thorium. Alpha-particle counting has also been carried out in order to cross-calibrate thick-source counting techniques. The maximum deviation from radioactive equilibrium that has been noted is 11 per cent—indicating that there is probably equilibrium in all the formations analyzed. Thick-source alpha-particle counting by means of a proportional counter or an ionization chamber leads to high results when the samples contain less than about 10 p.p.m. of uranium. For samples having a higher content of uranium the results are in excellent agreement with each other and with those obtained by direct analytical techniques. The thorium contents that have been obtained correspond well to the average values reported in the literature. The uranium content of marine sediments may be appreciably higher than the average values that have been reported for sedimentary rocks. Data show that there is up to fourteen times the percentage of uranium as of thorium in the formations studied and that the percentage of thorium never exceeds that of uranium. While the proximity of a depositional environment to a land mass may influence the concentration of uranium in a marine sediment, this is not true with thorium.

Geochimica et Cosmochimica Acta↗