Geology topics

Howard E. Taylor

Publications and source records attributed to Howard E. Taylor.

75 records · Page 5Linked to original sources

USGS1982

Leaching characteristics of ash from the May 18, 1980, eruption of Mount St. Helens Volcano, Washington

Leaching of freshly erupted air-fall ash, unaffected by rain, from the May 18, 1.980,eruption of Mount St. Helens volcano, Washington, shows that Ca 2+, Na+, Mg+, SO4 2-, and Cl- are the predominant chemical species released on first exposure of the ash to water. Extremely high correlation of Ca with SO4 and Na with Cl in water leachates suggests the presence of CaSO4 and NaCl salts on the ash. The amount of water soluble material on ash increases with distance from source and with the weight fraction of small (less than 63 micrometers) ash particles of high-surface area. This suggests that surface reactions such as adsorption are responsible for concentrating the soluble material. CaSO4, NaCl, and other salts are probably formed as microscopic crystals in the high-temperature core of the eruption column and are then adsorbed by silicate ash particles. The environmentally important elements Zn, Cu, Cd, F, Pb, and Ba are released by a water leach in concentrations which could pose short-term hazards to some forms of aquatic life. However, calculated concentrations are based on a water-to-ash ratio of 4:1 or less, which is probably an underestimation of the regionally operative ratio. A subsequent leach of ash by warm alkaline solution shows dramatic increases in the amount of dissolved SiO2, U, and V, which are probably caused by increased dissolution of the glassy component of ash. Glass dissolution by alkaline ground water is a mechanism for providing these three elements to sedimentary traps where they may co-accumulate as uraniferous silica or U-V minerals. Leaching characteristics of ash from Mount St. Helens are comparable to characteristics of ash of similar composition from volcanoes in Guatemala. Ashes from each locality show similar ions predominating for a given leachate and similar fractions of a particular element in the ash removed on contact with the leach solution.

Open-File Report↗

USGS1982

Impact of Mount St. Helens eruption on hydrology and water quality

The 1980 eruptions of Mount St. Helens in southeast Washington resulted in a pronounced effect on the surface and ground water resources of the state. In response to the volcanic activity, the U.S. Geological Survey intensified statewide surface and ground water sampling programs to determine the nature and magnitude of the volcanic-induced variations. Streams to the east of Mount St. Helens received the major ash fallout. Chemical effects were best noted in smaller streams sampled 60 to 70 miles northeast of Mount St. Helens. The chemical variations observed were pronounced but short lived. Sulfate and chloride increases in anionic composition were prevalent immediately following the eruption however, the original bicarbonate predominance was again attained within several days. Suspended iron and aluminum concentrations were similarly elevated during the period of greatest ash deposition (highest turbidity) however, the dissolved concentrations remained relatively constant. Depressions of pH were minor and short lived. Streams draining to the south, tributaries to the Columbia river, showed little observable changes in water chemistry. Streams draining to the west (Toutle river and its tributaries) were compositionally affected by the various volcanic activities. Chloride and sulfate anion percentage exceeded the bicarbonate percentage up to one month following the eruption period. Streams and lakes sampled in the immediate vicinity of Mount St. Helens, in addition to trace metals, contained organic compounds derived from decomposing wood buried in the debris deposits. This organic material may constitute a significant source of organic compounds to surface and ground water for some time to come.

Washington↗

USGS1981

Reduction of matrix interferences in furnace atomic absorption with the L'vov Platform

Use of a modified L'vov Platform and ammonium phosphate as a matrix modifier greatly reduced matrix interferences in a commercial Massmann-type atomic absorption furnace. Platforms were readily fabricated from furnace tubes and, once positioned in the furnace, caused no inconvenience in operation. Two volatile elements (Pb, Cd), two of intermediate volatility (Co, Cr) and two which form stable oxides (Al, Sn) were tested in natural water and selected synthetic matrices. In every case for which there was a significant matrix effect during atomization from the tube wall, the platform and platform plus modifier gave improved performance. With lead, for example, an average ratio of 0.48 ± 0.11 was found when the slope of the standard additions plot for six different natural water samples was compared to the slope of the standard working curve in dilute acid. The average slope ratio between the natural water matrices and the dilute acid matrix was 0.94 ± 0.03 with the L'vov Platform and 0.96 ± 0.03 with the platform and matrix modifier. In none of the cases studied did the use of the platform or platform plus modifier cause an interference problem where none existed while atomizing from the tube wall. An additional benefit of the platform was a factor of about two improvement in peak height precision.

Spectrochimica Acta Part B: Atomic Spectroscopy↗