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Geology topics

Howard E. Taylor

Publications and source records attributed to Howard E. Taylor.

At least 37 records · Page 2Linked to original sources
USGS2008

Development and evaluation of geochemical methods for the sourcing of archaeological maize

Strontium (Sr)-isotope values on bone from deer mice pairs from 12 field sites in the Chaco Canyon area, New Mexico, were compared with isotope values of synthetic soil waters from the same fields. The data indicate that mice obtain Sr from near-surface sources and that soil samples collected at depths ranging from 25 to 95 cm contain Sr that is more accessible to the deep roots of maize; thus, synthetic soil solutions provide better data for the sourcing of archaeological maize. However, the Sr-isotope composition of mice may be more valuable in sourcing archaeological remains of animals such as rabbit, turkey, and deer. In a separate study, five Native American maize (Zea mays L. ssp. mays) accessions grown out at New Mexico State University Agricultural Science Center, Farmington, New Mexico were used to determine if soil-water metal pairs partition systematically into cobs and kernels. The sampled maize included landraces from three Native American groups (Acoma, Hopi, Zuni) that still occupy the Four Corners area. Two cobs each were picked from 10 plants of each landrace. Partitioning of the Ba/Mn, Ba/Sr, Ca/Sr, and K/Rb metal pairs from the soil water to the cob appears to behave in a systematic fashion. In addition, 51 rare earth element (REE) pairs also appear to systematically partition from the soil water into cobs; however, the ratios of the REE dissolved in the soil waters are relatively invariant; therefore, the distribution coefficients that describe the partitioning of REE from the soil water to the cob may not apply to archeological cobs grown under chemically heterogeneous conditions. Partitioning of Ba/Rb, Ba/Sr, Mg/P, and Mn/P metal pairs from the soil water to kernels also behaves in a systematic fashion. Given that modern Native American landraces were grown under optimal environmental conditions that may not have been duplicated by prehistoric Native Americans, the distribution coefficients obtained in this study should be used with caution. ?? 2007 Elsevier Ltd. All rights reserved.

Journal of Archaeological Science↗
USGS2008

Evaluation of statistical treatments of left-censored environmental data using coincident uncensored data sets: I. Summary statistics

The main classes of statistical treatment of below-detection limit (left-censored) environmental data for the determination of basic statistics that have been used in the literature are substitution methods, maximum likelihood, regression on order statistics (ROS), and nonparametric techniques. These treatments, along with using all instrument-generated data (even those below detection), were evaluated by examining data sets in which the true values of the censored data were known. It was found that for data sets with less than 70% censored data, the best technique overall for determination of summary statistics was the nonparametric Kaplan-Meier technique. ROS and the two substitution methods of assigning one-half the detection limit value to censored data or assigning a random number between zero and the detection limit to censored data were adequate alternatives. The use of these two substitution methods, however, requires a thorough understanding of how the laboratory censored the data. The technique of employing all instrument-generated data - including numbers below the detection limit - was found to be less adequate than the above techniques. At high degrees of censoring (greater than 70% censored data), no technique provided good estimates of summary statistics. Maximum likelihood techniques were found to be far inferior to all other treatments except substituting zero or the detection limit value to censored data.

Environmental Science & Technology↗
USGS2007

Mercury and organic carbon dynamics during runoff episodes from a northeastern USA watershed

Mercury and organic carbon concentrations vary dynamically in streamwater at the Sleepers River Research Watershed in Vermont, USA. Total mercury (THg) concentrations ranged from 0.53 to 93.8 ng/L during a 3-year period of study. The highest mercury (Hg) concentrations occurred slightly before peak flows and were associated with the highest organic carbon (OC) concentrations. Dissolved Hg (DHg) was the dominant form in the upland catchments; particulate Hg (PHg) dominated in the lowland catchments. The concentration of hydrophobic acid (HPOA), the major component of dissolved organic carbon (DOC), explained 41–98% of the variability of DHg concentration while DOC flux explained 68–85% of the variability in DHg flux, indicating both quality and quantity of the DOC substantially influenced the transport and fate of DHg. Particulate organic carbon (POC) concentrations explained 50% of the PHg variability, indicating that POC is an important transport mechanism for PHg. Despite available sources of DHg and wetlands in the upland catchments, dissolved methylmercury (DmeHg) concentrations in streamwaters were below detection limit (0.04 ng/L). PHg and particulate methylmercury (PmeHg) had a strong positive correlation ( r 2 = 0.84, p < 0.0001), suggesting a common source; likely in-stream or near-stream POC eroded or re-suspended during spring snowmelt and summer storms. Ratios of PmeHg to THg were low and fairly constant despite an apparent higher methylmercury (meHg) production potential in the summer. Methylmercury production in soils and stream sediments was below detection during snowmelt in April and highest in stream sediments (compared to forest and wetland soils) sampled in July. Using the watershed approach, the correlation of the percent of wetland cover to TmeHg concentrations in streamwater indicates that poorly drained wetland soils are a source of meHg and the relatively high concentrations found in stream surface sediments in July indicate these zones are a meHg sink.

Water, Air, & Soil Pollution↗
USGS2006

Mass spectrometric in the analysis of inorganic substances

Mass spectrometry is an analytical technique used to measure the composition of a substance by isolating specific analyte components according to their individual atomic or molecular mass‐to‐charge ratios. Inorganic mass spectrometry is specifically used to determine the elemental and isotopic composition of the material being analyzed. The techniques are capable of the measurement of a range of concentrations from major components to ultratrace constituents. Several instrumental approaches are used to separate and measure the abundance of component ions formed from the sample. These techniques include electron ionization mass spectrometry (EIMS), inductively coupled plasma mass spectrometry (ICPMS), thermal ionization mass spectrometry (TIMS) and spark source mass spectrometry (SSMS). These techniques utilize a variety of mass spectrometers including ion trap, quadrupole, magnetic sector and time‐of‐flight mass analyzers, depending on the type of sample being analyzed and the desired quality of the results. Often sample introduction techniques can be utilized to enhance the capabilities for solving specific analytical chemistry problems.

Book chapter↗
USGS2006

Isotope sourcing of prehistoric willow and tule textiles recovered from western Great Basin rock shelters and caves - proof of concept

Isotope and trace-metal analyses were used to determine the origin of plants used to manufacture prehistoric textiles (basketry and matting) from archaeological sites in the western Great Basin. Research focused on strontium (87Sr/86Sr) and oxygen (18O/16O) isotope ratios of willow (Salix sp.) and tule (Schoenoplectus sp.), the dominant raw materials in Great Basin textiles. The oxygen-isotope data indicated that the willow and tule used to produce the textiles were harvested from the banks of rivers or in marshes characterized by flowing water and not from lakes or sinks. The strontium-isotope data were useful in showing which plants came from the Humboldt River and which came from rivers headed in the Sierra Nevada.

Journal of Archaeological Science↗
USGS2006

Geochemistry of bed and suspended sediment in the Mississippi river system: Provenance versus weathering and winnowing

Stream-bed sediment for the size fraction less than 150 μm, examined in 14,000 samples collected mostly from minor tributaries to the major rivers throughout the Mississippi River drainage system, is composed of 5 mineral fractions identified by factor analysis—Al-silicate minerals, quartz, calcite and dolomite, heavy minerals, and an Fe–Mn fraction. The Al-silicate fraction parallels its distribution in the regolith, emphasizing the local sediment source as a primary control to its distribution. Quartz and the heavy-mineral fraction, and associated trace elements, exhibit a complementary distribution to that of the Al-silicate fraction, with a level of enrichment in the bed sediment that is achieved through winnowing and sorting. The carbonate fraction has a distribution suggesting its dissolution during transport. Trace elements partitioned onto the Fe–Mn, possibly amorphous oxyhydride, fraction are introduced to the streams, in part, through human activity. Except for the heavy-mineral fraction, these fractions are identified in suspended sediment from the Mississippi River itself. Although comparison of the tributary bed sediment with the riverine suspended sediment is problematic, the geochemistry of the suspended sediment seems to corroborate the interpretation of the geochemistry of the bed sediment.

Arkansas basin, Ohio basin Tennessee basin, Lower ↗
USGS2005

Chemical loading into surface water along a hydrological, biogeochemical, and land use gradient: A holistic watershed approach

Identifying the sources and impacts of organic and inorganic contaminants at the watershed scale is a complex challenge because of the multitude of processes occurring in time and space. Investigation of geochemical transformations requires a systematic evaluation of hydrologic, landscape, and anthropogenic factors. The 1160 km 2 Boulder Creek Watershed in the Colorado Front Range encompasses a gradient of geology, ecotypes, climate, and urbanization. Streamflow originates primarily as snowmelt and shows substantial annual variation. Water samples were collected along a 70-km transect during spring-runoff and base-flow conditions, and analyzed for major elements, trace elements, bulk organics, organic wastewater contaminants (OWCs), and pesticides. Major-element and trace-element concentrations were low in the headwaters, increased through the urban corridor, and had a step increase downstream from the first major wastewater treatment plant (WWTP). Boron, gadolinium, and lithium were useful inorganic tracers of anthropogenic inputs. Effluent from the WWTP accounted for as much as 75% of the flow in Boulder Creek and was the largest chemical input. Under both hydrological conditions, OWCs and pesticides were detected in Boulder Creek downstream from the WWTP outfall as well as in the headwater region, and loads of anthropogenic-derived contaminants increased as basin population density increased. This report documents a suite of potential endocrine-disrupting chemicals in a reach of stream with native fish populations showing indication of endocrine disruption.

Environmental Science & Technology↗
USGS2005

Accumulation of contaminants in fish from wastewater treatment wetlands

Increasing demands on water resources in arid environments make reclamation and reuse of municipal wastewater an important component of the water budget. Treatment wetlands can be an integral part of the water-reuse cycle providing both water-quality enhancement and habitat functions. When used for habitat, the bioaccumulation potential of contaminants in the wastewater is a critical consideration. Water and fish samples collected from the Tres Rios Demonstration Constructed Wetlands near Phoenix, Arizona, which uses secondary-treated wastewater to maintain an aquatic ecosystem in a desert environment, were analyzed for hydrophobic organic compounds (HOC) and trace elements. Semipermeable membrane devices (SPMD) were deployed to investigate uptake of HOC. The wetlands effectively removed HOC, and concentrations of herbicides, pesticides, and organic wastewater contaminants decreased 40−99% between inlet and outlet. Analysis of Tilapia mossambica and Gambusia affinis indicated accumulation of HOC, including p,p ‘-DDE and trans -nonachlor. The SPMD accumulated the HOC detected in the fish tissue as well as additional compounds. Trace-element concentrations in whole-fish tissue were highly variable, but were similar between the two species. Concentrations of HOC and trace elements varied in different fish tissue compartments, and concentrations in Tilapia liver tissue were greater than those in the whole organism or filet tissue. Bioconcentration factors for the trace elements ranged from 5 to 58 000 and for the HOC ranged from 530 to 150 000.

Environmental Science & Technology↗
USGS2005

Aqueous stability of gadolinium in surface waters receiving sewage treatment plant effluent Boulder Creek, Colorado

In many surface waters, sewage treatment plant (STP) effluent is a substantial source of both regulated and unregulated contaminants, including a suite of complex organic compounds derived from household chemicals, pharmaceutical, and industrial and medical byproducts. In addition, STP effluents in some urban areas have also been shown to have a positive gadolinium (Gd) anomaly in the rare earth element (REE) pattern, with the Gd derived from its use in medical facilities. REE concentrations are relatively easy to measure compared to many organic wastewater compounds and may provide a more widely utilized tracer of STP effluents. To evaluate whether sewage treatment plant-associated Gd is a useful tracer of treatment plant effluent, an investigation of the occurrence, fate, and transport of rare earth elements was undertaken. The rare earth element patterns of four of five STP effluents sampled display positive Gd anomalies. The one site that did not have a Gd anomaly serves a small community, population 1200, with no medical facilities. Biosolids from a large metropolitan STP are not enriched in Gd even though the effluent is, suggesting that a substantial fraction of Gd remains in the aqueous phase through routine treatment plant operation. To evaluate whether STP-derived Gd persists in the fluvial environment, a 14-km study reach downstream of an STP was sampled. Gadolinium anomalies were present at all five downstream sites, but the magnitude of the anomaly decreased. Effluent from STPs is a complex mixture of organic and inorganic constituents, and to better understand the chemical interactions and their effect on REEs, the aqueous speciation was modeled using comprehensive chemical analyses of water samples collected downstream of STP input. These calculations suggest that the REEs will likely remain dissolved because phosphate and carbonate complexes dominate over free REE ions. This study supports the application of Gd anomalies as a useful tracer of urban wastewater.

Colorado↗
USGS2005

Mercury transport in a high-elevation watershed in Rocky Mountain National Park, Colorado

Mercury (Hg) was measured in stream water and precipitation in the Loch Vale watershed in Rocky Mountain National Park, Colorado, during 2001–2002 to investigate processes controlling Hg transport in high-elevation ecosystems. Total Hg concentrations in precipitation ranged from 2.6 to 36.2 ng/L and showed a strong seasonal pattern with concentrations that were 3 to 4 times higher during summer months. Annual bulk deposition of Hg was 8.3 to 12.4 μ g/m 2 and was similar to deposition rates in the Midwestern and Northeastern U.S. Total Hg concentrations in streams ranged from 0.8 to 13.5 ng/L and were highest in mid-May on the rising limb of the snowmelt hydrograph. Stream-water Hg was positively correlated with dissolved organic carbon suggesting organically complexed Hg was flushed into streams from near-surface soil horizons during the early stages of snowmelt. Methylmercury (MeHg) in stream water peaked at 0.048 ng/L just prior to peak snowmelt but was at or below detection (< 0.040 ng/L) for the remainder of the snowmelt season. Annual export of total Hg in Loch Vale streams ranged from 1.2 to 2.3 μ g/m 2 , which was less than 20% of wet deposition, indicating the terrestrial environment is a net sink of atmospheric Hg. Concentrations of MeHg in stream water and corresponding watershed fluxes were low, indicating low methylation rates or high demethylation rates or both.

Colorado↗
USGS2005

Water-chemistry data for selected springs, geysers, and streams in Yellowstone National Park Wyoming, 2001-2002

Water analyses are reported for one-hundred-twenty-one samples collected from hot springs and their overflow drainages, the Gibbon River, and one ambient-temperature acid stream in Yellowstone National Park (YNP) during 2001-2002. Twenty-five analyses are reported for samples collected during May 2001, fifty analyses are reported for samples collected during September 2001, eleven analyses are reported for samples collected during October 2001, and thirty-five analyses are reported for samples collected during June and July 2002. Water samples were collected and analyzed for major and trace constituents from nine areas of YNP including Norris Geyser Basin, Nymph Lake and Roadside Springs, Lower Geyser Basin, Washburn Springs, Calcite Springs, Crater Hills, Mammoth Hot Springs, West Thumb Geyser Basin, and Brimstone Basin. These water samples were collected and analyzed as part of research investigations in YNP on arsenic redox distribution in hot springs and overflow drainages, the occurrence and distribution of dissolved mercury, and sulfur redox speciation. Most samples were analyzed for major cations and anions, trace metals, and iron, arsenic, nitrogen, and sulfur redox species. Only mercury concentration, pH, and specific conductance were determined for samples collected in October 2001 as they were collected during a reconnaissance field trip. Analyses were performed at the sampling site, in an onsite mobile laboratory, or later in a U.S. Geological Survey laboratory, depending on stability of the constituent and whether it could be preserved effectively. Water samples were filtered and preserved onsite. Water temperature, specific conductance, pH, Eh, and dissolved hydrogen sulfide were measured onsite at the time of sampling. Alkalinity and acidity were determined by titration, usually within a few days of sample collection. Concentrations of thiosulfate (S 2 O 3 ) and polythionate (S n O 6 ) were determined as soon as possible (generally minutes to hours after sample collection) by ion chromatography in an onsite mobile laboratory vehicle. Total dissolved iron and ferrous iron concentrations often were measured onsite in the mobile laboratory. Concentrations of aluminum, arsenic, barium, beryllium, boron, cadmium, calcium, chromium, cobalt, copper, iron, lead, lithium, magnesium, manganese, molybdenum, nickel, potassium, selenium, silica, sodium, strontium, vanadium, and zinc were determined by inductively coupled plasma-optical emission spectrometry. Trace concentrations of antimony, cadmium, chromium, cobalt, copper, lead, and selenium were determined by Zeeman-corrected graphite-furnace atomic-absorption spectrometry. Concentrations of total arsenic and arsenite were determined by hydride-generation atomic-absorption spectrometry using a flow-injection analysis system. Concentrations of total mercury were determined by cold-vapor atomic fluorescence spectrometry. Concentrations of bromide, chloride, nitrate, and sulfate were determined by ion chromatography. Concentrations of ferrous and total iron were determined by the FerroZine colorimetric method. Concentrations of nitrite were determined by colorimetry or chemiluminescence. Concentrations of ammonia were determined by ion chromatography, with reanalysis by colorimetry when separation of sodium and ammonia peaks was poor. Dissolved organic carbon concentrations were determined by the wet persulfate oxidation method.

Wyoming↗
USGS2005

Physical and chemical characteristics of Knowles, Forgotten, and Moqui Canyons, and effects of recreational use on water quality, Lake Powell, Arizona and Utah

Side canyons of Lake Powell are the most popular recreation areas of the Glen Canyon National Recreation Area in Arizona and Utah. There are more than 90 side canyons that are tributaries to the main lake body of Lake Powell. Near Bullfrog and Halls Crossing marinas in Utah, visitors frequent Knowles, Forgotten, and Moqui Canyons to fish, boat, camp, and hike the sandstone formations for which Lake Powell is famous. Areas of recreational activity are greatest near beaches in side canyons. Emissions from houseboats, personal watercraft, speedboats, and from some nonboating recreational activities introduce contaminants to the lake and to beach areas. The U.S. Geological Survey documented concentrations of trace elements, volatile organic compounds, organic wastewater contaminants, and other byproducts of fuel-based contaminants in water and bed material in Knowles, Forgotten, and Moqui Canyons during the summers of 2001 and 2002. Field work was conducted during four trips when recreational use was at a minimum (before Memorial Day in May) and when it was at a maximum (near Labor Day in September). Knowles Canyon was treated as a control; therefore, public access by motorcraft was not permitted during the study. Electric-powered or oar-powered research boats were used to collect samples and measure properties in Knowles Canyon. Record-low reservoir elevations during 2000-2002 limited the availability of camping and day-use beaches in Forgotten and Moqui Canyons. Although more beach areas were exposed during this period, the steep slopes of the beaches made it difficult to use the beaches for camping purposes. Side canyon waters of Knowles, Forgotten, and Moqui Canyons were similarly stratified (physically and chemically) during the study from natural advective and convective reservoir processes. Metalimnetic oxygen minimas were observed in September 2001 and 2002 in the side canyons and the main body of Lake Powell. Chemical concentrations of several organic constituents were elevated in Forgotten and Moqui Canyons during the high-use period in September of 2001 and 2002 compared with concentrations during the low-use period in May of 2001 and 2002. Concentrations of some constituents decreased from the mouth of each canyon to the canyon's headwaters, indicating that there could be a mechanism for constituent removal or that the main body of Lake Powell is not in equilibrium with the headwaters of the side canyons. Concentrations of volatile organic compounds, such as benzene, toluene, ethylbenzene, and xylene (BTEX compounds), were highest in the upper reaches of Forgotten and Moqui Canyons where visitor use was greatest. Trace amounts of some organic wastewater compounds, including cholesterol, N,N-diethyl-meta-toluamide (DEET), and ethylenediaminetetraacetic acid (EDTA), were measured in Forgotten and Moqui Canyons. Except for minor concentrations of some volatile organic compounds and cholesterol, contamination from visitor use in Knowles Canyon was not detected, most likely because the canyon was closed to access. Concentrations of some organic compounds in bed material sampled in the side canyons near popular beach areas, including polyaromatic hydrocarbons, were above the laboratory detection limits. Several other constituents were present in trace amounts. Benzyl n-butylphthalate and bis (2 ethyl)-phthalate were detected at concentrations above laboratory detection limits. Numerous trace elements were detected above laboratory detection limits in Knowles, Forgotten, and Moqui Canyons. All water samples from the side canyon transects had low colony counts of Escherichia coli (E. coli); the highest count was less than one-fourth of the U.S. Environmental Protection Agency recommended limit for recreational water. Four water samples collected near beaches in Moqui Canyon had E. coli colony counts that exceeded the U.S. Environmental Protection Agency recommended limit.

Arizona, Utah↗
USGS2005

Chemical characteristics of ground-water discharge along the south rim of Grand Canyon in Grand Canyon National Park, Arizona, 2000-2001

Springs flowing from the south rim of Grand Canyon are an important resource of Grand Canyon National Park, offering refuge to endemic and exotic terrestrial wildlife species and maintaining riparian areas. Population growth on the Coconino Plateau has increased the demand for additional development of ground-water resources, and such development could reduce spring discharge and affect the sustainability of riparian areas within the park. In addition, springs are an important source of drinking water for hikers and are culturally and economically important to Native Americans living in the region. Water samples were collected from May 2000 to September 2001 from 20 spring and creek sites that discharge water from the Redwall-Muav Limestone aquifer along the south rim of Grand Canyon. Sample collection sites were described and samples were analyzed for major ions, nutrients, trace elements, radioactivity, and selected isotopes, and potential sources of ground-water flow to the springs. Rock samples representing the major stratigraphic units of Grand Canyon were collected near the Bright Angel Fault and analyzed for mineralogy, strontium-87/strontium-86, and carbon-13/carbon-12. The chemical composition of water samples collected from a given spring did not vary appreciably over the course of the study. Although water at each spring had a temporally constant composition, the composition was chemically distinct from that of every other spring sampled, indicating spatial variability in the ground-water composition. Most samples had a calcium magnesium bicarbonate composition; a few had a substantial sulfate component. Concentrations of arsenic, nitrate, selenium, uranium, and gross alpha approached or exceeded U.S. Environmental Protection Agency Maximum Contaminant Levels in water discharging from some springs. Oxygen and hydrogen isotopic compositions varied little among samples, and for most sites the isotopic data plot close to the global meteoric water line or below the local meteoric water line. Isotopic enrichment indicates fractionation due to evaporation occurs at some sites. The evaporative process may occur prior to recharge or post-discharge. Flow paths are differentiated between the eastern part of the study area where strontium-87/strontium-86 values for water from springs and creeks are more radiogenic than strontium-87/strontium-86 values for water that discharges from sites farther west. Tritium and carbon isotope analyses indicate that residence time of ground-water discharge from springs and creeks ranges from less than 50 years to about 3,400 years. Water with a residence time of less than 50 years is absent at several sites. Discharge of most springs and creeks is a mixture of younger and older waters.

Arizona↗
USGS2005

Geochemical characterization of water, sediment, and biota affected by mercury contamination and acidic drainage from historical gold mining, Greenhorn Creek, Nevada County, California, 1999-2001

In 1999, the U.S. Geological Survey (USGS) initiated studies of mercury and methylmercury occurrence, transformation, and transport in the Bear River and Yuba River watersheds of the northwestern Sierra Nevada. Because these watersheds were affected by large-scale, historical gold extraction using mercury amalgamation beginning in the 1850s, they were selected for a pilot study of mercury transport by the USGS and other cooperating agencies. This report presents data on methylmercury (MeHg) and total mercury (THg) concentrations in water, bed sediment, invertebrates, and frogs collected at 40 stations during 1999-2001 in the Greenhorn Creek drainage, a major tributary to Bear River. Results document several mercury contamination “hot spots” that represent potential targets for ongoing and future remediation efforts at abandoned mine sites in the study area. Water-quality samples were collected one or more times at each of 29 stations. The concentrations of total mercury in 45 unfiltered water samples ranged from 0.80 to 153,000 nanograms per liter (ng/L); the median was 9.6 ng/L. Total mercury concentrations in filtered water (41 samples) ranged from less than 0.3 to 8,000 ng/L; the median was 2.7 ng/L. Concentrations of methylmercury in the unfiltered water (40 samples) ranged from less than 0.04 to 9.1 ng/L; the median was 0.07 ng/L. Methylmercury in filtered water (13 samples) ranged from less than 0.04 to 0.27 ng/L; the median was 0.04 ng/L. Acidic drainage with pH values as low as 3.4 was encountered in some of the mined areas. Elevated concentrations of aluminum, cadmium, copper, iron, manganese, nickel, and zinc were found at several stations, especially in the more acidic water samples. Total mercury concentrations in sediment were determined by laboratory and field methods. Total mercury concentrations (determined by laboratory methods) in ten samples from eight stations ranged from about 0.0044 to 12 µg/g (microgram per gram, equivalent to parts per million). Methylmercury concentrations in these samples ranged from less than 0.00011 to 0.0095 µg/g. A field panning method was used to determine the concentration of liquid elemental mercury in 22 samples from 14 stations. Measured quantities of elemental mercury recovered by panning ranged from a trace amount estimated at 100 milligrams per kilogram (equivalent to parts per million) to 45,000 milligrams per kilogram (equivalent to 4.5 per cent, by weight). In total, 194 invertebrate samples were collected at 31 stations; 78 of the samples were analyzed for concentrations of THg and MeHg and used to calculate MeHg to THg ratios. A total of 69 frog samples were collected at 19 stations, and all were analyzed only for THg. Ranges of MeHg concentrations (µg/g, wet weight) in invertebrate samples and number of samples (n) were 0.0012-0.048 for banana slugs (Arionidae, n = 27), 0.027-0.39 for dobsonflies (Corydalidae, n = 14), 0.029-0.50 for predaceous diving beetles (Dytiscidae, n = 31), 0.026-0.52 for predaceous stoneflies (Perlidae, n = 18), 0.011-1.6 for dragonflies (Odonata, n = 46), and 0.061-0.55 for water striders (Gerridae, n = 56). The ratio of MeHg to THg in invertebrates was greater than 50 percent for 74 of 78 samples. The data from this reconnaissance sampling effort have been used by land-management agencies in selecting abandoned mine sites for remediation. The Forest Service has remediated the Sailor Flat site, and the Bureau of Land Management has initiated plans to remediate the Boston Mine drainage tunnel.

California↗
USGS2004

Rare earth element partitioning between hydrous ferric oxides and acid mine water during iron oxidation

Ferrous iron rapidly oxidizes to Fe (III) and precipitates as hydrous Fe (III) oxides in acid mine waters. This study examines the effect of Fe precipitation on the rare earth element(REE) geochemistry of acid mine waters to determine the pH range over which REEs behave conservatively and the range over which attenuation and fractionation occur. Two field studies were designed to investigate REE attenuation during Fe oxidation in acidic, alpine surface waters. To complement these field studies, a suite of six acid mine waters with a pH range from 1.6 to 6.1 were collected and allowed to oxidize in the laboratory at ambient conditions to determine the partitioning of REEs during Fe oxidation and precipitation. Results from field experiments document that even with substantial Fe oxidation, the REEs remain dissolved in acid, sulfate waters with pH below 5.1. Between pH 5.1 and 6.6 the REEs partitioned to the solid phases in the water column, and heavy REEs were preferentially removed compared to light REEs. Laboratory experiments corroborated field data with the most solid-phase partitioning occurring in the waters with the highest pH.

Applied Geochemistry↗
USGS2004

Trace elements and common ions in southeastern Idaho snow: Regional air pollutant tracers for source area emissions

Snow sampling and analysis methods which produce accurate and ultra-low measurements of trace elements and common ion concentration in southeastern Idaho snow, were developed. Snow samples were collected over two winters to assess trace elements and common ion concentrations in air pollutant fallout across the southeastern Idaho. The area apportionment of apportionment of fallout concentrations measured at downwind location were investigated using pattern recognition and multivariate statistical technical techniques. Results show a high level of contribution from phosphates processing facilities located outside Pocatello in the southern portion of the Eastern Snake River Plain, and no obvious source area profiles other than at Pocatello.

Conference Paper↗