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Hani N. Khoury

Publications and source records attributed to Hani N. Khoury.

2 recordsLinked to original sources

Mixed-layer kerolite/stevensite from the Amargosa Desert, Nevada

Mixed-layer clays composed of randomly interstratified kerolite/stevensite occur as lake and/or spring deposits of probable Pliocene and Pleistocene age in the Amargosa Desert of southern Nevada, U.S.A. The percentage of expandable layers of these clays, determined from computer-simulated X-ray diffractograms, ranges from almost 0 to about 80%. This range in expandabilities most likely results from differences in solution chemistry and/or temperature at the time of formation. An average structural formula for the purest clay (sample P-7), a clay with about 70% expandable layers, is: [(Mg 2.72 Al 0.07 Fe 0.03 Li 0.09 )(Si 3.96 Al 0.04 )O 10 (OH) 0.2 ] -0.21 [X + 0.21 ] +0.21 The data suggest that talc, kerolite, and stevensite form a continuous structural series based on layer charge.

Clays and Clay Minerals↗

Comparison of rapid methods for chemical analysis of milligram samples of ultrafine clays

Two rapid methods for the decomposition and chemical analysis of clays were adapted for use with 20–40-mg size samples, typical amounts of ultrafine products (≤0.5-µm diameter) obtained by modern separation methods for clay minerals. The results of these methods were compared with those of “classical” rock analyses. The two methods consisted of mixed lithium metaborate fusion and heated decomposition with HF in a closed vessel. The latter technique was modified to include subsequent evaporation with concentrated H 2 SO 4 and re-solution in HCl, which reduced the interference of the fluoride ion in the determination of Al, Fe, Ca, Mg, Na, and K. Results from the two methods agree sufficiently well with those of the “classical” techniques to minimize error in the calculation of clay mineral structural formulae. Representative maximum variations, in atoms per unit formula of the smectite type based on 22 negative charges, are 0.09 for Si, 0.03 for Al, 0.015 for Fe, 0.07 for Mg, 0.03 for Na, and 0.01 for K.

Clays and Clay Minerals↗