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Geology topics

H. T. Evans

Publications and source records attributed to H. T. Evans.

At least 37 records · Page 2Linked to original sources

Euramerican tonsteins: Overview, magmatic origin, and depositional-tectonic implications

Carboniferous tonsteins (kaolinized volcanic-ash beds) of wide geographic distribution are known in both Europe and North America. Relict volcanic minerals common in these Euramerican tonsteins are volcanic quartz (including beta-quartz paramorphs), zircon and ilmenite; less common are magnetite, fayalite, rutile, monazite, xenotime, apatite and sanidine. Data for two relatively thick (3-13 cm) and widespread (>400 km) European tonsteins (Erda and Sub-Worsley Four-foot) indicate an increase in detrital quartz near the top of the beds which indicates mixing with normal clastic sediments, including the introduction of heavy detrital minerals (e.g., tourmaline and garnet). These thick tonsteins show multiple horizontal bedding, normal graded bedding, disturbed bedding, and centimeter-scale scour surfaces. The Fire Clay tonstein in North America represents from one to five separate volcanic air-fall ash deposits as determined by normal graded bedding and mineralogical analysis. These features indicate several episodes of volcanic-ash deposition and very localized subsequent erosion and bioturbation. Electron microprobe data from glass inclusions in volcanic quartz in Euramerican tonsteins indicate a rhyolitic origin for these tonsteins and reveal chemical "fingerprints" valuable for intra- and inter-basinal correlations. However, the tectonic framework for European and North American tonsteins was quite different. In Europe, volcanic-ash beds were associated with Variscan collisional tectonics, whereas in North America, volcanic ash was associated with Ouachita tectonic activity, explosive volcanism from the Yucatan block, collision between the South American and North American plates, and the formation of Pangea.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

The crystal structure and crystal chemistry of fernandinite and corvusite

Using type material of fernandinite from Minasragra, Peru, and corvusite from the Jack Claim, La Sal Mountains, Utah, the properties and crystal chemistry of these minerals have been determined by Rietveld analysis of the powder X-ray-diffraction patterns. The crystal structure of both species is isotypic with the V2O5 -type layer first found for ??-Ag0.68V2O5; it consists of chains of VO6 octahedra linked by opposite corners (parallel to b) condensed by edge-sharing to form the layer. The vanadium has average valence 4.8, and the resulting layer-charge is balanced by varying amounts of Ca, Na, and K in the interlayer region accompanied by labile water. This study has confirmed the validity of fernandinite as a unique mineral species. It is closely related to corvusite, from which it is distinguished on the basis of the dominant interlayer cation: Ca for fernandinite, Na for curvusite. -Authors

Canadian Mineralogist↗

Heat capacities and entropies of sillimanite, fibrolite, andalusite, kyanite, and quartz and the Al2SiO5 phase diagram

Low-temperature heat capacities for sillimanite, fibrolite, and both fine-grained and coarse-grained quartz have been measured. Superambient heat capacities have been measured for four sillimanite, two andalusite, one kyanite, and two fibrolite samples. Equations are recommended for the temperature dependence of the heat capacities of kyanite, andalusite, sillimanite, and fibrolite. The heat capacity functions have been combined with thermal expansion (fibrolite and sillimanite reported here), enthalpy of solution, and phase equilibrium data in order to construct a phase diagram for the Al2SiO5 polymorphs. -from Authors

American Mineralogist↗

Crystal chemistry of the natural vanadium bronzes

The crystal chemistry of the natural vanadium bronze minerals is reviewed on the basis of published information and new studies (mainly by X-ray powder-diffraction methods) using type material wherever possible. The known V bronze minerals are divided into three categories: 1) the hewettite group, 2) the straczekite group, 3) other structure types including navajoite, schubnelite, fervanite, shcherbinaite, bannermanite, and melanovanadite. All known structures associated with the fibrous V bronzes (fiber spacing 3.6 A??) can be considered as various lateral linkages (into sheets or networks) of only two types of polyvanadate chains: 1) a divanadate chain (V2O6)n consisting of alternating square pyramids, and 2) a tetravanadate chain (V4O12)n consisting of four highly condensed single octahedral chains. -from Authors

American Mineralogist↗

Mineralogical studies of the nitrate deposits of Chile: VI. Hectorfloresite, Na9(IO3)(SO4)4, a new saline mineral

The new mineral hectorfloresite, known to occur in only one locality in the nitrate fields of northern Chile, consists of tiny prismatic crystals, generally less than 1 mm long and 0.2 mm in diameter, in cavities in dense nitrate ore consisting of saline-cemented silt, sand, and small rock fragments. The physical, optical and crystallographic properties of the new mineral are described. -from Authors

American Mineralogist↗

Thermophysical properties of ilvaite CaFe22+Fe3+Si2O7O (OH); heat capacity from 7 to 920 K and thermal expansion between 298 and 856 K

The heat capacity of ilvaite from Seriphos, Greece was measured by adiabatic shield calorimetry (6.4 to 380.7 K) and by differential scanning calorimetry (340 to 950 K). The thermal expansion of ilvaite was also investigated, by X-ray methods, between 308 and 853 K. At 298.15 K the standard molar heat capacity and entropy for ilvaite are 298.9??0.6 and 292.3??0.6 J/(mol. K) respectively. Between 333 and 343 K ilvaite changes from monoclinic to orthorhombic. The antiferromagnetic transition is shown by a hump in Cp0with a Ne??el temperature of 121.9??0.5 K. A rounded hump in Cp0between 330 and 400 K may possibily arise from the thermally activated electron delocalization (hopping) known to take place in this temperature region. ?? 1988 Springer-Verlag.

Physics and Chemistry of Minerals↗

Crystal structure and crystal chemistry of melanovanadite, a natural vanadium bronze.

The crystal structure of melanovanadite from Minas Ragra, Peru, has been determined in space group P1. The triclinic unit cell (non-standard) has a 6.360(2), b 18.090(9), c 6.276(2) A, alpha 110.18(4)o, beta 101.62(3)o, gamma 82.86(4)o. A subcell with b' = b/2 was found by crystal-structure analysis to contain CaV4O10.5H2O. The subcell has a layer structure in which the vanadate sheet consists of corner-shared tetrahedral VO4 and double square-pyramidal V2O8 groups, similar to that previously found in synthetic CsV2O5. Refinement of the full structure (R = 0.056) showed that the Ca atom, which half-occupies a general position in the subcell, is 90% ordered at one of these sites in the whole unit cell. Bond length-bond strength estimates indicate that the tetrahedra contain V5+, and the square pyramids, V4+.-J.A.Z.

American Mineralogist↗

X-ray crystallographic and tungsten-183 nuclear magnetic resonance structural studies of the [M4(H2O)2(XW9O34) 2]10- heteropolyanions (M = COII or Zn, X = P or As)

The crystal structures of K10[Co4(H2O)2(PW9O 34)2]??22H2O (1) and isomorphous K10[Zn4(H2O)2(AsW9O 34)2]??23H2O (2) have been determined {Mo-K?? radiation, space group P21/n, Z = 2; (1) a = 15.794(2), b = 21.360(2), c = 12.312(1) A??, ?? = 91.96??, R = 0.084 for 3 242 observed reflections [I ??? 3??(I)]; (2) a = 15.842(4), b = 21.327(5), c = 12.308(4) A??, ?? = 92.42(4)??, R = 0.066 for 4 675 observed reflections [F ??? 3??(F)]}. The anions have crystallographic symmetry 1 and non-crystallographic symmetry very close to 2/m (C2h). Each consists of two [XW9O34]9- moieties [??-B isomers; X = P (1) or As (2)] linked via four CoIIO6 or ZnO6 groups. Two Co or Zn atoms each carry a water ligand. The 183W n.m.r. spectra of the anions [Zn4(H2O)2(XW9O34) 2]10- (X = P or As) confirm that the anions retain 2/m symmetry in aqueous solution. Homonuclear coupling constants between 183W atoms are 5.8-9.0 Hz for adjacent WO6 octahedra sharing edges, and 19.6-25.0 Hz for octahedra sharing corners.

Journal of the Chemical Society, Dalton Transactio↗

Akermanite: phase transitions in heat capacity and thermal expansion, and revised thermodynamic data.

A small but sharp anomaly in the heat capacity of akermanite at 357.9 K, and a discontinuity in its thermal expansion at 693 K, as determined by XRD, have been found. The enthalpy and entropy assigned to the heat-capacity anomaly, for the purpose of tabulation, are 679 J/mol and 1.9 J/(mol.K), respectively. They were determined from the difference between the measured values of the heat capacity in the T interval 320-365 K and that obtained from an equation which fits the heat-capacity and heat-content data for akermanite from 290 to 1731 K. Heat-capacity measurements are reported for the T range from 9 to 995 K. The entropy and enthalpy of formation of akermanite at 298.15 K and 1 bar are 212.5 + or - 0.4 J/(mol.K) and -3864.5 + or - 4.0 kJ/mol, respectively. Weak satellite reflections have been observed in hk0 single-crystal X-ray precession photographs and electron-diffraction patterns of this material at room T. With in situ heating by TEM, the satellite reflections decreased significantly in intensity above 358 K and disappeared at about 580 K and, on cooling, reappeared. These observations suggest that the anomalies in the thermal behaviour of akermanite are associated with local displacements of Ca ions from the mirror plane (space group P421m) and accompanying distortion of the MgSi2O7 framework.-L.C.C.

Canadian Mineralogist↗

Kassite from the Diamond Jo quarry, Magnet Cove, Hot Spring County, Arkansas: The problem of cafetite and kassite

Small (<0.5 mm), brownish-pink platy rosettes and yellow spherules, in cavities in nepheline syenite at the Diamond Jo quarry, Magnet Cove, Hot Spring County, Arkansas, have been identified as kassite, CaTi 2 O 4 (OH) 2 , a mineral previously known only from the Kola Peninsula, USSR. The Magnet Cove kassite is orthorhombic, in space group Ammm, A2mm, A222 , or A2,22 , with unit-cell parameters a = 12.10, b = 31.65, c = 4.95 Å, and Z = 16; d calc = 3.28 g/cm 3 . Principal X-ray powder lines [ d in Å, ( I )] are 7.85(10), 3.26(7), 2.565(7), 1.910(8), 1.898(6). The X-ray powder and single-crystal data and density correspond to those reported by earlier workers for cafetite, (Ca,Mg)(Fe,Al) 2 Ti 4 O 12 ·4H 2 O, from Kola, but the chemical and physical properties correspond to those given in their description of kassite. These earlier workers may have intermixed samples during their X-ray study of kassite and cafetite.

Arkansas↗

Abhurite, a new tin hydroxychloride mineral, and a comparative study with a synthetic basic tin chloride.

Abhurite is a new mineral species found in blister-like protuberances on the surface of tin ingots submerged at a depth of 35 m in the Red Sea. It forms 1.5 mm diameter hexagonal plates bounded by the negative rhombohedron (0115); is colourless, transparent with opalescent lustre, white streak, hackly fracture, with no cleavage, and H.approx 2; D(calc) 4.34, D(meas) 4.29 g/cm3; epsilon approx 2.11, omega 2.06. Chemical analysis gave 73.4 wt.% Sn, 15.7 Cl, 11.0 0 and 0.4 H. leading to the formula Sn3O(OH)2Cl2. DTA shows release of H2O at 235oC and SnCl2 at 525oC. Indexed XRD powder data are tabulated; prominent lines 2.5313(100), 2.8915(70), 4.139(50), 3.404(50), 2.8175(50) A; a 10.0175(3), c 44.014(2) A; space group R3m, R3m or R32; Z = 21. Comparison is made with a hexagonal synthetic dimorph. The name refers to the geographical origin, an arm of the Red Sea known as Sharm Abhur.-L.T.T.

Canadian Mineralogist↗

Djurleite (Cu1.94S) and low chalcocite (Cu2S): New crystal structure studies

Additional x-ray structure studies on low chalcocite generally confirm the previously reported structure but show that either disorder is present or the true space group is not P 2 1 / c but Pc , four of the 96 copper atoms in the monoclinic unit cell taking on twofold (linear) coordination. The crystal structure of djurleite has been solved in space group P 2 1 / n , the monoclinic cell having parameters a = 26.897, b = 15.745, and c = 13.565 angstroms; β = 90.13 °; and a content of 248 copper and 128 sulfur atoms. Of the 62 different copper atoms in the structure, 52 are in threefold, triangular coordination with sulfur, nine in tetrahedral, and one in linear coordination.

Science↗

The crystal structure and thermal history of orthopyroxene from lunar anorthosite 15415

A single crystal of untwinned orthopyroxene from lunar anorthosite sample 15415, with composition (Mg 1.14 Fe 0.80 Mn 0.02 Ca 0.04 )(Si 1.97 Al 0.03 )O 6 , has a unit cell in space group Pbca with a = 18.310(15)Å, b = 8.904(10)Å, c = 5.214(7)Å, containing 2 formula units. A set of 742 counter-measured intensity data made with MoK α radiation has been used to refine the crystal structure in isotropic thermal mode to R = 0.116. Anisotropic refinement led to R = 0.092, but thermal parameters are distorted by non-random errors resulting from poor crystal texture. The resulting structure is in close agreement with that obtained by Ghose [9] for a hypersthene from Greenland. A parameter q , which gives ( Mg q Fe 1−q ) for cation site M (1) and (Mg 1.14− q Fe q −0.18 Ca 0.04 ) for site M (2), was included in the least-squares analysis, yielding q = 0.90(1). This orthopyroxene has the high degree of cation order expected of pyroxenes subjected to Apollonian metamorphism at lower than 500–600°C. No evidence exists for a subsequent thermal event of sufficient intensity to disorder the pyroxene. On the basis of previous laboratory studies of argon-release patterns of lunar plagioclase and order-disorder kinetics of terrestrial pyroxenes, we attribute the reported isotopic age (3.9–4.1 AE) to cessation of metamorphism, perhaps caused by impact excavation.

Earth and Planetary Science Letters↗

Cell dimensions and antiferromagnetism of lunar and terrestrial ilmenite single crystals

X-Ray diffraction and anisotropic magnetic measurements have been made on single crystals of lunar ilmenite and on terrestrial ilmenite from Bancroft, Ontario, Canada and the Ilmen Mountains, U.S.S.R. The elongated c "> c -axis of lunar ilmenite, previously reported, is confirmed by new measurements. The shorter c "> c -axis found in terrestrial specimens is ascribed to Fe 3+ substitution for Ti 4+ in the titanium layer. Magnetic measurements on the same specimens show that, in agreement with the Ishikawa-Shirane et al . model, the initial shortening of the c "> c -axis by the above substitution of small amounts of Fe 3+ (<8%) causes an increase in Fe 2+ −Fe 2+ exchange coupling through Fe 3+ in the titanium layer that lowers the Néel transition temperature. The Weiss temperatures and other magnetic parameters confirm this model proposed by Ishikawa and Shirane et al . Additional transitions found in one of the terrestrial specimens (Bancroft) have been ascribed to a small amount of an exsolved spinel phase, possibly a solid solution phase of magnetite-ülvospinel. The spinel phase is localized in hematite-rich blebs which exsolved from the host ilmenite-rich phase.

Journal of Physics and Chemistry of Solids↗

Lunar troilite: Crystallography

Fine, euhedral crystals of troilite from lunar sample 10050 show a hexagonal habit consistent with the high-temperature NiAs-type structure. Complete three-dimensional counter intensity data have been measured and used to confirm and refine Bertaut's proposed low-temperature crystal structure.

Science↗