Geology topics

Gilpin R. Robinson

Publications and source records attributed to Gilpin R. Robinson.

At least 19 recordsLinked to original sources

USGS2017

Graphite

Graphite is a form of pure carbon that normally occurs as black crystal flakes and masses. It has important properties, such as chemical inertness, thermal stability, high electrical conductivity, and lubricity (slipperiness) that make it suitable for many industrial applications, including electronics, lubricants, metallurgy, and steelmaking. For some of these uses, no suitable substitutes are available. Steelmaking and refractory applications in metallurgy use the largest amount of produced graphite; however, emerging technology uses in large-scale fuel cell, battery, and lightweight high-strength composite applications could substantially increase world demand for graphite. Graphite ores are classified as “amorphous” (microcrystalline), and “crystalline” (“flake” or “lump or chip”) based on the ore’s crystallinity, grain-size, and morphology. All graphite deposits mined today formed from metamorphism of carbonaceous sedimentary rocks, and the ore type is determined by the geologic setting. Thermally metamorphosed coal is the usual source of amorphous graphite. Disseminated crystalline flake graphite is mined from carbonaceous metamorphic rocks, and lump or chip graphite is mined from veins in high-grade metamorphic regions. Because graphite is chemically inert and nontoxic, the main environmental concerns associated with graphite mining are inhalation of fine-grained dusts, including silicate and sulfide mineral particles, and hydrocarbon vapors produced during the mining and processing of ore. Synthetic graphite is manufactured from hydrocarbon sources using high-temperature heat treatment, and it is more expensive to produce than natural graphite. Production of natural graphite is dominated by China, India, and Brazil, which export graphite worldwide. China provides approximately 67 percent of worldwide output of natural graphite, and, as the dominant exporter, has the ability to set world prices. China has significant graphite reserves, and China’s graphite production is expected to increase, although rising labor costs and some mine production problems are developing. China is expected to continue to be the dominant exporter for the near future. Mexico and Canada export graphite mainly to the United States, which has not had domestic production of natural graphite since the 1950s. Most graphite deposits in the United States are too small, low-grade, or remote to be of commercial value in the near future, and the likelihood of discovering larger, higher-grade, or favorably located domestic deposits is unlikely. The United States is a major producer of synthetic graphite.

Professional Paper↗

USGS2017

New method to integrate remotely sensed hydrothermal alteration mapping into quantitative mineral resource assessments

Hydrothermal alteration data mapped using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) were compiled into hydrothermal alteration polygons for use in an assessment of porphyry copper mineral resource potential in the southwestern United States. Hydrothermal alteration polygons along with geochemistry, gravity and magnetic, lithologic, and deposit and prospects data were compiled in a GIS to produce a quantitative set of physical properties for each polygon that were effectively used in making estimates of undiscovered deposits for each permissive tract. Results show a higher estimate of potential undiscovered deposits (17 vs 14) for permissive tracts when ASTER alteration data were used in the assessment.

Conference Paper↗

USGS2016

Geology and mineral resources of the North-Central Idaho Sagebrush Focal Area: Chapter C in Mineral resources of the Sagebrush Focal Areas of Idaho, Montana, Nevada, Oregon, Utah, and Wyoming

Summary The U.S. Department of the Interior has proposed to withdraw approximately 10 million acres of Federal lands from mineral entry (subject to valid existing rights) from 12 million acres of lands defined as Sagebrush Focal Areas (SFAs) in Idaho, Montana, Nevada, Oregon, Utah, and Wyoming (for further discussion on the lands involved see Scientific Investigations Report 2016–5089–A). The purpose of the proposed action is to protect the greater sage-grouse ( Centrocercus urophasianus ) and its habitat from potential adverse effects of locatable mineral exploration and mining. The U.S. Geological Survey Sagebrush Mineral-Resource Assessment (SaMiRA) project was initiated in November 2015 and supported by the Bureau of Land Management to (1) assess locatable mineral-resource potential and (2) to describe leasable and salable mineral resources for the seven SFAs and Nevada additions. This chapter summarizes the current status of locatable, leasable, and salable mineral commodities and assesses the potential of locatable minerals in the North-Central Idaho SFA, which extends from east-central to south-central Idaho. The geologically complex area is composed of many different rock units that locally contain potential mineral resources.

Idaho↗

USGS2015

Porphyry copper assessment of the Central Asian Orogenic Belt and eastern Tethysides: China, Mongolia, Russia, Pakistan, Kazakhstan, Tajikistan, and India: Chapter X in Global mineral resource assessment

The U.S. Geological Survey collaborated with international colleagues to assess undiscovered resources in porphyry copper deposits in the Central Asian Orogenic Belt and eastern Tethysides. These areas host 20 known porphyry copper deposits, including the world class Oyu Tolgoi deposit in Mongolia that was discovered in the late 1990s. The study area covers major parts of the world’s largest orogenic systems. The Central Asian Orogenic Belt is a collage of amalgamated Precambrian through Mesozoic terranes that extends from the Ural Mountains in the west nearly to the Pacific Coast of Asia in the east and records the evolution and final closure of the Paleo-Asian Ocean in Permian time. The eastern Tethysides, the orogenic belt to the south of the Central Asian Orogenic Belt, records the evolution of another ancient ocean system, the Tethys Ocean. The evolution of these orogenic belts involved magmatism associated with a variety of geologic settings appropriate for formation of porphyry copper deposits, including subduction-related island arcs, continental arcs, and collisional and postconvergent settings. The original settings are difficult to trace because the arcs have been complexly deformed and dismembered by younger tectonic events. Twelve mineral resource assessment tracts were delineated to be permissive for the occurrence of porphyry copper deposits based on mapped and inferred subsurface distributions of igneous rocks of specific age ranges and compositions. These include (1) nine Paleozoic tracts in the Central Asian Orogenic Belt, which range in area from about 60,000 to 800,000 square kilometers (km 2 ); (2) a complex area of about 400,000 km 2 on the northern margin of the Tethysides, the Qinling-Dabie tract, which spans central China and areas to the west, encompassing Paleozoic through Triassic igneous rocks that formed in diverse settings; and (3) assemblages of late Paleozoic and Mesozoic rocks that define two other tracts in the Tethysides, the 100,000 km 2 Jinsajiang tract and the 300,000 km 2 Tethyan-Gangdese tract. Assessment participants evaluated applicable grade and tonnage models and estimated numbers of undiscovered deposits at different confidence levels for each permissive tract. The estimates were then combined with the selected grade and tonnage models using Monte Carlo simulations to generate probabilistic estimates of undiscovered resources. Additional resources in extensions of deposits with identified resources were not specifically evaluated. Assessment results, presented in tables and graphs, show amounts of metal and rock in undiscovered deposits at selected quantile levels of probability (0.95, 0.9, 0.5, 0.1, and 0.05 confidence levels), as well as the arithmetic mean and associated standard deviations and variances for each tract. This assessment estimated a total of 97 undiscovered porphyry copper deposits within the assessed permissive tracts. This represents nearly five times the 20 known deposits. Predicted mean resources that could be associated with these undiscovered deposits are about 370,000,000 metric tons (t) of copper, 10,000 t of gold, 7,700,000 t of molybdenum, and 120,000 t of silver. The assessment area is estimated to contain about five times as much copper in undiscovered deposits as has been identified to date. This report includes a summary of the data used in the assessment, a brief overview of the geologic framework of the area, descriptions of permissive tracts and known deposits, maps, and tables. A geographic information system database that accompanies this report includes the tract boundaries and known porphyry copper deposits, significant prospects, and prospects. Assessments of overlapping younger rocks and adjacent areas are included in separate reports available on-line at http://minerals.usgs.gov/global/ .

Scientific Investigations Report↗

USGS2014

Porphyry copper assessment of Central America and the Caribbean Basin

Mineral resource assessments provide a synthesis of available information about distributions of mineral deposits in the Earth’s crust. The U.S. Geological Survey prepared a probabilistic mineral resource assessment of undiscovered resources in porphyry copper deposits in Central America and the Caribbean Basin in collaboration with geoscientists from academia and the minerals industry. The purpose of the study was to (1) delineate permissive areas (tracts) for undiscovered porphyry copper deposits within 1 kilometer of the surface at a scale of 1:1,000,000; (2) provide a database of known porphyry copper deposits and significant prospects; (3) estimate numbers of undiscovered deposits within the permissive tracts; and (4) provide probabilistic estimates of amounts of copper, molybdenum, gold, and silver that could be contained in undiscovered deposits. The assessment was done using a three-part mineral resource assessment based on established mineral deposit models. Permissive tracts were delineated based primarily on distributions of mapped igneous rocks related to magmatic arcs that formed in tectonic settings associated with convergent plate margins. Five permissive tracts were delineated: the Early Cretaceous through Eocene Santiago tract, the Late Cretaceous through Oligocene Chortis tract, the Paleocene through Oligocene Darién tract, the Miocene and Pliocene Cocos tract, and the Eocene to Holocene Lesser Antilles tract. These tracts range in size from about 3,000 to about 204,000 square kilometers. Probabilistic estimates of numbers of undiscovered deposits were made for all tracts. To estimate the number of undiscovered porphyry copper deposits, data on known mineral deposits, prospects, and occurrences were considered along with mapped alteration zones, local stream-sediment geochemistry, exploration history, descriptive deposit models, and grade and tonnage models. Most porphyry copper exploration in Central America and the Caribbean Basin has focused on Panama and on the exposed Cretaceous to Eocene central Cordilleran arc that extends from Cuba and Jamaica through Haiti and the Dominican Republic to Puerto Rico and the Virgin Islands. Interest in gold has prompted exploration of historical precious-metal prospects and small mines, some of which may represent high-sulfidation epithermal systems or skarns overlying, or adjacent to, porphyry copper systems. This assessment estimated a total mean of 37 undiscovered porphyry copper deposits within the assessed permissive tracts in Central America and the Caribbean Basin. This represents more than five times the seven known deposits. Predicted mean (arithmetic) resources that could be associated with these undiscovered deposits are about 130 million metric tons of copper and about 5,200 metric tons of gold, as well as byproduct molybdenum and silver. The reported identified resources for the seven known deposits total about 39 million metric tons of copper and about 930 metric tons of gold. The assessment area is estimated to contain nearly four times as much copper and six times as much gold in undiscovered porphyry copper deposits as has been identified to date.

Scientific Investigations Report↗

USGS2014

Porphyry copper assessment of eastern Australia

The U.S. Geological Survey (USGS) conducts national and global assessments of resources (mineral, energy, water, and biologic) to provide science in support of decision making. Mineral resource assessments provide syntheses of available information about where mineral deposits are known and suspected to occur in the Earth’s crust and which commodities may be present, together with estimates of amounts of resources that may be present in undiscovered deposits. The USGS collaborated with geologists of the Geological Survey of New South Wales and Geoscience Australia (formerly the Australian Geological Survey Organisation) on an assessment of Phanerozoic-age porphyry copper resources in Australia. Porphyry copper deposits contain about 11 percent of the identified copper resources in Australia. This study addresses resources of known porphyry copper deposits and expected resources of undiscovered porphyry copper deposits in eastern Australia. A three-part form of assessment was used for estimation of undiscovered resources. Using this method, four tracts were delineated that are permissive for porphyry copper deposits. A probabilistic estimate of the expected number of deposits in each tract was prepared on the basis of existing information about geology, geochemistry, geophysics, exploration history, and mineral occurrences. Monte Carlo simulation was used to combine the estimated number of deposits with an appropriate model of grade and tonnage for porphyry copper deposits to provide a probabilistic estimate of metal content and total tonnage for undiscovered deposits. The Delamerian permissive tract comprises igneous rocks of Cambrian age in the Delamerian Orogen, which borders the western margin of the Tasmanides. The Delamerian tract contains no known porphyry copper deposits, but the Adelaide sub-tract, one of three sub-tracts that compose the Delamerian tract, contains four porphyry copper prospects. The Adelaide sub-tract is estimated to contain 2.5±2.2 undiscovered deposits in an area of about 50,700 square kilometers. The Macquarie permissive tract comprises volcanic, volcaniclastic, and minor exposed intrusive igneous rocks of the Macquarie Arc. The nine known deposits in this tract are now estimated to contain a total of about 13.5 million metric tons of copper and 1,700 metric tons of gold. This tract is estimated to contain 6.9±3.5 undiscovered deposits for a total of about 16 deposits in an area of about 41,500 square kilometers. The Yeoval permissive tract includes subequal areas of permissive volcanic and intrusive rocks of Silurian to Devonian age exposed in and around the Cowra-Buchan Rift System, which overlaps the previously accreted Macquarie Arc. The Yeoval tract contains one porphyry copper deposit and several porphyry copper prospects. This tract is estimated to contain 1.3±0.75 undiscovered porphyry copper deposits, for a total of about 2 expected deposits in an area of about 53,200 square kilometers. The East Tasmanide permissive tract includes a semi-continuous belt of plutonic and subordinate volcanic rocks along the eastern margins of Queensland and northeastern New South Wales. The East Tasmanide tract contains 14 known porphyry copper deposits and many porphyry copper prospects, which are all in the Central sub-tract. This sub-tract is expected to contain 4.8±3.3 undiscovered porphyry copper deposits, for a total of about 19 deposits in an area of about 291,000 square kilometers. This assessment estimates that 15 undiscovered deposits contain an arithmetic mean of ~21 million metric tons or more of copper in four tracts, in addition to the 24 known porphyry copper deposits that contain identified resources of ~16 million metric tons of copper. In addition to copper, the mean expected amount of undiscovered byproduct gold predicted by the simulation is ~1,500 metric tons. The probability associated with these arithmetic means is on the order of 30 percent. Median expected amounts of metals predicted by the simulations may be ~50 percent lower than mean estimates.

Scientific Investigations Report↗

USGS2014

Porphyry copper assessment of East and Southeast Asia: Philippines, Taiwan (Republic of China), Republic of Korea (South Korea), and Japan

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of East and Southeast Asia as part of a global mineral resource assessment. The assessment covers the Philippines in Southeast Asia, and the Republic of Korea (South Korea), Taiwan (Province of China), and Japan in East Asia. The Philippines host world class porphyry copper deposits, such as the Tampakan and Atlas deposits. No porphyry copper deposits have been discovered in the Republic of Korea (South Korea), Taiwan (Province of China), or Japan. Thirteen geographic areas were delineated as tracts that are permissive for porphyry copper deposits in the assessed area. Individual tracts range from about 3,000 to 100,000 square kilometers in area. Permissive tracts are delineated on the basis of mapped distributions of igneous rocks of specific age ranges that define subduction-related magmatic arcs or magmatic belts that might contain porphyry copper deposits. Most of these magmatic arcs are subduction related, although some porphyry deposits and prospects are present in back-arc or poorly understood tectonic settings. Maps at various scales were used in the compilation; however, the final tract boundaries are intended for use at a scale of 1:1,000,000. Numbers of undiscovered deposits were estimated at different levels of confidence for 10 permissive tracts in the Philippines including one area that extends to eastern Taiwan (Republic of China); permissive tracts in South Korea and Japan are discussed qualitatively. Estimates of numbers of undiscovered deposits were combined with grade and tonnage models using Monte Carlo simulation to estimate amounts of undiscovered resources. Grades and tonnages of known porphyry copper deposits in the study area were compared with global grade and tonnage models to determine the appropriate model for simulation of undiscovered resources. Most of the known deposits are best described as copper-gold subtypes of porphyry copper deposits. For some permissive tracts, a general porphyry copper-gold-molybdenum model was used. Thirty-eight porphyry copper deposits are known in the Philippines; the mean number of undiscovered deposits was estimated to be 28. Mean (arithmetic) resources that could be associated with the undiscovered deposits are 90 million metric tons of copper and 5,800 metric tons of gold, as well as byproduct molybdenum and silver. Additional resources that could be discovered in extensions to known deposits were not evaluated. Assessment results, presented in tables and graphs, indicate expected amounts of total contained metal and mineralized rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. The Philippines have a long history of porphyry exploration cycles and mine development, interrupted at times by political and social unrest, environmental concerns, and natural disasters. Changes in mining laws within the region and the recent high price of gold on the world market have prompted renewed interest in porphyry copper deposits in the region. South Korea and Japan have been thoroughly explored for many types of mineral deposits. Available data suggest that the permissive rocks in South Korea typically are too deeply eroded to preserve porphyry copper deposits. Porphyry copper systems may be present in Japan, but are likely to lie at depths greater than the 1 kilometer from the surface protocol adopted for this study. Descriptions of the geologic basis for delineating each tract, the data used, the geologic criteria and rationale for the assessment, and results of the assessment are included in appendixes along with the description of a geographic information system (GIS) that includes tract boundaries, known porphyry copper deposits and significant prospects, and assessment results.

Scientific Investigations Report↗

USGS2014

Sandstone copper assessment of the Teniz Basin, Kazakhstan

The U.S. Geological Survey (USGS) conducts national and global resource assessments (mineral, energy, water, and biological) to provide data and scientific analyses to support decision making. Three-part mineral resource assessments result in informed, unbiased, quantitative, and probabilistic estimates of undiscovered mineral resources and deposits. In particular, mineral assessment results inform decisions concerning land-use and mineral-resource development. A probabilistic mineral resource assessment of the sandstone subtype of sediment-hosted stratabound copper deposits in the Teniz Basin, Kazakhstan, was undertaken by the USGS. The Teniz Basin is located in Akmola Oblast, central and western Kazakhstan. With an areal extent of almost 78,000 km 2 , the basin contains many sediment-hosted stratabound copper prospects, none of which are well described, and the majority of which may belong to the sandstone subtype of sediment-hosted copper deposits. There are no known locations within the Teniz Basin currently mined for copper. Within the basin, however, map units permissive for the sandstone subtype of sediment-hosted stratabound copper deposits include (from oldest to youngest): the Middle Carboniferous Kiery Suite; the Middle to Upper Carboniferous Vladimirov Suite (a stratigraphic equivalent of the Dzhezkazgan Suite, Chu-Sarysu Basin); and the Upper Carboniferous or lowest Permian Kayraktin Suite. The multicolored sedimentary rocks of the Vladimirov Suite, in which 14 potentially ore-bearing horizons of gray beds have been recorded, have the greatest potential for undiscovered, sandstone subtype, sediment-hosted stratabound copper deposits. A quantitative mineral resource assessment has been completed that (1) delineates one 49,714 km 2 tract permissive for undiscovered, sandstone subtype, sediment-hosted stratabound copper deposits, and (2) provides probabilistic estimates of numbers of undiscovered deposits and probable amounts of copper resource contained in those deposits. The permissive tract delineated in this assessment encompasses no previously known sandstone subtype, sediment-hosted stratabound copper deposits. However, this assessment estimates (with 30 percent probability) that a mean of nine undiscovered sandstone subtype copper deposits may be present in the Teniz Basin and could contain a mean total of 8.9 million metric tons of copper and 7,500 metric tons of silver.

Teniz Basin↗

USGS2013

A comparison of data-driven groundwater vulnerability assessment methods

Increasing availability of geo-environmental data has promoted the use of statistical methods to assess groundwater vulnerability. Nitrate is a widespread anthropogenic contaminant in groundwater and its occurrence can be used to identify aquifer settings vulnerable to contamination. In this study, multivariate Weights of Evidence (WofE) and Logistic Regression (LR) methods, where the response variable is binary, were used to evaluate the role and importance of a number of explanatory variables associated with nitrate sources and occurrence in groundwater in the Milan District (central part of the Po Plain, Italy). The results of these models have been used to map the spatial variation of groundwater vulnerability to nitrate in the region, and we compare the similarities and differences of their spatial patterns and associated explanatory variables. We modify the standard WofE method used in previous groundwater vulnerability studies to a form analogous to that used in LR; this provides a framework to compare the results of both models and reduces the effect of sampling bias on the results of the standard WofE model. In addition, a nonlinear Generalized Additive Model has been used to extend the LR analysis. Both approaches improved discrimination of the standard WofE and LR models, as measured by the c -statistic. Groundwater vulnerability probability outputs, based on rank-order classification of the respective model results, were similar in spatial patterns and identified similar strong explanatory variables associated with nitrate source (population density as a proxy for sewage systems and septic sources) and nitrate occurrence (groundwater depth).

Milan District↗

USGS2013

Porphyry copper assessment of Southeast Asia and Melanesia: Chapter D in Global mineral resource assessment

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of Southeast Asia and Melanesia as part of a global mineral resource assessment. The region hosts world-class porphyry copper deposits and underexplored areas that are likely to contain undiscovered deposits. Examples of known porphyry copper deposits include Batu Hijau and Grasberg in Indonesia; Panguna, Frieda River, and Ok Tedi in Papua New Guinea; and Namosi in Fiji. This assessment covers the countries of Cambodia, Indonesia, Lao People’s Democratic Republic, Malaysia, Myanmar, Papua New Guinea, Singapore, Thailand, and parts of southeastern China, India, the Solomon Islands, Vanuatu, and Fiji. Twenty-two geographic areas were delineated as tracts that are permissive for porphyry copper deposits in Southeast Asia. Permissive tracts are grouped into four broadly defined geographic/geologic areas, as follows: (1) the Indochina Peninsula area, (2) Indonesian and Malaysian Islands, (3) New Guinea Island and Papuan New Guinea islands, and (4) Melanesia. Individual tracts range from less than 1,000 to more than 350,000 square kilometers in area. Permissive tracts are based on mapped and inferred subsurface (<1 kilometer depth) distributions of igneous rocks of specific age ranges that define magmatic arcs and magmatic belts that are likely to contain porphyry copper deposits. Most of these magmatic arcs are subduction-related, although some have porphyry-style deposits occurring in postcollisional and (or) poorly understood tectonic settings. Although maps at a variety of different scales were used in the compilation, the final tract boundaries are intended for use at a scale of 1:1,000,000. Global grade and tonnage models for porphyry copper deposits were evaluated. Most of the known deposits are best described as fitting the copper-gold (Cu-Au) subtype of porphyry copper deposit. For some permissive tracts, a general porphyry copper-gold-molybdenum (Cu-Au-Mo) model was used. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for most of the permissive tracts. These estimates were combined with grade and tonnage models using a Monte Carlo simulation to estimate undiscovered resources. Additional resources in extensions of deposits with identified resources were not evaluated. Assessment results, presented in tables and graphs, show mean amounts of metal and mineralized rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. This assessment estimated a mean of 89 undiscovered porphyry copper deposits for the assessed permissive tracts in Southeast Asia and Melanesia. About 288 million metric tons (Mt) of copper and 18,000 metric tons (t) of gold, as well as byproduct molybdenum and silver, could be associated with undiscovered deposits. This represents about four times the number of deposits with identified resources (23) already discovered in Southeast Asia; reliable reported identified resources for those 23 deposits total 84 Mt of copper and 6,000 t of gold. Eleven permissive tracts have no known porphyry copper deposits with reported resources. Three of those 11 tracts lacked sufficient information for a probabilistic assessment and are discussed in qualitative terms. On a regional basis, both the Indochina Peninsula area and the Indonesian-Malaysian Islands area are estimated to contain about 10 times as much in place copper in undiscovered porphyry copper deposits as has been identified to date. For the New Guinea Island areas, the ratio of undiscovered to identified copper resources is about 2. Some parts of the region have a long history of porphyry exploration cycles and mine development, interrupted at times by political and social unrest, environmental concerns, and natural disasters. Changes in mining laws within the region and the recent high price of gold on the world market have prompted renewed interest in porphyry copper deposits in Southeast Asia and Melanesia. However, predicted undiscovered deposits may not be found, and if found, may not be developed. This assessment includes an overview of the assessment results with summary tables. Detailed descriptions of each tract are included in appendixes, with estimates of numbers of undiscovered deposits, and probabilistic estimates of amounts of copper, molybdenum, gold, and silver that could be contained in undiscovered deposits for each permissive tract. A geographic information system (GIS) that accompanies the report includes tract boundaries and a database of known porphyry copper deposits and significant prospects.

Scientific Investigations Report↗

USGS2012

Quality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007

Crystalline bedrock aquifers in New England and parts of New Jersey and New York (NECR aquifers) are a major source of drinking water. Because the quality of water in these aquifers is highly variable, the U.S. Geological Survey (USGS) statistically analyzed chemical data on samples of untreated groundwater collected from 117 domestic bedrock wells in New England, New York, and New Jersey, and from 4,775 public-supply bedrock wells in New England to characterize the quality of the groundwater. The domestic-well data were from samples collected by the USGS National Water-Quality Assessment (NAWQA) Program from 1995 through 2007. The public-supply-well data were from samples collected for the U.S. Environmental Protection Agency (USEPA) Safe Drinking Water Act (SDWA) Program from 1997 through 2007. Chemical data compiled from the domestic wells include pH, specific conductance, dissolved oxygen, alkalinity, and turbidity; 6 nitrogen and phosphorus compounds, 14 major ions, 23 trace elements, 222 radon gas (radon), 48 pesticide compounds, and 82 volatile organic compounds (VOCs). Additional samples were collected from the domestic wells for the analysis of gross alpha- and gross beta-particle radioactivity, radium isotopes, chlorofluorocarbon isotopes, and the dissolved gases methane, carbon dioxide, nitrogen, and argon. Chemical data compiled from the public-supply wells include pH, specific conductance, nitrate, iron, manganese, sodium, chloride, fluoride, arsenic, uranium, radon, combined radium ( 226 radium plus 228 radium), gross alpha-particle radioactivity, and methyl tert -butyl ether (M t BE). Patterns in fluoride, arsenic, uranium, and radon distributions were discernable when the data were compared to lithology groupings of the bedrock, indicating that the type of bedrock has an effect on the quality of groundwater from NECR aquifers. Fluoride concentrations were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and metaluminous granite lithology groups than from samples in the other lithology groups. Water samples from 1.4 percent of 2,167 studied wells had fluoride concentrations that were equal to or greater than the maximum contaminant level (MCL) of 4 milligrams per liter (mg/L) and 7.5 percent of the wells had fluoride concentrations that were equal to or greater than the secondary MCL of 2 mg/L. For arsenic, groundwater samples from the calcareous metasedimentary rocks in the New Hampshire-Maine geologic province, peraluminous granite, and pelitic rocks lithology groups had higher concentrations than did samples from the other lithology groups. Water samples from 13.3 percent of 2,054 studied wells had arsenic concentrations that were equal to or greater than the MCL of 10 micrograms per liter (μg/L), about double the national rate of occurrence in community-supply systems and in domestic wells of the United States. Uranium concentrations were significantly higher in groundwater samples from the peraluminous granite, alkali granite, and calcareous metasedimentary rocks in the New Hampshire-Maine geologic province lithology groups than from samples in the other lithology groups. Water samples from 14.2 percent of 556 studied wells had uranium concentrations equal to or greater than the MCL of 30 μg/L. Radon activities were equal to or greater than the proposed MCL of 300 picocuries per liter (pCi/L) in 95 percent of 943 studied wells, and 33 percent of the wells had radon activities were equal to or greater than the proposed alternative maximum contaminant level (AMCL) of 4,000 pCi/L. Radon activities exceeded the proposed AMCL in 20 percent or more of groundwater samples in each of the studied lithology groups with a minimum of 9 samples, but radon activities were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and Narragansett basin metasedimentary rocks lithology groups. Water samples from 3.2 percent of 564 studied wells had combined radium activities equal to or greater than the MCL of 5 pCi/L; however, combined radium activities were not significantly different among the studied lithology groups. Land use and population density also were evaluated to explain patterns in water quality. Concentrations of nitrate, sodium, chloride, and MtBE from the studied wells were significantly greater in areas of high population density (≥50 persons per square kilometer) than in areas of low population density (<50 persons per square kilometer). Concentrations of sodium, chloride, and M t BE from the studied wells were significantly greater in areas classified as developed (urban lands) than in areas classified as undeveloped (forested), agricultural, or mixed (no dominant land use). Nitrate concentrations from the public-supply wells were not significantly different among the four land use categories, but nitrate concentrations from the domestic wells were significantly greater in areas classified as developed than in areas classified as undeveloped, agricultural, or mixed. Chloride to bromide mass ratios in the domestic well samples indicate that the groundwater was probably affected by at least three halogen sources: local precipitation and recharge waters, remnant seawater and connate waters evolved from seawater, and recharge waters affected by road salt. The groundwater in the NECR aquifers generally contained low concentrations of nitrate, VOCs, and pesticides. Less than 1 percent of water samples from 4,781 studied wells had concentrations of nitrate greater than the MCL of 10 mg/L. Less than 1 percent of water samples from 1,299 studied wells exceeded the USEPA advisory level of 20 to 40 μg/L for M t BE. None of the other studied VOCs exceeded a human health benchmark. M t BE (36 percent frequency detection) and chloroform (32.9 percent frequency detection) were the most frequently detected (>0.02 μg/L) VOCs in the domestic wells. M t BE was detected more often in water samples with apparent ages of less than 25 years than in water samples with apparent ages greater than 25 years. This finding is consistent with the time period of high M t BE use in areas in the United States where reformulated gasoline was mandated. The largest pesticide concentration was an estimated concentration of 0.06 μg/L for the herbicide metolachlor. Deethylatrazine, a degradate of atrazine, (18 percent frequency detection) and atrazine (8 percent frequency detection) were the only pesticide compounds detected (>0.001 μg/L) in more than 3 percent of the domestic wells. None of the detected pesticide compounds exceeded human health benchmarks. Concentrations of nitrate and gross alpha-particle activities were significantly greater in the water samples from the domestic wells than in samples from the public-supply wells. Concentrations of sodium, chloride, iron, manganese, and uranium were significantly greater in the water samples from the public-supply wells than in the samples from the domestic wells. One possible explanation may be related to differences in field processing (filtered samples from the domestic wells compared to unfiltered samples from the public-supply wells). The high frequency of detections for a wide variety of manmade and naturally occurring contaminants in both domestic and public-supply wells shows the vulnerability of NECR aquifers to contamination. The highly variable water quality and the association with highly variable lithology of crystalline bedrock underscores the importance of testing individual wells to determine if concentrations for the most commonly detected contaminants exceed human health benchmarks.

Connecticut, Maine, Massachusetts, New Hampshire, ↗

USGS2012

Porphyry copper assessment of the Tibetan Plateau, China: Chapter F in Global mineral resource assessment

The U.S. Geological Survey collaborated with the China Geological Survey to conduct a mineral-resource assessment of resources in porphyry copper deposits on the Tibetan Plateau in western China. This area hosts several very large porphyry deposits, exemplified by the Yulong and Qulong deposits, each containing at least 7,000,000 metric tons (t) of copper. However, large parts of the area are underexplored and are likely to contain undiscovered porphyry copper deposits. Three tracts were delineated as permissive for porphyry copper deposits on the Tibetan Plateau—the Yulong (Eocene and Oligocene), Dali (Eocene through Miocene), and Gangdese (Oligocene and Miocene) tracts. The tracts were defined based on mapped and inferred subsurface distributions of igneous rocks of specific age ranges in which the occurrence of porphyry copper deposits is possible. These tracts range in area from about 95,000 to about 240,000 square kilometers. Although maps of different scales were used in the assessment, the final tract boundaries are intended for use at a scale of 1:1,000,000. The deposits on the Tibetan Plateau all formed in a post-subduction environment, one newly recognized as permissive for the occurrence of porphyry copper deposits. Based on the grade, tonnage, and geologic characteristics of the known deposits, two tracts, Yulong and Gangdese, were evaluated using the general (Cu-Mo-Au) porphyry copper grade and tonnage model. The Dali tract was evaluated using the gold-rich (Cu-Au) submodel. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for each permissive tract. These estimates were then combined with the selected grade and tonnage models using Monte Carlo simulation to generate quantitative probabilistic estimates of undiscovered resources. Additional resources in extensions of deposits with identified resources were not specifically evaluated. Assessment results, presented in tables and graphs, show mean expected amounts of metal and rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. This assessment estimated a mean of 39 undiscovered porphyry copper deposits within the assessed permissive tracts on the Tibetan Plateau. This represents nearly four times the number of known deposits (11) already discovered. Predicted mean (arithmetic) resources that could be associated with the undiscovered deposits are about 145,000,000 t of copper and about 4,900 t of gold, as well as byproduct molybdenum and silver. Reliable reports of the identified resources in the 11 known deposits total about 27,000,000 t of copper and about 800 t of gold. Therefore, based on the assessments of undiscovered Tibetan Plateau resources in this report, about six times as much copper may occur in undiscovered porphyry copper deposits as has been identified to date.

Tibetan Plateau↗

USGS2012

Porphyry copper assessment of the Mesozoic of East Asia: China, Vietnam, North Korea, Mongolia, and Russia: Chapter G in Global mineral resource assessment

The U.S. Geological Survey (USGS) collaborated with the China Geological Survey (CGS) to conduct a mineral resource assessment of Mesozoic porphyry copper deposits in East Asia. This area hosts several very large porphyry deposits, exemplified by the Dexing deposit in eastern China that contains more than 8,000,000 metric tons of copper. In addition, large parts of the area are undergoing active exploration and are likely to contain undiscovered porphyry copper deposits. Three tracts were delineated to be permissive for Mesozoic porphyry copper deposits in East Asia: the Manchuride, Coastal Pacific, and East Qinling tracts, all Jurassic through Cretaceous in age. The tracts are based on mapped and inferred subsurface distributions of igneous rocks that define areas where the occurrence of porphyry copper deposits is possible. These tracts range in area from about 170,000 to about 1,400,000 km 2 . Although maps at a variety of scales were used in the assessment, the final tract boundaries are intended for use at a scale of 1:1,000,000. These Mesozoic deposits in East Asia all formed in post-subduction environments, environments newly recognized as permissive for the occurrence of porphyry copper deposits. Based on the grade, tonnage, and geologic characteristics of the known deposits, two tracts, Manchuride and Coastal Pacific, were evaluated using the general (Cu-Mo-Au) porphyry copper grade and tonnage model. The East Qinling tract was evaluated using the molybdenum-rich (Cu-Mo) model. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for each permissive tract. These estimates were then combined with the selected grade and tonnage models using Monte Carlo simulation to generate quantitative probabilistic estimates of undiscovered resources. Resources in future extensions of deposits with identified resources were not specifically evaluated. Assessment results, presented in tables and graphs, show mean amounts of metal and rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. This assessment estimated a mean total of about 44 undiscovered porphyry copper deposits within the assessed permissive tracts in East Asia. This represents nearly 4 times the 12 known deposits. Predicted mean (arithmetic) resources that could be associated with these undiscovered deposits are about 198,000,000 metric tons (t) of copper and about 3,900 t of gold, as well as byproduct molybdenum and silver. The reported identified resources for those 12 known deposits total about 23,000,000 t of copper and about 850 t of gold. The assessment area is estimated to contain nearly nine times as much copper in undiscovered porphyry copper deposits as has been identified to date. This report includes an overview of the assessment results and summary tables. Descriptions of each tract are included in appendixes, with estimates of numbers of undiscovered deposits, and probabilistic estimates of amounts of copper, molybdenum, gold, and silver that could be contained in undiscovered deposits for each permissive tract. A geographic information system that accompanies the report includes tract boundaries and a database of known porphyry copper deposits and prospects.

Scientific Investigations Report↗

USGS2012

Economic filters for evaluating porphyry copper deposit resource assessments using grade-tonnage deposit models, with examples from the U.S. Geological Survey global mineral resource assessment: Chapter H in Global mineral resource assessment

An analysis of the amount and location of undiscovered mineral resources that are likely to be economically recoverable is important for assessing the long-term adequacy and availability of mineral supplies. This requires an economic evaluation of estimates of undiscovered resources generated by traditional resource assessments (Singer and Menzie, 2010). In this study, simplified engineering cost models were used to estimate the economic fraction of resources contained in undiscovered porphyry copper deposits, predicted in a global assessment of copper resources. The cost models of Camm (1991) were updated with a cost index to reflect increases in mining and milling costs since 1989. The updated cost models were used to perform an economic analysis of undiscovered resources estimated in porphyry copper deposits in six tracts located in North America. The assessment estimated undiscovered porphyry copper deposits within 1 kilometer of the land surface in three depth intervals. The results of the updated engineering cost model analysis for open-pit porphyry copper deposits are in agreement with the grade-tonnage boundary defining positive economic returns for copper deposits developed between 1989 and 2008. This correspondence demonstrates that the updated engineering cost equations are performing well and appear to be appropriate to evaluate the economic status of open-pit porphyry copper mines under current, and potentially future, economic conditions. Economic filters based on these simplified engineering cost models provide a method for estimating potential tonnages of undiscovered metals that may be economic in individual assessment areas. One implication of the economic filter results for undiscovered copper resources is that global copper supply will continue to be dominated by production from a small number of giant deposits. This domination of resource supply by a small number of producers may increase in the future, because an increasing proportion of new deposit discoveries are likely to occur in remote areas and be concealed deep beneath covering rock and sediments. Extensive mineral exploration activity will be required to meet future resource demand, because these deposits will be harder to find and more costly to mine than near-surface deposits located in more accessible areas. Relatively few of the new deposit discoveries in these high-cost settings will have sufficient tonnage and grade characteristics to assure positive economic returns on development and exploration costs.

Scientific Investigations Report↗

USGS2010

Global mineral resource assessment: porphyry copper assessment of Mexico: Chapter A in Global mineral resource assessment

Mineral resource assessments provide a synthesis of available information about distributions of mineral deposits in the Earth’s crust. A probabilistic mineral resource assessment of undiscovered resources in porphyry copper deposits in Mexico was done as part of a global mineral resource assessment. The purpose of the study was to (1) delineate permissive areas (tracts) for undiscovered porphyry copper deposits within 1 km of the surface at a scale of 1:1,000,000; (2) provide a database of known porphyry copper deposits and significant prospects; (3) estimate numbers of undiscovered deposits within those permissive tracts; and (4) provide probabilistic estimates of amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) that could be contained in undiscovered deposits for each permissive tract. The assessment was conducted using a three-part form of mineral resource assessment based on mineral deposit models (Singer, 1993). Delineation of permissive tracts primarily was based on distributions of mapped igneous rocks related to magmatic arcs that formed in tectonic settings associated with subduction boundary zones. Using a GIS, map units were selected from digital geologic maps based on lithology and age to delineate twelve permissive tracts associated with Jurassic, Laramide (~90 to 34 Ma), and younger Tertiary magmatic arcs. Stream-sediment geochemistry, mapped alteration, regional aeromagnetic data, and exploration history were considered in conjunction with descriptive deposit models and grade and tonnage models to guide estimates. The 12 permissive tracts delineated for this assessment are grouped by age (Jurassic-Early Cretaceous, Laramide (~90 to 34 Ma), Tertiary) and range in size from ~3,000 to 184,000 km 2 . Probabilistic estimates of numbers of undiscovered deposits were made for 10 tracts. A qualitative discussion is included for one Jurassic tract that extends into the U.S. from northern Mexico, and a preliminary outline of the northernmost part of a Tertiary tract that continues well to the south of Mexico is included in summary figures for reference. This assessment estimates that 39 undiscovered deposits contain an arithmetic mean estimate of ~144 million metric tons of copper or more in ten tracts for which probabilistic estimates were made, in addition to 21 porphyry copper deposits that contain identified resources of ~52 million metric tons of copper. Approximately 70 percent of the estimated mean undiscovered copper resources are associated with permissive tracts that contain identified resources; the remaining estimated resources are associated with permissive tracts with no reported porphyry copper resources. In addition to copper, the mean expected values of undiscovered byproduct resources predicted by the simulation are ~4 million metric tons of molybdenum, ~48 thousand metric tons of silver, and 4 thousand metric tons of gold. The probability associated with these arithmetic means is on the order of 30 percent. Median expected amounts of metals predicted by the simulations may be ~50 percent lower than mean estimates, and in some cases, zero. For tracts that contain identified resources, the ratios of undiscovered to identified copper resources indicate that: Jurassic-Early Cretaceous tracts MX-J1 and MX-J2 contain fewer estimated undiscovered copper resources (ratios <1) than identified resources; Laramide tract MX-L1 may contain significantly more copper than has been identified; Laramide tract MX-L2, the tract that contains most of the known deposits in Mexico, including the world-class deposits at Cananea and La Caridad, may contain about as much copper, molybdenum, and silver in undiscovered deposits and more gold than has been identified; Tertiary tracts MX-T1 and MX-T2, where no porphyry copper deposits are known, may contain undiscovered deposits; Tertiary tract MX-T3 may contain about three times more copper than has been identified; and Permissive tracts with no known deposits (MX-J3, MX-J5, MX-L3, MX-T1, MX-T2) contain approximately 30 percent of the total estimated undiscovered copper resources. Most porphyry copper exploration in Mexico focused on the exposed northern parts of the Laramide arc. This assessment suggests that the exposed and shallowly buried (<1 km) parts of the Laramide and Tertiary arcs delineated as permissive tracts are more likely to contain undiscovered deposits than are older (Jurassic-Early Cretaceous) arc segments. Interest in gold has prompted exploration of historical precious metal prospects and small mines in Mexico, some of which may represent high-sulfidation epithermal systems overlying or adjacent to porphyry copper systems. This report includes a brief overview of porphyry copper deposits in Mexico, a description of the assessment process used, a summary of results, and appendixes. Appendixes A through K contain summary information for each tract, as follows: location, the geologic feature assessed, the rationale for tract delineation, tables and descriptions of known deposits and significant prospects, exploration history, model selection, rationale for the estimates, assessment results, and references. The accompanying digital map files (shapefiles) provide permissive tract outlines, assessment results, and data for deposits and prospects in a GIS format (appendix L).

Scientific Investigations Report↗

USGS2008

Framework for Evaluating Water Quality of the New England Crystalline Rock Aquifers

Little information exists on regional ground-water-quality patterns for the New England crystalline rock aquifers (NECRA). A systematic approach to facilitate regional evaluation is needed for several reasons. First, the NECRA are vulnerable to anthropogenic and natural contaminants such as methyl tert-butyl ether (MTBE), arsenic, and radon gas. Second, the physical characteristics of the aquifers, termed 'intrinsic susceptibility', can lead to variable and degraded water quality. A framework approach for characterizing the aquifer region into areas of similar hydrogeology is described in this report and is based on hypothesized relevant physical features and chemical conditions (collectively termed 'variables') that affect regional patterns of ground-water quality. A framework for comparison of water quality across the NECRA consists of a group of spatial variables related to aquifer properties, hydrologic conditions, and contaminant sources. These spatial variables are grouped under four general categories (features) that can be mapped across the aquifers: (1) geologic, (2) hydrophysiographic, (3) land-use land-cover, and (4) geochemical. On a regional scale, these variables represent indicators of natural and anthropogenic sources of contaminants, as well as generalized physical and chemical characteristics of the aquifer system that influence ground-water chemistry and flow. These variables can be used in varying combinations (depending on the contaminant) to categorize the aquifer into areas of similar hydrogeologic characteristics to evaluate variation in regional water quality through statistical testing.

Open-File Report↗

USGS2007

Assessment of contamination from arsenical pesticide use on orchards in the great valley region, Virginia and West Virginia, USA

Lead arsenate pesticides were widely used in apple orchards from 1925 to 1955. Soils from historic orchards in four counties in Virginia and West Virginia contained elevated concentrations of As and Pb, consistent with an arsenical pesticide source. Arsenic concentrations in approximately 50% of the orchard site soils and approximately 1% of reference site soils exceed the USEPA Preliminary Remediation Goal (PRG) screening guideline of 22 mg kg-1 for As in residential soi, defined on the basis of combined chronic exposure risk. Approximately 5% of orchard site soils exceed the USEPA PRG for Pb of 400 mg kg-1 in residential soil; no reference site soils sampled exceed this value. A variety of statistical methods were used to characterize the occurrence, distribution, and dispersion of arsenical pesticide residues in soils, stream sediments, and ground waters relative to landscape features and likely background conditions. Concentrations of Zn, Pb, and Cu were most strongly associated with high developed land density and population density, whereas elevated concentrations of As were weakly correlated with high orchard density, consistent with a pesticide residue source. Arsenic concentrations in ground water wells in the region are generally <0.005 mg L-1. There was no spatial association between As concentrations in ground water and proximity to orchards. Arsenic had limited mobility into ground water from surface soils contaminated with arsenical pesticide residues at concentrations typically found in orchards.

Journal of Environmental Quality↗

USGS2007

Rock-Bound Arsenic Influences Ground Water and Sediment Chemistry Throughout New England

The information in this report was presented at the Northeastern Region Geological Society of America meeting held March 11-14, 2007, in Durham, New Hampshire. In the New England crystalline bedrock aquifer, concentrations of arsenic that exceed the drinking water standard of 10 ?g/L occur most frequently in ground water from wells sited in specific metamorphic and igneous rock units. Geochemical investigations indicate that these geologic units typically have moderately elevated whole-rock concentrations of arsenic compared to other rocks in the region. The distribution of ground water wells with As > 5 ?g/L has a strong spatial correlation with specific bedrock units where average whole-rock concentrations of arsenic exceed 1.1 mg/kg and where geologic and geochemical factors produce high pH ground water. Arsenic concentrations in stream sediments collected from small drainages reflect the regional distribution of this natural arsenic source and have a strong correlation with both rock chemistry and the distribution of bedrock units with elevated arsenic chemistry. The distribution of ground water wells with As > 5 ?g/L has a strong spatial correlation with the distribution of stream sediments where concentrations of arsenic exceed 6 mg/kg. Stream sediment chemistry also has a weak correlation with the distribution of agricultural lands where arsenical pesticides were used on apple, blueberry, and potato crops. Elevated arsenic concentrations in bedrock wells, however, do not correlate with agricultural areas where arsenical pesticides were used. These results indicate that both stream sediment chemistry and the solubility and mobility of arsenic in ground water in bedrock are influenced by host-rock arsenic concentrations. Stream sediment chemistry and the distribution of geologic units have been found to be useful parameters to predict the areas of greatest concern for elevated arsenic in ground water and to estimate the likely levels of human exposure to elevated arsenic in drinking water in New England. However, the extreme local variability of arsenic concentrations in ground water from these rock sources indicate that arsenic concentrations in ground water are affected by other factors in addition to arsenic concentrations in rock.

Open-File Report↗