Search USGS⌕ Search

Geology topics

George E. Groschen

Publications and source records attributed to George E. Groschen.

9 recordsLinked to original sources
USGS2009

Occurrence and distribution of iron, manganese, and selected trace elements in ground water in the glacial aquifer system of the northern United States

Dissolved trace elements, including iron and manganese, are often an important factor in use of ground water for drinking-water supplies in the glacial aquifer system of the United States. The glacial aquifer system underlies most of New England, extends through the Midwest, and underlies portions of the Pacific Northwest and Alaska. Concentrations of dissolved trace elements in ground water can vary over several orders of magnitude across local well networks as well as across regions of the United States. Characterization of this variability is a step toward a regional screening-level assessment of potential human-health implications. Ground-water sampling, from 1991 through 2003, of the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey determined trace element concentrations in water from 847 wells in the glacial aquifer system. Dissolved iron and manganese concentrations were analyzed in those well samples and in water from an additional 743 NAWQA land-use and major-aquifer survey wells. The samples are from monitoring and water-supply wells. Concentrations of antimony, barium, beryllium, cadmium, chromium, cobalt, copper, iron, lead, manganese, molybdenum, nickel, selenium, strontium, thallium, uranium, and zinc vary as much within NAWQA study units (local scale; ranging in size from a few thousand to tens of thousands of square miles) as over the entire glacial aquifer system. Patterns of trace element concentrations in glacial aquifer system ground water were examined by using techniques suitable for a dataset with zero to 80 percent of analytical results reported as below detection. During the period of sampling, the analytical techniques changed, which generally improved the analytical sensitivity. Multiple reporting limits complicated the comparison of detections and concentrations. Regression on Order Statistics was used to model probability distributions and estimate the medians and other quantiles of the trace element concentrations. Strontium and barium were the most frequently detected and usually were present in the highest concentrations. Iron and manganese were the next most commonly detected and next highest in concentrations. Iron concentrations were the most variable with respect to the range of variations (both within local networks and aquifer-wide) and with respect to the disparity between magnitude of concentrations (detections) and the frequency of samples below reporting limits (nondetections). Antimony, beryllium, cadmium, silver, and thallium were detected too infrequently for substantial interpretation of their occurrence or distributions or potential human-health implications. For those elements that were more frequently detected, there are some geographic patterns in their occurrence that primarily reflect climate effects. The highest concentrations of several elements were found in the West-Central glacial framework area (High Plains and northern Plains areas). There are few important patterns for any element in relation to land use, well type, or network type. Shallow land-use (monitor) wells had iron concentrations generally lower than the glacial aquifer system wells overall and much lower than major-aquifer survey wells, which comprise mostly private- and public-supply wells. Unlike those for iron, concentration patterns for manganese were similar among shallow land-use wells and major-aquifer survey wells. An apparent relation between low pH and relatively low concentrations of many elements, except lead, may be more indicative of the relatively low dissolved-solids content in wells in the Northeastern United States that comprise the majority of low pH wells, than of a pH dependent pattern. Iron and manganese have higher concentrations and larger ranges of concentrations especially under more reducing conditions. Dissolved oxygen and well depth were related to iron and manganese concentrations. Redox conditions also affect several trace elements such as arsenic and copper; however, a comparison of redox categories, based in part on iron and manganese concentrations, indicated that the concentrations of many redox-sensitive elements were not significantly different among redox categories. Some of the redox-related patterns were not what would be expected on the basis of solubility constraints. Furthermore, barium is affected by redox conditions in at least one well network even though it is not a redox-sensitive element. Concentrations of barium in portions of the glacial aquifer system are limited by sulfate, which is strongly affected by redox conditions. Few samples had concentrations of any trace element that exceeded drinking-water standards (Maximum Contaminant Levels), for compounds regulated in drinking water or Health-Based Screening Levels for unregulated trace elements. More unregulated trace elements had concentrations greater than benchmarks than regulated trace elements. More samples had manganese concentrations greater its benchmark than any other element in the glacial aquifer system wells. Of the 1,590 wells sampled for manganese, only 556 are for private or public drinking-water supplies, and of those, 9.9 percent (55) exceeded the manganese Lifetime Health Advisory. Concentrations of arsenic, selenium, and uranium less frequently exceeded Maximum Contaminant Levels. There are 29 wells that had 2 element concentrations that exceeded their respective benchmarks. Most concentrations that exceeded a health-based benchmark were from wells in the West-Central area (Iowa, Minnesota, North and South Dakota, Nebraska, and Kansas); however, there is little geographical pattern to the wells with element concentrations of concern.

Scientific Investigations Report↗
USGS2009

Diel Sampling of Groundwater and Surface Water for Trace Elements and Select Water-Quality Constituents at a Former Zinc Smelter Site near Hegeler, Illinois, August 1-3, 2007

Surface water can exhibit substantial diel variations in the concentration of a number of constituents. Sampling regimens that do not characterize diel variations in water quality can result in an inaccurate understanding of site conditions and of the threat posed by the site to human health and the environment. Surface- and groundwater affected by acid drainage were sampled every 60 to 90 minutes over a 48-hour period at a former zinc smelter known as the Hegeler Zinc Superfund Site, in Hegeler, Ill. Groundwater-quality data from a well at the site indicate stable, low pH, weakly oxidizing geochemical conditions in the aquifer. With the exceptions of temperature and pH, no constituents exhibited diel variations in groundwater. Variations in temperature and pH likely were not representative of conditions in the aquifer. Surface water was sampled at a site on Grape Creek. Diel variations were observed in temperature, dissolved oxygen, pH, and specific conductance, and in the concentrations of nitrite, barium, iron, lead, vanadium, and possibly uranium. Concentrations during the diel cycles varied by about an order of magnitude for nitrite and varied by about a factor of two for barium, iron, lead, vanadium, and uranium. Temperature, dissolved oxygen, specific conductance, nitrite, barium, lead, and uranium generally reached maximum values during the afternoon and minimum values during the night. Iron, vanadium, and pH generally reached minimum values during the afternoon and maximum values during the night. These variations would need to be accounted for during sampling of surface-water quality in similar hydrologic settings. The temperature variations in surface water were affected by variations in air temperature. Concentrations of dissolved oxygen were affected by variations in the intensity of photosynthetic activity and respiration. Nitrite likely was formed by the oxidation of ammonium by dissolved oxygen and degraded by its anaerobic oxidation by ammonium or as part of the decomposition of organic matter. Variations in pH were affected by the photoreduction of Fe3+ to Fe2+ and the precipitation of iron oxyhydroxides. Diel variations in concentrations of iron and vanadium were likely caused by variations in the dissolution and precipitation of iron oxyhydroxides, oxyhydroxysulfates, and hydrous sulfates, which may have been affected by in the intensity of insolation, iron photoreduction, and the concentration of dissolved oxygen. The concentrations of lead, uranium, and perhaps barium in Grape Creek may have been affected by competition for sorption sites on iron oxyhydroxides. Competition for sorption sites was likely affected by variations in pH and the concentration of Fe2+. Constituent concentrations likely also were affected by precipitation and dissolution of minerals that are sensitive to changes in pH, temperature, oxidation-reduction conditions, and biologic activity. The chemical and biologic processes that resulted in the diel variations observed in Grape Creek occurred within the surface-water column or in the underlying sediments.

Scientific Investigations Report↗
USGS2008

Hydrochemical Regions of the Glacial Aquifer System, Northern United States, and Their Environmental and Water-Quality Characteristics

The glacial aquifer system in the United States is a large (953,000 square miles) regional aquifer system of heterogeneous composition. As described in this report, the glacial aquifer system includes all unconsolidated geologic material above bedrock that lies on or north of the line of maximum glacial advance within the United States. Examining ground-water quality on a regional scale indicates that variations in the concentrations of major and minor ions and some trace elements most likely are the result of natural variations in the geologic and physical environment. Study of the glacial aquifer system was designed around a regional framework based on the assumption that two primary characteristics of the aquifer system can affect water quality: intrinsic susceptibility (hydraulic properties) and vulnerability (geochemical properties). The hydrochemical regions described in this report were developed to identify and explain regional spatial variations in ground-water quality in the glacial aquifer system within the hypothetical framework context. Data analyzed for this study were collected from 1991 to 2003 at 1,716 wells open to the glacial aquifer system. Cluster analysis was used to group wells with similar ground-water concentrations of calcium, chloride, fluoride, magnesium, potassium, sodium, sulfate, and bicarbonate into five unique groups. Maximum Likelihood Classification was used to make the extrapolation from clustered groups of wells, defined by points, to areas of similar water quality (hydrochemical regions) defined in a geospatial model. Spatial data that represented average annual precipitation, average annual temperature, land use, land-surface slope, vertical soil permeability, average soil clay content, texture of surficial deposits, type of surficial deposit, and potential for ground-water recharge were used in the Maximum Likelihood Classification to classify the areas so the characteristics of the hydrochemical regions would resemble the characteristics of the clusters. The result of the Maximum Likelihood Classification is a map showing five hydrochemical regions of the glacial aquifer system. Statistical analysis of ion concentrations (calcium, chloride, fluoride, magnesium, sodium, potassium, sulfate, and bicarbonate) in samples collected from wells completed in the glacial aquifer system illustrates that variations in water quality can be explained, in part, by related environmental characteristics that control the movement of ground water through the aquifer system. A comparison of median concentrations of chemical constituents in ground water among the five hydrochemical regions indicates that ground water in the Midwestern Agricultural Region, the Urban-Influenced Region, and the Western Agriculture and Grassland Region has the highest concentrations of major and minor ions, whereas ground water in the Northern and Great Lakes Forested Region and the Mountain and Coastal Forested Region has the lowest concentrations of these ions. Median concentrations of barium, arsenic, lithium, boron, strontium, and nitrite plus nitrate as nitrogen also are significantly different among the hydrochemical regions.

Scientific Investigations Report↗
USGS2005

Evaluation of Measurements Collected with Multi-Parameter Continuous Water-Quality Monitors in Selected Illinois Streams, 2001-03

Eight streams, representing a wide range of environmental and water-quality conditions across Illinois, were monitored from July 2001 to October 2003 for five water-quality parameters as part of a pilot study by the U.S. Geological Survey (USGS) in cooperation with the Illinois Environmental Protection Agency (IEPA). Continuous recording multi-parameter water-quality monitors were installed to collect data on water temperature, dissolved-oxygen concentrations, specific conductivity, pH, and turbidity. The monitors were near USGS streamflow-gaging stations where stage and streamflow are continuously recorded. During the study period, the data collected for these five parameters generally met the data-quality objectives established by the USGS and IEPA at all eight stations. A similar pilot study during this period for measurement of chlorophyll concentrations failed to achieve the data-quality objectives. Of all the sensors used, the temperature sensors provided the most accurate and reliable measurements (generally within ?5 percent of a calibrated thermometer reading). Signal adjustments and calibration of all other sensors are dependent upon an accurate and precise temperature measurement. The dissolved-oxygen sensors were the next most reliable during the study and were responsive to changing conditions and accurate at all eight stations. Specific conductivity was the third most accurate and reliable measurement collected from the multi-parameter monitors. Specific conductivity at the eight stations varied widely-from less than 40 microsiemens (?S) at Rayse Creek near Waltonville to greater than 3,500 ?S at Salt Creek at Western Springs. In individual streams, specific conductivity often changed quickly (greater than 25 percent in less than 3 hours) and the sensors generally provided good to excellent record of these variations at all stations. The widest range of specific-conductivity measurements was in Salt Creek at Western Springs in the Greater Chicago metropolitan area. Unlike temperature, dissolved oxygen, and specific conductivity that have been typically measured over a wide range of historical streamflow conditions in many streams, there are few historical turbidity data and the full range of turbidity values is not well known for many streams. Because proposed regional criteria for turbidity in regional streams are based on upper 25th percentiles of concentration in reference streams, accurate determination of the distribution of turbidity in monitored streams is important. Digital data from all five sensors were recorded within each of the eight sondes deployed in the streams and in automated data recorders in the nearby streamflow-gaging houses at each station. The data recorded on each sonde were retrieved to a field laptop computer at each station visit. The feasibility of transmitting these data in near-real time to a central processing point for dissemination on the World-Wide Web was tested successfully. Data collected at all eight stations indicate that a number of factors affect the dissolved-oxygen concentration in the streams and rivers monitored. These factors include: temperature, biological activity, nutrient runoff, and weather (storm runoff). During brief periods usually in late summer, dissolved-oxygen concentrations in half or more of the eight streams and rivers monitored were below the 5 milligrams per liter minimum established by the Illinois Pollution Control Board to protect aquatic life. Because the streams monitored represent a wide range in water-quality and environmental conditions, including diffuse (non-point) runoff and wastewater-effluent contributions, this result indicates that deleterious low dissolved-oxygen concentrations during late summer may be widespread in Illinois streams.

Scientific Investigations Report↗
USGS2004

Water quality in the upper Illinois River basin: Illinois, Indiana, and Wisconsin, 1999-2001

This report contains the major findings of a 1999?2001 assessment of water quality in the upper Illinois River Basin. It is one of a series of reports by the National Water-Quality Assessment (NAWQA) Program that present major findings in 51 major river basins and aquifer systems across the Nation. In these reports, water quality is discussed in terms of local, State, and regional issues. Conditions in a particular basin or aquifer system are compared to conditions found elsewhere and to selected national benchmarks, such as those for drinking-water quality and the protection of aquatic organisms. This report is intended for individuals working with water-resource issues in Federal, State, or local agencies, universities, public-interest groups, or in the private sector. The information will be useful in addressing a number of current issues, such as the effects of agricultural and urban land use on water quality, human health, drinking water, source-water protection, hypoxia and excessive growth of algae and plants, pesticide registration, and monitoring and sampling strategies. This report also is for individuals who wish to know more about the quality of streams and ground water in areas near where they live, and how that water quality compares to the quality of water in other areas across the Nation. The water-quality conditions in the upper Illinois River Basin summarized in this report are discussed in detail in other reports that can be accessed from (http://il.water.usgs.gov/nawqa/uirb). Detailed technical information, data and analyses, collection and analytical methodology, models, graphs, and maps that support the findings presented in this report in addition to reports in this series from other basins can be accessed from the national NAWQA Web site at (http://water.usgs.gov/nawqa).

Illinois, Indiana, and Wisconsin↗
USGS1997

Hydrogeologic framework and geochemistry of the Edwards aquifer saline-water zone, south-central Texas

The Edwards aquifer supplies drinking water for more than 1 million people in south-central Texas. The saline-water zone of the Edwards aquifer extends from the downdip limit of freshwater to the southern and eastern edge of the Stuart City Formation. Water samples from 16 wells in the Edwards aquifer saline-water zone were collected during July–September 1990 and analyzed for major and minor dissolved constituents, selected stable isotopes, and radioisotopes. These data, supplemental data from an extensive water-quality data base, and data from other previous studies were interpreted to clarify the understanding of the saline-waterzone geochemistry. Most of the isotope and geochemical data indicate at least two distinct hydrological and geochemical regimes in the saline-water zone of the Edwards aquifer. On the basis of hydrogen and oxygen isotopes and radiocarbon data, the shallower updip regime is predominantly meteoric water that has been recharged probably from the freshwater zone within recent geologic time (less than tens of thousands of years). Also, on the basis of hydrogen and oxygen isotope data, water in the hydrologically stagnant regime (downdip) has been thermally altered in reactions with the carbonate rocks of the zone. The deeper water probably is much older than water in the shallow zone and is nearly stagnant relative to that in the shallow zone. The geochemical grouping observed in the wellwater data from well samples in the saline-water zone indicates that the zone is hydrologically compartmentalized, in part because of faults that function as barriers to downdip flow of recharge water. These fault barriers also probably impede updip flow. Flow compartmentalization and the resulting disparity in geochemistry between the two regimes indicate that updip movement of substantial amounts of saline water toward the freshwater zone is unlikely. Estimated in-place temperature of the samples collected indicates an increase with depth and (or) distance from the downdip limit of freshwater. The pH of the samples decreases with increasing distance from the downdip limit of freshwater, but the decrease is caused partly by the increase in temperature. Dissolved major ions and dissolved solids concentrations all indicate a progressive but monotonic increase in salinity from updip to downdip. The alkalinity of the water samples is predominantly bicarbonate because the low-molecular weight aliphatic-acid anion concentrations are small relative to the bicarbonate concentrations. The dissolved organic carbon concentrations also are lower than expected for an aquifer with economic amounts of oil and gas hydrocarbons.

Texas↗
USGS1996

Hydrogeologic factors that affect the flowpath of water in selected zones of the Edwards Aquifer, San Antonio region, Texas

The Edwards aquifer in the San Antonio region supplies drinking water for more than 1 million people. Proper development and protection of the aquifer is a high priority for local and State authorities. To better understand the flow of water in two major flowpaths in the Edwards aquifer, stratigraphic, structural, hydrologic, and geochemical data were analyzed. The western Medina flowpath is in parts of Uvalde, Medina, and Bexar Counties, and the eastern flowpath is in northern Bexar and central Comal Counties. A major hydrogeologic factor that affects the pattern of flow in the Edwards aquifer is the spatial and temporal distribution of recharge. Other hydrogeologic factors that affect flowpaths include internal boundaries and the location and rate of spring discharge. The relative displacement of faults and the high permeability layers have substantial control on the discharge at springs and on the flowpaths in the Edwards aquifer. Analysis of the estimated recharge to the Edwards aquifer during 1982 89 indicated that during years of substantial precipitation, a large part of the net recharge probably is diffuse infiltration of precipitation over large parts of the recharge area. During years with below-normal precipitation, most recharge is leakage from rivers and streams that drain the catchment subbasins. In the western Medina flowpath, concentrations of major ions indicate saturation of calcite and undersaturation of dolomite the two minerals that constitute most of the Edwards aquifer matrix. Concentrations of dissolved calcium, alkalinity, and dissolved chloride in the eastern flowpath are greater than those in the western Medina flowpath. These upward trends in concentrations might result in part from: (1) increased development in the recharge area, (2) mineralized effluent from developed areas, or (3) increased dissolution of aquifer material. Tritium data from wells sampled in and near the western Medina flowpath indicate no vertical stratification of flow. Tritium concentrations in the recharge area of the western Medina flowpath are smaller than would be expected from previous studies and for the amount of recharge the area presumably received since 1952. Stable-isotopic data indicate that the water in the Edwards aquifer is meteoric and, except in one known area, has not been subjected to substantial evaporation or other isotope-fractionating processes. Evaporation of water from Medina Lake results in a heavier stable-isotopic ratio in lake water, which subsequently recharges the Edwards aquifer. The stable-isotopic data indicate that lake water does not enter either of the two flowpaths.

Texas↗
USGS1985

Simulated effects of projected pumping on the availability of freshwater in the Evangeline Aquifer in an area southwest of Corpus Christi, Texas

This study is an investigation of the continued availability of freshwater in the Evangeline aquifer along the Texas Gulf Coast and the potential for degradation of the water quality by salinewater intrusion. Recharge to the aquifer occurs by the infiltration of precipitation in the outcrop area and by cross-formational flow from deeper aquifers. The predevelopment recharge rate is about 6 to 8 cubic feet per second. The predevelopment flow is toward the coast. The flow is semiconfined in the outcrop area and confined underneath the Chicot aquifer in the eastern two-thirds of the study area. Discharge, under natural conditions, is upward into the Chicot aquifer and to the Nueces River or Gulf of Mexico. Intensive pumping by irrigators, industries, and municipalities over the last 80 years has created a cone of depression as deep as 219 feet below sea level under the city of Kingsville in Kleberg County. The total rate of pumpage in 1982 was 29.6 cubic feet per second. A mathematical model of the flow and water quality in the Evangel ine aquifer was developed using available data to simulate the historical effect of pumping on the potentiometric surface and water quality, and to simulate the effect of projected pumping on the potentiometric surface and water quality to the year 2020. The water quality in the aquifer is only marginally suitable for drinking water. The chloride concentration before development in the 1930's and 1940's, ranged from 9 to 1,971 milligrams per liter. The mean chloride concentration was 353 (standard deviation 262) milligrams per liter. The potential sources of water-quality degradation on a regional scale are: Salinewater intrusion from under the Gulf of Mexico; movement of poor quality water within outlying sections of the aquifer; and downward leakage from the overlying Chicot aquifer. Leakage from the Chicot is the most likely to cause serious regional water-quality degradation. Other local potential sources of contamination are: Leaky well casings, oil-field brine disposal, water movement along faults, and in-situ uranium mining. These sources might create some local water-quality degradation. The results of the historical period simulation indicate, as do current field data, that little or no significant deterioration has occurred in the water quality of the Evangeline aquifer. The simulations and the sensitivity tests of the aquifer properties, conditions, and assumptions indicate that vertical conductivity of the Chicot aquifer is the most sensitive and least well known part of the system. The storage coefficient of the Evangeline aquifer and the aggregate thickness of high-conductivity sand layers within the aquifer as well as the vertical distribution of these layers are also important properties that are not well known. Two simulations of the projected pumping a low estimate, as much as 46.2 cubic feet per second during 2011-20; and a high estimate, as much as 60.0 cubic feet per second during the same period indicate that no further regional water-quality deterioration is likely to occur. Many important properties and conditions are estimated from poor or insufficient field data, and possible ranges of these properties and conditions are tested. In spite of the errors and data deficiencies, the results are based on the best estimates currently available. The reliability of the conclusions rests on the adequacy of the data and the demonstrated sensitivity of the model results to errors in estimates of these properties.

Texas↗