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Geology topics

George E. Claypool

Publications and source records attributed to George E. Claypool.

At least 37 records · Page 2Linked to original sources
USGS1981

Petroleum geology of Cook Inlet basin: An exploration model

Oil exploration commenced onshore adjacent to lower Cook Inlet on the Iniskin Peninsula in 1900, shifted with considerable success to upper Cook Inlet from 1957 through 1965, then returned to lower Cook Inlet in 1977 with the COST well and Federal OCS sale. Lower Cook Inlet COST No. 1 well, drilled to a total depth of 3,775.6 m, penetrated basinwide unconformities at the tops of Upper Cretaceous, Lower Cretaceous, and Upper Jurassic strata at 797.1, 1,540.8, and 2,112.3 m, respectively. Sandstone of potential reservoir quality is present in the Cretaceous and lower Tertiary rocks. All siltstones and shales analyzed are low (0 to 0.5 wt. %) in oil-prone organic matter, and only coals are high in humic organic matter. At total depth, vitrinite readings reached a maximum ave age reflectance of 0.65. Several indications of hydrocarbons were present. Oil analyses suggest that oils from the major fields of the Cook Inlet region, most of which produce from the Tertiary Hemlock Conglomerate, have a common source. More detailed work on stable carbon isotope ratios and the distribution of gasoline-range and heavy (C 12 + ) hydrocarbons confirms this genetic relation among the major fields. In addition, oils from Jurassic rocks under the Iniskin Peninsula and from the Hemlock Conglomerate at the southwestern tip of the Kenai lowland are members of the same or a very similar oil family. The Middle Jurassic strata of the Iniskin Peninsula are moderately rich in organic carbon (0.5 to 1.5 wt. %) and yield shows of oil and of gas in wells and in surface seeps. Extractable hydrocarbons from this strata are similar in chemi al and isotopic composition to the Cook Inlet oils. Organic matter in Cretaceous and Tertiary rocks is thermally immature in all wells analyzed. Oil reservoirs in the major producing fields are of Tertiary age and unconformably overlie Jurassic rocks; the pre-Tertiary unconformity may be significant in exploration for new oil reserves. The unconformable relation between reservoir rocks and likely Middle Jurassic source rocks also implies a delay in the generation and expulsion of oil from Jurassic until late Tertiary when localized basin subsidence and thick sedimentary fill brought older, deeper rocks to the temperature required for petroleum generation. Reservoir porosities, crude oil properties, the type of oil field traps, and the tectonic framework of the oil fields on the west flank of the basin provide evidence used to reconstruct an oil migration route. The route is inferred to commence deep in the truncated Middle Jur ssic rocks and pass through the porous West Foreland Formation in the McArthur River field area to a stratigraphic trap in the Oligocene Hemlock Conglomerate and the Oligocene part of the Tyonek Formation at the end of Miocene time. Pliocene deformation shut off this route and created localized structural traps, into which the oil moved by secondary migration to form the Middle Ground Shoal, McArthur River, and Trading Bay oil fields. Oil generation continued into the Pliocene, but this higher API gravity oil migrated along a different route to the Granite Point field.

Alaska↗
USGS1981

Two oil types on North slope of Alaska: Implications for exploration

Forty oil samples from across the North Slope of Alaska have been analyzed by the U.S. Bureau of Mines and the U.S. Geological Survey. Results of these analyses suggest two separate genetic oil types. The first, the Simpson-Umiat oil type, occurs in reservoir rocks of Cretaceous and Quaternary age and includes oil from seeps in the Skull Cliff, Cape Simpson, Manning Point, and Ungoon Point areas, and oils from Wolf Creek test 3, and the Cape Simpson and Umiat oil fields. These are higher gravity, low-sulfur oils with no, or slight, odd-numbered n-alkane predominance and pristane to phytane ratios greater than 1.5. Also, these oils have ^dgr 13 C values ranging from -29.1 to -27.8 parts per thousand (ppt) and ^dgr 34 S values from -10.3 to -4.9 ppt. The s cond type, the Barrow-Prudhoe oil type, occurs in reservoir rocks of Carboniferous to Cretaceous age and includes oils from South Barrow gas field, Prudhoe Bay oil field, and the Fish Creek test well 1. Physical properties of Barrow-Prudhoe oils are variable, but in general the oils are medium-gravity, high-sulfur oils with slight even-numbered n-alkane predominance and pristane to phytane ratios less than 1.5. Also these oils have ^dgr 13 C values of -30.3 to -29.8 ppt and ^dgr 34 S values from -30.0 to +2.1 ppt. The two types are believed to originate from different source rocks; the Barrow-Prudhoe type may have originated from a carbonate or other iron-deficient source rock, and the Simpson-Umiat type from a siliciclastic source rock. Occurrences of the two oil types when outlined on a map, indicate at least two areas for additional exploration: for the Barrow-Prudhoe type, in stratigraphic traps along and adjacent to the Barrow arch, and for the Simpson-Umiat type, in Cretaceous rocks along the trend between the Simpson and Umiat oil fields and in Cretaceous and Tertiary rocks from Prudhoe Bay field to the William O. Douglas Arctic Wildlife Range.

Alaska↗
USGS1981

Origin of organic-carbon-rich mid-Cretaceous limestones, Mid-Pacific Mountains and southern Hess Rise

Limestones of mid-Cretaceous age containing as much as 8.6 percent organic carbon were cored at one site (463) in the Mid-Pacific Mountains and at two sites (465, 466) on southern Hess Rise, central North Pacific Ocean, during Leg 62 of the Deep Sea Drilling Project. In the Mid-Pacific Mountains, three layers containing more than 2% organic carbon are associated with volcanic ash in silicified limestone of early Aptian age (—112-113 m.y. old), a time when the site was south of the equator and considerably shallower than at present (2525 m). The beds of laminated, organiccarbon-rich limestone, implying deposition in an oxygen-deficient environment, are interbedded with normal pelagic limestones. This sequence lies on interbedded pelagic limestones and clastic limestones containing locally derived shallow-water carbonate debris, and it is overlain by interbedded green, gray, and pink limestones. The organic-carbonrich strata on southern Hess Rise are dark-olive, laminated limestones with rare interbeds of altered volcanic ash of the late Aptian to early Cenomanian ( — 98 to 103 m.y. old), a time when the site was passing under the equatorial highproductivity zone and subsiding from shallow to intermediate water depths. The organic-carbon-rich limestone sequence overlies volcanic basement (trachyte) in this part of Hess Rise. The association of volcanogenic sediments with organic-carbon-rich strata on Hess Rise is not as striking as in the Mid-Pacific Mountains, but the occurrences do suggest a coincidence of mid-plate volcanic activity and accumulation of organic matter at intermediate water depths in the tropical North Pacific Ocean during the mid-Cretaceous. Pyrolysis assays indicate that most of the organic matter in the limestone on Hess Rise is composed of lipid-rich kerogen derived from marine organisms. Limestones from the Mid-Pacific Mountains contain lower concentrations of organic matter. Pyrolysis assays and extractable hydrocarbons indicate that the organic matter in samples from Hole 463 is also predominantly of marine origin, and that contributions of terrigenous organic matter were probably minor. Analyses of stable carbon isotopes indicate that the organic carbon in all analyzed samples is isotopically light (δ13C 24 to - 29‰) relative to most modern marine organic carbon (δ13C - 9 to - 30%), and that the lightest carbon (δ13C 28 to - 29‰) is also the most lipid-rich. The organic-carbon-rich mid-Cretaceous limestones on Hess Rise, the Mid-Pacific Mountains, and other elevated plateaus and seamounts in the Pacific Ocean are approximately equivalent in age (mid-Cretaceous, -85-120 m.y.) to organic-carbon-rich lithofacies elsewhere in the world ocean, particularly in the Atlantic Ocean and parts of the Indian Ocean. However, strata of equivalent age deposited in the Pacific Ocean at greater depths do not contain any carbon rich horizons. This observation, together with the evidence that the plateau sites were considerably shallower and close to the equator during the mid-Cretaceous, suggests that an expanded mid-water oxygen minimum, together with local restrictions in circulation, may have resulted in the preservation of organic matter in an oxygen-deficient environment where the oxygen minimum impinged on elevated platforms such as Hess Rise and the Mid-Pacific Mountains.

Initial reports of the Deep Sea Drilling Project↗
USGS1980

The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation

Three hundred new samples of marine evaporite sulfate, of world-wide distribution, were analyzed for δ 34 S, and 60 of these also for δ 18 O in the sulfate ion. Detailed δ 34 S age curves for Tertiary—Cretaceous, Permian—Pennsylvanian, Devonian, Cambrian and Proterozoic times document large variations in δ 34 S. A summary curve forδ 18 O also shows definite variations, some at different times than δ 34 S, and always smaller. The measured δ 34 S and δ 18 O correspond to variations in these isotopes in sulfate of the world ocean surface. The variations of δ 18 O are controlled by input and output fluxes of sulfur in the ocean, three of which are the same that control δ 34 S: deposition and erosion of sulfate, and deposition of sulfide. Erosion of sulfide differs in its effect on the S and O systems. δ 18 O in the sulfate does not seem to be measurably affected by equilibration with either seawater or with subsurface waters after crystallization. In principle, the simultaneous application of both δ 34 S and δ 18 O age curves should help reduce the number of assumptions in calculations of the cycles of sulfur and oxygen through geological time, and a new model involving symmetrical fluxes is introduced here to take advantage of the oxygen data. However, all previously published models as well as this one lead to anomalies, such as unreasonable calcium or oxygen depletions in the ocean—atmosphere system. In addition, most models are incapable of reproducing the sharp rises of the δ 34 S curve in the late Proterozoic, the Devonian and the Triassic which would be the result of unreasonably fast net sulfide deposition. This fast depletion could result from an ocean that has not always been mixed (as previously assumed in all model calculations).

Chemical Geology↗
USGS1980

Organic composition of some Upper Cretaceous shale, Powder River Basin, Wyoming

The lower Upper Cretaceous strata in northeastern Wyoming, which have yielded major quantities of oil and gas, were sampled at boreholes in Converse, Johnson, and Weston Counties. Cores of noncalcareous shale of largely nearshore-marine origin were obtained from the Frontier Formation and the overlying Cody Shale at depths of 3,780.6 to 3,879.9 m in Converse County, near the axis of the Powder River basin, and at depths of less than 320 m in Johnson County, on the western flank of the basin. Cores of calcareous and noncalcareous shale representing offshore-marine and nearshore-marine environments were acquired from the Belle Fourche Shale, Greenhorn Formation, and Carlile Shale at depths of less than 270 m in Weston County, on the eastern flank of the Powder River basin. Analyses of the shale for organic carbon content, total pyrolytic hydrocarbon yield, volatile hydrocarbon content, temperature of maximum pyrolytic yield, and vitrinite reflectance indicate that the amount and character of the organic matter in the sampled rocks is related to the content of calcium carbonate, the depositional environment, and the burial depth of the strata. On the east flank of the Powder River basin, calcareous shale of offshore-marine origin contains abundant hydrogen-rich organic matter derived mainly from aquatic plants. Noncalcareous shale of largely nearshore-marine origin, on the west flank of the basin, locally contains significant hydrogen-poor organic matter derived mostly from land plants. The noncalcareous, nearshore-marine shale in the middle of the basin probably contained similar amounts of hydrogendeficient organic matter prior to deep burial and thermal alteration. The calcareous shale in Weston County is a potentially rich source of oil and gas, but it is thermally immature and is in a very early stage of the hydrocarbon-generation process. The noncalcareous shale in Johnson County is a potential source rock for gas, but also is in an early stage of thermal alteration. In Converse County, the sampled beds are thermally mature and have generated hydrocarbons. The extent of this contribution of hydrocarbons to the commercial petroleum occurrences of the area can be inferred from the composition of the original organic matter in the beds. Furthermore, the degree of thermal alteration of the organic matter at these localities indicates that the depth of the sampled strata was never as great on the flanks of the Powder River basin as in the basin center.

Wyoming↗
USGS1980

Origin of gasoline-range hydrocarbons and their migration by solution in carbon dioxide in Norton basin, Alaska.

Carbon dioxide from a submarine seep in Norton Sound, Alaska, carries a minor component of gas- and gasoline-range hydrocarbons. The molecular and isotopic compositions of the hydrocarbon gases and the presence of gasoline-range hydrocarbons indicate that these molecules are derived from thermal alteration of marine and/or nonmarine organic matter buried within Norton basin. In the gasoline-range hydrocarbons, individual cyclic and branched-chain molecules are much more abundant than straight-chain hydrocarbons. This distribution suggests that the hydrocarbon mixture is an immature, petroleumlike condensate of lower temperature origin than normal crude oil. The submarine seep provides a natural example in support of a carbon dioxide solution transport mechanism thought to be operative in the migration of hydrocarbons in certain reservoirs.

Alaska↗
USGS1980

Biogenic and thermogenic origins of natural gas in Cook Inlet basin, Alaska.

Two types of natural gas occurrences are present in the Cook Inlet basin. The major reserves (1.8 × 10 11 m 3 ) occur in shallow (less than 2,300 m), nonassociated dry gas fields that contain methane with ^dgr 13 C in the range of -63 to -56 per mil. These gas fields are in sandstones interbedded with coals of the Sterling and Beluga Formations; the gas fields are interpreted as biogenic in origin. Lesser reserves (1.1 × 10 10 m 3 ) of natural gas are associated with oil in the deeper Hemlock Conglomerate at the base of the Tertiary section; associated gas contains methane with ^dgr 13 C of about -46 per mil. The gases associated with oil in the Hemlock Conglomerate are thermogenic in origin.

Alaska↗