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George D. Spence

Publications and source records attributed to George D. Spence.

4 recordsLinked to original sources

Anaerobic methane oxidation in low-organic content methane seep sediments

Sulfate-dependent anaerobic oxidation of methane (AOM) is the key sedimentary microbial process limiting methane emissions from marine sediments and methane seeps. In this study, we investigate how the presence of low-organic content sediment influences the capacity and efficiency of AOM at Bullseye vent, a gas hydrate-bearing cold seep offshore of Vancouver Island, Canada. The upper 8 m of sediment contains < 0.4 wt% total organic carbon (OC) and primarily consists of glacially-derived material that was deposited 14,900 to 15,900 yrs BP during the retreat of the late Quaternary Cordilleran Ice Sheet. We hypothesize this aged and exceptionally low-OC content sedimentary OM is biologically refractory, thereby limiting degradation of non-methane OM by sulfate reduction and maximizing methane consumption by sulfate-dependent AOM. A radiocarbon-based dissolved inorganic carbon (DIC) isotope mass balance model demonstrates that respired DIC in sediment pore fluids is derived from a fossil carbon source that is devoid of 14 C. A fossil origin for the DIC precludes remineralization of non-fossil OM present within the sulfate zone as a significant contributor to pore water DIC, suggesting that nearly all sulfate is available for anaerobic oxidation of fossil seep methane. Methane flux from the SMT to the sediment water interface in a diffusion-dominated flux region of Bullseye vent was, on average, 96% less than at an OM-rich seep in the Gulf of Mexico with a similar methane flux regime. Evidence for enhanced methane oxidation capacity within OM-poor sediments has implications for assessing how climate-sensitive reservoirs of sedimentary methane (e.g., gas hydrate) will respond to ocean warming, particularly along glacially-influenced mid and high latitude continental margins.

Geochimica et Cosmochimica Acta

Evidence and biogeochemical implications for glacially-derived sediments in an active margin cold seep

Delineating sediment organic matter origins and sediment accumulation rates at gas hydratebearing and hydrocarbon seeps is complicated by the microbial transfer of 13C-depleted and 14Cdepleted methane carbon into sedimentary pools. Sediment 13C and 14C measurements from four cores recovered at Bullseye vent on the northern Cascadia margin are used to identify methane carbon assimilation into different carbon pools. While the total organic carbon (TOC) is mostly unaltered and primarily terrigenous in origin, planktonic foraminifera and the bulk carbonate display evidence of methane overprinting. Mass balance models are applied to determine the extent to which methane overprinting increased the radiocarbon ages of the biogenic foraminifera. The corrected and calibrated foraminifera ages between sediment depths of 70 and 573 cm are from 14.9 to 15.9 ka BP, which coincides with the retreat of the late Quaternary Cordilleran Ice Sheet from Vancouver Island. Uniform TOC _13C values of -24.5 &plusmn; 0.5&permil; from the upper 8 meters of sediment at Bullseye vent suggest all cored material is Pleistocene-derived glacimarine material deposited as the ice edge retreated landward. Bullseye vent is located within an uplifted sediment block isolated from turbidite deposition and has been a site of non-deposition since the ice sheet retreated from the shelf. Biogeochemical implications of seep sediments being dominated by aged, organic-poor (<0.4 wt% TOC) material are that methane is the primary energy source, and microbes directly and indirectly associated with the anaerobic oxidation of methane (AOM) will dominate the seep microbial community.

Conference Paper

Wide-angle seismic recording from the 2002 Georgia Basin Geohazards Initiative, northwestern Washington and British Columbia

This report describes the acquisition and processing of shallow-crustal wide-angle seismicreflection and refraction data obtained during a collaborative study in the Georgia Strait, western Washington and southwestern British Columbia. The study, the 2002 Georgia Strait Geohazards Initiative, was conducted in May 2002 by the Pacific Geoscience Centre, the U.S. Geological Survey, and the University of Victoria. The wide-angle recordings were designed to image shallow crustal faults and Cenozoic sedimentary basins crossing the International Border in southern Georgia basin and to add to existing wide-angle recordings there made during the 1998 SHIPS experiment. We recorded, at wide-angle, 800 km of shallow penetration multichannel seismic-reflection profiles acquired by the Canadian Coast Guard Ship (CCGS) Tully using an air gun with a volume of 1.967 liters (120 cu. in.). Prior to this reflection survey, we deployed 48 Refteks onshore to record the airgun signals at wide offsets. Three components of an oriented, 4.5 Hz seismometer were digitally recorded at all stations. Nearly 160,300 individual air gun shots were recorded along 180 short seismic reflection lines. In this report, we illustrate the wide-angle profiles acquired using the CCGS Tully, describe the land recording of the air gun signals, and summarize the processing of the land recorder data into common-receiver gathers. We also describe the format and content of the archival tapes containing the SEGY-formated, common-receiver gathers for the Reftek data. Data quality is variable but the experiment provided useful data from 42 of the 48 stations deployed. Three-fourths of all stations yielded useful first-arrivals to source-receiver offsets beyond 10 km: the average maximum source-receiver offset for first arrivals was 17 km. Six stations yielded no useful data and useful firstarrivals were limited to offsets less than 10 km at five stations. We separately archived our recordings of 86 local and regional earthquakes ranging in magnitude from 0.2 to 4.3 and 16 teleseisms ranging in magnitude 5.5 to 6.5.

British Columbia;Washington

Wide-angle seismic recordings from the 1998 Seismic Hazards Investigation of Puget Sound (SHIPS), western Washington and British Columbia

This report describes the acquisition and processing of deep-crustal wide-angle seismic reflection and refraction data obtained in the vicinity of Puget Lowland, the Strait of Juan de Fuca, and Georgia Strait, western Washington and southwestern British Columbia, in March 1998 during the Seismic Hazards Investigation of Puget Sound (SHIPS). As part of a larger initiative to better understand lateral variations in crustal structure along the Cascadia margin, SHIPS participants acquired 1000 km of deep-crustal multichannel seismic-reflection profiles and 1300 km of wideangle airgun shot lines in this region using the R/V Thompson and R/V Tully. The Tully was used to record airgun shots fired by the Thompson in two different geometries: (1) expanding spread profiles (ESPs) and (2) constant offset profiles (COPs). Prior to this reflection survey, we deployed 257 Reftek and 15 ocean-bottom seismic recorders to record the airgun signals at far offsets. All data were recorded digitally on large-capacity hard disks. Although most of these stations only recorded the vertical component of motion, 95 of these seismographs recorded signals from an oriented 3-component seismometer. By recording signals generated by the Thompson's marine air gun array, operated in two differing geometries having a total volume of 110 and 79 liters (6730 and 4838 cu. in.), respectively, the arrays of wide-angle recorders were designed to (1) image the crustal structure, particularly in the vicinity of crustal faults and Cenozoic sedimentary basins, (2) determine the geometry of the Moho, and (3) image the subducting Gorda and Juan de Fuca plates. Nearly 33,300 air gun shots were recorded along several seismic lines. In this report, we illustrate the expanding spread profiles acquired using the Thompson and Tully, describe the land and ocean-bottom recording of the air gun signals, discuss the processing of the land recorder data into common receiver gathers, and illustrate the processed wide-angle seismic data collected using the Refteks and ocean-bottom seismometers. We also describe the format and content of the archival tapes containing the SEGY-formated, common-receiver gathers for the Reftek data. Data quality is variable but SHIPS appears to have successfully obtained useful data from almost all the stations deployed to record the airgun shots. Several interesting arrivals were observed: including refractions from the sedimentary basin fill in several basins, refractions from basement rocks forming the upper crust, Pg, refractions from the upper mantle, Pn, as well as reflections from within the crust and from the top of the upper mantle, PmP. We separately archived more than 30 local earthquakes recorded by the Reftek array during our deployment.

Washington