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Gary S. Dwyer

Publications and source records attributed to Gary S. Dwyer.

18 recordsLinked to original sources

A 600-kyr reconstruction of deep Arctic seawater δ18O from benthic foraminiferal oxygen isotopes and ostracode Mg/Ca paleothermometry

The oxygen isotopic composition of benthic foraminiferal tests ( δ 18 O b ) is one of the pre-eminent tools for correlating marine sediments and interpreting past terrestrial ice volume and deep-ocean temperatures. Despite the prevalence of δ 18 O b applications to marine sediment cores over the Quaternary, its use is limited in the Arctic Ocean because of low benthic foraminiferal abundances, challenges with constructing independent sediment core age models, and an apparent muted amplitude of Arctic δ 18 O b variability compared to open-ocean records. Here we evaluate the controls on Arctic δ 18 O b by using ostracode Mg / Ca "> paleothermometry to generate a composite record of the δ 18 O of seawater ( δ 18 O sw ) from 12 sediment cores in the intermediate to deep Arctic Ocean (700–2700 m) that covers the last 600 kyr based on biostratigraphy and orbitally tuned age models. Results show that Arctic δ 18 O b was generally higher than open-ocean δ 18 O b during interglacials but was generally equivalent to global reference records during glacial periods. The reduced glacial–interglacial Arctic δ 18 O b range resulted in part from the opposing effect of temperature, with intermediate to deep Arctic warming during glacials counteracting the whole-ocean δ 18 O sw increase from expanded terrestrial ice sheets. After removing the temperature effect from δ 18 O b , we find that the intermediate to deep Arctic experienced large ( ≥1 ‰) variations in local δ 18 O sw , with generally higher local δ 18 O sw during interglacials and lower δ 18 O sw during glacials. Both the magnitude and timing of low local δ 18 O sw intervals are inconsistent with the recent proposal of freshwater intervals in the Arctic Ocean during past glaciations. Instead, we suggest that lower local δ 18 O sw in the intermediate to deep Arctic Ocean during glaciations reflected weaker upper-ocean stratification and more efficient transport of low- δ 18 O sw Arctic surface waters to depth by mixing and/or brine rejection.

Climate of the Past

A 1.8 million year history of Amazon vegetation

During the Pleistocene, long-term trends in global climate were controlled by orbital cycles leading to high amplitude glacial-interglacial variability. The history of Amazonian vegetation during this period is largely unknown since no continuous record from the lowland basin extends significantly beyond the last glacial stage. Here we present a paleoenvironmental record spanning the last 1800 kyr based on palynological data, biome reconstructions, and biodiversity metrics from a marine sediment core that preserves a continuous archive of sediments from the Amazon River. Tropical rainforests dominated the Amazonian lowlands during the last 1800 ka interchanging with surrounding warm-temperate rainforests and tropical seasonal forests. Between 1800 and 1000 ka, rainforest biomes were present in the Amazon drainage basin, along with extensive riparian wetland vegetation. Tropical rainforest expansion occurred during the relatively warm Marine Isotope Stages 33 and 31 (ca. 1110 to 1060 ka), followed by a contraction of both forests and wetlands until ca. 800 ka. Between 800 and 400 ka, low pollen concentration and low diversity of palynological assemblages renders difficult the interpretation of Amazonian vegetation. A strong synchronicity between vegetation changes and glacial-interglacial global climate cycles was established around 400 ka. After 400 ka, interglacial vegetation was dominated by lowland tropical rainforest in association with warmer temperatures and higher CO 2 . During cooler temperatures and lower CO 2 of glacial stages, tropical seasonal forests expanded, presumably towards eastern Amazonia. While this study provides no evidence supporting a significant expansion of savanna or steppe vegetation within the Amazonian lowlands during glacial periods, there were changes in the rainforest composition in some parts of the basin towards a higher proportion of deciduous elements, pointing to less humid conditions and/or greater seasonality of precipitation. Nevertheless, rainforest persisted during both glacial and interglacial periods. These findings confirm the sensitivity of tropical lowland vegetation to changes in CO 2 , temperature, and moisture availability and the most suitable conditions for tropical rainforests occurred during the warmest stages of the Mid Pleistocene Transition and during the interglacial stages of the past 400 kyr.

Quaternary Science Reviews

Mg/Ca ratios in ostracode genera Sarsicytheridea and Paracyprideis: A potential paleotemperature proxy for Arctic and subarctic continental shelf and slope waters

We evaluate the potential utility of Mg/Ca ratios in the sublittoral ostracode genera Sarsicytheridea and Paracyprideis as a paleotemperature proxy for continental shelf and upper slope waters of the Arctic Ocean and adjacent seas. Using sediment core-top and surface sediment samples, the shells of three species, S. bradii, S. punctillata, and P. pseudopunctillata, were analyzed from Arctic Ocean sites ranging in water depth from 7 to 200 meters and bottom-water temperatures (BWT) of -1.5 °C to 12 °C. Generally, Mg/Ca ratios range from 4 to 9 mmol/mol. The results show excellent agreement with the range of Mg/Ca ratios obtained in a previous study by Ingram (1998) of core-top shells of Sarsicytheridea from the sub-polar North Atlantic Ocean and adjacent seas, with BWT ranging from 1 to 11.4 °C. However, unlike this previous study of Sarsicytheridea, and previous work on the Arctic ostracode marine genus Krithe showing strong correlations between Mg/Ca and BWT, Mg/Ca ratios in Arctic specimens analyzed here are not correlated with BWT below 0°C. We hypothesize that this has to do with uncertainty regarding the actual ambient BWT at the time of shell secretion. As with many continental shelf sites, the individual sites used in the study have large interannual and seasonal variations in BWT, in some cases >5-8 °C. Thus, there is considerable difficulty in assigning a proper shell secretion temperature and, in turn, fully assessing the utility of Sarsicytheridea Mg/Ca ratios as a paleotemperature proxy below 0 °C. There are a number of possible solutions, such as laboratory culturing of these genera under controlled conditions, adding additional sites with a range of maximal and minimal bottom water temperatures, and pairing other geochemical or isotopic measures of temperature, among others. Regardless, the good overall calibration of Mg/Ca results from samples with temperatures above 0 °C is encouraging and justifies continued evaluation of this potential paleothermometer for Arctic continental shelf and upper slope environments.

Marine Micropaleontology

Interglacial paleoclimate in the Arctic

Marine Isotope Stage 11 from ~424 to 374 ka experienced peak interglacial warmth and highest global sea level ~410–400 ka. MIS 11 has received extensive study on the causes of its long duration and warmer than Holocene climate, which is anomalous in the last half million years. However, a major geographic gap in MIS 11 proxy records exists in the Arctic Ocean where fragmentary evidence exists for a seasonally sea ice-free summers and high sea-surface temperatures (SST; ~8–10 °C near the Mendeleev Ridge). We investigated MIS 11 in the western and central Arctic Ocean using 12 piston cores and several shorter cores using proxies for surface productivity (microfossil density), bottom water temperature (magnesium/calcium ratios), the proportion of Arctic Ocean Deep Water versus Arctic Intermediate Water (key ostracode species), sea ice (epipelagic sea ice dwelling ostracode abundance), and SST (planktic foraminifers). We produced a new benthic foraminiferal δ 18 O curve, which signifies changes in global ice volume, Arctic Ocean bottom temperature, and perhaps local oceanographic changes. Results indicate that peak warmth occurred in the Amerasian Basin during the middle of MIS 11 roughly from 410 to 400 ka. SST were as high as 8–10 °C for peak interglacial warmth, and sea ice was absent in summers. Evidence also exists for abrupt suborbital events punctuating the MIS 12-MIS 11-MIS 10 interval. These fluctuations in productivity, bottom water temperature, and deep and intermediate water masses (Arctic Ocean Deep Water and Arctic Intermediate Water) may represent Heinrich-like events possibly involving extensive ice shelves extending off Laurentide and Fennoscandian Ice Sheets bordering the Arctic.

Paleoceanography and Paleoclimatology

Enhanced Arctic amplification began at the Mid-Brunhes Event 430,000 years ago

Arctic Ocean temperatures influence ecosystems, sea ice, species diversity, biogeochemical cycling, seafloor methane stability, deep-sea circulation, and CO 2 cycling. Today's Arctic Ocean and surrounding regions are undergoing climatic changes often attributed to "Arctic amplification" - that is, amplified warming in Arctic regions due to sea-ice loss and other processes, relative to global mean temperature. However, the long-term evolution of Arctic amplification is poorly constrained due to lack of continuous sediment proxy records of Arctic Ocean temperature, sea ice cover and circulation. Here we present reconstructions of Arctic Ocean intermediate depth water (AIW) temperatures and sea-ice cover spanning the last ~ 1.5 million years (Ma) of orbitally-paced glacial/interglacial cycles (GIC). Using Mg/Ca paleothermometry of the ostracode Krithe and sea-ice planktic and benthic indicator species, we suggest that the Mid-Brunhes Event (MBE), a major climate transition ~ 400-350 ka, involved fundamental changes in AIW temperature and sea-ice variability. Enhanced Arctic amplification at the MBE suggests a major climate threshold was reached at ~ 400 ka involving Atlantic Meridional Overturning Circulation (AMOC), inflowing warm Atlantic Layer water, ice sheet, sea-ice and ice-shelf feedbacks, and sensitivity to higher post-MBE interglacial CO 2 concentrations.

Scientific Reports

Calibration of a conodont apatite-based Ordovician 87 Sr/ 86 Sr curve to biostratigraphy and geochronology: Implications for stratigraphic resolution

The Ordovician 87 Sr/ 86 Sr isotope seawater curve is well established and shows a decreasing trend until the mid-Katian. However, uncertainties in calibration of this curve to biostratigraphy and geochronology have made it difficult to determine how the rates of 87 Sr/ 86 Sr decrease may have varied, which has implications for both the stratigraphic resolution possible using Sr isotope stratigraphy and efforts to model the effects of Ordovician geologic events. We measured 87 Sr/ 86 Sr in conodont apatite in North American Ordovician sections that are well studied for conodont biostratigraphy, primarily in Nevada, Oklahoma, the Appalachian region, and Ohio Valley. Our results indicate that conodont apatite may provide an accurate medium for Sr isotope stratigraphy and strengthen previous reports that point toward a significant increase in the rate of fall in seawater 87 Sr/ 86 Sr during the Middle Ordovician Darriwilian Stage. Our 87 Sr/ 86 Sr results suggest that Sr isotope stratigraphy will be most useful as a high-resolution tool for global correlation in the mid-Darriwilian to mid-Sandbian, when the maximum rate of fall in 87 Sr/ 86 Sr is estimated at ∼5.0–10.0 × 10 –5 per m.y. Variable preservation of conodont elements limits the precision for individual stratigraphic horizons. Replicate conodont analyses from the same sample differ by an average of ∼4.0 × 10 –5 (the 2σ standard deviation is 6.2 × 10 –5 ), which in the best case scenario allows for subdivision of Ordovician time intervals characterized by the highest rates of fall in 87 Sr/ 86 Sr at a maximum resolution of ∼0.5–1.0 m.y. Links between the increased rate of fall in 87 Sr/ 86 Sr beginning in the mid-late Darriwilian ( Phragmodus polonicus to Pygodus serra conodont zones) and geologic events continue to be investigated, but the coincidence with a long-term rise in sea level (Sauk-Tippecanoe megasequence boundary) and tectonic events (Taconic orogeny) in North America provides a plausible explanation for the changing magnitude and 87 Sr/ 86 Sr of the riverine Sr flux to the oceans.

GSA Bulletin

Climate variability during the Medieval Climate Anomaly and Little Ice Age based on ostracod faunas and shell geochemistry from Biscayne Bay, Florida

An 800-year-long environmental history of Biscayne Bay, Florida, is reconstructed from ostracod faunal and shell geochemical (oxygen, carbon isotopes, Mg/Ca ratios) studies of sediment cores from three mudbanks in the central and southern parts of the bay. Using calibrations derived from analyses of modern Biscayne and Florida Bay ostracods, palaeosalinity oscillations associated with changes in precipitation were identified. These oscillations reflect multidecadal- and centennial-scale climate variability associated with the Atlantic Multidecadal Oscillation during the late Medieval Climate Anomaly (MCA) and the Little Ice Age (LIA). Evidence suggests wetter regional climate during the MCA and drier conditions during the LIA. In addition, twentieth century anthropogenic modifications to Everglades hydrology influenced bay circulation and/or processes controlling carbon isotopic composition.

Florida

Reevaluation of mid-Pliocene North Atlantic sea surface temperatures

Multiproxy temperature estimation requires careful attention to biological, chemical, physical, temporal, and calibration differences of each proxy and paleothermometry method. We evaluated mid-Pliocene sea surface temperature (SST) estimates from multiple proxies at Deep Sea Drilling Project Holes 552A, 609B, 607, and 606, transecting the North Atlantic Drift. SST estimates derived from faunal assemblages, foraminifer Mg/Ca, and alkenone unsaturation indices showed strong agreement at Holes 552A, 607, and 606 once differences in calibration, depth, and seasonality were addressed. Abundant extinct species and/or an unrecognized productivity signal in the faunal assemblage at Hole 609B resulted in exaggerated faunal-based SST estimates but did not affect alkenone-derived or Mg/Ca–derived estimates. Multiproxy mid-Pliocene North Atlantic SST estimates corroborate previous studies documenting high-latitude mid-Pliocene warmth and refine previous faunal-based estimates affected by environmental factors other than temperature. Multiproxy investigations will aid SST estimation in high-latitude areas sensitive to climate change and currently underrepresented in SST reconstructions.

Paleoceanography

PRISM3 DOT1 Atlantic Basin Reconstruction

PRISM3 DOT1 (Pliocene Research, Interpretation and Synoptic Mapping 3, Deep Ocean Temperature 1) provides a three-dimensional temperature reconstruction for the mid-Pliocene Atlantic basin, the first of several regional data sets that will comprise a global mid-Pliocene reconstruction. DOT1 is an alteration of modern temperature values for the Atlantic Ocean in 4 degree x 5 degree cells in 13 depth layers for December 1 based on Mg/Ca-derived BWT estimates from seventeen DSDP and ODP Sites and SST estimates from the PRISM2 reconstruction (Dowsett et al., 1999). DOT1 reflects a vaguely modern circulation system, assuming similar processes of deep-water formation; however, North Atlantic Deep Water (NADW) production is increased, and Antarctic Bottom Water (AABW) production is decreased. Pliocene NADW was approximately 2 degreesC warmer than modern temperatures, and Pliocene AABW was approximately 0.3 degreesC warmer than modern temperatures.

Data Series

Middle Pliocene sea surface temperature variability

Estimates of sea surface temperature (SST) based upon foraminifer, diatom, and ostracod assemblages from ocean cores reveal a warm phase of the Pliocene between about 3.3 and 3.0 Ma. Pollen records and plant megafossils, although not as well dated, show evidence for a warmer climate at about the same time. Increased greenhouse forcing and altered ocean heat transport are the leading candidates for the underlying cause of Pliocene global warmth. Despite being a period of global warmth, this interval encompasses considerable variability. Two new SST reconstructions are presented that are designed to provide a climatological error bar for warm peak phases of the Pliocene and to document the spatial distribution and magnitude of SST variability within the mid-Pliocene warm period. These data suggest long-term stability of low-latitude SST and document greater variability in regions of maximum warming. Copyright 2005 by the American Geophysical Union.

Paleoceanography

Mid-Pliocene deep-sea bottom-water temperatures based on ostracode Mg/Ca ratios

We studied magnesium:calcium (Mg/Ca) ratios in shells of the deep-sea ostracode genus Krithe from a short interval in the middle Pliocene between 3.29 and 2.97 Ma using deep-sea drilling sites in the North and South Atlantic in order to estimate bottom water temperatures (BWT) during a period of climatic warmth. Results from DSDP and ODP Sites 552A, 610A, 607, 658A, 659A, 661A and 704 for the period Ma reveal both depth and latitudinal gradients of mean Mg/Ca values. Shallower sites (552A, 610A and 607) have higher mean Mg/Ca ratios (10.3, 9.7, 10.1 mmol/mol) than deeper sites (661A, 6.3 mmol/mol), and high latitude North Atlantic sites (552A, 610A, 607) have higher Mg/Ca ratios than low latitude (658A: 9.8 mmol/mol, 659A: 7.7 mmol/mol, 661A: 6.3 mmol/mol) and Southern Ocean (704: 8.0 mmol/mol) sites. Converting Mg/Ca ratios into estimated temperatures using the calibration of Dwyer et al. (1995) [Dwyer, G.S., Cronin, T.M., Baker, P.A., Raymo, M.E., Buzas, J.S., Corre??ge, T., 1995. North Atlantic deepwater temperature change during late Pliocene and late Quaternary climatic cycles. Science 270, 1347-1351] suggests that mean middle Pliocene bottom water temperatures at the study sites in the deep Atlantic were about the same as modern temperatures. However, brief pulses of elevated BWT occurred several times between 3.29 and 2.97 Ma in both the North and South Atlantic Ocean suggesting short-term changes in deep ocean circulation.

Marine Micropaleontology

Population ecology and shell chemistry of a phytal ostracode species (Loxoconcha matagordensis) in the Chesapeake Bay watershed

Population ecology and shell chemistry were studied in the phytal ostracode Loxoconcha matagordensis (Swain 1955) collected from Zostera marina seagrass beds in the Chesapeake Bay to provide seasonal constraints on shell secretion time for paleothermometry. Population density and age structure were defined by two main breeding cycles that occurred between 01 to 15 June and 02 to 16 August 2001. The time interval between breeding cycles was ???2 months and total juvenile standing crop increased almost three-fold between the first and second breeding cycles. Dark brown over-wintered adults comprised the majority of the population between March and April 2001, while newly secreted translucent adults were predominant between June and September. Seasonal shell Mg/Ca and Sr/Ca ratios were positively correlated with water temperature at both sites, with the strongest correlations occurring between June and September from newly secreted shells at Dameron Marsh. Old, dark brown shells contained 10% to 23% and 1% to 6% less Mg/Ca and Sr/Ca, respectively, than new shells. Because a fossil assemblage of L. matagordensis will contain ???30% old shells (dark-brown), these results suggest that fossil Mg/Ca ratios yield an integrated late spring to summer temperature signal. Shell Mg/Ca and Sr/Ca ratios of specimens of L. matagordensis collected from living Zostera were positively correlated, suggesting that temperature may influence both elemental ratios. Mg/Ca and Sr/Ca ratios of fossil shells of the related species Loxoconcha sp. A obtained from four sediment cores were also studied and exhibited a weaker correlation between the two elemental ratios. ?? 2004 Elsevier B.V. All rights reserved.

Marine Micropaleontology

Climate variability from the Florida Bay sedimentary record: Possible teleconnections to ENSO, PNA and CNP

We analyzed decadal and interannual climate variability in South Florida since 1880 using geochemical and faunal paleosalinity indicators from isotopically dated sediment cores at Russell Bank in Florida Bay (FB). Using the relative abundance of 2 ostracode species and the Mg/Ca ratios in Loxoconcha matagordensis shells to reconstruct paleosalinity, we found evidence for cyclic oscillations in the salinity of central FB. During this time salinity fluctuated from as low as ~18 parts per thousand (ppt) to as high as ~57 ppt. Time series analyses suggest, in addition to a 5.6 yr Mg/Ca based salinity periodicity, there are 3 other modes of variability in paleosalinity indicators: 6-7, 8-9, and 13-14 yr periods which occur in all paleo-proxies. To search for factors that might cause salinity to vary in FB, we compared the Russell Bank paleosalinity record to South Florida winter rainfall, the Southern Oscillation Index (SOI), winter North Atlantic Oscillation (NAO), and the winter Pacific North American (PNA) index, and a surrogate for the PNA in the winter season, the Central North Pacific (CNP) index. SOI and PNA/CNP appear to be associated with South Florida winter precipitation. Time series analyses of SOI and winter rainfall for the period 1910-1999 suggest ~5, 6-7, 8-9 and 13-14 yr cycles. The 6-7 yr and 13-14 yr cycles correspond to those observed in the faunal and geochemical time series from Russell Bank. The main periods of the CNP index are 5-6 and 13-15 yr, which are similar to those observed in FB paleosalinity. Cross-spectral analyses show that winter rainfall and salinity are coherent at 5.6 yr with a salinity lag of ~1.6 mo. These results suggest that regional rainfall variability influences FB salinity over interannual and decadal timescales and that much of this variability may have its origin in climate variability in the Pacific Ocean/atmosphere system.

Climate Research

Changes in North Atlantic deep-sea temperature during climatic fluctuations of the last 25,000 years based on ostracode Mg/Ca ratios

We reconstructed three time series of last glacial-to-present deep-sea temperature from deep and intermediate water sediment cores from the western North Atlantic using Mg/Ca ratios of benthic ostracode shells. Although the Mg/Ca data show considerable variability (“scatter”) that is common to single-shell chemical analyses, comparisons between cores, between core top shells and modern bottom water temperatures (BWT), and comparison to other paleo-BWT proxies, among other factors, suggest that multiple-shell average Mg/Ca ratios provide reliable estimates of BWT history at these sites. The BWT records show not only glacial-to-interglacial variations but also indicate BWT changes during the deglacial and within the Holocene interglacial stage. At the deeper sites (4500- and 3400-m water depth), BWT decreased during the last glacial maximum (LGM), the late Holocene, and possibly during the Younger Dryas. Maximum deep-sea warming occurred during the latest deglacial and early Holocene, when BWT exceeded modern values by as much as 2.5°C. This warming was apparently most intense around 3000 m, the depth of the modern-day core of North Atlantic deep water (NADW). The BWT variations at the deeper water sites are consistent with changes in thermohaline circulation: warmer BWT signifies enhanced NADW influence relative to Antarctic bottom water (AABW). Thus maximum NADW production and associated heat flux likely occurred during the early Holocene and decreased abruptly around 6500 years B.P., a finding that is largely consistent with paleonutrient studies in the deep North Atlantic. BWT changes in intermediate waters (1000-m water depth) of the subtropical gyre roughly parallel the deep BWT variations including dramatic mid-Holocene cooling of around 4°C. Joint consideration of the Mg/Ca-based BWT estimates and benthic oxygen isotopes suggests that the cooling was accompanied by a decrease in salinity at this site. Subsequently, intermediate waters warmed to modern values that match those of the early Holocene maximum of ∼7°C. Intermediate water BWT changes must also be driven by changes in ocean circulation. These results thus provide independent evidence that supports the hypothesis that deep-ocean circulation is closely linked to climate change over a range of timescales regardless of the mean climate state. More generally, the results further demonstrate the potential of benthic Mg/Ca ratios as a tool for reconstructing past ocean and climate conditions.

Geochemistry, Geophysics, Geosystems

Deep-sea ostracode species diversity: Response to late Quaternary climate change

Late Quaternary ostracode assemblages from the North Atlantic Ocean were studied to establish the effect of climatic changes of the past 210,000 yr (marine oxygen isotope stages 7–1) on deep-sea benthic biodiversity and faunal composition. Two-hundred and twenty five samples from the Chain 82-24 Core 4PC (41°43′N, 32°51′W, 3427 m water depth) on the western Mid-Atlantic Ridge revealed high amplitude fluctuations in ostracode abundance and diversity coincident with orbital and suborbital scale climate oscillations measured by several paleoceanographic proxy records. During the past 210,000 yr, ostracode biodiversity as measured by species number ( S ) and the Shannon–Weaver index, H ( S ), oscillated from H ( S )=0.4 during glacial periods (marine isotope stages 6, 5d, 5b, 4, and 2) to H ( S )=1.1 during interglacial and interstadial periods (stages 7, 5e, 5c, 5a, 3 and 1). A total of 23 diversity peaks could be recognized. Eleven of these signify major periods of high diversity [ H ( S )>0.8, S = 10–21] occurring every 15–20 ka. Twelve were minor peaks which may represent millennial-scale diversity oscillations. The composition of ostracode assemblages varies with Krithe -dominated assemblages characterizing glacial intervals, and Argilloecia–Cytheropteron characterizing deglacials, and trachyleberid genera ( Poseidonamicus , Echinocythereis , Henryhowella , Oxycythereis ) abundant during interglacials. Diversity and faunal composition changes can be matched to independent deep-sea paleoceanographic tracers such as benthic foraminiferal carbon isotopes, Krithe trace elements (Mg/Ca ratios), and to North Atlantic region climate records such as Greenland ice cores. When interpreted in light of ostracode species' ecology, these faunal and diversity patterns provide evidence that deep-sea benthic ecosystems experience significant reorganization in response to climate changes over orbital to millennial timescales.

Marine Micropaleontology

Deep-sea ostracode shell chemistry (Mg:Ca ratios) and late Quaternary Arctic Ocean history

The magnesium:calcium (Mg:Ca) and strontium:calcium (Sr:Ca) ratios were investigated in shells of the benthic ostracode genus Krithe obtained from 64 core-tops from water depths of 73 to 4411 m in the Arctic Ocean and Nordic seas to determine the potential of ostracode shell chemistry for palaeoceanographic study. Shells from the Polar Surface Water (−1 to −1.5°C) had Mg:Ca molar ratios of about 0.006–0.008; shells from Arctic Intermediate Water (+0.3 to +2.0°C) ranged from 0.09 to 0.013. Shells from the abyssal plain and ridges of the Nansen, Amundsen and Makarov basins and the Norwegian and Greenland seas had a wide scatter of Mg:Ca ratios ranging from 0.007 to 0.012 that may signify post-mortem chemical alteration of the shells from Arctic deep-sea environments below about 1000 m water depth. There is a positive correlation ( r 2 = 0.59) between Mg:Ca ratios and bottom-water temperature in Krithe shells from Arctic and Nordic seas from water depths <900 m. Late Quaternary Krithe Mg:Ca ratios were analysed downcore using material from the Gakkel Ridge (water depths 3047 and 3899 m), the Lomonosov Ridge (water depth 1051 m) and the Amundsen Basin (water depth 4226 m) to test the core-top Mg:Ca temperature calibration. Cores from the Gakkel and Lomonosov ridges display a decrease in Mg:Ca ratios during the interval spanning the last glacial/deglacial transition and the Holocene, perhaps related to a decrease in bottom water temperatures or other changes in benthic environments.

Geological Society Special Publication

North Atlantic deepwater temperature change during late pliocene and late quaternary climatic cycles

Variations in the ratio of magnesium to calcium (Mg/Ca) in fossil ostracodes from Deep Sea Drilling Project Site 607 in the deep North Atlantic show that the change in bottom water temperature during late Pliocene 41,000-year obliquity cycles averaged 1.5°C between 3.2 and 2.8 million years ago (Ma) and increased to 2.3°C between 2.8 and 2.3 Ma, coincidentally with the intensification of Northern Hemisphere glaciation. During the last two 100,000-year glacial-to-interglacial climatic cycles of the Quaternary, bottom water temperatures changed by 4.5°C. These results show that glacial deepwater cooling has intensified since 3.2 Ma, most likely as the result of progressively diminished deep-water production in the North Atlantic and of the greater influence of Antarctic bottom water in the North Atlantic during glacial periods. The ostracode Mg/Ca data also allow the direct determination of the temperature component of the benthic foraminiferal oxygen isotope record from Site 607, as well as derivation of a hypothetical sea-level curve for the late Pliocene and late Quaternary. The effects of dissolution on the Mg/Ca ratios of ostracode shells appear to have been minimal.

Science