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Geology topics

G.K. Czamanske

Publications and source records attributed to G.K. Czamanske.

32 records · Page 2Linked to original sources

Geochemistry of intrusive rocks associated with the Latir volcanic field, New Mexico, and contrasts between evolution of plutonic and volcanic rocks

Plutonic rocks associated with the Latir volcanic field comprise three groups: 1) ???25 Ma high-level resurgent plutons composed of monzogranite and silicic metaluminous and peralkaline granite, 2) 23-25 Ma syenogranite, and alkali-feldspar granite intrusions emplaced along the southern caldera margin, and 3) 19-23 Ma granodiorite and granite plutons emplaced south of the caldera. Major-element compositions of both extrusive and intrusive suites in the Latir field are broadly similar; both suites include high-SiO2 rocks with low Ba and Sr, and high Rb, Nb, Th, and U contents. Moreover, both intermediateto siliciccomposition volcanic and plutonic rocks contain abundant accessory sphene and apatite, rich in rare-earth elements (REE), as well as phases in which REE's are essential components. Strong depletion in Y and REE contents, with increasing SiO2 content, in the plutonic rocks indicate a major role for accessory mineral fractionation that is not observed in volcanic rocks of equivalent composition. Considerations of the rheology of granitic magma suggest that accessory-mineral fractionation may occur primarily by filter-pressing evolved magmas from crystal-rich melts. More limited accessory-mineral crystallization and fractionation during evolution of the volcanic magmas may have resulted from markedly lower diffusivities of essential trace elements than major elements. Accessory-mineral fractionation probably becomes most significant at high crystallinities. The contrast in crystallization environments postulated for the extrusive and intrusive rocks may be common to other magmatic systems; the effects are particularly pronounced in highly evolved rocks of the Latir field. High-SiO2 peralkaline porphyry emplaced during resurgence of the Questa caldera represents non-erupted portions of the magma that produced the Amalia Tuff during caldera-forming eruption. The peralkaline porphyry continues compositional and mineralogical trends found in the tuff. Amphibole, mica, and sphene compositions suggest that the peralkaline magma evolved from metaluminous magma. Extensive feldspar fractionation occurred during evolution of the peralkaline magmas, but additional alkali and iron enrichment was likely a result of high halogen fluxes from crystallizing plutons and basaltic magmas at depth. ?? 1989 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Selective chemical dissolution of sulfides: An evaluation of six methods applicable to assaying sulfide-bound nickel

Six analytical techniques for the selective chemical dissolution of sulfides are compared with the purpose of defining the best method for accurately determining the concentration of sulfide-bound nickel. Synthesized sulfide phases of known elemental content, mixed with well-analyzed silicates, were used to determine the relative and absolute efficiency, based on Ni and Mg recovery, of the techniques. Tested leach-methods purported to dissolve sulfide from silicate phases include: brominated water, brominated water-carbon tetrachloride, nitric-hydrochloric acid, hydrogen peroxide-ammonium citrate, bromine-methanol and hydrogen peroxide-ascorbic acid. Only the hydrogen peroxide-ammonium citrate method did not prove adequate in dissolving the sulfide phases. The remaining five methods dissolved the sulfide phases, but the indicated amount of attack on the silicate portion ranged from 3% to 100%. The bromine-methanol method is recommended for assaying sulfide-Ni deposits when Ni is also present in silicate phases. ?? 1986.

Chemical Geology↗

Origin and evolution of the alkalic ultramafic rocks in the Coyote Peak diatreme, Humboldt County, California

Instrumental-neutron-activation analyses are reported for two uncontaminated rocks, a phlogopite-rich clot, and two contaminated rocks from the Coyote Peak diatreme, northwestern California. These data, combined with Nd, Sr, and Pb isotopic evidence, have been modeled to a multi-stage evolution for the uncontaminated rocks. Fertile mantle material (refractory elements 2.5× chondritic abundances; Rb / Sr = 0.029 by weight) was depleted about 900 m.y. ago by congruent melting and removal of ~4% basaltic liquid; this depleted residue provided the source rock from which the Coyote Peak magma was ultimately derived. About 66 m.y. ago, the depleted mantle residue was incongruently melted in the presence of H 2 O and CO 2 at a total pressure > 26 kb to yield ~0.5% of a Si-poor, Ca-rich melt. This melt then metasomatized depleted garnet-free harzburgite in the upper mantle at about 26 kb to produce a rock similar to phlogopite-bearing wehrlite. About 29 m.y. ago, this rock was subjected to an increase in pressure to >26 kb and incongruently melted to give ~0.5% of a second-stage melt resembling olivine melilitite in composition. Enroute to the surface, about 28% olivine and 2% titanomagnetite were lost from the highly fluid melt. Coarse-grained phlogopite-rich clots in the uncontaminated rocks apparently crystallized from a latestage liquid derived from the uncontaminated melt. Contaminated rocks appear to be the result of partial assimilation of, and dilution by, ~14% Franciscan graywacke country rock. The diatreme was emplaced near a converging plate margin where young hot oceanic mantle and crust of the Juan de Fuca plate was probably subducting obliquely beneath a thin lip of the North American plate. The unusual chemistry of the rocks may be the result of this complex tectonic setting which could also have included local strike-slip and extensional environments within the two plates pierced by the diatreme.

Geochimica et Cosmochimica Acta↗

Preliminary mineralogic, fluid inclusion, and stable isotope study of the Mahd adh Dhahab gold mine, Kingdom of Saudi Arabia

The Mahd adh Dhahab mine, located about 280 km northeast of Jiddah, Kingdom of Saudi Arabia, has yielded more than 2 million ounces of gold from periodic production during the past 3,000 years. A new orebody on the southern side of the ancient workings, known as the South orebody, is being developed by Gold Fields-Mahd adh Dhahab Limited. A suite of samples was collected from the newly exposed orebody for preliminary mineralogic, stable isotope, fluid inclusion, and geochemical studies. The Mahd adh Dhahab deposit is in the carapace of a Proterozoic epizonal rhyolite stock that domed pyroclastic and metasedimentary rocks of the Proterozoic Halaban group. Ore of gold, silver, copper, zinc, tellurium, and lead is associated with north-trending, steeply dipping quartz veins in a zone 1,000 m long and 400 m wide. The veins include an assemblage of quartz-chlorite-pyrite-hematite-chalcopyrite-sphalerite-precious metals, which is similar to the mineral assemblage at the epithermal deposit at Creede, Colorado. The primary ore contains abundant chalcopyrite, sphalerite, and pyrite in addition to a complex precious metal assemblage. Gold and silver occur principally as minute grains of telluride minerals disseminated in quartz-chlorite-hematite and as inclusions in chalcopyrite and sphalerite. Telluride minerals include petzite, hessite, and sylvanite. Free gold is present but not abundant. All of the vein-quartz samples contained abundant, minute inclusions of both low-density, vapor-rich fluids and liquid-rich fluids. Primary fluid inclusions yielded homogenization temperatures of from 110? to 238? C. Preliminary light-stable isotope studies of the sulfide minerals and quartz showed that all of the d34S values are between 1.2 and 6.3 per mil, which is a typical range for hydrothermal sulfide minerals that derive their sulfur from an igneous source. The data-suggest that the sulfide sulfur isotope geochemistry was controlled by exchange with la large sulfur isotope reservoir at depth. The d18O values of all stages of vein quartz in the South orebody range between 8.5 and 11.1 per mil. This range is similar to that for quartz from the North orebody and indicates that the hydrothermal system consisted of dominantly exchanged meteoric water, which was uniform in temperature and d18O content throughout the area during the entire period of mineralization. Lead isotope analyses of two galena samples indicate that the lead in the South orebody is less radiogenic than that from the North orebody and confirm that the lead was derived from oceanic crust approximately 700 Ma ago.

Open-File Report↗

Orickite and coyoteite, two new sulfide minerals from Coyote Peak, Humboldt County, California.

Minute quantities of orickite and coyoteite occur with rare alkali iron sulphides in a mafic alkalic diatreme near Orick, Humboldt County. Orickite, NaxKyCu0.95Fe1.06zH2O (x,y < 0.03, z < 0.5), is hexagonal, a 3.695, c 6.16 A, D 4.212 g/cm3, Z = 4. The strongest XRD reflections are 3.08(100), 3.20(90), 2.84(60), 1.73(55), 1.583(30) A. The mineral is brass yellow, opaque, weakly pleochroic, but strongly anisotropic (greyish brown to greyish blue) in reflected light. Orickite is compositionally near to Fe-rich chalcopyrite, but it may be related to synthetic chalcogenides with a distorted wurtzite-(2H) structure. Coyoteite, NaFe3S5.2H2O, is triclinic, P1 or P1, a 7.409(8), b 9.881(6), c 6.441(3) A, alpha 100o25(3)', beta 104o37(5)', gamma 81o29(5)', D 2.879 g/cm3, Z = 2; strongest XRD reflections are 5.12(100), 7.13(90), 3.028(80), 3.080(70), 9.6(60), 5.60(60) A. Coyoteite is black, opaque, weakly pleochroic (pale brownish grey) and strongly anisotropic (grey to dull golden orange) in reflected light. It is unstable under normal atmospheric conditions. -J.A.Z.

American Mineralogist↗

Taeniolite, an uncommon lithium-mica from Coyote Peak, Humboldt County, California.

Taeniolite has been found in a late pegmatitic clot in a mafic alkalic diatreme at Coyote Peak; associated species are natrolite, pectolite, aegirine, barytolamprophyllite, rasvumite and sphalerite. The taeniolite is green-brown with sp. gr. (meas.) 2.85(1) and H. 31/2. Optically it is biaxial (-) with alpha 1.541(2), beta = gamma 1.570(2), 2V approx 0o and moderate pleochroism with gamma = beta reddish-brown, alpha pale greenish brown. Single-crystal precession photographs show it to be of the 1M type, with a 5.254(2), b 9.110(4), c 10.187(2) A, beta 99.85(4)o and V = 480.4(1) A3. Combined microprobe and ion probe analyses gave SiO2 53.5, Al2O3 3.00, TiO2 1.06, FeO 3.35, MnO 0.21, MgO 18.3, Li2O 2.4, K2O 11.3, Na2O 0.27, F 6.3 = 99.69; SrO and BaO are both <0.04 wt.%; B, Be, Ca and Cl were not detected. Assuming (F + OH) = 2 and assigning 1.30 wt.% H2O gives 409(K1.01Na0.04)(Al0.01Ti0.06Fe2+0.20Mn0.01Mg1.92Li0.68)(Si3.76Al0.24)O10- (F1.40OH0.60).-G.W.R.

Mineralogical Record↗

Age measurements of potassium-bearing sulfide minerals by the 40Ar/39Ar technique

K-Ar ages have been determined for sulfide minerals for the first time. The occurrence of adequate amounts of potassium-bearing sulfides with ideal compositions K 3 Fe 10 S 14 (∼10 wt.% K) and KFe 2 S 3 (∼16 wt.% K) in samples from a mafic alkalic diatreme at Coyote Peak, California, prompted an attempt to date these materials. K 3 Fe 10 S 14 , a massive mineral with conchoidal fracture, gives an age of 29.4 ± 0.5m.y.( 40 Ar/ 39 Ar) , indistinguishable from the 28.3 ± 0.4m.y.( 40 Ar/ 39 Ar) and 30.2 ± 1.0m.y. 8 (conventional K-Ar) ages obtained for associated phlogopite (8.7 wt.% K). KFe 2 S 3 , a bladed, fibrous sulfide, gives a younger age, 26.5 ± 0.5m.y.( 40 Ar/ 39 Ar) , presumably owing to Ar loss.

Earth and Planetary Science Letters↗

An investigation of the critical liquid-vapor properties of dilute KCl solutions

The three parameters that define the critical point, temperature, pressure, and volume have been experimentally determined by means of filling studies in a platinum-lined system for five KCl solutions ranging from 0.006 to 0.568 m . The platinum-lined vessels were used to overcome the problems with corrosion experienced by earlier workers. The critical temperature ( t c ), pressure ( P c ), and volume ( V c ) were found to fit the equations t c = 374.14 &#xA0; + &#xA0; 16.602 m &#xA0; + &#xA0; 41.740 m&#xA0; &#x00B1; 0.5 &#x2218; C P c = 220.9 &#xA0; + &#xA0; 135.164 m&#xA0; + &#xA0; 41.173 m 2 &#xA0; &#x00B1; &#xA0; 0.5 b a r s V c = 3.155 &#xA0; &#x2212; &#xA0; 1.373 m &#xA0; + &#xA0; 0.507 m&#xA0; &#x00B1; &#xA0; 0.008 c m 3 &#x2212; g &#x2212; 1 "> t c = 374.14 + 16.602 m −−√ + 41.740 m ± 0.5 ∘ C P c = 220.9 + 135.164 m + 41.173 m 2 ± 0.5 b a r s V c = 3.155 − 1.373 m −−√ + 0.507 m ± 0.008 c m 3 − g − 1 tc=374.14 + 16.602m + 41.740m ±0.5∘CPc=220.9 + 135.164m + 41.173m2 ± 0.5barsVc=3.155 − 1.373m + 0.507m ± 0.008cm3−g−1 from infinite dilution to 1.0 m .

Journal of Solution Chemistry↗

Zoned Cr, Fe-spinel from the La Perouse layered gabbro, Fairweather Range, Alaska

Zoned spinel of unusual composition and morphology has been found in massive pyrrhotite-chalcopyrite-pent-landite ore from the La Perouse layered gabbro intrusion in the Fairweather Range, southeastern Alaska. The spinel grains show continuous zoning from cores with up to 53 wt.% Cr 2 O 3 to rims with less than 11 wt.% Cr 2 O 3 . Their composition is exceptional because they contain less than 0.32 wt.% MgO and less than 0.10 wt.% Al 2 O 3 and TiO 2 . Also notable are the concentrations of MnO and V 2 O 3 , which reach 4.73 and 4.50 wt.%, respectively, in the cores. The spinel is thought to have crystallized at low oxygen fugacity and at temperatures above 900°C, directly from a sulfide melt that separated by immiscibility from the gabbroic parental magma.

Earth and Planetary Science Letters↗

Titanium dioxide in pyroclastic layers from volcanoes in the Cascade Range

Rapid determinations of titanium dioxide have been made by x-ray emission techniques to evaluate the potentiality of using the TiO 2 content of samples for checking field correlations and assisting in identification of pyroclastic units from Cascade volcanoes. Preliminary data suggest that the two most widespread units have characteristic ranges of TiO 2 content and that other, less extensive layers have ranges which, though characteristic, often overlap the ranges of the more widespread layers. Relative to fresh samples, weathered samples from B and C soil horizons are enriched in TiO 2 .

Cascade Range↗

Neutron activation analysis of fluid inclusions for copper, manganese, and zinc

Microgram quantities of copper, manganese, and zinc, corresponding to concentrations greater than 100 parts per million, were found in milligram quantities of primary inclusion fluid extracted from samples of quartz and fluorite from two types of ore deposits. The results indicate that neutron activation is a useful analytical method for studying the content of heavy metal in fluid inclusions.

Science↗