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G. Ambats

Publications and source records attributed to G. Ambats.

5 recordsLinked to original sources

Geochemistry of water at Cajon Pass, California: Preliminary results

Samples of water and associated gases were collected from the Cajon Pass well using downhole samplers, and from the pipe stands at the completion of drill stem tests. The fluids were recovered from fracture systems in granitic rocks from two uncased test intervals located at 1,829 to 1,905 m and 1,829 to 2,115 m. Results of chemical analysis indicate major differences in the composition of water from different fracture systems. Water from one fracture system in the first test interval has a salinity of 2,150 mg/L dissolved solids and is relatively high in Cl, Ca and Fe, but low in HCO 3 and SO 4 ; water salinity from a second fracture system is only 950 mg/L and is dominated by Na, HCO 3 and SO 4 . Most of the water from the second interval likely originated from one fracture system; it is alkaline, low in HCO 3 , has a salinity of 1,150 mg/L, and is a NaSO 4 type water characteristic of pore water in the granitic rocks of the area. The differences in water composition indicate different evolutionary paths and isolation of water within relatively proximal fracture systems.

Geophysical Research Letters↗

Mantle fluids in the San Andreas fault system, California

Fluids associated with the San Andreas and companion faults n central and south-central California have high 3He/4He ratios. The lack of correlation between helium isotopes and fluid chemistry or local geology requires that fluids enter the fault system from the mantle. Mantle fluids passing through the ductile lower crust must enter the brittle fault zone at or near lithostatic pressures; estimates of fluid flux based on helium isotopes suggest that they may thus contribute directly to fault-weakening high-fluid pressures at seismogenic depths.

Science↗

Removal of selenium from contaminated agricultural drainage water by nanofiltration membranes

Seleniferous agricultural drainage wastewater has become a new major source of pollution in the world. In the USA, large areas of farmland in 17 western states, generate contaminated salinized drainage with Se concentrations much higher than 5 ??g/l, the US Environmental Protection Agency water-quality criterion for the protection of aquatic life; Se values locally reach 4200 ??g/l in western San Joaquin Valley, California. Wetland habitats receiving this drainage have generally shown Se toxicosis in aquatic birds causing high rates of embryonic deformity and mortality, or have indicated potential ecological damage. Results of our laboratory flow experiments indicate that nanofiltration, the latest membrane separation technology, can selectively remove > 95% of Se and other multivalent anions from > 90% of highly contaminated water from the San Joaquin Valley, California. Such membranes yield greater water output and require lower pressures and less pretreatment, and therefore, are more cost effective than traditional reverse osmosis membranes. Nanofiltration membranes offer a potential breakthrough for the management of Se contaminated wastes not only from agricultural drainage, but from other sources also.

Applied Geochemistry↗

Generation of aliphatic acid anions and carbon dioxide by hydrous pyrolysis of crude oils

Two crude oils with relatively high (0.60 wt%) and low (0.18 wt%) oxygen contents were heated in the presence of water in gold-plated reactors at 300??C for 2348 h. The high-oxygen oil was also heated at 200??C for 5711 h. The compositions of aqueous organic acid anions of the oils and of the headspace gases were monitored inn order to investigate the distribution of organic acids that can be generated from liquid petroleum. The oil with higher oxygen content generated about five times as much organic anions as the other oil. The dominant organic anions produced were acetate, propionate and butyrate. Small amounts of formate, succinate, methyl succinate and oxalate were also produced. The dominant oxygen-containing product was CO2, as has been observed in similar studies on the hydrous pyrolysis of kerogen. These results indicate that a significant portion (10-30%) of organic acid anions reported i be generated by thermal alteration of oils in reservoir rocks. The bulk of organic acid anions present in formation waters, however, is most likely generated by thermal alteration of kerogen in source rocks. Kerogen is more abundant than oil in sedimentary basins and the relative yields of organic acid anions reported from the hydrous pyrolysis of kerogen are much higher than the yields obtained for the two oils. ?? 1993.

Applied Geochemistry↗