Geology topics

Francisco E. Apen

Publications and source records attributed to Francisco E. Apen.

3 recordsLinked to original sources

USGS2025

RioM-1: A new calcite reference material for U-Pb LA-ICP-MS geochronology

Determining absolute ages of carbonate diagenesis, faulting, fossil formation, speleothem growth, carbonate-hosted hydrocarbon deposits, vein mineralisation and hydrothermal alteration has become increasingly accessible through LA-ICP-MS U-Pb dating of calcite, complementing traditional isotope dilution methods still applicable to certain materials (e.g., speleothems via micro-drilling). However, well-calibrated reference materials for LA-ICP-MS calcite geochronology remain scarce. Here, we characterise the Rio Maior calcite, designated ‘RioM-1’, as a potential reference material for U-Pb dating by LA-ICP-MS. Fragments (0.1 to 1 cm 3 ) from a single scalenohedral crystal were analysed by ID-TIMS (U-Pb), LA-ICP-MS (U-Pb and 87 Sr/ 86 Sr), and SIMS (O isotopes). RioM-1 displays high U mass fraction and low, though variable, proportions of common Pb. Combined ID-TIMS analyses from two independent laboratories yielded a Tera-Wasserburg lower intercept date of 63.93 ± 0.11 Ma (2 s , MSWD = 1.3, n = 16). LA-ICP-MS U-Pb data from three independent laboratories are concordant with the TIMS age, producing a pooled date of 64.10 ± 0.12/1.2 Ma (2 s , MSWD = 7.7, n = 708) and an initial 207 Pb/ 206 Pb ratio of 0.85 ± 0.01. Other calcite reference materials, when normalised to RioM-1, yielded dates within uncertainty of their published values. SIMS measurements returned a mean 18 O/ 16 O of 0.002044450 ± 181 (1 s ) and δ 18 O SMOW of 19.57 ± 0.92‰ (1 s ), while LA-ICP-MS strontium isotope measurement yielded a mean 87 Sr/ 86 Sr of 0.708177 ± 9 (2 s ).

Geostandards and Geoanalytical Research↗

USGS2021

The paleogeography of Laurentia in its early years: New constraints from the Paleoproterozoic East-Central Minnesota batholith

The ca . 1.83 Ga Trans-Hudson orogeny resulted from collision of an upper plate consisting of the Hearne, Rae, and Slave provinces with a lower plate consisting of the Superior province. While the geologic record of ca . 1.83 Ga peak metamorphism within the orogen suggests that these provinces were a single amalgamated craton from this time onward, a lack of paleomagnetic poles from the Superior province following Trans-Hudson orogenesis has made this coherency difficult to test. We develop a high-quality paleomagnetic pole for northeast-trending diabase dikes of the post-Penokean orogen East-Central Minnesota Batholith (pole longitude: 265.8°; pole latitude: 20.4°; A 95 : 4.5°; K: 45.6 N: 23) whose age we constrain to be 1,779.1 ± 2.3 Ma (95% CI) with new U-Pb dates. Demagnetization and low-temperature magnetometry experiments establish dike remanence be held by low-Ti titanomagnetite. Thermochronology data constrain the intrusions to have cooled below magnetite blocking temperatures upon initial emplacement with a mild subsequent thermal history within the stable craton. The similarity of this new Superior province pole with poles from the Slave and Rae provinces establishes the coherency of Laurentia following Trans-Hudson orogenesis. This consistency supports interpretations that older discrepant 2.22–1.87 Ga pole positions between the provinces are the result of differential motion through mobile-lid plate tectonics. The new pole supports the northern Europe and North America connection between the Laurentia and Fennoscandia cratons. The pole can be used to jointly reconstruct these cratons ca . 1,780 Ma strengthening the paleogeographic position of these major constituents of the hypothesized late Paleoproterozoic supercontinent Nuna.

Minnesota↗

USGS2020

Four-dimensional thermal evolution of the East African Orogen: Accessory phase petrochronology of crustal profiles through the Tanzanian Craton and Mozambique Belt, northeastern Tanzania

U–Pb petrochronology of deep crustal xenoliths and outcrops across northeastern Tanzania track the thermal evolution of the Mozambique Belt and Tanzanian Craton following the Neoproterozoic East African Orogeny (EAO) and subsequent Neogene rifting. At the craton margin, the upper–middle crust record thermal quiescence since the Archean (2.8–2.5 Ga zircon, rutile, and apatite in granite and amphibolite xenoliths). The lower crust of the craton documents thermal pulses associated with Neoarchean ultra-high temperature metamorphism (ca. 2.64 Ga, > 900 °C zircon), the EAO (600–500 Ma rutile), and fluid influx during rifting (< 5 Ma apatite). Rutile in garnet granulite xenoliths exhibits partial Pb loss related to slow cooling of the lower crust after the EAO and suggests residence at 500–600 °C prior to entrainment. In contrast to the craton, the entire crust of the Mozambique Belt underwent differential cooling following the EAO. Both the upper and middle crust record metamorphism from 640 to 560 Ma (zircon, monazite, and titanite) and rapid exhumation at 510–440 Ma (rutile and apatite). Lower crustal xenoliths contain Archean zircon, but near-zero age rutile and apatite, indicating residence > 650 °C (above Pb closure of rutile and apatite) at the time of eruption. Zoned titanite records growth during cooling of the lower crust at 550 Ma, followed by fluid influx during slow cooling and exhumation (0.1–1 °C/Myr after 450 Ma). Permissible lower-crustal temperatures for the craton and orogen suggest variable mantle heat flow through the crust and reflect differences in mantle lithosphere thickness rather than advective heating from rifting.

Contributions to Mineralogy and Petrology↗