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Floyd Gray

Publications and source records attributed to Floyd Gray.

At least 19 recordsLinked to original sources

“Leaky weirs” capture alluvial deposition and enhance seasonal mountain-front recharge in dryland streams

“Leaky weirs” are rock structures installed in dryland streams, which are anchored into exposed bedrock, loosely cemented, and designed to allow water to slowly pass through. They are being tested at a ranch in southeastern Arizona, USA, to restore and conserve the historic range and desert wetlands. Data are collected to assess how leaky weirs impact surface water, subsurface water, and groundwater recharge—including stream discharge, timing, and depth of infiltration, and groundwater elevations. Three adjacent watersheds, two with outlets just below leaky weirs and one with leaky weirs farther upstream, were instrumented with water-level loggers, wildlife cameras, and crest stage instruments with temperature sensors in the soil. As most groundwater recharge is assumed to be focused along the mountain fronts in this region, mountain-block recharge is also evaluated to differentiate between the two using isotope analyses. Finally, a single, late-season flood event is scrutinized to consider the leaky weir effect on all monitored components in the water budget. Results indicated groundwater flow is primarily from the mountains to the east via older, regional mountain-block recharge. However, the development of shallow alluvial aquifers is supported by the leaky weirs, that slow flows, capture permeable sediments, and allow infiltration, thus enhancing mountain-front recharge. In turn, these new pockets of water help support the restoration of historic wetlands. Sediment accumulates where leaky weirs are installed, reducing flashy peak flows, and resulting in a series of infiltration ponds along the channel that support vegetation during growing seasons and recharge the shallow aquifer during non-growing seasons.

Arizona↗

Geologic map and hydrogeologic investigations of the upper Santa Cruz River basin, southern Arizona

This report includes an updated geologic map and cross sections of the upper Santa Cruz River basin, southern Arizona. The map and cross sections describe the geometry, thickness, and structure of the Miocene to Holocene units which form the main aquifers in the basin. The report also includes results of new hydrogeologic studies including (1) mapping and defining depth to bedrock based on geophysical data in the map area to better define the geometry and structure of the basin aquifers, (2) describing newly recognized hydrologically significant faults in the Peck Canyon and Sopori Wash areas, and (3) evaluating groundwater sources and hydrogeology of the Potrero Creek wetlands.

Arizona↗

Microbial endophytes and compost improve plant growth in two contrasting types of hard rock mining waste

The re-vegetation of mining wastes with native plants is a comparatively low-cost solution for mine reclamation. However, re-vegetation fails when extreme pH values, low organic matter, or high concentrations of phytotoxic elements inhibit plant establishment and growth. Our aim was to determine whether the combined addition of municipal waste compost and diazotrophic endophytes (i.e., microorganisms that fix atmospheric N 2 and live within plants) could improve plant growth, organic matter accumulation, and phytostabilization of trace element contaminants in two types of hard rock mine waste. We grew a widespread native perennial grass, Bouteloua curtipendula , for one month in alkaline waste rock (porphyry copper mine) and tailings (Ag-Pb-Au mine, amended with dolomite) sourced from southeastern Arizona, United States. B. curtipendula tolerated elevated concentrations of multiple phytotoxic trace elements in the tailings (Mn, Pb, Zn), stabilizing them in roots without foliar translocation. Adding compost and endophyte seed coats improved plant growth, microbial biomass, and organic matter accumulation despite stark differences in the geochemical and physical characteristics of the mining wastes. The widespread grass B. curtipendula is a potential candidate for re-vegetating mine wastes when seeded with soil additives to increase pH and with microbial and organic amendments to increase plant growth.

International Journal of Phytoremediation↗

Preliminary geologic map of the Greater Antilles and the Virgin Islands

Introduction This geologic map of the Greater Antilles and the Virgin Islands is a compilation of information from the literature, integrated to provide a seamless geologic map of the region. The geology shown on sheet 1 covers Cuba, the island of Hispaniola, which includes Haiti and the Dominican Republic, Jamaica, the Cayman Islands, Puerto Rico, and the U.S. and British Virgin Islands. A second more detailed sheet shows the geology of Puerto Rico and the Virgin Islands. The map units shown here are integrated across the islands of the Greater Antilles and the Virgin Islands. The Greater Antilles and the Virgin Islands, although they appear to reflect the character of a magmatic arc, actually represent multiple, distinct geologic features. Only in Cuba are there unquestioned Jurassic-age, and perhaps older, rocks present. On the islands of Hispaniola (Haiti and the Dominican Republic) and Puerto Rico, metamorphic assemblages contain rocks that may be of Jurassic age. Ophiolite assemblages that may include rocks of Jurassic age are present in Cuba, the Dominican Republic, Haiti, and Puerto Rico. Metamorphic rocks of Cretaceous age are more widespread, present in Cuba, Hispaniola, and the U.S. and British Virgin Islands. Cretaceous plutonic rocks are present in Cuba and Puerto Rico, as well as in the Dominican Republic (in the Cordillera Central and in the eastern part of the country). Gabbro and trondhjemite of inferred Early Cretaceous age are present in the U.S. Virgin Islands. Cretaceous volcanic rocks are widespread in Cuba, Hispaniola, Puerto Rico, and the Virgin Islands; they are of variable age and do not appear to reflect a single arc system. Cretaceous volcanic rocks are also found in Jamaica, in inliers on the eastern part of the island. Eocene volcanic rocks are prominent in southern Cuba, Haiti, eastern Jamaica, Puerto Rico, and the Virgin Islands. Volcanic rocks possibly as young as early Miocene are present in the southern Dominican Republic; the youngest volcanic rocks in the region are the Low Layton Lavas of Jamaica of late Miocene age and alkali basalt of Quaternary age on Hispaniola. Carbonate rocks are an important component of the sedimentary section in the Greater Antilles, which is as old as Jurassic in Cuba and as young as Holocene in many areas. In Cuba, Early Cretaceous sedimentary rocks tend to be dominantly carbonates; volcanic clasts and debris are not present until the Late Cretaceous in Cuba, as well as in Jamaica and Puerto Rico. In contrast, Early Cretaceous volcaniclastic sedimentary rocks are common in the Virgin Islands. Olistostrome deposits are commonly described in latest Cretaceous and Eocene rocks; in the Paleocene and the early Eocene, these deposits are commonly associated with mélange units. Volcanic debris and tuff are common in sedimentary rocks of Paleocene and Eocene age, typically associated with carbonate rocks. Sedimentary rocks that postdate the Eocene either are dominantly carbonates or are mixed clastic and carbonate rocks in which the clastic component reflects erosion of earlier units, including older carbonate rocks. Rocks that contain lignite, which are only present in Cuba and on Hispaniola, generally are of Miocene age.

Greater Antilles, Hispaniola, Puerto Rico, Virgin ↗

Mapa metalogenético de América Central y El Caribe

La Asociación de Servicios Geológicos y Mineros de Iberoamérica (ASGMI), bajo los auspicios de la Comisión de la Carta Geológica del Mundo (CCGM) preparó la primera versión del Mapa Metalogénico de América Central y el Caribe. La coordinación general estuvo a cargo del Servicio Geológico Minero Argentino (SEGEMAR), con tres coordinaciones regionales: América Central a cargo del Servicio Geológico Mexicano (SGM), las islas del Caribe a cargo del Servicio Geológico Nacional de la República Dominicana y el norte de América del Sur a cargo del Servicio Geológico Colombiano. Participaron además los Servicios Geológicos, Direcciones de Minería u organismos equivalentes de los países involucrados, que designaron Coordinadores Nacionales. El proyecto fue presentado y aprobado en ocasión de la Asamblea de ASGMI realizada en La Habana (Cuba) en 2017. Posteriormente fue presentado ante la Comisión de la Carta Geológica del Mundo (CCGM) en París en 2018. Los objetivos, criterios metodológicos y cronograma de trabajo fueron así establecidos. En los años 2018 y 2019 se realizaron dos reuniones de los participantes, una en Santo Domingo, República Dominicana, y otra en Tegucigalpa, Honduras. Los avances del mapa fueron presentados durante la Reunión Santo Domingo de 2018 y en ocasión del XV Simposio IAGOD, celebrado en Salta (Argentina) ese mismo año. El mapa fue generado digitalmente a partir del Mapa Estructural del Caribe (Bouysse et al., 2020), provisto por la Comisión de la Carta Geológica del Mundo, realizándose una actualización de la información geológica, a partir de la bibliografía citada en el texto. Los polígonos fueron reclasificados y reagrupados en orden a definir unidades tectonoestratigráficas y mejor reflejar la metalogénesis de la región.

Servicio Geológico Minero Argentino, Anales↗

Geologic framework and hydrogeology of the Rio Rico and Nogales 7.5’ quadrangles, upper Santa Cruz Basin, Arizona, with three-dimensional hydrogeologic model

Rapid population growth and declining annual recharge to aquifers in the upper Santa Cruz Basin area of southern Arizona, have increased the demand for additional groundwater resources. This demand is predicted to escalate in the future because of higher temperatures, longer droughts, less aquifer recharge, and decreased river and stream base flow. We conducted geologic studies to help evaluate and better understand groundwater resources in the basin. Results of these studies are presented in this report, which summarizes the basin geologic framework and hydrogeology, and presents a threedimensional (3D) hydrogeologic model for the Rio Rico and Nogales 7.5′ quadrangles. Three major hydrogeologic units are displayed in the 3D model; a lower basement confining unit, consisting of Jurassic, Cretaceous, and Tertiary (Paleocene and Oligocene) rocks; a middle unit composed entirely of the Miocene Nogales Formation; and an upper unit consisting of late Miocene to Holocene surficial deposits. The Nogales Formation and the late Miocene to Holocene sediments are the main aquifers in the upper Santa Cruz Basin. The 3D model integrates the hydrogeologic units and faults to define the geometry, structure, and thickness of the aquifer system that provides water to Nogales and surrounding communities of southernmost Arizona. The report includes an EarthVision 3D Viewer, consisting of software enabling the user to view data interactively in 3D space to help explain the internal complexities of the basin geometry, structure, stratigraphy, and hydrology. The 3D model is a synthesis of geologic data from geologic maps, cross sections, and lithologic descriptions and interpretations; and geophysical data including gravity, magnetic data, and airborne electromagnetic data.

Arizona↗

Assessment of geochemical and hydrologic conditions near Old Yuma Mine in Saguaro National Park, Arizona, 2014–17

The Old Yuma Mine is an abandoned copper, lead, zinc, silver, and gold mine located within the boundaries of Saguaro National Park, Tucson Mountain District, Arizona. This study analyzed the geochemistry of sediments associated with the Old Yuma Mine and assessed hydrologic and geochemical conditions of groundwater to evaluate the area surrounding the Old Yuma Mine. The purpose of the study was to establish the geochemical signature of material associated with the Old Yuma Mine and to compare it with background material and groundwater in the area. Few groundwater samples exceeded the U.S. Environmental Protection Agency (EPA) drinking water standards. Concentrations of several elements were elevated in the waste rock and mine tailings compared with concentrations in sediments collected in background areas. A subset of 15 sediment samples was leached to simulate precipitation interacting with the solid material. Analysis of leachate samples compared to groundwater samples suggests that groundwater samples collected in this study are distinct from leachate samples associated with mining related material. Results suggest that at this time groundwater samples collected during this investigation are not influenced by elements leached from Old Yuma Mine materials.

Arizona↗

Probabilistic mineral resource assessment of U.S. Territories of the Caribbean Basin and adjacent areas: Progress report

The U.S. Geological Survey is partnering with the IberoAmerican Association of Geological and Mining Surveys (ASGMI) to conduct an assessment of undiscovered metallic and non-metallic resources in the Greater Antilles region. The assessment plans to provide science-based information on the geologic availability of these resources for development, land-use planning, and decision making. The USGS anticipates contributing information generated for the Greater Antilles assessment project to the concurrent ASGMI project “Metallogenetic Map of Central America and the Caribbean”. ASGMI, in turn, anticipates contributing expertise on the metallogeny of the region to the USGS assessment project. For this purpose, the USGS plans to conduct a workshop on assessment methodology to support ASGMI’s participation in the probabilistic estimation of undiscovered deposits. Both projects stand to benefit significantly from this collaborative effort.

US Virgin Islands, Puerto Rico↗

Preliminary assessment of porphyry copper deposits in the Sierra Maestra, Cuba

The U.S. Geological Survey’s “three-step” form of mineral-resource assessment was used to obtain a preliminary estimate of copper resources in undiscovered porphyry deposits of the Paleogene Sierra Maestra Arc. Results of this preliminary assessment suggest that a mean of 3.2 undiscovered deposits are likely present. This estimate is comparable to results from an independently-derived porphyry deposit density model, which points to 3.9 undiscovered deposits. Monte Carlo simulation results further show that the mean estimate of undiscovered copper resources in this porphyry copper tract is in the order of 12 million metric tons. Notwithstanding having been a relatively short-lived (20-25 Ma) magmatic event, the Sierra Maestra Arc was a particularly favorable environment for the formation of porphyry copper deposits.

Conference Paper↗

Hydrogeologic investigations of the Miocene Nogales Formation in the Nogales Area, Upper Santa Cruz Basin, Arizona

Hydrogeologic investigations were conducted to evaluate the groundwater resource potential for the Miocene Nogales Formation in the Nogales area, southern Arizona. Results indicate that parts of the formation may provide new, deeper sources of groundwater for the area. Geologic mapping determined the hydrogeologic framework of the formation by defining lithologic, mineralogic, and stratigraphic characteristics; identifying potential aquifers and confining units; and mapping faults and fractures which likely influence groundwater flow. Geophysical modeling was used to determine the basin geometry and thickness of the Nogales Formation and younger alluvial aquifers and to identify target areas (deep subbasins) which may prove to be productive aquifers. Volcaniclastic sandstone samples from the formation were analyzed for porosity, bulk density, saturated hydraulic conductivity, and fabric. Effective porosity ranges from 16 to 42 percent, bulk density from 1.6 to 2.47 grams per cubic centimeter, and saturated hydraulic conductivity (SHC) from 4 to 57 centimeters per day (4.9×10 -5 to 6.7×10 -4 centimeters per second). Thin sections show that sandstone framework grains consist of quartz, feldspar, biotite, hornblende, pumice, volcanic glass, and opaque minerals. The matrix in most samples consists of pumice fragments, and some contain predominantly silt and clay. Samples with a mostly silt and clay matrix have lower porosity and SHC compared to samples with mostly pumice, which have higher and wider ranges of porosity and SHC. Pore space in the Nogales Formation sediments includes moldic, intercrystalline, and fracture porosity. Some intercrystalline pore space is partially filled with calcite cement. About one third of the samples contain fractures, which correspond to fractures noted in outcrops in all members of the formation. Scanning electron microscope (SEM) and x-ray diffraction (XRD) analyses indicate that most of the samples contained the zeolite clinoptilolite and mixed-layer clay. X-ray diffraction analyses verified clinoptilolite as the only zeolite in Nogales Formation samples; they also verified the presence of smectite and illite clay and some kaolinite. Samples which contain greater amounts of clinoptilolite and lesser amounts of smectite have high porosity and SHC in narrow ranges. However, samples with abundant smectite and lesser amounts of clinoptilolite span the entire ranges of porosity and SHC for the formation. All members of the Nogales Formation are fractured and faulted as a result of Tertiary Basin and Range extensional deformation, which was broadly contemporaneous with deposition of the formation. These structures may have significant influence on groundwater flow in the upper Santa Cruz basin because, although many of the sediments in the formation have characteristics indicating they may be productive aquifers based only on porous-media flow, fracturing in these sediments may further enhance permeability and groundwater flow in these basin-fill aquifers by orders of magnitude.

Arizona↗

Geologic map of the Rio Rico and Nogales 7.5’ quadrangles, Santa Cruz County, Arizona

The Rio Rico and Nogales (Arizona) 1:24,000-scale quadrangles are located in the Basin and Range Province of southern Arizona, and the southern edge of the map is the international border with Sonora, Mexico. The major urban area is Nogales, a bi-national city known as “the gateway to Mexico.” Rocks exposed in the map area range in age from Jurassic through Quaternary. Major physiographic, geologic, and hydrologic features in the map area include the southern San Cayetano Mountains, Grosvenor Hills, and Sonoita Creek in the northern part, and Mount Benedict and the Mount Benedict horst block in the southcentral part. The horst block is bounded by the Santa Cruz River on the east and Nogales Wash on the west. The objectives of our mapping were to define the geologic framework for the Nogales area and the upper Santa Cruz basin to support ongoing multidisciplinary projects. This new work will improve understanding of the Nogales Formation to more fully assess its groundwater resource potential. We significantly revised the Miocene Nogales Formation based on geologic mapping combined with new geochronologic, geophysical, and petrographic studies.

Arizona↗

San Pedro River Aquifer Binational Report

The United States and Mexico share waters in a number of hydrological basins and aquifers that cross the international boundary. Both countries recognize that, in a region of scarce water resources and expanding populations, a greater scientific understanding of these aquifer systems would be beneficial. In light of this, the Mexican and U.S. Principal Engineers of the International Boundary and Water Commission (IBWC) signed the “Joint Report of the Principal Engineers Regarding the Joint Cooperative Process United States-Mexico for the Transboundary Aquifer Assessment Program" on August 19, 2009 (IBWC-CILA, 2009). This IBWC “Joint Report” serves as the framework for U.S.-Mexico coordination and dialogue to implement transboundary aquifer studies. The document clarifies several details about the program such as background, roles, responsibilities, funding, relevance of the international water treaties, and the use of information collected or compiled as part of the program. In the document, it was agreed by the parties involved, which included the IBWC, the Mexican National Water Commission (CONAGUA), the U.S. Geological Survey (USGS), and the Universities of Arizona and Sonora, to study two priority binational aquifers, one in the San Pedro River basin and the other in the Santa Cruz River basin. This report focuses on the Binational San Pedro Basin (BSPB). Reasons for the focus on and interest in this aquifer include the fact that it is shared by the two countries, that the San Pedro River has an elevated ecological value because of the riparian ecosystem that it sustains, and that water resources are needed to sustain the river, existing communities, and continued development. This study describes the aquifer’s characteristics in its binational context; however, most of the scientific work has been undertaken for many years by each country without full knowledge of the conditions on the other side of the border. The general objective of this study is to use new and existing research to define the general hydrologic framework of the Binational San Pedro Aquifer (BSPA), to gather hydrogeological and other relevant data in preparation for future work such as an updated groundwater conceptual model and budget and to establish the basis for a binational numerical model. The specific objectives are as follows: Understand the current state of knowledge with respect to climate, geology, soils, land cover, land use, and hydrology of the aquifer in its binational context; Compile and create a database of scientific information from both countries; Identify data gaps and identify what data would be necessary to update, in a subsequent phase, the hydrologic model of the aquifer system, including surface- and groundwater interactions on a binational level. The BSPB is one of the most studied basins in the region, and a database of publications has been compiled as part of this project. Previous studies include topics that range from geophysics and hydrogeology to biology and ecosystem services. The economic drivers on each side of the border are quite different. In the Arizona 4 portion of the basin military and tourism dominate while in the Sonoran portion, mining is the most important industry. Water management is also different in the two countries. In Mexico, primary authority for management of water resources devolves from the federal government. In the United States, primary authority rests with the states except in cases of interstate surface waters. Binational waters are not currently jointly managed by the two countries except in cases where treaties have been negotiated such as for the Rio Grande and Colorado Rivers. Thus, there is currently no binational coordination or treaty governing the management of groundwater.

Report↗

Hydrologic response of streams restored with check dams in the Chiricahua Mountains, Arizona

In this study, hydrological processes are evaluated to determine impacts of stream restoration in the West Turkey Creek, Chiricahua Mountains, southeast Arizona, during a summer-monsoon season (June–October of 2013). A paired-watershed approach was used to analyze the effectiveness of check dams to mitigate high flows and impact long-term maintenance of hydrologic function. One watershed had been extensively altered by the installation of numerous small check dams over the past 30 years, and the other was untreated (control). We modified and installed a new stream-gauging mechanism developed for remote areas, to compare the water balance and calculate rainfall–runoff ratios. Results show that even 30 years after installation, most of the check dams were still functional. The watershed treated with check dams has a lower runoff response to precipitation compared with the untreated, most notably in measurements of peak flow. Concerns that downstream flows would be reduced in the treated watershed, due to storage of water behind upstream check dams, were not realized; instead, flow volumes were actually higher overall in the treated stream, even though peak flows were dampened. We surmise that check dams are a useful management tool for reducing flow velocities associated with erosion and degradation and posit they can increase baseflow in aridlands.

Arizona↗

Porphyry copper assessment of Central America and the Caribbean Basin

Mineral resource assessments provide a synthesis of available information about distributions of mineral deposits in the Earth’s crust. The U.S. Geological Survey prepared a probabilistic mineral resource assessment of undiscovered resources in porphyry copper deposits in Central America and the Caribbean Basin in collaboration with geoscientists from academia and the minerals industry. The purpose of the study was to (1) delineate permissive areas (tracts) for undiscovered porphyry copper deposits within 1 kilometer of the surface at a scale of 1:1,000,000; (2) provide a database of known porphyry copper deposits and significant prospects; (3) estimate numbers of undiscovered deposits within the permissive tracts; and (4) provide probabilistic estimates of amounts of copper, molybdenum, gold, and silver that could be contained in undiscovered deposits. The assessment was done using a three-part mineral resource assessment based on established mineral deposit models. Permissive tracts were delineated based primarily on distributions of mapped igneous rocks related to magmatic arcs that formed in tectonic settings associated with convergent plate margins. Five permissive tracts were delineated: the Early Cretaceous through Eocene Santiago tract, the Late Cretaceous through Oligocene Chortis tract, the Paleocene through Oligocene Darién tract, the Miocene and Pliocene Cocos tract, and the Eocene to Holocene Lesser Antilles tract. These tracts range in size from about 3,000 to about 204,000 square kilometers. Probabilistic estimates of numbers of undiscovered deposits were made for all tracts. To estimate the number of undiscovered porphyry copper deposits, data on known mineral deposits, prospects, and occurrences were considered along with mapped alteration zones, local stream-sediment geochemistry, exploration history, descriptive deposit models, and grade and tonnage models. Most porphyry copper exploration in Central America and the Caribbean Basin has focused on Panama and on the exposed Cretaceous to Eocene central Cordilleran arc that extends from Cuba and Jamaica through Haiti and the Dominican Republic to Puerto Rico and the Virgin Islands. Interest in gold has prompted exploration of historical precious-metal prospects and small mines, some of which may represent high-sulfidation epithermal systems or skarns overlying, or adjacent to, porphyry copper systems. This assessment estimated a total mean of 37 undiscovered porphyry copper deposits within the assessed permissive tracts in Central America and the Caribbean Basin. This represents more than five times the seven known deposits. Predicted mean (arithmetic) resources that could be associated with these undiscovered deposits are about 130 million metric tons of copper and about 5,200 metric tons of gold, as well as byproduct molybdenum and silver. The reported identified resources for the seven known deposits total about 39 million metric tons of copper and about 930 metric tons of gold. The assessment area is estimated to contain nearly four times as much copper and six times as much gold in undiscovered porphyry copper deposits as has been identified to date.

Scientific Investigations Report↗

The Borderlands and climate change: Chapter 10 in United States-Mexican Borderlands: Facing tomorrow's challenges through USGS science

The prediction of global climate change in response to both natural forces and human activity is one of the defining issues of our times. The unprecedented observational capacity of modern earth-orbiting satellites coupled with the development of robust computational representations (models) of the Earth’s weather and climate systems afford us the opportunity to observe and investigate how these systems work now, how they have worked in the past, and how they will work in the future when forced in specific ways. In the most recent report on global climate change by the Intergovernmental Panel on Climate Change (IPCC; Solomon and others, 2007), analyses using multiple climate models support recent observations that the Earth’s climate is changing in response to a combination of natural and human-induced causes. These changes will be significant in the United States–Mexican border region, where the process of climate change affects all of the Borderlands challenge themes discussed in the preceding chapters. The dual possibilities of both significantly-changed climate and increasing variability in climate make it challenging to take full measure of the potential effects because the Borderlands already experience a high degree of interannual variability and climatological extremes.

United States-Mexico Borderlands↗

Geochemistry of soils from the San Rafael Valley, Santa Cruz County, Arizona

This study was conducted to determine whether surficial geochemical methods can be used to identify subsurface mineraldeposits covered by alluvium derived from surrounding areas. The geochemical investigation focused on an anomalous geo-physical magnetic high located in the San Rafael Valley in Santa Cruz County, Arizona. The magnetic high, inferred to be asso-ciated with a buried granite intrusion, occurs beneath Quaternary alluvial and terrace deposits. Soil samples were collected at a depth of 10 to 30 centimeters below land surface along transects that traverse the inferred granite. The samples were analyzed by inductively coupled plasma-mass spectrometry and by the partial-leach Mobile Metal Ion™ method. Principal component and factor analyses showed a strong correlation between the soils and source rocks hosting base-metal replacement deposits in the Harshaw and Patagonia Mining Districts. Factor analysis also indicated areas of high metal concentrations associated with the Meadow Valley Flat. Although no definitive geochemical signature was identified for the inferred granite, concentrations otungsten and iron in the surrounding area were slightly elevated.

Arizona↗

Nickel-cobalt laterites: A deposit model

Nickel-cobalt (Ni-Co) laterite deposits are supergene enrichments of Ni±Co that form from intense chemical and mechanical weathering of ultramafic parent rocks. These regolith deposits typically form within 26 degrees of the equator, although there are a few exceptions. They form in active continental margins and stable cratonic settings. It takes as little as one million years for a laterite profile to develop. Three subtypes of Ni-Co laterite deposits are classified according to the dominant Ni-bearing mineralogy, which include hydrous magnesium (Mg)-silicate, smectite, and oxide. These minerals form in weathering horizons that begin with the unweathered protolith at the base, saprolite next, a smectite transition zone only in profiles where drainage is very poor, followed by limonite, and then capped with ferricrete at the top. The saprolite contains Ni-rich hydrous Mg-silicates, the Ni-rich clays occur in the transition horizon, and Ni-rich goethite occurs in the limonite. Although these subtypes of deposits are the more widely used terms for classification of Ni-Co laterite deposits, most deposits have economic concentrations of Ni in more than one horizon. Because of their complex mineralogy and heterogeneous concentrations, mining of these metallurgically complex deposits can be challenging. Deposits range in size from 2.5 to about 400 million tonnes, with Ni and Co grades of 0.66–2.4 percent (median 1.3) and 0.01–0.15 percent (median 0.08), respectively. Modern techniques of ore delineation and mineralogical identification are being developed to aid in streamlining the Ni-Co laterite mining process, and low-temperature and low-pressure ore processing techniques are being tested that will treat the entire weathered profile. There is evidence that the production of Ni and Co from laterites is more energy intensive than that of sulfide ores, reflecting the environmental impact of producing a Ni-Co laterite deposit. Tailings may include high levels of magnesium, sulfate, and manganese and have the potential to be physically unstable.

Scientific Investigations Report↗