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F.T. Dulong

Publications and source records attributed to F.T. Dulong.

14 recordsLinked to original sources
USGS1998

Influence of an igneous intrusion on the inorganic geochemistry of a bituminous coal from Pitkin County, Colorado

Although the effects of igneous dikes on the organic matter in coal have been observed at many localities there is virtually no information on the effects of the intrusions of the inorganic constituents in the coal. Such a study may help to elucidate the behavior of trace elements during in situ gasification of coal and may provide insights into the resources potential for coal and coke affected by the intrusion. To determine the effects of an igneous intrusion on the inorganic chemistry of a coal we used a series of 11 samples of coal and natural coke that had been collected at intervals from 3 to 106 cm from a dike that intruded the bituminous Dutch Creek coal in Pitkin, CO. The samples were chemically analyzed for 66 elements. SEM-EDX and X-ray diffraction analysis were performed on selected samples. Volatile elements such as F, Cl, Hg, and Se are not depleted in the samples (coke and coal) nearest the dike that were exposed to the highest temperatures. Their presence in these samples is likely due to secondary enrichment following volatilization of the elements inherent in the coal. Equilibration with ground water may account for the uniform distribution of Na, B, and Cl. High concentrations of Ca, Mg, Fe, Mn, Sr, and CO2 in the coke region are attributed to the reaction of CO and CO2 generated during the coking of the coal with fluids from the intrusion, resulting in the precipitation of carbonates. Similarly, precipitation of sulfide minerals in the coke zone may account for the relatively high concentrations of Ag, Hg, Cu, Zn, and Fe. Most elements are concentrated at the juncture of the fluidized coke and the thermally metamorphosed coal. Many of the elements enriched in this region (for example, Ga, Ge, Mo, Rb, U, La, Ce, Al, K, and Si) may have been adsorbed on either the clays or the organic matter or on both.Although the effects of igneous dikes on the organic matter in coal have been observed at many localities there is virtually no information on the effects of the intrusions on the inorganic constituents in the coal. Such a study may help to elucidate the behavior of trace elements during in situ gasification of coal and may provide insights into the resource potential of coal and coke affected by the intrusion. To determine the effects of an igneous intrusion on the inorganic chemistry of a coal we used a series of 11 samples of coal and natural coke that had been collected at intervals from 3 to 106 cm from a dike that intruded the bituminous Dutch Creek coal in Pitkin, CO. The samples were chemically analyzed for 66 elements. SEM-EDX and X-ray diffraction analysis were performed on selected samples. Volatile elements such as F, Cl, Hg, and Se are not depleted in the samples (coke and coal) nearest the dike that were exposed to the highest temperatures. Their presence in these samples is likely due to secondary enrichment following volatilization of the elements inherent in the coal. Equilibration with ground water may account for the uniform distribution of Na, B, and Cl. High concentrations of Ca, Mg, Fe, Mn, Sr, and CO2 in the coke region are attributed to the reaction of CO and CO2 generated during the coking of the coal with fluids from the intrusion, resulting in the precipitation of carbonates. Similarly, precipitation of sulfide minerals in the coke zone may account for the relatively high concentrations of Ag, Hg, Cu, Zn, and Fe. Most elements are concentrated at the juncture of the fluidized coke and the thermally metamorphosed coal. Many of the elements enriched in this region (for example, Ga, Ge, Mo, Rb, U, La, Ce, Al, K, and Si) may have been adsorbed on either the clays or the organic matter or on both.

International Journal of Coal Geology↗
USGS1991

Effects of detrital influx in the Pennsylvanian Upper Freeport peat swamp

Quartz cathodoluminescence properties and mineralogy of three sets of samples and vegetal and/ or miospore data from two sets of samples from the Upper Freeport coal bed, west-central Pennsylvania, show that detrital influence from a penecontemporaneous channel is limited to an area less than three km from the channel. The sets of samples examined include localities of the coal bed where (1) the coal is thin, split by partings, and near a penecontemporaneous fluvial channel, (2) the coal is relatively thick and located approximately three km from the channel, and (3) the coal is thick and located approximately 12 km from the channel. Samples from locality 1 (nearest the channel) have relatively high-ash yields (low-temperature ash average = 27.3% on a pyrite- and calcite-free basis) and high proportions of quartz and clay minerals. The quartz is primarily detrital, as determined by cathodoluminescent properties, and the ratio of kaolinite to illite is low. In addition, most of the plant remains and miospores indicate peat-forming plants that required low nutrient levels for growth. In contrast, samples from localities 2 and 3, from the more interior parts of the bed, contained predominantly authigenic quartz grains nd yielded low-temperature ash values of less than 14% on a pyrite- and calcite-free basis. The low-temperature ash contains low concentrations of quartz and clay minerals and the ratio of kaolinite to illite is relatively high. Although intact core was not available for paleobotanical analyses, another core collected within 1 km from locality 3 contained plant types interpreted to have required high nutrient levels for growth. These data indicate that mineral formation is dominated by authigenic processes in interior parts of the coal body. Some of the authigenic quartz may have been derived from herbaceous ferns as indicated by patterns in the palynological and paleobotanical data. In contrast, detrital processes appeared to be limited to in areas directly adjacent to the penecontemporaneous channel where the coal bed is high in ash, split by mineral-rich partings, and of little or no economic value.

International Journal of Coal Geology↗
USGS1990

Palynological assessment of organic tissues and metallic minerals in the Jerritt Canyon gold deposit, Nevada (U.S.A.)

Organic tissues and metallic minerals were studied in acid residues and thin section of the Jerritt Canyon (Bell Mine) gold deposit. The purpose was to compare gold-bearing and gold-free rocks, characterize their differences, and assess a possible relationship between the invisible gold and the organic tissues in these early Paleozoic, carbonaceous limestones, dolomites, and claystones. The most visually abundant acid-resistant component in the sooty, unoxidized, gold-bearing rocks is a black, rectangular, carbon-bearing mineraloid. In X-ray diffraction, it is poorly crystalline; in nuclear magnetic resonance, it is a highly aromatized structure. The increase in gold content that accompanies the increase in content of this protographite suggests that it may be the major gold-bearing compound. Less abundant among the acid-resistant residues are uncarbonized organic tissues that are typical of marine settings. The tissues not in the vicinity of silicified veins are medium to dark brown. The dominant tissues are the amorphous remains of algae and their zooplankton predators. These uncarbonized indigenous tissues indicate that temperatures were lower than those determined by geochemical and fluid inclusion methods. The presence of different kinds of carbon-bearing compounds could account for the discrepancy between the palynological and geochemical data. The uncarbonized organic tissues comprise such a small percentage of these rocks that they could be easily missed by bulk analytical methods. The presence of uncarbonized tissues helps to constrain the duration of the high heat flow that is shown by the fluid inclusion data. The presence of mixed signals suggests that the protographite may be the product of chemical rather than thermal reactions.

Nevada↗
USGS1989

Chemistry and origin of minor and trace elements in vitrinite concentrates from a rank series from the eastern United States, England, and Australia

A rank series consisting of twelve vitrinite concentrates and companion whole-coal samples from mined coal beds in the eastern United States, England, and Australia were analyzed for C, H, N, O, ash, and 47 trace and minor elements by standard elemental, instrumental neutron activation analysis (INAA), and direct-current-arc spectrographic (DCAS) techniques. The reflectance of vitrinite, atomic H:C and O:C, and ash-free carbon data were used to determine ranks that range from high-volatile C bituminous coal to meta-anthracite. A van Krevelen (atomic H:C vs. O:C) diagram of the vitrinite concentrates shows a smooth curve having its lowest point at H:C = 0.18 and O:C = 0.01. This improves the van Krevelen diagram by the addition of our vitrinite concentrate from meta-anthracite from the Narragansett basin of New England. Boron content (400–450 ppm) in two Illinois basin vitrinite concentrates was about an order of magnitude higher than B contents in other concentrates analyzed. We attribute this to marine origin or hydrothermal activity. The alkaline-earth elements Ca, Mg and Ba (DCAS) have higher concentrations in our vitrinite concentrates from bituminous coals of the Appalachian basin, than they do in vitrinite concentrates from the marine-roofed bituminous coals of the Illinois basin; therefore, a nonmarine origin for these alkaline-earth elements is postulated for the Appalachian basin coals. An ion-exchange mechanism due to high concentrations of these elements as ions in diagenetic water, but probably not recent ground water, may be responsible for the relatively high values of these elements in Appalachian concentrates. Higher concentrations of Ni and Cr in one of the English vitrinite concentrates and of Zr in the Australian concentrate probably indicate organic association and detrital influence, respectively.

International Journal of Coal Geology↗
USGS1987

Oxidation of pyrite in an anoxic atmosphere

Pyrite (FeS 2 ) inclusions in coal, when heated in an oxygen deficient atmosphere (approximately 1% oxygen), become coated with magnetic Fe 3 O 4 due to oxidation. Most of the FeS 2 can thus be removed from the coal by magnetic separation to reduce the sulphur concentration. The oxidation products have been studied in greater detail by measuring the SO 2 and O 2 in the effluent gas during the heating process and by performing further magnetic measurements. At 582 K, the pyrite surface was oxidized to FeSO 4 . Significant oxidation of FeSO 4 and FeS 2 to Fe 3 O 4 was observed starting at 677 K. At about 681 K, the Fe 3 O 4 is further oxidized to α-Fe 2 O 3 . At 681 K, under isothermal conditions, the oxidation is impeded by the α-Fe 2 O 3 formed on the surfaces of the grains. If the temperature is rapidly increased, the oxygen penetrates the α-Fe 2 O 3 veneer to the FeS 2 core of the pyrite grains and oxidizes essentially the whole pyrite mass to Fe 3 O 4 before α-Fe 2 O 3 can be formed.

Fuel↗
USGS1987

PROTON MICROPROBE ANALYSIS OF TRACE-ELEMENT VARIATIONS IN VITRINITES IN THE SAME AND DIFFERENT COAL BEDS.

The PIXE (proton-induced X-ray emission) microprobe can be used for nondestructive, in-situ analyses of areas as small as those analyzed by the electron microprobe, and has a sensitivity of detection as much as two orders of magnitude better than the electron microprobe. Preliminary studies demonstrated that PIXE provides a capability for quantitative determination of elemental concentrations in individual coal maceral grains with a detection limit of 1-10 ppm for most elements analyzed. Encouraged by the earlier results, we carried out the analyses reported below to examine trace element variations laterally (over a km range) as well as vertically (cm to m) in the I and J coal beds in the Upper Cretaceous Ferron Sandstone Member of the Mancos Shale in central Utah, and to compare the data with the data from two samples of eastern coals of Pennsylvanian age.

Scanning Micros↗
USGS1983

RECENT DEVELOPMENTS ON THE ORIGIN OF MINERAL MATTER IN COAL.

This study attempts to quantify some of the various origins of mineral matter. Data developed for the Upper Freeport coal bed indicates that mineral matter other than pyrite and calcite is primarily derived from the vegetal matter that ultimately became coal. Cathodoluminesence was used to verify that the quartz in the Upper Freeport coal is dominantly authigenic and not detrital in origin. Sulfur variability in coal beds of the central Appalachian Basin was investigated stratagraphically.

Conference Paper↗
USGS1983

SUBMICROSCOPIC ( less than 1 mu m) MINERAL CONTENTS OF VITRINITES IN SELECTED BITUMINOUS COAL BEDS.

An important aspect of the petrographic description of coal is the characterization of coal quality, including chemical attributes. For geologic investigations, data on the concentrations, distribution, and modes of occurrence of minor and trace elements provide a basis for reconstructing the probable geochemical environment of the swamp material that was converted into peat, and the geochemical conditions that prevailed during and subsequent to coalification. We have been using electron (EPMA) and proton (PIXE) microprobe analytical methods to obtain data on the chemical characteristics of specific coal constituents in their original associations within coal samples. The present study is aimed at evaluation of the nature of mineral occurrences and heterogeneous elemental concentrations within vitrinites. Vitrinites are usually the most abundant, and therefore most important, maceral group in bituminous coal. 8 refs.

Conference Paper↗
USGS1982

Geologic factors that control mineral matter in coal

Elements other than organically derived and bound C, H, N, O, and S constitute mineral matter in coal. Mineral matter may consist of discrete minerals such as calcite, quartz, clays, and pyrite, and/or organic compounds that contain organically bonded elements such as Ca and CI. Processes that may affect the association and content of mineral matter are operable from the initial peat-forming stage to the time of utilization of the coal. However, the objective of this paper is to discuss some of the various geologic processes that may influence content and associations in unmined coal.

Book chapter↗